ライフサイエンスコーパス: cal

1 ol(-1), DeltaS(double dagger) = -6.5 +/- 2.0 cal mol(-1) K(-1), DeltaG(double dagger)(298) = 11.9 +/-

2 ation is small but negative (DeltaS() = -3.0 cal mol(-1) K(-1)), while there is almost a 2-fold diffe

3 kcal mol(-1) and DeltaS(++) = -25.4 +/- 5.0 cal mol(-1) K(-1).

4 avity will not typically be greater than 7.0 cal/mol/K per water molecule, corresponding to a contrib

5 es from approximately -15 to approximately 0 cal/mol x K as a function of the nature and concentratio

6 ) and DeltaS(double dagger) = -32.0 (+/-5.0) cal.mol(-1).K(-1) for the reaction of (Ph3P)Au-Si(t-Bu)P

7 rbon-dated from approximately 4,200 to 1,000 cal BP (Late Holocene).

8 the west coast, arrived approximately 10,000 cal YBP in Labrador and ca. 6,000 cal YBP in Newfoundlan

9 favored forest development after ca. 10,000 cal years B.P.

10 and traversable corridor by at least 13,000 cal y BP, just before the first appearance of Clovis tec

11 rly 60 mug Hg m(-2) yr(-1) ca. 13,000-14,000 cal years BP, declined sharply during the Younger Dryas,

12 f Hg (and Fe) increased rapidly about 16,000 cal years BP, peaked at nearly 60 mug Hg m(-2) yr(-1) ca

13 and Northwest Europe between 8,000 and 4,000 cal.

14 mpanian Ignimbrite volcanic eruption (40,000 cal BP) and the beginning of HE4, artifact assemblages a

15 Heinrich Event 4 (HE4) (approximately 40,000 cal BP).

16 te to this time period (approximately 42,000 cal BP) but are not associated with artifacts.

17 Between 45,000 cal years BP and the beginning of the Holocene, the accu

18 ely 10,000 cal YBP in Labrador and ca. 6,000 cal YBP in Newfoundland [2, 3].

19 dden increase in summer temperature at 6,000 cal.

20 ety does not appear in the north until 6,000 cal.

21 y of farming rapidly extended north at 6,000 cal.

22 epo) cultivation appearing as early as 8,000 cal B.C. followed by many other plants, such as maize (Z

23 and 5, spanning 8,200 to approximately 9,000 cal B.C., associate with round-house architecture and ar

24 uncatalyzed lyase reaction (-15.77 +/- 0.02 cal/(mol K)) documented here.

25 n in deposits dating between 4,340 and 4,020 cal B.P., and again between 2,350 and 980 cal B.P.

26 BP, 44,200-42,350 cal BP, and 54,400-46,050 cal BP (all at the 95.4% confidence level).

27 ita argyrosperma does not appear until 2,065 cal years B.P.

28 DeltaG(eq) approximately -6 kcal.mol(-1) (1 cal = 4.18 J) and tau(f) approximately 6 mus, folding re

29 Ru(II)(acac)(2)(py-imH) + TEMPO, 4.9 +/- 1.1 cal mol(-1) K(-1), as reported earlier.

30 al/mol and DeltaS(double dagger) = -22 +/- 1 cal mol(-1) K(-1)), which subsequently isomerizes to (et

31 0.2 kcal mol(-1), DeltaS(on)(++) = -24 +/- 1 cal mol(-1) K(-1); MesCN: DeltaH(on)(++) = 5.0 +/- 0.3 k

32 0.3 kcal mol(-1), DeltaS(on)(++) = -26 +/- 1 cal mol(-1) K(-1)).

33 ference in binding entropy (+5.9 versus -4.1 cal mol(-1) K(-1)) was observed between 4-CPI and BEI, r

34 of 61 +/- 6 cal/(mol.K) (relative to 7 +/- 1 cal/(mol.K) in solution).

35 At medium EIS [1.5 kcal/mol (1 cal = 4.18 J)], unfolded conformations almost disappear,

36 ding, measured earlier as 43 kcal per mol (1 cal = 4.184 J) of rings, is required for driving the for

37 ) kcal mol(-1), DeltaS(double dagger) = 1(1) cal mol(-1) K(-1) and DeltaG(298)(double dagger) = 18.5(

38 5 kcal mol(-1)), entropy (DeltaS(m)=150+/-10 cal mol(-1) K(-1)), and average cooperative melting unit

39 acity change for the reaction is -256 +/- 10 cal/(K mol of Hoechst).

