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1 olic NH moiety with a meso-sp(3) -hybridized carbon atom.
2 out-of-plane ppi occupancies of the central carbon atom.
3 arkably short Pd-Cu bond and a trigonal ipso carbon atom.
4 ach have bonds to three sulfur atoms and one carbon atom.
5 associated with pyramidalization around this carbon atom.
6 hat accumulate positive charge at the acetal carbon atom.
7 m stabilization of the electron-deficient C1 carbon atom.
8 of O2(*-) and Ph(*) addition to the nitronyl carbon atom.
9 -catalyzed monohydroxylation of the benzylic carbon atom.
10 a-nitroamines possessing a fully substituted carbon atom.
11 h an unconventional strategy for replacing a carbon atom.
12 nnected via the N-atom to the former carbene carbon atom.
13 egardless of the chirality at the asymmetric carbon atom.
14 ttern opposite T but with N3 replaced with a carbon atom.
15 yl ring and the adjacent hydroxy-substituted carbon atom.
16 roved most effective in installing the final carbon atom.
17 n comparison, the cyano radical adds via its carbon atom.
18 ic acid groups precisely every 21st backbone carbon atom.
19 ly leading to derivatization of the internal carbon atom.
20 t of d --> p backbonding from gold to the C1 carbon atom.
21 dispersed and surrounded by sp(3)-hybridized carbon atoms.
22 bearing functionality at one of the tertiary carbon atoms.
23 reactive aliphatic or electron-rich aromatic carbon atoms.
24 roduced by a condensing enzyme from 28 to 30 carbon atoms.
25 A vs. 2.783(2) A] between the ipso and para carbon atoms.
26 C-C bonds between adjacent sp(2)-hybridized carbon atoms.
27 s for a dimerization are always the terminal carbon atoms.
28 "fullerene-type chemistry" at their interior carbon atoms.
29 om a mixture of sp(2)- and sp(3)-coordinated carbon atoms.
30 is consistent with a fatty acid of about 10 carbon atoms.
31 ely large organic molecules containing 15-20 carbon atoms.
32 th unique eta(5) interactions involving meso-carbon atoms.
33 voring the ring carbon atoms over the linear carbon atoms.
34 lic olefins having ring sizes exceeding five carbon atoms.
35 1)-hydroxylated fatty acids comprising 26-34 carbon atoms.
36 e small optical absorption of a monolayer of carbon atoms.
37 red electron is delocalized over two carbene carbon atoms.
38 cally contain fatty acids (FAs) of 16 and 18 carbon atoms.
39 between two sterically encumbered quaternary carbon atoms.
40 eridine rings with adjacent tetrasubstituted carbon atoms.
41 alkyl chain of the bolaform has more than 14 carbon atoms.
42 yl-beta-hydroxy fatty acids comprising 60-90 carbon atoms.
43 gle bond rotation or through the loss of two carbon atoms.
44 ospholipids with hydrocarbon chains of 18-22 carbon atoms.
45 building blocks for bond formation to sp(3) carbon atoms.
46 ers with the carbon chain containing 2 to 10 carbon atoms.
47 ert alcohols into aldehydes elongated by two carbon atoms.
48 nked by an ethylene bridge between the alpha-carbon atoms.
49 to the bonding configuration of near-surface carbon atoms.
50 ies are extremely sensitive to the number of carbon atoms.
51 o sp(2) rehybridization of one of the alkyne carbon atoms.
52 g two different molecule lengths of 6 and 11 carbon atoms.
53 g constants, Aiso((13)C), for the individual carbon atoms.
54 construct C-C bonds between sp(3)-hybridized carbon atoms.
55 nd olefin migration can be sustained over 30 carbon atoms.
