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1 te functionality via the ring opened primary carbon centered radical.
2 tom transfer (HAT), forming a tertiary alkyl carbon-centered radical.
3 nd 4 was investigated by EPR for oxygen- and carbon-centered radicals.
4 fides are particularly attractive sources of carbon-centered radicals.
5 tylenes are efficient for alkyne transfer on carbon-centered radicals.
6 litated hydrogen atom transfer and resultant carbon-centered radicals.
7 activation of the endoperoxide to cytotoxic carbon-centered radicals.
8 ts as well as the stability of the resulting carbon-centered radicals.
9 um ion trapping of photochemically generated carbon-centered radicals.
10 artemisinin (1) forms primary and secondary carbon-centered radicals.
11 pathways forming relatively stable alpha-oxa carbon-centered radicals.
12 ficient photochemical production of reactive carbon-centered radicals.
13 reaction is proceeding through addition of a carbon-centered radical across an olefin followed by oxi
14 ve a spectrum consistent with that of a POBN/carbon-centered radical adduct (aN=14.94+/-0.07 G and ab
16 trapping demonstrated that TBHP initiated a carbon-centered radical after 1 min of exposure in micro
17 ified two previously unrecognized classes of carbon-centered radicals, alkylaminocarbonyl and acyl ra
19 from a metal hydride to directly generate a carbon-centered radical appears to be the most reasonabl
20 ns are characteristic of a cationic process; carbon-centered radicals are not known to rearrange in t
21 mation through the reaction of O2 with alpha carbon-centered radicals at 1 atm of N2 are estimated as
22 tert-butylnitrone, which reacts rapidly with carbon-centered radicals but is unreactive with superoxi
23 nitrones were also found to efficiently trap carbon-centered radicals, but complex spectra were obser
24 rder assessment indicate the trapping of the carbon-centered radical by the enamine, to form the carb
25 alarial effects by iron-induced formation of carbon-centered radicals capable of alkylating heme and/
26 catalyzed cross-coupling reactions involving carbon-centered radicals, control experiments and spectr
29 and also prevented lipid peroxidation by the carbon-centered radical generator 2,2'-azobis(2-methyl p
31 steady-state mechanism for the formation of carbon-centered radicals in cigarette smoke involving NO
32 ot in general appear to be a major source of carbon-centered radicals in fresh mainstream cigarette s
33 e widely accepted mechanism of formation for carbon-centered radicals in the gas-phase cigarette smok
34 hat formation of either primary or secondary carbon-centered radicals is a necessary but insufficient
35 that the MNP adduct resulted from trapping a carbon-centered radical located on the aromatic ring of
36 radicals may transform intramolecularly into carbon-centered radicals located on the (alpha)C moiety
37 s (or H shifts) to form primary or secondary carbon-centered radicals rather than further reduction o
38 a second electron transfer step to reduce a carbon-centered radical, rendering the overall process r
41 studies suggested that the formation of the carbon-centered radical species occurred after or in con
42 d by copper bromide in step (ii) to afford a carbon-centered radical that is spin-trapped in situ by
43 hydrogen atom transfer (HAT) generation of a carbon-centered radical that leads to engagement of a ni
44 sorbed on ZSM-5 zeolites produces persistent carbon-centered radicals that can be readily observed by
45 sulfur center proteins, which then generates carbon-centered radicals that initiate lipid peroxidatio
46 aph (HPLC) used to separate a broad suite of carbon-centered radicals trapped as the O-alkylhydroxyla
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