40 carboxylation of OMP are 3.6 kcal/mol and 10 cal K(-1) mol(-1) more positive, respectively, for MtOMP

41 . kyr bp, and boreal forest approximately 10 cal. kyr bp.

42 s were found in substratum 4k (10,900-10,100 cal B.P.).

43 oundary or YDB (approximately 12,900 +/- 100 cal BP or 10,900 +/- 100 (14)C years).

44 orth America at approximately 12,900 +/- 100 cal BP.

45 recommend that children consume </=25 g (100 cal or approximately 6 teaspoons) of added sugars per da

46 ese lakes during the past 12 ka (1 ka = 1000 cal yr BP).

47 rge heat capacity of binding of -705(+/-113) cal/molK, consistent with an important role of solvent d

48 pholipid and DeltaS degrees = +1.68 +/- 1.12 cal/K mol of phospholipid.

49 taH(m) is 90 kcal/mol, and DeltaC(p) is 1300 cal/Kmol.

50 r heat capacity (DeltaC(p) approximately 138 cal mol(-1) K(-1)) that suggests bonding at the protein-

51 y DeltaS(double dagger) of approximately -15 cal/mol x K for the edge interconversion process, compat

52 hen Europeans, who settled approximately 150 cal y ago, used fire as a tool for forest clearance, but

53 s coupled with the loss of approximately 150 cal/mol complex in binding free energy.

54 e individuals from Rathlin Island (2026-1534 cal BC), including one high coverage (10.5x) genome, sho

55 d have an entropy change of approximately 17 cal/(Kmol), whereas the B-to-S transition is nonhysteret

56 tication context approximately 11,300-11,175 cal B.P., which support recent arguments for the deliber

57 o CGCG were in good agreement (-142 and -177 cal mol(-)(1) K(-)(1), respectively).

58 probe increases, with a DeltaDeltaG of -190 cal/methylene.

59 nge coupling, J/k approximately -0.1 K ~ 0.2 cal mol(-1), between the S = 2 tetraradicals.

60 d lyase reaction (DeltaS(++) = -24.3 +/- 0.2 cal/(mol K)) is larger than that of the uncatalyzed lyas

61 of -8000 +/- 300 cal/mol and DeltaS of -15.2 cal/mol/degree at 283 K), involves a single binding site

62 0.4 kcal mol(-1), DeltaS(++)(k1) = -18 +/- 2 cal mol(-1) K(-1), and DeltaH(++)(k2) = 11.1 +/- 0.2 kca

63 l, and DeltaS(double dagger) = -35.0 +/- 2.2 cal K(-1) mol(-1); and the temperature range 288-308 K f

64 /- 0.99 kcal/mol, DeltaS(++) = -24.8 +/- 3.2 cal/(mol K)), giving k(abs) at 25 degrees C of (2.5 +/-

65 negative than the DeltaS(o)(HAT) = -30 +/- 2 cal mol(-1) K(-1) for the two iron complexes and the Del

66 6 kcal mol-1, and DeltaS degrees = -30 +/- 2 cal mol-1 K-1.

67 ntropy for hydrogen atom transfer, -41 +/- 2 cal mol(-1) K(-1).

68 kcal/mol, and DeltaS degrees = -55.9 +/- 5.2 cal mol(-1) K(-1)) species.

69 r 8 and 13.8 kcal/mol (DeltaS = -6.6 +/- 6.2 cal mol(-1) K(-1); DeltaH = 11.8 +/- 1.8 kcal/mol) for 9

70 -0.8 +/- 0.4 kcal/mol, DeltaS() = -72 +/- 2 cal/(mol.K)) indicate that the cleavage of strong N-H bo

71 10.6 +/- 0.7 kcal/mol, and DeltaS = 9 +/- 2 cal mol(-1) degrees C(-1).

72 nd has an entropy change of approximately -2 cal/(Kmol).

73 l mol(-1) and DeltaS(double dagger) = -13(2) cal K(-1).

