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2 lexity, the Suzuki-Miyaura cross-coupling of brominated 2,1-borazaronaphthalenes has been investigate
4 aracter of the procedure was demonstrated by brominating a diverse set of 19 substrates containing di
7 be stable on both the Br-Ash and commercial brominated AC sorbents, while the bromine leached into t
8 ion of the alkyl-Ni(III) adduct, formed from brominated acids with eight or fewer total carbons, with
9 ce changes and the Hg capture performance of brominated activated carbon (AC) pellets, sulfur-treated
10 bind to the reduced sulfur by the commercial brominated activated carbon, in contrast to mercury bind
13 assume HOBr is the only kinetically relevant brominating agent in solutions of free bromine may be in
14 stants were calculated for reactions of each brominating agent with anisole, 2-bromoanisole, and 4-br
21 , Br(2), BrOCl, and Br(2)O can also serve as brominating agents of the herbicide dimethenamid in solu
22 tal of 107 bromo-organic compounds, 11 other brominating agents, and a few natural bromine sources we
24 mong all known DLCs determined in biosolids, brominated analogs contributed 370% more TEQ than did ch
25 1.5 A resolution, together with that of the brominated analogue d(G(4)(Br)UTTG(4)) at 2.4 A resoluti
27 PE), the occurrence of N-Cl-DCAM and its two brominated analogues (i.e., N-chloro-2,2-bromochloroacet
28 scriminate between chloride and bromide, and brominated analogues were formed alongside chloroform.
30 conditions, we were able to effectively beta-brominate and beta-chlorinate for the first time cyclic
32 s of 13 organophosphate esters (OPEs) and 45 brominated and chlorinated flame retardants (BFRs) were
34 nd allows the room temperature conversion of brominated and chlorinated nucleobases or nucleobase pre
38 W altered the speciation toward formation of brominated and iodinated trihalomethanes (THMs) and brom
40 ) is a commercial flame retardant mixture of brominated and organophosphate compounds applied to poly
44 onist activities of a series of chlorinated, brominated, and mixed bromo/chlorocarbazoles, some of wh
48 ic palladium-catalyzed cycloisomerization of brominated aryl propiolates produces brominated coumarin
51 t BDE-209 may release BDE-99 and other lower brominated BDEs through biotic and abiotic degradation,
52 involved in the dehalogenation of all tested brominated benzenes, including the reductive dehalogenas
53 (HBCDDs), and new types of flame retardants: brominated (BFRs) and organophosphate esters (OPEs).
56 .e., polybrominated diphenyl ethers (PBDEs), brominated biphenyl (BB)-153, and hexabromocyclododecane
58 as the synthetic brominated fire retardants, brominated bisphenol A (BBPA), and polybrominated diphen
59 tal complexes of the NavMs pore with several brominated blocker compounds depict a common antagonist
63 anothermobacter marburgensis and a series of brominated carboxylic acids, with carbon chain lengths o
67 rations were low with a limited formation of brominated (chlorinated) disinfection byproducts (DBPs).
68 dibenzofurans (PCDFs), chlorinated and mixed brominated/chlorinated anthracenes/phenanthrenes, and py
72 cessibility ( approximately 80%) compared to brominated compounds (e.g., PBDEs), and values generally
73 a uniform response factor for bromine across brominated compounds of drastically different chemical s
74 (or number of bromine elements) for 19 other brominated compounds of minor intensity are also provide
76 flame retardants (OPFRs) as well as aromatic brominated compounds such as Firemaster 550 (FM550).
80 ems related to physicochemical properties of brominated compounds, including UV- and temperature-indu
81 the discovery of numerous bioactive natural brominated compounds, such as hydroxylated polybrominate
82 9, and -100) declined 4-10% while the higher brominated congeners (BDE-153 and -154) increased by abo
85 anization recently proposed the inclusion of brominated congeners in addition to chlorinated congener
86 mixtures and by increased fractions of lower brominated congeners relative to higher brominated conge
87 caused greater proportional uptake of higher-brominated congeners such as BDE-154 and -153 compared t
88 ereas BDE-209 decreases with depth, the less-brominated congeners, particularly BDE-47 and BDE-99, in
89 xpected values were observed for the highest brominated congeners, which we attribute to steric hindr
94 rns was applied to identify chlorinated- and brominated-containing substances with more than two halo
99 tablish V-BrPO's role in the biosynthesis of brominated cyclic sesquiterpene structures from marine r
106 tion mass spectrometry revealed 462 distinct brominated DBPs at a relative abundance in the mass spec
108 usly characterized DBPs in addition to novel brominated DBPs, although several hundred compounds rema
109 ecular formulas matched those of other known brominated DBPs, such as dibromomethane, which could be
115 thermal intramolecular C-H insertion of the brominated diazopiperidinylamide are obtained in moderat
118 nd the solid residue proved the formation of brominated dioxins and furans at 300, 400, and 500 degre
119 he exposure of small children (1-3 y old) to brominated diphenyl ether (BDE)-99 may exceed acceptable
126 man dermal absorption of eight mono- to deca-brominated diphenyl ethers (PBDEs) was investigated for
127 2, M9, and M10 generate several congeners of brominated diphenyl ethers and their OH/OCHCH2 substitue
132 e in seawater, and leads to the formation of brominated disinfection byproducts, known to be more tox
133 ngeners, which indicates the need to include brominated DLCs in the exposure and risk assessment of l
134 and MS techniques indicated the formation of brominated-DMSO, MeBr, and HBr as byproducts in this tra
137 ins, and bastadins, as well as the synthetic brominated fire retardants, brominated bisphenol A (BBPA
138 ododecane (HBCD) is a high production volume brominated flame retardant added to building insulation
140 s home to major manufacturing facilities for brominated flame retardant chemicals (BFRs) in the U.S.