56 s of QMs produced following ESPT to aromatic carbon atoms: (1) reverse proton transfer (RPT) to regen
57 e ring are, the (1) coplanarity of the three carbon atoms, (2) relatively shorter (1.51 A) C-C bonds,
58 catecholamide units was increased from four carbon atoms (4-LICAM(4-)) to five, six and eight (5-, 6
59 re is an allylic substituent on the benzylic carbon atom, a chemoselective switch was observed, which
60 ction of a bond between two sp(3)-hybridized carbon atoms, a fundamental unit of organic chemistry, r
63 en-rich triazole features a highly polarized carbon atom allowing the complexation of anions by hydro
64 ally a nucleophilic substitution at an sp(2) carbon atom, allows the direct regioselective incorporat
65 roup that possesses a tertiary or quaternary carbon atom alpha to the carbon-zirconium bond can not b
66 planarization of the central tetracoordinate carbon atom and demonstrates the influence of bridgehead
68 onolayer of alkanethiols with a length of 11 carbon atoms and a carboxyl terminal group can efficient
70 lipid species were weighted by the number of carbon atoms and double bonds, the strongest inverse ass
71 ng the electronic structures of the adjacent carbon atoms and facilitates the adsorption of OER inter
72 wo or more contiguous stereogenic quaternary carbon atoms and key reactions in their total or partial
73 e between the electrophilic and nucleophilic carbon atoms and the structure of the phosphorus moiety.
75 ts that build up to form chains and rings of carbon atoms and ultimately form those well-known isolat
77 Most of these organic compounds retain 10 carbon atoms, and some of them are remarkably highly oxi
78 ations influence the phonon bands of bonding carbon atoms, and the discrepancies of phonon bands betw
80 that the bulky methyl-substituted bridgehead carbon atoms are attached to C2 and C3 of the 1,3-butadi
82 non-soap, amphiphilic molecules in which the carbon atoms are derived from annually renewable feedsto
83 e amino acids with alpha,alpha-disubstituted carbon atoms are described, including the discovery of o
84 lpha-hydroxylated acyl-chains of at least 24 carbon atoms are enriched in secretory vesicle subdomain
89 nd the discrepancies of phonon bands between carbon atoms are responsible for the remarkable drops in
93 as 1.6 nm, comprising only approximately 400 carbon atoms, are capable of housing stable photolumines
95 phene, which is a two-dimensional crystal of carbon atoms arranged in a hexagonal lattice, has attrac
96 sp hybridization of the ACP internal alkene carbon atom as controlling the regiochemistry of the ACP
97 ion, so it does not undergo 1,2-shift of the carbon atom, as observed in the acid-catalyzed reaction.
99 established the presence of an interstitial carbon atom at the center of the iron-molybdenum cofacto
101 rs, to form products containing a quaternary carbon atom at the nucleophile moiety and a tertiary car
102 ions of acetals having benzyloxy groups four carbon atoms away can be highly diastereoselective.
104 During SNAr, attack of a nucleophile at a carbon atom bearing a 'leaving group' leads to a negativ
105 han the competing process of addition to the carbon atom bearing a nucleofugal group (usually a halog
106 double-trifluoromethylated sp(3)-hybridized carbon atom between the two aromatic rings and 2) the tw
109 contain all-carbon quaternary stereocentres-carbon atoms bonded to four distinct carbon substituents
110 first reported example of a five-coordinate carbon atom bound only to separate (that is, monodentate
111 ew graphitic structure formed of rings of 10 carbon atoms bridged by carbene groups yielding seven-me
112 n sp(2)-to-sp(3) hybridization change of the carbon atom bridging the chromophore cyclic moieties was
113 s of four products having the same number of carbon atoms but slightly different hydrogen numbers ran
114 f imidazolines with a fully substituted beta-carbon atom by a Mannich-type addition/cyclization react
115 a temporary functional group at the terminal carbon atom by C-H bond functionalization, followed by t
117 nerate stable radical centers on the carbene carbon atoms by employing the so far hidden and unique a
118 itional isotopomer distribution of aspartate carbon atoms by gas chromatography/tandem mass spectrome
120 t semi-quantitative estimate of the oxidized carbon atoms by silver-based nanoparticles is achieved.