74 ion analysis PLSR models were developed; R(2)cal were 0.99 for magnesium and potassium and 0.97 for a

75 ate constants were 1.5 s(-1) from the Ca(2+)/cal.alphaCaMKII and 0.023 s(-1) from the Ca(2+)/cal.phos

76 es in the Ca(2+) sensitivities of the Ca(2+)/cal.alphaCaMKII and Ca(2+)/cal.phospho-Thr(286)-alphaCaM

77 .alphaCaMKII and 0.023 s(-1) from the Ca(2+)/cal.phospho-Thr(286)-alphaCaMKII complex, accounting for

78 M [Ca(2+)] partially Ca(2+)-saturated Ca(2+)/cal.phospho-Thr(286)-alphaCaMKII complexes existed.

79 ies of the Ca(2+)/cal.alphaCaMKII and Ca(2+)/cal.phospho-Thr(286)-alphaCaMKII enzymes.

80 binding with DNA and DeltaCp = -2010 +/- 20 cal mol(-1) K(-1) for the addition of beta to complete t

81 f DeltaH) is large and negative (-210 +/- 20 cal K(-1) mol(-1)), indicating a large hydrophobic contr

82 ition, we determined DeltaS approximately 20 cal/(K.mol) and DeltaH approximately 7 kcal/mol.

83 ',5'-ADP to CPR (TDeltaS(B) = -13400 +/- 200 cal mol(-)(1), 35 degrees C) was compared with binding o

84 ourd (Lagenaria siceraria) is dated at 7,200 cal years B.P.

85 ve manipulation by humans by or before 8,200 cal B.C.

86 moukar, Tell Brak and Tell Leilan (6500-2000 cal bc), we reveal that labour-intensive practices such

87 hange (DeltaC(p)) values for 2',5'-ADP (-210 cal mol(-)(1) K(-)(1)), NADP(+) (-230 cal mol(-)(1) K(-)

88 stablish the presence of maize there by 2100 cal. B.C. (calibrated calendrical years before the Chris

89 e (unfavorable interaction free energy, +211 cal mol(-1)m(-1) for the potassium salt), an ion that mi

90 xistence of a thriving peatland at 2700-2150 cal.

91 peat accumulation ( 0.1 cm/year) until 2150 cal.

92 taCp) for this interaction changes from -220 cal mol-1 K-1 in the wild-type enzyme to -580 cal mol-1

93 0 cal mol(-)(1) K(-)(1)), and H(4)NADP (-220 cal mol(-)(1) K(-)(1)) indicate no significant contribut

94 s agricultural activity intensified ca. 2200 cal.

95 DeltaC(p) of protein unfolding of 826 +/- 23 cal mol(-)(1) K(-)(1) and a DeltaC(p) of 1554 +/- 29 cal

96 nal entropy, DeltaSconf, of approximately 23 cal mol(-1) K(-1) per nucleotide, which signifies libera

97 overages by a large positive entropy (>or=23 cal K(-)(1) mol(-)(1)), which may be partially due to th

98 ordering (DeltaS(double dagger) = -13 to -23 cal/K.mol) and substantial overall bond disruption (Delt

99 (-210 cal mol(-)(1) K(-)(1)), NADP(+) (-230 cal mol(-)(1) K(-)(1)), and H(4)NADP (-220 cal mol(-)(1)

100 chaeological record dating from 1,530 to 230 cal BP recording rates of blunt and sharp force skeletal

101 l/(mol.K)) compared to the second site (-234 cal/(mol.K)) suggests that the importance of nonpolar an

102 cument an active Last Glacial Maximum (18-24 cal ka B.P.) monsoon with similar delta(18)O values to t

103 disfavored (DeltaS degrees approximately -24 cal mol(-1) K(-1)).

104 ic sites across Europe (dating ca. 5900-2400 cal B.C.), which show that early farmers used livestock

105 reruption from Taupo volcano (25,580 +/- 258 cal.

106 pertoire of Mexican domesticates by ca. 2600 cal B.C., that its cultivation was widespread in Mexico

107 ge DeltaC(p) values (113 +/- 9 and 42 +/- 27 cal x K(-1) x mol(-1) of bp), were in the range of value

108 t capacity changes ranging from -800 to -271 cal mol(-1) K(-1).

