ライフサイエンスコーパス: carboxylate

1 he N-terminus of the peptide to a side chain carboxylate.

2 WJ379 was also synergistic with oseltamivir carboxylate.

3 cond beta-hydride elimination to furnish the carboxylate.

4 are generally lower for carbonates than for carboxylates.

5 iral recognition of alpha-amino acid-derived carboxylates.

6 red nucleophiles that react with CO2 to form carboxylates.

7 photocycloaddition of 2,3-dihydropyridone-5-carboxylates.

8 e separation and detection of the respective carboxylates.

9 amples that is capable of oxidizing aromatic carboxylates.

10 quantify precursors that form perfluoroalkyl carboxylates.

11 sulfonates (-0.8-1.9, PFSAs), perfluoroalkyl carboxylates (-0.4-1.7, PFCAs), and PFPAs (0.2-1.5).

12 e addition of enolates derived from indenone-carboxylate 15 to 2H-azirines 1 led to the formation of

13 ted-6-methyl-1,2,3,4-tetrahy-dropyrimidine-5-carboxylates (16) were designed by bioisosteric replacem

14 oylcarbamoyl)-2',3-dinitro-[1,1'-biphenyl]-4-carboxylate ( 26: ) preferentially inhibited viruses enc

15 oylcarbamoyl)-2',3-dinitro-[1,1'-biphenyl]-4-carboxylate ( 27: ) acts both on adamantane-sensitive an

16 through the intermediate 5-methylphenazine-1-carboxylate (5-Me-PCA), a reactive compound that has elu

17 ng experiments with methyl 1-methylpyrrole-2-carboxylate (6).

18 Our results reveal that alkylaminium carboxylate aerosols exhibit distinct hygroscopic and de

19 (CCN) activity for a series of alkylaminium carboxylate aerosols have been measured using a hygrosco

20 picity parameter (kappa) of the alkylaminium carboxylate aerosols was derived from the HGF and CCN re

21 the considerably softer hydrogels made from carboxylated agarose use a scaffold of unpaired beta-str

22 further development of a series of thiophene carboxylate allosteric inhibitors of NS5B polymerase tha

23 tocols include the use of hypervalent iodide carboxylates alone or in conjunction with molecular iodi

24 le for these dramatic alterations are the Zn carboxylates (also known as Zn soaps) originated by the

25 model complexes showed that a mixed alkoxide/carboxylate aluminum intermediate preferentially opens c

26 to the family of ATP-binding and hydrolyzing carboxylate-amine ligases of the glutamine synthetase ty

27 by the deprotonation of Cys56-thiol by Glu47-carboxylate and (ii) a second thiol-disulfide exchange b

28 thway, a positive correlation between urea-1-carboxylate and AHR was observed in plasma metabolites,

29 mperature sodium-ion battery electrodes with carboxylate and carbonyl groups have been widely studied

30 terial benzyl (S)-2-methyl-4-oxopiperidine-1-carboxylate and employs an Overman rearrangement to cont

31 OO(-)], where Ca(2+) ions are bridged by the carboxylate and hydroxyl groups of lactate and the carbo

32 ate II, the complex has an unbonded dangling carboxylate and is six-coordinated while still diamagnet

33 In addition to metal carboxylate and methane coproducts, reactions with CdMe2

34 ular weights, (2) less aromaticity, (3) more carboxylate and N-containing COO functional groups, and

35 0 and pH 12, revealed shifts consistent with carboxylate and phenolate formation, but structural chan

36 nation of the lithium atom to the oxygens of carboxylate and sulfinyl units was proposed, being in ag

37 ion of a twisted peptide bond involving this carboxylate and the following tyrosine residue.

38 rboxylate oxygens), to the angle between the carboxylate and the ribose, and to the ribose's ring con

39 nding modes, varying with orientation of the carboxylate and thiol moieties.

40 ants in the presence of the NAIs oseltamivir carboxylate and zanamivir in MDCK cells.

