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3 the relatively short lifetime of HFC-1447fz (ca. 8 days) implies that its global warming potential at
4 the substrates and pre-catalyst (NiCl2.6H2O, ca. $9.5/mol) bode well for the immediate widespread ado
6 nsertion caused minimal change at pH 8 but a ca. 50 degrees C drop in the melting temperature (Tm ) w
8 taining one modification (10:15) displayed a ca. DeltaDeltaG degrees of +4 kcal/mol with respect to i
10 its represent a rich source of provitamin A (ca. 124 mug retinol-activity-equivalents/100g pulp, FW).
11 ved organic carbon (DOC) concentration above ca. 250 muM the binding capacity was only 50% of the the
12 isible and IR wavelengths at pressures above ca. 56 GPa, suggesting the imminent closure of its optic
13 phases of particularly rapid C accumulation (ca. 6.6-6.1 and ca. 4.9-3.9 ka BP), potentially resultin
14 e gonads were rich in essential amino acids (ca. 32.1% of total amino acids) with the most predominan
15 for carbon dioxide over nitrogen and adsorbs ca. 3 wt % of CO2 at ambient temperature and pressure.
17 ularly rapid C accumulation (ca. 6.6-6.1 and ca. 4.9-3.9 ka BP), potentially resulting from increased
18 essed at the wildtype Michaelis complex, and ca. 50% is only expressed at the wildtype transition sta
19 stability for 50 charge/discharge cycles and ca. 7h at a discharge current density of 0.2mAcm(-2).
21 ystallization space than a random search and ca. 6 times more than humans and increases the crystalli
23 al of terrestrial organisms at approximately ca. 20 and 6 Ma and corresponding events separating mari
24 assisted sampling of micrometer-sized areas (ca. 11 x 17 mum wide x 2.4 mum deep) from relatively low
25 de and longitude as co-variates explained as ca. 75% of the variability of the contaminant sediment c
26 ibits lattice thermal conductivity as low as ca. 0.5 W/mK near room temperature, owing to rattling dy
30 vation of displaced water libration bands at ca. 730 cm(-1) upon solvent replacement by adsorbed MOP.
31 ontiguous United States, extinction began at ca. 12,900-13,200 BP, and at ca. 12,600-13,900 BP in Sou
34 th 2 equiv of ethylene or t-butylethylene at ca. 25 degrees C to yield Sn2(Ar((i)Pr6))2R2(R = ethyl o
37 -aryldiazenes in preheated diphenyl ether at ca. 150-250 degrees C for 5-25 min affords in most cases
38 itions for these complexes were all found at ca. 420 nm, their emission bands exhibited large Stokes
39 ugh flash vacuum pyrolysis of CF3 S(O)NCO at ca. 1200 K, sulfinyl isocyanate, bearing resonance struc
42 ity (including ignimbrite and mafic rock) at ca. 52-51 Ma corresponds to a sudden decrease in the Ind
44 racterized by a broad (1)H chemical shift at ca. 12-15 ppm that is reported here for the first time.
45 a first-order structural phase transition at ca. 4 GPa similar to previous reports on other Cu(II)-Cl
46 a previously unreported phase transition at ca. 8 GPa and dramatic piezochromism from translucent re
49 30 400 copies per haploid genome, averaging ca. 1900 copies per telomere, and synthesized by telomer
50 ca. 30-150 nm derived from Ni wire backbone (ca. 2 mum in diameter) is directly synthesized on commer
53 ts at 298 K are consistently predicted to be ca. 25 kcal/mol, whereas barriers for 1,5- and 1,6-shift
55 k of regeneration of these populations began ca. 165 ya (around 1850) after major anthropogenic distu
56 t near a critical point (contact angle being ca. 153 degrees ) the bulk thermal resistance has the le
57 on and the onset of the GOE occurred between ca. 2,460 and 2,426 Ma, approximately 100 My earlier tha
61 eir visible absorption and emission bands by ca. 200 nm compared to the unsubstituted parent compound
62 itionally understood to have fully closed by ca. 3.5 million years ago (Ma), and this date has been u
63 nts show that increasing heme E degrees ' by ca. 210 mV results in increases in electron transfer (ET
