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1 energy and chemistry, involve the making or breaking of a bond between carbon, nitrogen and oxygen.
2 r different catalytic motifs to catalyze the breaking of a carbon-carbon bond in a nonnatural substra
3 response to a local perturbation such as the breaking of a chemical bond or the absorption of a photo
4 chemical and physical processes such as the breaking of a chemical bond or the vibrational motion of
8 tners either (i) through thermally activated breaking of a hydrogen bond that creates a dangling hydr
12 s involving hydrocarbons (homolytic C-C bond breaking of alkanes, progressive insertions of triplet m
13 ence of the plastic phase which involved the breaking of all hydrogen bonds, and modeling of small cl
15 transitions that the compounds induced: (i) breaking of an interaction between Tyr-223 and Arg-187 i
16 We find that the barrier crossing involves breaking of an interhelical hydrogen bond between helix5
18 single walker, which require the making and breaking of As-S bonds, and occur in aqueous solution at
22 he transformation are proposed which require breaking of at least one in six of the covalent bonds th
25 ich could have important implications on the breaking of B cell central tolerance in autoimmunity.
26 the patient-oncologist encounter during the breaking of bad news, comprising essential aspects of th
27 and electronics on the gradual weakening and breaking of bonds was studied by investigating bridgehea
28 etal complexes that result in the making and breaking of C-N, C-O and C-S bonds via fundamental organ
29 imately 0.25 eV and intra-unit cell symmetry breaking of charge distribution in individual alpha-RuCl
30 atic and twist-bend nematic with spontaneous breaking of chiral symmetry is crucially dependent on th
31 emerging as a result of spontaneous symmetry breaking of clock/counterclockwise rotation of self-asse
35 out external concentrations necessitates the breaking of detailed balance and consumption of energy,
40 ress has been made in understanding both the breaking of embryonic L-R symmetry and how the Nodal-Pit
42 emonstrated a strong capability for C-C bond breaking of ethanol than pure Pt and intermetallic Pt/Sn
43 actor exceeds alpha(C), spontaneous symmetry breaking of fraction of cooperators presents itself betw
46 sufficient to observe repeated formation and breaking of helical structure, which we found to occur o
47 on, in an SW-defective (5,5) BNNT results in breaking of hydrogen bonding with neighboring water mole
48 in forced unfolding in TI I27 is largely the breaking of hydrogen bonds and hydrophobic interactions
50 consistent with the view that formation and breaking of hydrogen bonds in such water chains is a lim
51 ich is characterized by first stretching and breaking of hydrogen bonds, followed by deformation of c
53 thelial NF-kappaB activation orchestrate the breaking of inhalational tolerance and allergic antigen
54 ore, our data suggest that the formation and breaking of inter- and intradomain salt bridges control
55 g of FN-III(10) A and B-strands and precedes breaking of inter-strand hydrogen bonds between F and G-
57 and global climate, largely results from the breaking of internal gravity waves--disturbances propaga
61 ch necessarily involves the energy intensive breaking of intramolecular hydrogen bonds, provides a ph
63 rmolecular ion hopping through formation and breaking of ion-associations involving four polymerized
65 tivistic electrons are generated through the breaking of large-amplitude relativistic plasma waves cr
69 , a photon Devil's staircase, induced by the breaking of long-range translation symmetry, can emerge.
71 criterion identifies a new kind of symmetry breaking--of magnetic translations--where nonvanishing c
72 ation of sulfur from the thiol complexes via breaking of mercury-sulfur bonds as in an alkylation rea
73 and acetyl species indeed helps the C-O bond breaking of methoxy species and therefore the direct eth
74 ifically of tau proteins leads to mechanical breaking of microtubules at high strain rates, whereas e
75 nodules to bands may result from a symmetry breaking of mineral dissolution and precipitation trigge
76 edge that pivots to enforce rapid making and breaking of miRNA:target base pairs in the 3' half of th
77 twisting energy, resulting in a spontaneous breaking of mirror symmetry; the chiral twisted state pe
79 rmalities of the myelin sheaths included the breaking of myelin at several locations, a splitting and
80 only by promoting the formation but also the breaking of Nepsilon-(gamma-glutamyl)lysine isopeptides.