143 nated diphenyl ethers (PBDEs) are a class of brominated flame retardant that is distally transported
145 x binding phage-borne peptides to detect the brominated flame retardant, brominated diphenyl ether 47
150 e matrix to estimate serum concentrations of brominated flame retardants (BFRs) in toddlers for biomo
152 as to determine whether prenatal exposure to brominated flame retardants (BFRs) is associated with au
153 The concentrations of 13 currently used brominated flame retardants (BFRs) were analyzed in 16 s
154 anticipated that the demand for alternative brominated flame retardants (BFRs) will grow, but little
155 ants included organophosphate esters (OPEs), brominated flame retardants (BFRs), and Dechlorane-relat
156 the marine atmosphere of several alternative brominated flame retardants (BFRs), Dechlorane Plus (DP)
158 OCPs), polychlorinated biphenyls (PCBs), and brominated flame retardants (BFRs), were measured using
161 centrations of alpha-HBCD and eight emerging brominated flame retardants (EBFRs) in the standard refe
163 olychlorinated biphenyls (PCBs), pesticides, brominated flame retardants [e.g., polybrominated diphen
164 enyl ethers (PBDEs) and selected alternative brominated flame retardants [pentabromoethyl benzene (PB
165 shed methods for studying the degradation of brominated flame retardants are not useful when working
166 the ambient concentrations of pesticides and brominated flame retardants in the Canadian High Arctic
169 ractions with high average concentrations of brominated flame retardants mainly originate from the tr
170 P-A) and hexabromocyclododecanes (HBCDs) are brominated flame retardants that have been found in huma
171 yltin, polycyclic aromatic hydrocarbons, and brominated flame retardants were the major contributors
173 enyls (PCBs), 6 organochlorine pesticides, 8 brominated flame retardants, and 4 perfluoroalkyl substa
174 ty is a common structural feature of several brominated flame retardants, and we have previously repo
175 Rgamma1 activation by 30 common SVOCs (e.g., brominated flame retardants, organophosphates, and phtha
178 , house dust, and cat food were analyzed for brominated flame retardants/natural products (polybromin
181 id (TBBA), a urinary metabolite of the major brominated FM550 component 2-ethylhexyl-2,3,4,5-tetrabro
183 ed diphenyl ether (PBDE) congeners, 19 other brominated FRs, 11 phosphorus FRs (PFRs), 2 Dechlorane-P
186 from a chlorinated site correlated best with brominated haloacetic acid concentrations (Br-HAAs) (r =
187 ted and iodinated trihalomethanes (THMs) and brominated haloacetonitriles (HANs), and dilutions as lo
190 An inner separation layer allows use of a brominated hydrocarbon oil-based fluidic core, demonstra
194 e experiments demonstrated the potential for brominated industrial solid waste from biomass combustio
195 cosystems and promote the formation of toxic brominated-, iodinated-, and nitrogen disinfection bypro
196 on governing mechanisms and that even fully brominated isomers of BFRs are capable of forming PBDD/F
197 sO(4)-catalyzed hydroxylation of an apically brominated lactam, 7-bromo-2-azabicyclo[2.2.1]hept-5-en-
198 the phase problem of diffraction, we used a brominated lipid and performed multiwavelength anomalous
200 ophan on the membrane-binding interface with brominated lipids along with mutagenesis of VP40 to unde
201 bilayers, quenching of pHLIP fluorescence by brominated lipids and acrylamide, and measurements of en
206 imate step in the biosynthesis of the highly brominated marine bacterial product pentabromopseudilin
207 crystal structures of the postsynthetically brominated materials, which show a mechanical contractio
208 Biological activities of these iodinated and brominated meroditerpenes and additional new, related br
209 a diverse mixture of volatile iodinated and brominated metabolites including the natural product cya
210 pyridyl complexes were employed to construct brominated metallo-organic intermediates, followed by a
212 methanethiosulfonate spin label (MTSL) and a brominated MTSL as a function of increasing peptide conc
218 um ion or equivalent in the active site that brominates one face of the terminal olefin of nerolidol.
219 r the simultaneous detection of chlorinated, brominated, or mixed halogen-substituted compounds in a
220 e effects associated with transformations of brominated organic compounds are still poorly explored.
