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1 te, one of the most soluble forms of calcium carbonate.
2 s that can further react with CO to dimethyl carbonate.
3 cycle by sequestering volatile CO2 in solid carbonate.
4 haloperidol and the mood stabilizer lithium carbonate.
5 d by ring-opening polymerization of ethylene carbonate.
6 te, 60% high-Mg calcite, and 14% amorphous carbonate.
7 n storage by trapping injected CO2 as stable carbonates.
8 olution saturation with respect to secondary carbonates.
9 in the formation of core-shell structures in carbonates.
10 tetrahedral coordination, and polymerized di-carbonates.
11 tes, including organophosphates, esters, and carbonates.
12 This work assessed the effects of calcium carbonate (0.0-2.0%w/w CaCO3) on the morphology, crystal
13 search was to evaluate the effect of calcium carbonate (1%, 2%, and 4% of addition) at two different
14 ntation with vitamin D3 (1000 IU) or calcium carbonate (1200 mg elemental calcium) or both or neither
15 ide (21.0g.L(-1)), bicarbonate (4.0g.L(-1)), carbonate (4.0g.L(-1)), chloride (5.0g.L(-1)), citrate (
16 The direct observation of amorphous barium carbonate (ABC), which transforms into a previously unkn
17 itions and using an amorphous calcium-barium carbonate (ACBC) (Ca1-x Ba x CO3 .1.2H2 O) precursor.
18 mploys transient phases of amorphous calcium carbonate (ACC) in the construction of crystalline shell
19 hydrated and one anhydrous amorphous calcium carbonate (ACC); that these are formed in the tissue as
20 y be a hitherto unrecognised feature of fish carbonates across a wide range of neritic and oceanic se
21 enables the deposition of amorphous calcium carbonate, amorphous calcium phosphate, calcite and apat
22 of considerable lower reaction constants of carbonates, an inversion of relative reactivities betwee
23 of relative reactivities between aryl/alkyl carbonate and another leaving group of similar nucleofug
25 q rocks contain isotopically light carbon in carbonate and carbonaceous material, which occurs as gra
26 red the tolerability and efficacy of lithium carbonate and divalproex in 224 inpatients and outpatien
28 nontronite), Fe- and Mg-serpentine, Mg-Fe-Ca-carbonate and probable Fe-sulphide that likely formed in
29 y of bioinspired coprecipitation patterns of carbonate and silica, we develop a geometrical theory fo
30 first defluorinated to form soluble vinylene carbonate and vinoxyl species, which react to form both
31 rees for solvolysis of benzhydryl aryl/alkyl carbonates and benzhydryl carboxylates reveal that a giv
33 ethod was first applied to soluble inorganic carbonates and bicarbonates and then extended to insolub
34 e the (13)C/(12)C isotope ratio in inorganic carbonates and bicarbonates with applications in differe
36 ella-like ferrihydrite stalks to Fe (hydroxy)carbonates and Fe sulfides, as well as alteration of the
37 Pd intermediates, derived from allylic ester carbonates and palladium(0) catalyst, were found to unde
38 cal acidification, leading to dissolution of carbonates and release of phosphate, and via local stimu
39 he protocol uses highly modular vinyl cyclic carbonates and unactivated aromatic amine nucleophiles a
40 %, suggesting poly(3,4-dihydroxybutyric acid carbonate) and related derivatives may serve as platinum
42 4-iodoanisole as an arylating agent, sodium carbonate, and mesitylenic acid as additives in DMF solv
43 one step using formic acid, urea, guanidine carbonate, and phenylisocyanate, respectively, whereas 8
45 can recognize and extract the hydroxide and carbonate anions as their cesium salts, as confirmed by
46 xtend inland into density-stratified coastal carbonate aquifers containing a surprising diversity of
47 -red spectroscopy (DRIFTS) results show that carbonates are formed as intermediates when single suppo
49 re higher with the less reactive allylphenyl carbonates as chemoselective copper-hydride elimination
51 re we investigate the behaviour of pure iron carbonate at pressures over 100 GPa and temperatures ove
53 erved after cycling in the standard ethylene carbonate-based electrolyte are suppressed in the presen
54 rbonate (FEC) as an additive in the standard carbonate-based electrolyte for Li-ion batteries, the so
56 as anode and lithium hexafluorophosphate in carbonate-based electrolyte; a configuration correspondi
58 ivity toward liquid electrolytes, especially carbonate-based electrolytes, resulting in poor electroc
59 mantle by hydrous, oxidizing sulfate and/or carbonate-bearing fluids derived from subducting slabs.