81 ecifically, we demonstrate that the symmetry breaking of network connectivity constitutes a timescale
82 resolution permits direct observation of the breaking of nuclear spin degeneracy for the 1S0 and 3P0
83 oses the catalytic loop concertedly with the breaking of one of the two C-O bonds of CO2 and with pro
84 ting that mate change by pair members and/or breaking of pair bonds by unmated individuals is more fr
87 iated killing of endothelial cells indicated breaking of peripheral immune tolerance against this sel
88 single IV dose up to 15 mg/kg, resulting in breaking of peripheral immune tolerance to self-tissues
90 lated electron-hole pair diagrams illustrate breaking of pi-conjugation in three-arm dendrimers due t
91 he ligand is undocked from the binding site, breaking of protein-disaccharide H-bonds takes place in
94 DCvC relies on the reversible formation and breaking of rather strong covalent bonding within molecu
95 essive numbers illustrate why the making and breaking of RBCs is at the heart of iron physiology, pro
96 representing intra-unit-cell nematicity: the breaking of rotational symmetry by the electronic struct
102 h parameters that typically lead to symmetry breaking of signalling states between neighbouring cells
103 d that this barrier is due to the concurrent breaking of six interstrand hydrogen bonds (H-bonds) bet
105 Proteases are enzymes that catalyse the breaking of specific peptide bonds in proteins and polyp
106 d radiative transfer, which reveals that the breaking of spherical symmetry is a critical factor in d
110 e propose that the origin of this gap is the breaking of sublattice symmetry owing to the graphene-su
111 is underscores the importance of spontaneous breaking of symmetries, Fermi surface reconstruction, an
113 nvolves cilia as essential components in the breaking of symmetry, an asymmetric signaling cascade, a
115 ucture and dynamics that take place with the breaking of the Asp-His hydrogen bond in the catalytic t
119 tion, in the absence of enzyme, involves the breaking of the C O bond facilitated by intramolecular p
120 of 1.04 +/- 0.01 was measured, showing that breaking of the C-S bond in the substrate Me-S-CoM is th
122 Unlike in C60, in doped fullerenes, the breaking of the cage spherical symmetry makes super atom
123 ayer atomic registry results in both a local breaking of the carbon sublattice symmetry and a long-ra
125 f Rho primarily proceeds through spontaneous breaking of the covalent linkage between opsin and 11-ci
128 glutamate is due to two motions: Spontaneous breaking of the D1 dimer interface and hyperextension of
129 nsistent with the outward rotation of H6 and breaking of the dark-state Glu134(3.49)-Arg135(3.50)-Glu
130 ation to the In(III) center, and concomitant breaking of the dimer into monomeric porphyrin species,
135 n state, the rate-determining step, involves breaking of the exocyclic P-O bond where a metal-ligated
136 embrane and axoneme alterations, followed by breaking of the flagellar membrane connected to the tryp
138 es trans-cis isomerization, which results in breaking of the H-bond between Glu46 and the chromophore
141 rovides a potential molecular mechanism: the breaking of the hydrogen bond between the side chains of
142 ogresses, we find a sequential weakening and breaking of the hydrogen bonds between the ATP molecule
144 During vertebrate embryo development, the breaking of the initial bilateral symmetry is translated
145 CB2 binding pocket is sufficient to trigger breaking of the intracellular TMH3/6 ionic lock and the
146 ucial step for the complex formation was the breaking of the intramolecular hydrogen bond in urea der
147 rmational switches in beta(2)AR, namely, the breaking of the ionic lock between R131(3.50) at the int
148 odopsin and other class A GPCRs, namely, the breaking of the ionic lock between R135(3.50) at the int
149 typal model, rhodopsin, such as the apparent breaking of the ionic lock that stabilizes the inactive
150 idized state, which results in the transient breaking of the iron-methionine-sulfur bond and sufficie
152 ectedly large flexoelectric response exhibit breaking of the macroscopic centric symmetry through inh
154 p (>C=NH), most likely to MnB, is coupled to breaking of the MnB-(mu-H2O) bond, forming a terminal aq
155 reaction coordinates of the reaction are the breaking of the O-O bond of H2O2 and the formation of th
158 -entry pathway, which involves formation and breaking of the salt bridge between side chains of Arg(8
159 is that this large dipole moment drives the breaking of the salt bridges between the two monomer sub
160 ation of a trigonal intermediate and then by breaking of the scissile bond between the beta- and gamm
163 I copper species that appears results from a breaking of the strong antiferromagnetic coupling of the
164 place as the arrival of MPT(+) triggers the breaking of the strong Fe-H(delta-)...H(delta+)-O dihydr
165 es is "anticorrelated" in the sense that the breaking of the T252-G248 hydrogen bond is concurrent wi
168 hus a macroscopic witness of the progressive breaking of the tetrahedral hydrogen bond network that m
170 changes and cannot be fully accounted for by breaking of the top contact, we argue that the cause is
171 tilted outward at the tip end, leading to a breaking of the trimerous symmetry and distortion at a r
172 -dependent DFT calculations predict that the breaking of the two strong Ru-O bonds and the formation
175 r role except in the case of gold, for which breaking of the weak Au-S bond that tethers the monolaye
178 Conversely, the corresponding sequential breaking of these bonds is driven by rotation of the sha
180 ies and the intrinsic orientational symmetry-breaking of these materials gives rise to a host of intr
181 e failure of conscious access results in the breaking of this chain and a subsequent slow decay of th
187 es, the Kelvin and Yanai modes, owing to the breaking of time-reversal symmetry by Earth's rotation.
189 rength of the deformations, temperature, and breaking of time-reversal symmetry were also investigate
194 To understand the role of T cells in the breaking of tolerance, an anti-DNA site-specific transge
196 Using the analogy of crystals in space, the breaking of translational symmetry in time and the emerg
198 eta-strands A' and G that is preceded by the breaking of two to three hydrogen bonds between strands
199 s, the main transition was identified as the breaking of van der Waals interactions between the acyl
200 ket in a step-wise process involving (i) the breaking of water-mediated hydrogen bonds and van der Wa
201 tailed analysis of DNA stretching shows that breaking of Watson-Crick bonds is not necessary for the
203 metastable configurations that form from the breaking of weak bonds between metals and underlying hig
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