41 2-oxo-2,3,6,7-tetrahydro-1H-1,3-diazepine-5-carboxylates and 5-acyl-2,3,6,7-tetrahydro-1H-1,3-diazep

42 g substrates, including even- and odd-carbon carboxylates and alcohols other than ethanol.

43 eagent (oil) and formation of products (lead carboxylates and glycerol) can be easily followed and qu

44 property relationship for hypervalent iodide carboxylates and halide initiators in both the free radi

45 s with itself to form a variety of hydrazine carboxylates and intercept intermediates of this reactio

46 likely metabolites such as n:3-fluorotelomer carboxylates and n:2-fluorotelomer sulfonamides.

47 Multidentate interactions with carboxylates and other electron-rich moieties are to be

48 onates is more important than in the case of carboxylates and phenolates.

49 4-Aminopyrrole-3-carboxylates and pyrazine-2-carboxylates were synthesize

50 sistently >50% for long-chain perfluoroalkyl carboxylates and sulfonates (>/=C8 and >/= C6, respectiv

51 ters solvolyze faster than the corresponding carboxylates and that the enhancement of aromatic carbon

52 The binding between the carboxylates and the AuNP surface is found to occur in t

53 plexes with a range of monounsaturated fatty carboxylates and their corresponding methyl esters.

54 ons with all carbon groups and with anionic (carboxylate) and amide oxygen are unfavorable, while KGl

55 rg(245) is crucial for binding the substrate carboxylate, and R245E/L mutations severely compromise a

56 enting the nondissociated acid form, and the carboxylate anion group, representing the dissociated fo

57 on of a 1:1 hydrogen-bonded complex with the carboxylate anion of Boc-d-proline.

58 The strong binding affinity between carboxylate anions and calcium cations in the formulatio

59 is that the carbonyl groups of the potassium carboxylate are responsible for the directed C-H activat

60 a-lactones is observed when cyclopentanone-2-carboxylates are converted in a cerium-catalyzed reactio

61 Carboxylates are the strongest HBAs studied, with beta p

62 dependent enzyme that is capable of directly carboxylating aromatic catechol substrates under ambient

63 the use of methyl bicyclo[2.2.1]hept-2-ene-2-carboxylate as the mediator are crucial for realizing th

64 ts in the formation of 1,2-dihydropyrazine-2-carboxylates as the main products, which can be converte

65 orbornene (methyl bicyclo[2.2.1]hept-2-ene-2-carboxylate) as a transient mediator has been developed

66 Computational studies on carboxylate-assisted C-H activation and functionalizatio

67 ided, and this outlines the understanding of carboxylate-assisted C-H activation in terms of the "amb

68 of catalytic C-H functionalization based on carboxylate-assisted C-H activation.

69 proposed to proceed by means of an external carboxylate-assisted concerted metalation/deprotonation

70 late intermediates is provided, unraveling a carboxylate-assisted formation of aryl-Co(III) masked-ca

71 g the protonation state change of adamantane carboxylate at pH 5.8, and (3) by a dual pH-photochemica

72 to the capsule in a J-shaped motif with the carboxylate at the equatorial region of the dimeric caps

73 nonanuclear [RE9(mu3-OH)12(mu3-O)2(O2C-)12] carboxylate-based cluster, points of extension matching

74 enolic porphyrins, instead of commonly known carboxylate-based types.

75 dues and probed each mutant with a series of carboxylate bases of similar pKa but varying size.

76 Ribose-carboxylate bidentate interactions in other folds are no

77 esent near the gold surface, indicating that carboxylate binding occurs as a 2e(-) L-type interaction

78 B structural elements and a highly conserved carboxylate-binding loop.

79 ccurs through the cleavage of strong hafnium-carboxylate bonds and is effected under mild conditions,

80 us electrolyte, an increase in the amount of carboxylate bonds at the interface, as a result of hydro

81 All of the carboxylates bound to the capsule in a J-shaped motif wi

82 gs using O2 is catalyzed by several non-heme carboxylate-bridged diiron enzymes.

83 from the substitution of the proline-derived carboxylate by a bromine atom.