109 capacity change (-621, -467, -235, and -275 cal x mol(-1) x K(-1), with GTP, GTPgammaS, GDPNP, and G

110 Peat inception was dated at 2750 cal.

111 ropy (Delta(double dagger)S degrees ) of ~28 cal/mol.K.

112 eep decline in dustfall persisted after 2800 cal BP maintaining sawgrass vegetation at the coring sit

113 The climatic change after 2800 cal BP was probably produced by a shift in the Bermuda H

114 adings of aeolian dust prevailed before 2800 cal BP (calibrated years before present) when vegetation

115 -)(1) K(-)(1) and a DeltaC(p) of 1554 +/- 29 cal mol(-)(1) K(-)(1) for the coupled unfolding and diss

116 /- 0.43 kcal/mol, DeltaS(++) = -21.7 +/- 1.3 cal/(mol K)) and H(2)S (DeltaH(++) = 5.13 +/- 0.99 kcal/

117 17.2 +/- 0.8 kcal/mol, DeltaS++ = -11 +/- 3 cal/mol.K).

118 py, |DeltaS degrees Fe(H2bim)/ET| = 29 +/- 3 cal mol-1 K-1, is consistent with a vibrational origin.

119 9 kcal mol-1, and DeltaS degrees = -30 +/- 3 cal mol-1 K-1.

120 tically different, with DeltaCp = -305 +/- 3 cal mol(-1) K(-1) for alpha binding with DNA and DeltaCp

121 l(-1), and DeltaS(double dagger) = -37 +/- 3 cal mol(-1) K(-1), measured over the range 70-90 degrees

122 0.8 +/- 0.8 kcal/mol and DeltaS13 = 45 +/- 3 cal/mol/K for the transition from the ternary complex to

123 nding to MMP-3cd are much smaller (-53 +/- 3 cal K(-1) mol(-1)), and some of the entropy increase may

124 +/- 0.8 kcal mol(-1), DeltaS(++) = -9 +/- 3 cal K(-1) mol(-1), and KIE = 5.7.

125 steretic transition, DeltaS approximately -3 cal/(K.mol) and DeltaH approximately 1 kcal/mol.

126 kcal/mol and DeltaS(double dagger) = -18(3) cal/(mol K), consistent with an associative-type mechani

127 s DeltaH = 24(7) kcal/mol and DeltaS = -2(3) cal/mol.K, and the post-rate-determining step to be C-H

128 -12.5(3) kcal mol(-1) and DeltaS(o) = -26(3) cal K(-1) mol(-1); N(2): DeltaH(o) = -13.9(7) kcal mol(-

129 al/mol and DeltaS(double dagger) = -44(+/-3) cal/(mol.K).

130 s DeltaH = 21(1) kcal/mol and DeltaS = -8(3) cal/mol.K.

131 e of -10 kcal/mol, and entropy change of -30 cal/(mol K).

132 mol(-1) and DeltaS() approximately -5 to -30 cal K(-1) mol(-1).

133 etic continuity for at least the past 10,300 cal y B.P.

134 -binding domain (TDeltaS(B) = -11200 +/- 300 cal mol(-)(1), 35 degrees C) indicate that the number of

135 le grain existed in Central America by 4,300 cal B.P.

136 stication traits were not yet fixed by 5,300 cal B.P. in the highlands of Mexico.

137 ncrease in enthalpy (DeltaH of -8000 +/- 300 cal/mol and DeltaS of -15.2 cal/mol/degree at 283 K), in

138 A Neolithic woman (3343-3020 cal BC) from a megalithic burial (10.3x coverage) posses

139 eltaC(p) for Taz2 binding to the first (-330 cal/(mol.K)) compared to the second site (-234 cal/(mol.

140 an estimated deltaC(P)(0) of binding (-3300 cal x mol(-1) x K(-1)) that is larger and more negative

141 e in heat capacity changes (-604 versus -331 cal mol(-1) K(-1)), which is inferred to result from the

142 rized by DeltaH = 8 kcal/mol and DeltaS = 34 cal/mol K.

143 ages of 38,650-36,750 cal BP, 44,200-42,350 cal BP, and 54,400-46,050 cal BP (all at the 95.4% confi

144 -round living at higher altitudes since 3600 cal yr B.P.