121 ween the methyl hydrogen atoms and the ortho carbon atom C(o) well below the van der Waals distance o
123 Br < CN < COOMe < PO(OEt)(2)], attack at the carbon atom C4 prevails, delivering the respective trans
124 that the combination of two unusual forms of carbon atoms can lead to unexpected chemical behavior, a
127 fects of organic substituents at the carbene carbon atom coordinated to the gold atom are evaluated f
134 sphorus substituent from the nitrogen to the carbon atom followed a retentive course with some racemi
137 s separated by two or three sp(3)-hybridized carbon atoms from the actual chromophore, solvation effe
139 o occur, while substitution at the exocyclic carbon atom has an impact on the reaction pathway and en
142 hene, a two-dimensional honeycomb lattice of carbon atoms, has been attracting much interest in recen
144 of O-doped benzorylenes, in which peripheral carbon atoms have been replaced by oxygen atoms, has bee
145 is- or trans-position of the terminal alkene carbon atom (hex-4-enyl and hex-4-enoyl substitution), t
146 ontained minor fatty acids with more than 20 carbon atoms, higher hydrocarbons and phytosterols.
147 r both highly unsaturated fatty acids (>/=20 carbon atoms) (HUFAs) and polyunsaturated fatty acids (>
148 ssing numerous contiguous, fully substituted carbon atoms (i.e., tertiary alcohols and quaternary cen
149 rmed the largest negative charge for the C12 carbon atom in antipodal position, in agreement with the
150 of pretreated barley straw adsorbent and pi* carbon atom in benzene ring attached to fluorine of levo
151 d by abstraction of a hydrogen atom from the carbon atom in gamma-position relative to the carbonyl o
153 induce undesired epimerization of the alpha-carbon atom in polyesters resulting in the loss of isota
154 ntroducing various coupling functions on one carbon atom in the beta-N position of the macrocycle, le
155 n the imino nitrogen (pathway "a") or on the carbon atom in the C horizontal lineN moiety of aroylimi
156 (CN) with acetylene, the replacement of the carbon atom in the cyano group by an isovalent silicon a
157 deuterated methyl groups at the distal (C3) carbon atom in the double bond under dissociative and as
158 i values were achieved by inserting an extra carbon atom in the linker connecting the N(9) atom of gu
159 ntioselective oxygen transfer from sulfur to carbon atom in the presence of chiral rhodium(II) carbox
161 aphene molecules, bearing more than 90 sp(2) carbon atoms in aromatic cores, is very challenging, whi
163 amide species with an even and odd number of carbon atoms in both chains were detected in all ceramid
164 the molecular weight and the exact number of carbon atoms in each molecule provides extremely accurat
165 embranes of the three domains, the number of carbon atoms in eubacteria was found to be similar to th
166 etries, (ii) inexpensive 4-31G basis set for carbon atoms in fc calculations, and (iii) individual pa
167 ron sites that are coordinated to sulfur and carbon atoms in FeMoco have been proposed to be the subs
169 data show exactly the opposite-the number of carbon atoms in lipids of eukaryotes was higher than in
170 ances of all isotopomers of ergosterol whose carbon atoms in the 5,7-diene moiety of the sterol skele
171 ) elucidate the isotopic affiliation between carbon atoms in the alkaloids and those in the precursor
172 rrier concentration by substituting specific carbon atoms in the hexagonal graphene lattice with p- o
174 zation of NBO hybridization coefficients for carbon atoms in the involved C-H bonds allows for a sign
175 carbon and CO components show clustering of carbon atoms in the melt at high pressures, hinting towa
176 wo or more contiguous stereogenic quaternary carbon atoms in their intricate structures are reviewed
178 of n-alkanethiolates SCn (with n = number of carbon atoms) incorporated in junctions having structure
179 on shows that the reactivity of the terminal carbon atoms increases with increasing numbers of alkyne
182 ose to the initial value of Atz, because the carbon atoms involved in the reaction step are not prese
183 n increase in the crowdedness of the central carbon atom is explained by differences in sp(3) charact
184 of molecules contacted via an sp-hybridized carbon atom is lower than the ones using sp(3) hybridiza
185 t the photochemical reactivity of a specific carbon atom is modified as a result of the presence of t