60 least in part, by the melting of a subducted carbonate-bearing slab, and that 10 Ma younger carbonati
63 s are possible compared to manually prepared carbonate-bicarbonate eluents and with considerable savi
64 m fate of sequestered scCO2 , harbor a 'deep carbonated biosphere' with carbon cycling potential.
66 e report major declines in shallow fore-reef carbonate budgets, these shifting from strongly net posi
69 n-denaturing aqueous (phosphate, borate, and carbonate) buffers at various conditions of ionic streng
70 n-denaturing aqueous (phosphate, borate, and carbonate) buffers at various ionic strengths (I) on all
72 s for sodium and potassium ions in propylene carbonate by obtaining over 3 orders of magnitude greate
73 bicarbonates and then extended to insoluble carbonates by converting them to Na2CO3, following a sim
75 ase in dust (79-96%), occurs whether calcium carbonate (calcite) is present or not, although the incr
76 igates adding 50-500mg increments of calcium carbonate, calcium chloride, calcium citrate and calcium
77 Four calcium sources were studied: calcium carbonate, calcium citrate malate, calcium phosphate and
79 tion step by alkaline carbonates or hydrogen carbonates can completely suppress the formation of 3-MC
82 a sustained +2 per thousand increase in the carbonate carbon isotope (delta(13)C) record by approxim
84 tion is strongly debated, and the effects of carbonate chemistry changes in the geological past are p
87 mental and archaeological data, we show that carbonate clumped-isotope thermometry can be used to det
88 caprolactone) and poly(glycerol monostearate carbonate-co-caprolactone), and a cellulose/polyester co
90 the first monomeric, four-coordinate silicon carbonate complex 4 was isolated and fully characterized
91 on reactions for uranyl hydroxide and uranyl carbonate complexes to surface sites, the model can succ
94 for catalyzing conversion of CO2 into cyclic carbonate (conversion >95% at 100 degrees C and 1.2 MPa
95 a suggests that biological fixation of solid carbonate could have been relevant since the mid-Protero
96 ral types found in leaves: amorphous calcium carbonate cystoliths, calcium oxalates, and silica phyto
97 1.0 M LiPF6/ethylene carbonate (EC)/diethyl carbonate (DEC), reduction products on crystalline silic
98 norganic carbonate record dates the onset of carbonate deposition in the mid-Holocene in Kivu's deep
99 perconjugation on the solvolytic behavior of carbonate diesters has been investigated kinetically by
101 aragonite saturation horizon (ASH) and high carbonate dissolution rates there, fueled the hypothesis
102 nced by Omega arag, with greater net calcium carbonate dissolution under more acidic conditions.
103 emiarid soils: atmospheric pressure pumping, carbonate dissolution, and percolation of soil water thr
105 in a binary ethylene carbonate (EC)-dimethyl carbonate (DMC) 1:1 v/v solvent mixture, obtained by the
107 n had high positive loadings for fast foods, carbonated drinks, and refined grains, and high negative
108 ulations suggest that enhanced weathering of carbonates driven by glacio-eustatically controlled sea-
109 ntrated LiPF6 solutions in a binary ethylene carbonate (EC)-dimethyl carbonate (DMC) 1:1 v/v solvent
110 d a common electrolyte, 1.0 M LiPF6/ethylene carbonate (EC)/diethyl carbonate (DEC), reduction produc
111 up to 4.8 V vs Li/Li(+) on the first charge, carbonate electrolyte degradation negligibly contributes
112 ately 0.1 wt %) after synthesis, and not the carbonate electrolyte, we further show that, up to 4.8 V
113 which minimizes the corrosion reaction with carbonate electrolytes and suppresses dendrite formation
114 of our notion of oxidative decomposition of carbonate electrolytes on TMO surfaces and, more general
116 more versatile than current electrodialytic carbonate eluent generators and can easily generate sign
117 ion between propargylic alcohols and allylic carbonates, engaging vanadium and palladium catalysts, i
118 s, but bioavailability of nano-sized calcium carbonate-enriched-milk was significantly (P<0.05) bette
120 ssumed that stony corals precipitate calcium carbonate extracellularly as aragonite in a calcifying m
122 To elucidate the role of fluoroethylene carbonate (FEC) as an additive in the standard carbonate
123 n electrolyte additive (fluorinated ethylene carbonate - FEC) mediates the thickness and composition
131 the relatively positive delta(18)O values in carbonate from the same deposits that indicate low palae
132 we measured (87)Sr/(86)Sr and delta(13)C of carbonates from the Copenhagen Canyon section in Nevada,
133 h methyl iodide in the presence of potassium carbonate gave mono- and dialkylation products, and trea
134 ol)-block-poly(2-methyl-2-carboxyl-propylene carbonate-graft-dodecanol; PEG-PCD) to prepare micelles.