67 ofossils of aquatic plants are in many cases ca. 2 degrees C warmer in the early Holocene (11,700-7,5
68 zing bimetallic PtCo nanoparticle catalysts (ca. 1.5 nm) highly dispersed in the framework of nitroge
71 naked eye well below sub-ppm concentrations (ca. 30 ppb) with analytical detection limits of 5.4 ppb
72 oximately 800-1300 CE) and wetter conditions ca. 2 ka were caused by changes in the El Nino/Southern
73 ibits ultralow lattice thermal conductivity (ca. 0.18 Wm(-1) K(-1) ) and a high figure of merit of ab
77 e [ca. 661 (597-736) Ma], Corallinophycidae [ca. 579 (543-617) Ma], and the split of Ahnfeltiophycida
79 The algorithm-based search is able to cover ca. 9 times more crystallization space than a random sea
80 rmite species preserved in Early Cretaceous (ca. 100 mya) amber from Myanmar, one described as Krishn
82 14 is highly enriched in the binary culture (ca. 10% genomic reads) and its ungapped 0.95 Mbp genome
87 Local patches of strained material (diameter ca. 5 mum) form interwoven patterns seen in birefringenc
88 ted "corn-like" SnO2 nanoparticles (diameter ca. 5 nm) decorated along a "cob", addressed the irrever
89 n, NiO-decorated Ni nanowires with diameters ca. 30-150 nm derived from Ni wire backbone (ca. 2 mum i
91 such varieties could be reduced drastically (ca. 80%) without affecting considerably the overall qual
92 ) influx through TRPA1 cation channels (EC50 ca. 200 nM), thereby explaining its ability to stimulate
94 acyclovir, with high entrapment efficiency (ca. 46-56%), could be prepared, and sustained release of
95 II) with reduced band gap; that is, enabling ca. 0.41 eV band gap modulation through introduction of
96 oduces each stereocenter with high enantio- (ca. 93% e.e.), diastereo- (up to 25:1 d.r.), and regiose
98 epopulation-following mission establishment (ca. 1775 CE)-reduced the self-limiting effect of Native
103 charged with KCN, transport is much faster (ca. 100 h) and higher K2MX4 equilibrium ratios are obtai
106 NBS-LPE, only a small amount of apple flesh (ca. 10mg) was sampled directly using a syringe needle an
107 l assemblages precipitated from mixed fluids ca. 65 m below the Cretaceous paleo-seafloor at temperat
108 rous fishes consumed dramatically less food (ca. 90%) but fed at a faster rate when they did feed (ca
111 lower impact, but were still responsible for ca. 9% of juvenile mortality on shags, whereas sport tro
112 nely-laminated sediments were deposited from ca. 5000 years ago until the present, and human activity
113 lk water protons increased dramatically from ca. 1.5 mm(-1) s(-1) to 13 mm(-1) s(-1) between pH 5 and
114 essive NMR shielding of the (1)H nuclei from ca. 4.70 to 1.25 ppm going away from the border of the r
115 nuclear phylogenomic datasets, ranging from ca. 25 Kb to 16.8 Mb and inferred topologies using both
118 of YAP/TAZ, and subsequent stiffening (from ca. 3.5 to 28 kPa) increased the cell area and nuclear l
120 subset{Mo24 Fe12 } macrocycle forms a giant ca. 220 nm(3) unit cell containing 16 macrocycles cluste
121 -alignment of macro-nanodiscs (diameter of > ca. 40 nm) can be exploited for solid-state NMR studies
123 Although the oxidation potential of BPAs (>ca. 1.80 V SHE) is significantly higher than the estimat
125 f Scopoli's shearwaters and Audouin's gulls (ca. 28% and 23% of total mortality, respectively) and al
127 designed sequence was found to activate HCII ca. 250-fold, while leaving aside antithrombin, a closel
129 lved the emergence of Hildenbrandiophycidae [ca. 781 (681-879) Ma], Nemaliophycidae [ca. 661 (597-736
134 if (TTTTTTAGGG)n in C. elegans, occurring in ca. 30 400 copies per haploid genome, averaging ca. 1900
135 s from four unique species, were prepared in ca. 70% isolated yields and fully characterized by multi
136 d as a catalyst and sorbent; this results in ca. 10% higher micropore volume with limited impact on i
137 versatility of the strategy is showcased in ca. 50 examples involving a plethora of electrophiles.