187 O25-Ice Proxy for the Southern Ocean with 25 carbon atoms-is proposed as a proxy name for diene II.
189 mainly involve motion of the pseudo-anomeric carbon atom, knowledge that should stimulate the design
191 ofuran (THF) ring at the stereogenic central carbon atom led to a significant shift in physicochemica
192 for the selective cyanation of the carbonyl carbon atom linked to the N atom of proline residues wit
193 enyl pyridine groups attached to two methano-carbon atoms located at the trans-1 positions was design
196 odes are attached to those positions of an N-carbon atom N-electron closed-shell hydrocarbon where th
197 observed POA was characterized by number of carbon atoms (NC), number of double bond equivalents (ND
198 kanethiolates having odd and even numbers of carbon atoms (nodd and neven) using junctions with the s
200 mall bite angles favor attack on the central carbon atom of an allenylpalladium intermediate to affor
201 The (13)C chemical shift of the central carbon atom of carbenes in their parent and protonated f
202 ce more downfield shift, whereas the central carbon atom of carbones will experience a lesser downfie
203 attack by a nucleophilic Pd-OH moiety on the carbon atom of coordinated micro-OCS2, which on deproton
205 synthase, AroA) is protonating the methylene carbon atom of phosphoenolpyruvate, or EPSP, in the reve
206 nosulfide radical with its boron atom to the carbon atom of the acetylene molecule, leading to the tr
208 s a base that abstracts a proton from the C2 carbon atom of the covalently bound subsite -1 glucosyl
210 ts as a nucleophile by attacking the central carbon atom of the isocyanate (interacting with the pi-s
215 elementary reactions with methane where the carbon atom of the product is oxidized and has a FOS les
218 contains the chemical formulas and retained carbon atoms of a wide range of trimethylsilyl and tert-
219 rbonyl has demonstrated that the boron-bound carbon atoms of all of these reaction products arise fro
220 tion of a single bond between the C2' and C6 carbon atoms of cis-resveratrol that generates a new cen
221 onic surfactants, with increasing numbers of carbon atoms of double chain surfactant, were analyzed o
222 valent functionalization degree of 3% of the carbon atoms of graphene is reached after 3-5 h of ion e
223 hene, a two-dimensional honeycomb lattice of carbon atoms of great interest in (opto)electronics and
224 ygenase that is able to act on two different carbon atoms of its C4-aminated substrate, allowing its
225 ists of a localized strain soliton where the carbon atoms of one graphene layer shift by the carbon-c
226 charged lipid headgroups and the very first carbon atoms of the acyl chains, at the PimA-phospholipi
227 ndary amine building block that contains all carbon atoms of the D and E ring of the natural product
228 extremely close contact between the central carbon atoms of the threaded hexayne chains (C...C dista
231 the atomic distance between reference alpha carbon atoms of transmembrane domains IV and V and I and
233 properties based purely on pi electrons from carbon atoms offer a fertile ground in the search for ex
234 he C horizontal lineC bond and at the iminic carbon atom on the chemoselectivity of the reduction was
238 caused an increase in the average number of carbon atoms per molecule of the HOMs, which is consiste
239 e of the FAD isoalloxazine with the anomeric carbon atom poised for nucleophilic attack by the FAD N5
240 well as atomic-resolution observation of the carbon atom positions between neighboring crystal grains
241 from the methylene (CH2OH) and methyl (CH3) carbon atom positions of the original ethanol, respectiv
242 amed 4-6 carbophene by authors, in which all carbon atoms possess sp(2) hybrid orbitals with some dis
243 we found that the efficient diffusion of the carbon atoms present at the interface between Cu and the
244 ally a nucleophilic substitution at an sp(2) carbon atom, proceeds by a concerted addition-eliminatio
245 omplex in which iron has bonds to sulfur and carbon atoms, providing a model for N2 coordination in t
247 that led to cyclopentenones with vicinal all-carbon-atom quaternary centers (see example; SEM=2-(trim
248 mmetric centers, one tertiary and one an all-carbon-atom quaternary stereocenter, in high yield and o
249 elective asymmetric synthesis of vicinal all-carbon-atom quaternary stereocenters is a challenging pr
251 nits, whereas the reactivity of the internal carbon atoms remains very low independent of the number
253 anotube sidewall segments with more than 200 carbon atoms represents a challenging task for tradition
259 ns, such as methyl transfer to electrophilic carbon atoms, sulfur to Calpha atom thioether bonds, or
260 In the series of complexes 3-5, the bridging carbon atom systematically changes its hybridization fro
261 phores Cy3 and Cy5 attached to DNA via three-carbon atom tethers, showing that they stacked onto the
262 aps, akin to s-p hybridization in an organic carbon atom that is beneficial to form stable species.