145 taH(EAL) = -13 kcal/mol and DeltaS(EAL) = 38 cal/mol/K.

146 hexammine- and spermine-DNA binding (-23.39 cal/mol K and -17.98 cal/mol K, respectively) suggest th

147 ts made by Neanderthals and is older than 39 cal kyr BP.

148 +/- 0.6 kcal mol(-1), DeltaS(++) = -27 +/- 4 cal mol(-1) K(-1).

149 kcal/mol, and DeltaS degrees = -56.2 +/- 5.4 cal mol(-1) K(-1)) and freely diffusing (DeltaH degrees

150 cal/mol and DeltaS(double dagger) = -6 +/- 4 cal mol(-1) K(-1)).

151 gy of -17.7 kcal/mol and an entropy of +61.4 cal/mol K (-TDeltaS=-18.3 kcal/mol) at the 1 M state.

152 = -6.9(7) kcal/mol, DeltaS degrees = -26(4) cal mol(-1) K(-1)).

153 ed heat capacity change (DeltaCp = 70 +/- 40 cal.mol(-1).K(-1)) suggests that large-scale conformatio

154 arly Formative periods ( approximately 3,400 cal y BC to 1,600 cal y BC).

155 icant temperature dependence (DeltaCp = -401 cal mol-1 K-1).

156 pholipid and DeltaS degrees = -4.48 +/- 0.44 cal/K mol of phospholipid.

157 (-1) mol(-1) in S(degrees)298, and about 0.5 cal K(-1) mol(-1) in the C(degrees)p.

158 +/- 4 kcal/mol, and DeltaS was 102.7 +/- 0.5 cal/(mol-K).

159 +/- 2 kcal/mol, and DeltaS was 56.9 +/- 0.5 cal/(mol-K).

160 be 1.97 +/- 0.46 kcal/mol and -18.1 +/- 1.5 cal/(mol K), respectively, giving k(abs) = (2.3 +/- 0.23

161 with evidence of moose and elk at about 11.5 cal. kyr bp, and boreal forest approximately 10 cal. kyr

162 ol(-1), and DeltaS(double dagger) = 16 +/- 5 cal mol(-1) K.

163 - 1 kcal mol(-1), DeltaS(on)(++) = -28 +/- 5 cal mol(-1) K(-1); PhCN: DeltaH(on)(++) = 5.2 +/- 0.2 kc

164 .5 kcal/mol and unfavorable entropy of -32.5 cal/mol K (-TDeltaS= +9.7kcal/mol) at a 1M reference sta

165 .5 kcal mol(-1), DeltaS(degrees) = -40 +/- 5 cal mol(-1) K(-1).

166 .5 kcal mol(-1), DeltaS(degrees) = -52 +/- 5 cal mol(-1) K(-1).) Solution calorimetric studies show t

167 The average DeltaC(p) was 70 +/- 5 cal K(-)(1) (mol of base pairs)(-)(1).

168 -13.9(7) kcal mol(-1) and DeltaS(o) = -32(5) cal K(-1) mol(-1)).

169 iments dating to approximately 12,950 +/- 50 cal BP at Arlington Canyon, Santa Rosa Island, Californi

170 limate Anomaly (MCA; approximately 1,000-500 cal B.P.), the period most similar to recent decades, wa

171 entral Alaska dating to approximately 11,500 cal B.P.

172 = 10(7.7+/-0.4) s(-1) x exp {(13300 +/- 500 cal/mol)/RT}.

173 ome boreal trees along valleys around 43,500 cal B.P.

174 of Greenland Interstadial 11, around 43,500 cal B.P., and thus is older than any other Aurignacian a

175 Cool summers before 5,500 cal B.P. coincided with extensive summer ice cover in th

176 fully developed agrarian societies by 7,500 cal.

177 years (cal) B.C.] to the later Iron Age (500 cal B.C.), alongside modern data from 13 locations.

178 econd 60 mug Hg m(-2) yr(-1) peak about 5000 cal years BP.

179 neral increase in flood frequency after 5000 cal. yr BP consistent with a weakening in zonal circulat

180 1, and entropy driven, with DeltaSrxn of +51 cal K-1 mol-1.