135 l)-block-poly (2-methyl-2-carboxyl-propylene carbonate-graft-SMART-graft-dodecanol) (abbreviated as P
137 tly intracellularly within polyphosphate and carbonate granules and resulted in the formation of core
138 data provide enhanced discrimination of the carbonate group compared to x-ray diffraction data, owin
139 al loading of U(VI), pH, and the presence of carbonate) has been systematically examined for U(VI) ad
141 -thick phyllosilicate-bearing layers along a carbonate-hosted seismogenic extensional fault in the ce
143 transforms into a previously unknown barium carbonate hydrate (herewith named gortatowskite) within
145 pervasive precipitation of microcrystalline carbonate (i.e. micrite) in microbial mats forming frame
148 e-haematite granules, and is associated with carbonate in direct contact with the putative microfossi
152 reduction reaction that could directly split carbonate into carbon monoxide and molecular oxygen via
154 ing measurable declines in surface ocean pH, carbonate ion concentration ([CO3(2-)]), and saturation
155 be excellent recorders of climate change, as carbonate ion concentration and temperature in the upper
156 pectrophotometric determinations of seawater carbonate ion concentrations ([CO3(2-)]spec) derived fro
158 have in turn decreased ocean pH and altered carbonate ion concentrations: so called ocean acidificat
163 supply the vast majority of the calcium and carbonate ions required for supersaturation with respect
164 metry and atomic charge were detected on the carbonate ions, implying that the proton migration is a
167 ray diffraction analysis showed that calcium carbonate is formed into the germ structure to 2.1 w/w o
168 Despite its size, the pool of lithospheric carbonate is not known to be a direct source for autotro
170 intrinsic barrier on solvolytic behavior of carbonates is more important than in the case of carboxy
171 xylates and that the enhancement of aromatic carbonates is more pronounced indicates that the negativ
172 ubstituted spiroketals from racemic, allylic carbonates is reported, which enables the installation o
173 e show that the presence of residual lithium carbonate (Li2CO3) on the surface of both Ni-rich Li-sto
174 tional groups appear to be out-competing the carbonate ligands associated with the aqueous U species.
178 e note that the explicit inclusion of sodium carbonate, mesitylenic acid, and solvent molecules on so
179 pes of enriched (calcium citrate and calcium carbonate) milks homogenized to a nano-sized particle di
180 capacity, severe acidification and increased carbonate mineral dissolution in the USA's largest estua
182 me and surface area of reactive minerals for carbonate mineral formation in geologic carbon sequestra
183 Marine tufa-columns, formed by the hydrated carbonate mineral ikaite, present a unique alkaline micr
184 the cement becomes less permeable because of carbonate mineral precipitation within the pore space.
186 d Sb can interact with calcite, a widespread carbonate mineral, through a coupled dissolution-precipi
189 g fluid-rock interaction, the dissolution of carbonate minerals in Eagle Ford shale leads to the phys
191 ore the identity and spatial distribution of carbonate minerals that form in dead-end one-dimensional
192 accelerated process for the precipitation of carbonate minerals was implemented in a sample of serpen
193 ommon view that the immobilization of CO2 as carbonate minerals within geologic reservoirs takes seve
194 hloric acid cause substantial dissolution of carbonate minerals, as expected, increasing effective fr
196 port the results of a study of molten sodium carbonate (Na2CO3) which combines high energy X-ray diff
197 odium fluoride (NaF) and the expected sodium carbonate (Na2CO3), as well as the desired reaction prod
198 re, based on the current results the calcium carbonate nano-sized enriched milk could be an effective
199 nt Iron Formation contain Fe-silicate and Fe-carbonate nanocrystal concentrations in cell interiors.
201 istinct layers of methane-derived authigenic carbonate nodules in the sediments indicate centurial to
202 a deep depression along the melting curve of carbonated oceanic crust at depths of approximately 300
203 Harnessing of Morita-Baylis-Hillman (MBH) carbonates of acetylenic aldehydes as handy synthons has
204 thanol with CO for the synthesis of dimethyl carbonate on metallic electrodes at low overpotentials.