263 in a chiral molecule is an sp(3)-hybridized carbon atom that is connected to four different substitu
264 milies depending on the number of contiguous carbon atoms that constitute their central framework.
265 establish a CH/pi bond with one of the ortho carbon atoms (the C(o) side), leading to a characteristi
267 yyne, with up to 24 contiguous sp-hybridized carbon atoms, threaded through a variety of macrocycles.
268 ar spring that attracts the surrounding cage carbon atoms through strong interactions with the two mo
269 ayer below the 1st layer as the diffusion of carbon atoms through the Cu bulk after complete dehydrog
270 and iodine) are equivalently attached to two carbon atoms through three-center bonds, are well establ
271 th 1 via nucleophilic attack at the carbonyl carbon atom to give boryl-functionalized Fischer carbene
272 hanging the alkyl on phenone from a tertiary carbon atom to secondary to primary toward an unsubstitu
274 somer the distance between hydrogen atom and carbon atom to which it migrates in the result of the si
275 n approximately half of these compounds, the carbon atom to which the halogen is bound is sp(3) -hybr
276 ound enabled the assignment of the number of carbon atoms to each fragment signal and allowed the gen
279 n-enhanced wrinkles cause the aggregation of carbon atoms towards the inner edge and contribute to th
280 example of a four-electron reaction involves carbon atom transfer from BAC to create a cyanide ligand
281 n which gold is bound to a formally divalent carbon atom, typically formulated as gold carbenes or al
282 e, SAMs of alkylthiolates with more than ~12 carbon atoms undergo an abrupt change of orientation fro
283 ogy, in that more than half of the substrate carbon atoms undergo changes in bonding and hybridizatio
284 high yield, and the reactivity of meso-free carbon atom was demonstrated by carrying out functionali
285 saturated fatty acid chloride containing 18 carbon atoms was studied in order to obtain procyanidin
286 e group, the O atoms on the second and third carbon atoms were proved to be the most probable sites f
287 er (-C*HXR(2)) adjacent to the electrophilic carbon atom, were prepared and subjected to SN1-type sub
288 for the structural relaxation of graphene's carbon atoms when placed on a boron nitride substrate, a
289 SN2 reaction is its intolerance for tertiary carbon atoms: whereas primary and secondary alcohols are
290 hydride in 1 from the ruthenium to the meta-carbon atom, which generates 1'' with a frustrated Lewis
291 n-insensitive densities of ~18 branches/1000 carbon atoms, which are ~17 and ~3 times (conversion-dep
292 cycles containing a high proportion of sp(3)-carbon atoms, which confer precise spatial definition up
293 etic characteristic between the magnetic and carbon atoms, which leads to either ferromagnetic or ant
295 molecular gas-phase reaction of ground-state carbon atoms with 1,3,5-cycloheptatriene (C7 H8 ) on the
296 ) mediated fluorinations of aliphatic Csp(2)-carbon atoms with special focus on the opportunities pro
297 er goal, but complexes of highly substituted carbon atoms with transition metals are rare, and the fa
298 ate single-layer, two-dimensional network of carbon atoms with ultrasensitive sensing capabilities.
299 s activity against substrates with up to six carbon atoms, with optimal activity against propionaldeh
300 The better compound (TPP(+)C10) contained 10 carbon atoms within the linker chain and exhibited an IC
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