181 t was overwhelmed by marine inundation 7,550 cal. yr bp.

182 al mol-1 K-1 in the wild-type enzyme to -580 cal mol-1 K-1 in the deletion mutant.

183 -0.14 kcal/mol and DeltaS(++) = 0.81 +/- 0.6 cal mol(-1) K(-1).

184 mutase reaction (DeltaS(++) = -12.1 +/- 0.6 cal/(mol K)) is comparable to that of the previously rep

185 ers (DeltaG) of 11.1 (DeltaS = -19.4 +/- 1.6 cal mol(-1) K(-1); DeltaH = 6.5 +/- 0.4 kcal/mol) for 8

186 ups in unglaciated North America before 12.6 cal. kyr bp, are unlikely to have travelled by this rout

187 ion, bison and mammoth by approximately 12.6 cal. kyr bp, followed by open forest, with evidence of m

188 of the B conformer and DeltaS(B<-->S) = 15.6 cal mol(-1) K(-1) in favor of the intercalated S conform

189 cks (Ps < 0.05) and consumed 532.6 +/- 295.6 cal during late-night hours (2200-0359).

190 halpy of -11.6 kcal/mol and entropy of -39.6 cal/(mol K).

191 ge, favorable activation entropy of 61 +/- 6 cal/(mol.K) (relative to 7 +/- 1 cal/(mol.K) in solution

192 taH(m)=27+/-2 kcal mol(-1); DeltaS(m)=86+/-6 cal mol(-1) K(-1)) and noncooperative unfolding (<n(c)>

193 with DeltaH=-40.3 kcal mol(-1), DeltaS=-97.6 cal mol(-1)K(-1), and DeltaG=-10.73 kcal mol(-1).

194 proximately 35 kcal/mol and approximately 60 cal/mol x K, respectively.

195 nd DeltaS(double dagger) of approximately 60 cal/mol x K.

196 iods ( approximately 3,400 cal y BC to 1,600 cal y BC).

197 Between approximately 5,800 and 3,600 cal B.P. the biggest architectural monuments and largest

198 argely entropy driven, with DeltaSrxn of +61 cal K-1 mol-1.

199 llapse during the stadial, at ~12,920-12,640 cal BP and 12,050-11,900 cal BP.

200 t was large and negative (approximately -650 cal mol-1 K-1), suggestive of significant structural cha

201 h reveal a RSL history between 6850 and 6500 cal years BP that includes two 0.6 m fluctuations, with

202 ore reaching 'near-modern' values at ~12,660 cal BP, consistent with synchronous recovery of overturn

203 evidence that already by approximately 6600 cal.

204 tes australis (Cav.)) and dated to 6775-6645 cal. yr. BP.

205 rn and southern divisions approximately 6900 cal. B.C. and the dispersal of maize agriculture from Me

206 of 2.8 kcal mol(-1) in DeltaHf(degrees), 0.7 cal K(-1) mol(-1) in S(degrees)298, and about 0.5 cal K(

207 be 2.03 +/- 0.56 kcal/mol and -19.3 +/- 1.7 cal/(mol K), respectively, giving k(abs) = (1.2 +/- 0.49

208 = 34.0 kcal mol(-)(1) and DeltaS(++) = 18.7 cal mol(-)(1) K(-)(1) by Eyring plot analysis.

209 a positive heat capacity change of 194 +/- 7 cal K(-)(1) mol(-)(1) at 25 degrees C.

210 +/- 0.2 kcal M(-1), DeltaS(++) = 0.3 +/- 2.7 cal M(-1) K(-1).

211 2 kcal mol(-1), DeltaS(degrees) = -20 +/- 7 cal mol(-1) K(-1).

212 = 25 +/- 3 kcal M(-1), DeltaS(++) = 25 +/- 7 cal M(-1) K(-1) and DeltaH(++) = 17.1 +/- 0.2 kcal M(-1)

213 enthalpy (+10.9 kcal/mol) and entropy (+40.7 cal/deg mol) of binding relative to unmodified protein.

214 stems is estimated to have occurred at ca. 7 cal.