207 ithiol to yield polymers containing either a carbonate or zwitterionic phosphocholine within the poly
208 il before the deodorization step by alkaline carbonates or hydrogen carbonates can completely suppres
209 ndolithic communities from intertidal marine carbonate outcrops present carbon isotopic signatures co
211 The migration of proton prefers an inter-carbonate pathway with an energy barrier of 8.0 kcal/mol
212 her eluent concentrations (at least to 40 mM carbonate), paving the way for future higher capacity co
219 n mature continental arcs that have accreted carbonate platforms, indicating that reworking of crusta
220 Copper inorganic complexes (hydroxides, carbonates) played a role in metal bioavailability in si
222 e a direct geomicrobial link between mineral carbonate pools and reduced organic carbon, which, given
223 Corrosion inhibitors can affect calcium carbonate precipitation and associated in situ and in-se
224 y (YKB), by coupling mineral equilibria with carbonate precipitation kinetics and rates of sedimentat
228 in The Bahamas has potentially reduced fish carbonate production by up to 58% in certain habitats, w
230 at the role of heat-tolerant foraminifera in carbonate production will most likely increase in future
231 sociated with basic anions, such as hydrogen carbonate, prolinate, and imidazolate, is an active cata
234 (ozone, chlorine dioxide, and phosphate and carbonate radicals) by correlating relative rate constan
240 -capped poly(potassium 3,4-dihydroxybutyrate carbonate) resulted in formation of the biomasses, beta-
243 mately 3,100 y before present (3.1 ka), when carbonate-rich sediments first appeared in the Holocene
244 o the strong phosphorus fixation capacity of carbonate-rich sediments, yet they form densely vegetate
249 te rosettes, apatite blades intergrown among carbonate rosettes and magnetite-haematite granules, and
250 occurs as graphitic inclusions in diagenetic carbonate rosettes, apatite blades intergrown among carb
251 cies (UO2(2+) and uranyl hydroxide(s) and/or carbonate(s)) and calculated the respective stability co
254 h density functional theory predict that the carbonate salt plays two important catalytic roles in th
255 mmonia-bearing hydrated minerals, water ice, carbonates, salts, and organic material indicates a very
256 situ values can be used to determine calcium carbonate saturation states that are in good agreement w
257 (delta (18)OC) measurements in foraminiferal carbonate shells can be combined to reconstruct seawater
258 enolith-derived geotherm also intersects the carbonate-silicate solidus, suggesting that partial melt
259 but also displays the rotational disorder on carbonate sites that is typical for high-temperature cal
260 embedded organic template structure within a carbonate skeleton of the foraminifera Orbulina universa
261 per capita added-sugars intakes derived from carbonated soft drinks fell 26% between 1997 and 2011 (f
263 igate the nature of these structures, sodium carbonate soluble pectins from strawberry fruits were di
264 fication of constituents from common organic carbonate solvent-based electrolyte systems in lithium i
265 benzhydryl carboxylates reveal that a given carbonate solvolyzes over the higher Marcus intrinsic ba
268 dolithic cyanobacteria use to excavate solid carbonates suggests that minerals could directly supply
269 ominant species are silicon-polyhedral bound carbonates, tetrahedral coordination, and polymerized di
271 lumped isotope behaviour in modern cold seep carbonates that must be considered when characterizing e
272 sence of halite, sodium sulfates, and sodium carbonates that were strongly correlated with kappa unde
273 ilibration of clumped isotopes in aragonitic carbonates, this allows specific processing, cooking or
274 s analysis, isotopic labeling, and a surface carbonate titration, we show that the presence of residu
275 id-state transformation of amorphous calcium carbonate to aragonite, demonstrating the co-existence o
277 bone mineral density portrayed by increased carbonate to phosphate ratio and decreased Phosphate to
278 plished by a facile low-temperature ammonium carbonate treatment, for significantly improved hydrogen
279 and subsequent CO2 production mediated by Pt carbonates under O2 (MS/IR) displays a first order depen
285 chically organized architectures for calcium carbonate (vaterite) can be controlled simply by adding
286 diversity varied as a function of substrate (carbonate versus sediment), activity (low activity versu
290 n an enantiomerically pure pyrrolidine-based carbonate was used, the reaction with phenols proceeds v
291 s a copolymer of ethylene oxide and ethylene carbonate, was synthesized by ring-opening polymerizatio
292 n 3 individuals randomly assigned to receive carbonated water (26-121 ng/mL; mean +/- SD: 60.7 +/- 52
294 Increased organic-carbon burial or enhanced carbonate weathering during glacioeustatic sea-level reg
295 which demonstrates how erosional forcing of carbonate weathering outweighs that of organic burial on
296 arita lithophora, both forming intracellular carbonates, were investigated in laboratory cultures.
297 es with N-substituted pyrroles and potassium carbonate which played a role of heterogeneous catalyst
298 tures, and is made of conchiolin and calcium carbonate, which provides protection from predators and
299 ining organic functional groups or inorganic carbonate, while uraninite and U((VI)) represent only mi
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