138 n early development of metabolic syndrome in ca. 25% of healthy male individuals suggesting a healthy
139 barriers was integrated with an inexpensive (ca. $300) electronic craft plotter/cutter for paper cutt
140 yet discovered in Amazonia (peat initiation ca. 8.9 ka BP), and developed in three stages: (i) peat
147 at of the native enzyme, with a kcat that is ca. 3 times higher than that of the native enzyme, a kca
149 polymer matrices with this method, which is ca. two to five times higher than that of phosphor-doped
152 specific surface area in a relatively large (ca. 750 nm overall diameter) stable structure, can be va
154 their rates were symmetrical until the last ca. 6 Ma, when northern migration of South American line
155 nuclei concentration background by at least ca. 20%, supporting a marine biosphere-climate link thro
156 largely invariant for all foldamer lengths (ca. 60 ps), the subsequent hole transfer to the donor va
160 ), and the local carrier lifetimes are long (ca. 200 ns) and surprisingly homogenous among grains, an
164 the same reaction in aqueous microdroplets (ca. 5 mum diameter) and find that the cycloaddition reac
165 n group Caragana, dated to the early Miocene ca. 18 Ma and onwards, can be linked to the Himalayan Mo
168 tivity in the hydrogenation of E/Z mixtures (ca. Z/E = 75:25) of alpha,beta-dialkylvinyl substrates,
171 ate the critical distance between molecules (ca. 4.5 A) needed to explain the vibronic structure quen
172 ent ROS diffusion through ultrathin 2D MOLs (ca. 1.2 nm) enable highly effective X-PDT to afford supe
173 quantitatively evaluated by the exponent n (ca. 3) of the temperature dependence of the relaxation r
174 ly dispersed ultrafine MgO nanocrystallites (ca. 3 nm in size), together with the rGO sheets and in s
175 synthesis is described for Au nanoparticles (ca. 20 nm) supported on N-doped carbon (Au@NC), which wa
177 ispersed, silica-supported Cu nanoparticles (ca. 2 nm) prepared via surface organometallic chemistry
178 " approach for the synthesis of very narrow (ca. 0.5 nm) and soluble GNRs using a nonoxidative alkyne
179 dae [ca. 781 (681-879) Ma], Nemaliophycidae [ca. 661 (597-736) Ma], Corallinophycidae [ca. 579 (543-6
183 , enables convenient structure assignment of ca. 200 components from wild-type and peroxisomal beta-o
184 ormed atropisomers separated by a barrier of ca. 15 kcal/mol, whose interconversion was studied by DF
185 4.6 F cm(-3) (and gravimetric capacitance of ca. 773.6 F g(-1) ) at a current density of 0.5 A g(-1)
186 dense monodisperse nanoparticles composed of ca. 50 POMs that were characterized by SAXS and transmis
187 um returns with this slower time constant of ca. 150 ms, indicating that the almost fully folded prot
188 protection occurring with a time constant of ca. 85 ms, but slower protection is observed around a re
189 f ca. 1.0 V, an attractive energy density of ca. 43 Wh kg(-1) based on both electrodes' active mass,
193 resulting in pSi particles with diameters of ca. 500 nm, composed of a porous network of Si nanocryst
198 s, this system enhances energy by factors of ca. 11 and 3.5, respectively, with a specific energy of
199 ic pre-exponential ln (A/min(-1)) factors of ca. 19-35 and 28-41, in the same order, depending on the
200 to monitor slow reactions at a frequency of ca. 180 h(-1) (on the Mini 12) with no sample carryover
201 th turnover number and turnover frequency of ca. 540 and 1.9 min(-1), respectively, and with 94% sele
203 ndamental photoluminescence (PL) lifetime of ca. 660 ns, which is very encouraging for photovoltaic a
205 ensor presents a very low detection limit of ca. 10 pM, (S/N=3) and a very high selectivity towards s
208 3.3 % and carbon-13 polarization (%P13C ) of ca. 1.8 % were achieved in ethyl acetate utilizing 50 %
209 t proton nuclear spin polarization (%PH ) of ca. 3.3 % and carbon-13 polarization (%P13C ) of ca. 1.8
210 atalytic currents with an onset potential of ca. (-) 0.15 V vs Ag/AgCl, affording higher glucose sens
212 its of detection (LODs) were in the range of ca. 1-9 ppm, lower than the minimum exposure limit (25 p
213 he nakhlite-source volcano grew at a rate of ca. 0.4-0.7 m Ma(-1)-three orders of magnitude slower th
214 results show that, within our resolution of ca. 0.1 nm, slip of the surfaces is not correlated with
215 Because of the limiting exposure time of ca. 20 s of the membranes with the sample, this approach
216 an be extended to dipolar evolution times of ca. 80 mus, permitting distances up to 170 A to be acces
217 layed low micromolar activity (EC50 value of ca. 2 muM) and limited cytotoxic liability (CC50 > 100 m
219 o estimate the CBM, which provides values of ca. -4.0 eV versus vacuum on both ITO and TiO2 electrode