215 anized transition state (DeltaS(++) = -43(7) cal.mol(-1) K(-1)) and a remarkably low enthalpic barrie

216 nal deposits dated between 15,000 and 13,700 cal B.P. provide evidence for systematic harvesting and

217 rew in these drainages between 1,070 and 700 cal yr BP, during the Medieval Climatic Anomaly.

218 The value of approximately 700 cal/mol basepair for the enthalpy of the B-Z transition

219 eing more endothermic than (dC-dG)(4) by 700 cal/mol basepair.

220 -1, and entropy driven with DeltaSrxn of +72 cal K-1 mol-1.

221 g more exothermic than (dm(5)C-dG)(4) by 720 cal/mol basepair.

222 in Nahal Hemar cave (Israel, ca. 8200 -7300 cal.

223 ic basin indicate ages from 16,380 to 13,740 cal yr BP, synchronous with paleolake Tauca on the Boliv

224 bia dating from approximately 6,075 to 1,750 cal y B.P.

225 e same layer, yielding ages of 38,650-36,750 cal BP, 44,200-42,350 cal BP, and 54,400-46,050 cal BP (

226 kcal mol(-1), DeltaS(++)(k2) = -7.5 +/- 0.8 cal mol(-1) K(-1).

227 +/- 0.3 kcal/mol and DeltaS() = -7.5 +/- 0.8 cal.mol(-1) K(-1), consistent with intramolecular proton

228 84+/-0.2 kcal/mol and a DeltaS of -2.9+/-0.8 cal/(mol.K) were determined.

229 be 1.54 +/- 0.25 kcal/mol and -25.5 +/- 0.8 cal/mol K, respectively, giving k abs = 1.3 x 10 (6) M (

230 o pottery dating from about 15,000 to 11,800 cal bp (the Incipient Jomon period), the oldest pottery

231 and use around Lake Sauce changed at ca. 800 cal.

232 terials isolated from sediments dated 15,818 cal yr B.P. to present (including the Bolling-Allerod-YD

233 and had appeared in central Anatolia by 8300 cal BC [4].

234 endent enthalpy (heat capacity of 610 +/- 84 cal/Mol K), is slowed in the presence of TMAO and speede

235 s, and median daily caloric intake was 1,840 cal (IQR 1,487-2,222).

236 (DeltaH = 5.9 kcal mol(-1) and DeltaS = 33.9 cal mol(-1) K(-1)).

237 ncrement of ligand dissociation is 363 +/- 9 cal mol(-)(1) K(-)(1) per site.

238 l, and DeltaS(double dagger) = -30.3 +/- 5.9 cal K(-1) mol(-1).

239 py of activation (DeltaS(double dagger) = -9 cal mol(-1) K(-1)) and an inverse solvent isotope effect

240 s DeltaH = 31(16) kcal/mol and DeltaS = 3(9) cal/mol x K.

241 taH = 10.4(3) kcal/mol and DeltaS = -32.3(9) cal/mol.K.

242 , at ~12,920-12,640 cal BP and 12,050-11,900 cal BP.

243 barraged North America approximately 12,900 cal yr B.P. and caused these events.

244 known as "Egbert" between 43,200 and 42,900 cal B.P. and the IUP-associated modern human maxilla kno

245 n as "Ethelruda" before approximately 45,900 cal B.P.

246 nger deposits, dating to approximately 6,900 cal B.P., also contained tools with S. jamesii granules,

247 ter, it declined nearly to background by 900 cal years BP.

248 DeltaC(p spermine)) is significant (-220.94 cal/mol K).

249 e 5HT2c octapeptide was determined to be -94 cal/mol, and a calculated estimate indicates burial of p

250 ine-DNA binding (-23.39 cal/mol K and -17.98 cal/mol K, respectively) suggest that upon binding to DN

251 20 cal B.P., and again between 2,350 and 980 cal B.P.

252 etween 50,000 and 40,000 calendar years ago (cal B.P.).

253 tely 23,000 until 13,400 calendar years ago (cal y BP), after which we find the first evidence, to ou

254 was present by 8,700 calendrical years ago (cal. B.P.).

255 mains date to approximately 10,300 calendar (cal) y B.P.

256 Marmara Sea since at least 9.6 ka calendar (cal) B.P.

257 ave, dating to 7,920 calibrated calendrical (cal) years B.P.

