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1 ate-limiting attack by a hydroxide at a MIDA carbonyl carbon.
2 rotein catalysts of proton transfer at alpha-carbonyl carbon.
3 ard deprotonation of the alpha-hydroxy alpha-carbonyl carbon.
4 endant amines close (3.30 and 3.38 A) to the carbonyl carbon.
5 nsition state for proton transfer from alpha-carbonyl carbon.
6 glycolaldehyde labeled with carbon-13 at the carbonyl carbon ([1-(13)C]-GA) at pD 7.0 in the presence
7 glycolaldehyde labeled with carbon-13 at the carbonyl carbon ([1-(13)C]-GA) catalyzed by triosephosph
9 cts in the present investigation include the carbonyl carbon (13k = 1.028 +/- 0.001), the carbonyl ox
10 protonation of a wide range of neutral alpha-carbonyl carbon acids by hydroxide ion, from -0.40 to -1
14 bond of the acrylamide rather than the amide carbonyl carbon adjacent to the active site cysteine.
17 g methanol molecules, a methanol adds to the carbonyl carbon and a proton relay occurs with formation
18 limination of a nickel alkoxide, between the carbonyl carbon and either one of the carbons of the ole
19 was attributed to a weaker bond between the carbonyl carbon and the three-membered ring in the forme
20 is to 2'-AADPR by the attack of water on the carbonyl carbon, and (4) an SIR2-independent transesteri
21 isotopic substitution at the alpha-hydrogen, carbonyl carbon, and carbonyl oxygen of the amino acid,
22 Chemical shift anisotropies of F12 and V16 carbonyl carbons are uniaxially averaged in 1,2-dilauryl
23 s well as for the selective cyanation of the carbonyl carbon atom linked to the N atom of proline res
25 -enzymes show similar key features, with the carbonyl carbon atom of the cleaved beta-lactam bond cov
27 react with 1 via nucleophilic attack at the carbonyl carbon atom to give boryl-functionalized Fische
30 carbonyl showed that almost all Tyr and Leu carbonyl carbon atoms were approximately 0.5 nm from the
31 duct, wherein the no. 2 carbon (originally a carbonyl carbon) becomes substituted with -NH(2) and -OH
34 nded these (15)N assignments to the adjacent carbonyl carbons by means of one-dimensional (13)C[(15)N
35 of the 1,2-dithiolan-3-one 1-oxide ring, the carbonyl carbon (C3') and the sulfinyl sulfur (S1') of t
37 the C-terminal asparagine side chain on its carbonyl carbon, causing succinimide formation and simul
38 cular, the amide nitrogen, amide proton, and carbonyl carbon chemical shifts are highly sensitive to
39 e racemase inhibitor) reveal three different carbonyl carbon chemical-shift environments, arising fro
42 ack of the bridging water on the beta-lactam carbonyl carbon, electrostatic stabilisation of a negati
43 y was observed; only dihydropyrans where the carbonyl carbon forms a carbon-carbon bond with a carbon
44 addition of the hydroxide nucleophile to the carbonyl carbon in the substrate lactam ring leads to a
46 othane molecules are located below the lipid carbonyl carbons, in agreement with photolabeling experi
47 ion of the Gly67 amide nitrogen to the Ser65 carbonyl carbon is catalyzed by the protein fold and lea
49 at is highly tetrahedral (Dkobs = 0.79); the carbonyl-carbon KIE (13kobs = 1.031) is in agreement wit
51 ng rise to 20-30 protein atom types, such as carbonyl carbons, methyl groups, and hydroxyl groups.
53 H < 7, this carbanion reacts mainly with the carbonyl carbon of 1 to form a stable Claisen-type adduc
54 (H3 peptide substrate) directly attacks the carbonyl carbon of AcCoA, transferring the acetyl group
56 neral base, which then attacks the thioester carbonyl carbon of acetyl-CoA to yield a tetrahedral add
57 addition of the resulting gamma-anion to the carbonyl carbon of benzaldehyde, and intramolecular tran
58 amino group of L-ornithine which attacks the carbonyl carbon of carbamoyl phosphate in the enzyme-cat
60 dianion, which displays selectivity for the carbonyl carbon of chloromethyl carbonyl electrophiles.
61 odeled assuming a nucleophilic attack on the carbonyl carbon of D-Tyr by the Thr-80 O(gamma) atom and
62 sition the alpha amino group adjacent to the carbonyl carbon of esterified P site substrate in an ori
63 tack of an active site hydroxyl on the gamma-carbonyl carbon of gammaGlu-X with displacement of X.
64 complex, the active site serine attacks the carbonyl carbon of PNAA with general-base catalysis to f
65 ole complex of methanol weakly bonded to the carbonyl carbon of protonated acetyl chloride is stabili
66 it results in shorter distances between the carbonyl carbon of residue i and the amide nitrogen of r
68 erve to polarize the electrons away from the carbonyl carbon of the acyl group, thereby making it mor
70 ophilic attack of the phenolic oxygen on the carbonyl carbon of the acylpalladium complex with simult
71 tion of an adsorbed amide, which attacks the carbonyl carbon of the aldehyde, forming an adsorbed hem
72 accomplished by a nucleophilic attack at the carbonyl carbon of the amide linkage in the substrate, l
77 ullikan charge populations revealed that the carbonyl carbon of the highest-energy conformer was the
80 t carries out the nucleophilic attack on the carbonyl carbon of the scissile bond are present; it is
83 om Ser241 to Ser217, attack of Ser241 on the carbonyl carbon of the substrate, and elimination of the
84 r intermediate (the N-terminal amine and the carbonyl carbon of the thioester) increased as glycopept
86 ion of multiple methylene groups between the carbonyl carbons of readily available alpha-diketones to
88 and in silico docking studies show that both carbonyl carbons of the curcumin molecule are highly sus
89 stance between the gamma-methyl and backbone carbonyl carbons of Thr-87 is consistent with a gauche-
91 on involves nucleophilic water attack at the carbonyl carbon, proton transfer to the amide nitrogen l
92 so includes the AM1-calculated charge on the carbonyl carbon (q(C=)) and a calculated log octanol-wat
94 The carbon spectrum showed two peaks in the carbonyl carbon region of nearly equal intensities at -1
95 activated asparagine attacks its main-chain carbonyl carbon, the resulting oxyanion is stabilized by
96 Cys, Ser, or Thr side chain and the backbone carbonyl carbon to form a thiazoline, oxazoline, or meth
97 ogen (1.20 A) and partial bond loss from the carbonyl carbon to the amide leaving group (1.52 A).
98 217, and attack of Ser241 on the substrate's carbonyl carbon to yield a tetrahedral intermediate, whi
99 stance between the fluorine and the 3'-amide carbonyl carbon was 9.8 +/- 0.5 A, and the distance betw
101 OM contained significantly more aromatic and carbonyl carbons whereas Marine DOM was markedly enriche
103 of the Zn(II)-OH oxygen on the benzaldehyde carbonyl carbon, which has an O...C distance of 1.877 A.
104 ectrons at the electrophilic beta-carbon and carbonyl carbon, while a slight increase in electron den
105 ough-space electrostatic interactions of the carbonyl carbon with the Cl ligands bound to Si, rather
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