221 potent MIF inhibitors bind with Kd values of ca. 50 nM; two are from our laboratory, and the other is
222 performance: an average operation voltage of ca. 1.0 V, an attractive energy density of ca. 43 Wh kg(
225 ding yeast, in high temporal resolution over ca. 2.5 cycles of the short-period respiratory oscillati
227 the two chemotypes show significant overlap (ca. 90 %) both qualitatively and semi-quantitatively, su
228 ed molecular hybrid organic-inorganic oxides ca. 4-9 nm in size, with molecular weights ranging 2-10
229 aving evolved well after the rise of oxygen (ca. 867 million years ago), and thus cannot be progenito
231 egion, dating to the early Neolithic period (ca. 6,000-5,000 BC), provide the earliest biomolecular a
232 iferous (Pennsylvanian) and Permian Periods (ca. 323-252 Ma), when arborescent vascular plants relate
235 nd 1050 nm (fwhm approximately 145 meV, PLQY ca. 1.8%), which is the first observation of narrow near
236 ydrogen-bonded DMSO near the eutectic point (ca. 35 mol %) which also correlates with several abnorma
237 ur approach to co-occurring Late Precontact (ca. A.D. 1000-1600) monuments in Michigan: (i) mounds an
238 a high selectivity towards C2 /C3 products (ca. 60 %) for up to 5 h in 0.1 m KHCO3 at -1.0 V vs. RHE
239 In two natural waters, a high proportion (ca. 93-100%) of dissolved Zn was measured, and the resid
240 gh photoluminescence (PL) quantum yield (QY; ca. 15-55 %) and product yield have been synthesized usi
241 of transmission through the reaction region (ca. 20-200 ms), representing a 50-1000-fold improvement
244 nalyses on a molecular timetree representing ca. 82% of the extant families, and reassess the insect
245 e possesses low equivalent series resistance ca. 3.5 Omega, resulting in superior power performance a
247 lation following postglacial sea-level rise, ca. 2.5 ka, to characterize long-term change in insular
249 both of which provided similar sensitivity (ca. 0.2 mM(-1)) when normalized to the same standard.
250 the Gold Rush and Euro-American settlement (ca. 1865 CE), fire activity declined, and the strong mul
253 kite nanocrystals (PNCs) of different sizes (ca. 2.5-100 nm) with high photoluminescence (PL) quantum
254 from the upper Permian (Changhsingian Stage, ca. 254-252 million-years ago) of China documenting a mi
256 declines in microbial decay in a long-term (ca. 20 yrs.) N deposition experiment have altered the bi
257 ere in terms of S/N at wavenumbers less than ca. 1400 cm(-1) despite the weaker signal enhancement de
258 y those organics with an IP value lower than ca. 9.0 eV can be oxidized in the CPPy-F-8/PMS system.
260 zed reactions of substrate pieces shows that ca. 50% of the wildtype TIM dianion binding energy, elim
264 erator-collector distance (ranging from 3 to ca. 500 mum) on the collection efficiencies obtained at
268 e causative low-density structure extends to ca. 6 km depth, which we interpret as a shallow plumbing
270 ese substances occur in raw wastewater up to ca. 1.6 mug L(-1) and in treated wastewater up to ca. 1
276 nanolimulus luopingensis, a Middle Triassic (ca. 244 million years old) horseshoe crab from Yunnan Pr
279 n donor-acceptor distance (DAD) is typically ca. 2.7 A, considerably shorter than normal van der Waal
282 ghest CO2 gravimetric and volumetric uptake (ca. 1.3 mmol/g and 51.4 cm(3) (STP) cm(-3)) for a physic
283 fluorescence quenching is demonstrated using ca. 200 nm diameter template-synthesized polyfluorene na
284 e most to tropical peatland area and volume (ca. 44% for both) partly related to some yet unaccounted
285 by light-weight (ca. 3 mg) and small volume (ca. 30 mm x 2 mm x 10 mum) is driven by a microcontrolle
288 etained to a remarkably high level of water (ca. 42 wt % H2 O) because of solvophobic sequestration o
289 he most active species is a high wavenumber (ca. 1685 cm-1) carbonate that we associate directly with
290 brid actuator characterised by light-weight (ca. 3 mg) and small volume (ca. 30 mm x 2 mm x 10 mum) i
291 the fact that circulating levels of JH were ca. 2 orders of magnitude higher in queens than those in
293 -MnP phase transition under compression with ca. 22 % unit-cell volume changes, which was found to be
294 ovoltaic tests demonstrate that devices with ca. 10% of mixed phases outperform pure-phase devices.
295 mensional (3D) supramolecular framework with ca. 2.8 nm diameter one-dimensional (1D) hexagonal chann
299 lent in the corresponding isotope world with ca. 43 new species in the D world and ca. 39 new species
300 terized by high fluorescence quantum yields (ca. 0.5-0.7) and brightness (ca. 35000-40000 M(-1) cm(-1
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