222 n of chlorate, perchlorate, chlorinated, and brominated organics may compromise the quality of the tr
223 presence of bromide due to the formation of brominated oxidant species such as bromochloramine (NHBr
224 catalyzed cross-coupling reaction of various brominated PAHs with cyclohexanone to yield alpha-arylat
227 rved, suggesting a transition to more highly brominated PBDEs is occurring in Great Lakes trout.
228 hat concentrations of mercury (Hg) and lower-brominated PBDEs were often higher in umbilical cord blo
231 rgy to break C-Br bonds of TDBDPB and lesser brominated PBDPBs increased from UV-B or -C to UV-A.
232 s of quenching of tryptophan fluorescence by brominated PC, indicated that the opening of the N-termi
233 ure-activity study to include marine-derived brominated phenol ethers (including a newly discovered t
238 erculosis and used fluorescence quenching by brominated phospholipids to detect the presence of a bin
239 ,3-dihydro-1H-pyrrolo[3,4-b]quinoline with a brominated phthalide to generate a substituted pentacycl
241 PhOBz and BDE-209, and possibly other highly brominated polyphenyl ethers, is of great concern from a
243 were efficiently synthesized by reactions of brominated porphyrin precursors with amines via palladiu
244 ly synthesized from direct reactions of meso-brominated porphyrins with thiols via palladium-mediated
245 or possibly their nonmethoxylated and higher brominated precursors may have been more abundant in die
246 gate the distribution of biologically active brominated precursors to Tyrian purple in the hypobranch
248 razide derivative of helioxanthin 28 and its brominated product 42 exhibited moderately potent activi
251 to UV-B and -C radiation also produced less brominated products, although the rate was much slower a
252 rom commercially available 2-bromophenols or brominated pyridine derivatives bearing different patter
254 alkyl amines are developed using NBS as the brominating reagent and catalytic amount of Cu(II) /phen
259 The mutagenic potencies of samples from a brominated site correlated best (r = 0.82) with the conc
260 .36, with correlations higher for individual brominated species (BDCM, 0.62; DBCM, 0.53; TBM, 0.54) t
261 toxicokinetic properties, the proportion of brominated species (BDCM, DBCM, and TBM) in blood varied
264 surprisingly, higher concentrations of most brominated species were measured in the treatment plant
265 rsystem crossing to the triplet state of the brominated species, as evidenced by the formation of sin
266 ed by eosinophil peroxidase-derived reactive brominating species in the presence of 100 microM NaBr d
267 l ether bond of plasmalogens by the reactive brominating species produced by eosinophil peroxidase an
271 cordingly, it was hypothesized that reactive brominating species, a unique oxidant formed at the site
272 of eosinophil peroxidase-generated reactive brominating species, reactive nitrogen species, or tyros
275 n was not as significant for chlorinated and brominated substances as observed for humid carrier gase
276 port near-tropopause measurements of organic brominated substances found over the tropical Pacific du
277 these MeO-PBDPB congeners are not "emerging" brominated substances, but rather "recently discovered"
278 ated from an early synthetic step in which a brominated tetralone motif was generated in a ring-closi
279 ne oxidation of naturally occurring bromide, brominates the deprotonated DMS(-) anion with a near-dif
280 neck presented by the utilization of certain brominated thiophene units and propose some potential so
281 4 THM in 1 model, chloroform and the sum of brominated THM in 1 model, and a principal-components an
282 1.53 (95% CI: 1.01, 2.32), p-trend=0.16] and brominated THMs [OR=1.98 (95% CI: 1.19, 3.29), p-trend=0
283 In the presence of bromide, the formation of brominated THMs during chloramination can be attributed
286 he highest category of showering/bathing for brominated THMs was 1.43 (95% CI: 0.80, 2.42), p-trend=0
287 s at the 95th percentile for chlorinated and brominated THMs were 1.77 (95% CI: 1.05, 2,.99), p-trend
288 GIS mapping of median THMs levels indicated brominated THMs were most prevalent in coastal areas and
291 valuated maternal exposure to drinking water brominated trihalomethanes (BTHM) in relation to MN freq
292 n bladder cancer and total, chlorinated, and brominated trihalomethanes (THMs) through various exposu
293 In 75% of the homes, we detected TDBPP, or brominated "Tris," which was banned in children's sleepw
295 hlorinated tyrosines and decreased yields of brominated tyrosines following treatments with HOCl and
296 nstrate that a halogen bond formed between a brominated uracil and phosphate oxygen can be engineered
297 ase or myeloperoxidase, which preferentially brominates uracil at plasma concentrations of halide and
298 e and rapid method for the quantification of brominated vegetable oil (BVO) in soft drinks based upon
299 dily alpha-chlorinated with CCl(4) and alpha-brominated with CBrCl3 in KOH-t-BuOH via radical-anion r
300 Accordingly, CH3/SC4H3-Si(111) surfaces were brominated with N-bromosuccinimide, to produce mixed CH3
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