258 ed on the island until ca. 9,000 calibrated (cal) YBP [1].

259 re linkages over the last 18,000 calibrated (cal) years B.P., and (iii) evaluate the role of humans i

260 cci sublayer 23A [32,614 +/- 429 calibrated (cal) B.P.], Southern Italy, have demonstrated that early

261 he Balkans by approximately 6200 calibrated (cal.) BC or later.

262 nnium and early ninth millennium calibrated (cal) BC and had appeared in central Anatolia by 8300 cal

263 Finally, an anti-CD22/cal and CTLA4-Ig-based combination therapy displayed rem

264 lycemic mice were treated with the anti-CD22/cal mAb, 100% of B-cell-depleted mice became normoglycem

265 Anti-CD22/cal monoclonal antibody (mAb) therapy resulted in early

266 Anti-CD22/cal-mediated B-cell depletion promotes the reduction of

267 ody conjugated with calicheamicin [anti-CD22/cal]) efficiently depleted B cells in all three models o

268 e cooperativities, DeltaH(van't Hoff)/DeltaH(cal) approximately 1, for helix-bundle proteins.

269 the wild type and a 40% reduction in DeltaH(cal).

270 ylene group can contribute approximately 1 K cal mol(-1) to the overall stability of the protein-alco

271 d transitional industries; (ii) the 44-42 ka cal BP assemblages are based on an expedient technology

272 chnological change at approximately 44-42 ka cal BP, marked by adoption of techniques and materials t

273 curred during the refreshening after ~2.5 ka cal B.P. with the onset of the cool and wet Subatlantic

274 odern population in Southeast Asia at ~50 ka cal BP.

275 rance of this species (about 17 or 13-11 kyr cal. BP).

276 s reach no farther back than about 41-39 kyr cal BP, leaving a gap.

277 000 calendar years before present (43-42 kyr cal BP), by association with Aurignacian sites and lithi

278 Instead, KC4 dates to 44.2-41.5 kyr cal BP.

279 reenland Stadial 1 (GS-1; ~12.9 to 11.65 kyr cal BP) was a period of North Atlantic cooling, thought

280 celerator mass spectrometry to 36.4-34.7 kyr cal BP.

281 brated radiocarbon years before present (kyr cal. BP), or the time of last appearance of this species

282 an now be pushed back to the 12th millennium cal B.P.

283 est Anatolia by the early seventh millennium cal BC and quasi-synchronously into Europe, although the

284 egions, at least from the seventh millennium cal BC, likely fulfilling a variety of technological and

285 atp DeltaH(o)F=-16.12kJ.mol(-1) and DeltaH(o)cal=-42.63kJ.mol(-1).

286 an entropic driven binding process (DeltaH(o)cal=29.11kJ.mol(-1)).

287 by approximately 9,000 calendar years B.P. (cal B.P.), but it remains unclear when maize was product

288 and 12,000 calibrated years before present (cal bp), towards the end of the Late Pleistocene epoch,

289 calibrated radiocarbon years before present (cal BP).

290 calibrated radiocarbon years before present (cal. kyr bp), glacial retreat opened an approximately 1,

291 hina, 7,700 calibrated years before present (cal. yr bp).

292 y by 5200 calendar years before the present (cal yr B.P.).

293 er production are 1960 + or - 40 BP (2-sigma cal. 40 BC to AD 120) and 1870 + or - 40 BP (2-sigma cal

294 BC to AD 120) and 1870 + or - 40 BP (2-sigma cal. AD 60 to 240) representing the oldest known silver

295 Stopped-flow experiments using Ca(2+)/TA-cal [Ca(2+)/2-chloro-(epsilon-amino-Lys(75))-[6-[4-(N,N-

296 rth America at 10,900-10,100 calendar years (cal) B.P. in the form of well-preserved starch granules

297 aori), who arrived 700-800 calibrated years (cal y) ago, and then Europeans, who settled approximatel

298 Aceramic Neolithic [10,000 calibrated years (cal) B.C.] to the later Iron Age (500 cal B.C.), alongsi

299 ng to approximately 11,500 calibrated years (cal) B.P. at the Upward Sun River site in central Alaska

300 atures during 10,000-5,500 calibrated years (cal) B.P. were generally lower than modern and that peak