84 nverted by a one-pot procedure to pyrazine-2-carboxylates by heating with catalytic amounts of TsOH.

85 ative population distributions of tautomeric carboxylate (C(-)) and phenoxide (P(-)) ions (m/z 137) g

86 sp(3) (aliphatic) C; sp(2) (aromatic, amide, carboxylate) C; amide and anionic (carboxylate) O; and a

87 via its C-4 carboxylate rather than the C-1 carboxylate/C-2 keto groups.

88 Without oleic acid impurities, cadmium carboxylate can be completely displaced from the surface

89 otentials between internal versus C-terminal carboxylates can be exploited towards obtaining C-termin

90 o current proposals, phosphine ligated Ag(I)-carboxylates can efficiently carry out C-H activation on

91 lectrochemical nanosensor based on assembled carboxylated carbon nanotubes (COOH-CNTs) and poly-L-lys

92 osphonate catalysts and fast bimolecular bis-carboxylate catalysts, have reached turnover frequencies

93 (1)H(alpha)-(13)C(alpha) dipolar tensor and carboxylate chemical shift anisotropy tensor of aspartat

94 of ATRP initiators via the phosphate-Zr(4+)-carboxylate chemistry.

95 linium ion intermediate by a chiral thiourea.carboxylate complex is both rate- and enantioselectivity

96 be the synthesis of a family of aryl-Co(III)-carboxylate complexes and their reactivity with ethyl di

97 Cobalt dialkyl and bis(carboxylate) complexes bearing alpha-diimine ligands hav

98 Elucidating the binding mode of carboxylate-containing ligands to gold nanoparticles (Au

99 lysis suggests that D210 and other conserved carboxylate-containing residues at the active site colla

100 Bisthiazolidines (BTZs) are carboxylate-containing, bicyclic compounds, considered a

101 Carboxylated (COOH) and aminated (NH2) polystyrene micro

102 Carboxylated corroles 3 and 4, which exhibited about 10-

103 or instance by stabilizing the corresponding carboxylate counterion.

104 eted liposomes were developed to deliver the carboxylated derivative, 5(6)-carboxy-DCFH2, to hepatocy

105 A set of carboxylate derivatives demonstrated markedly improved i

106 A number of catalysts (rhodium(II) carboxylate dimers, copper(I) triflate, and an iron(III)

107 In contrast, the l-BTZ carboxylate dominates interactions with the monozinc B2

108 ng ability of Z-1, i.e., more strongly bound carboxylate enantiomer as well as higher enantiomer conc

109 to elevate the CO2 concentration around the carboxylating enzyme ribulose bisphosphate carboxylase/o

110 able, often lower than the KM of the primary carboxylating enzyme Rubisco, and in order to photosynth

111 Seven silicon(IV) phthalocyanine carboxylate esters (SiPcs, 1-7) with non-, partially- an

112 Homoallylic boronate carboxylate esters derived from unsaturated aldehydes vi

113 econd boryl addition to give 1,3-diborylated carboxylate esters.

114 1-(dimethoxymethyl)-9H-pyrido[3,4-b]indole-3-carboxylate, formaldehyde, and primary amines.

115 P(t)Bu3 catalyzed synthesis of imidazolinium carboxylates from aryl iodides, imines, and carbon monox

116 The syntheses of carboxylates from petroleum feedstock require a series o

117 size 2-oxa-7-azabicyclo[4.1.0]hept-3-en-1-yl carboxylates from their corresponding 4-H-pyrans and spi

118 rthosteric agonists despite the absence of a carboxylate function.

119 cated that Eu(III) and U(VI) complexation to carboxylate functional group is the main mechanism for t

120 The introduction of ester and carboxylate functionalities at the bay region of the ace

121 However, masking both DON's amine and carboxylate functionalities imparted sufficient chemical

122 th benzoic acid derivatives during which the carboxylate functionality directs the alkyne to the orth

123 We conclude that carboxylated gallium corroles are promising chemotherape

124 Additionally, the labile carboxylate group allows water to bind early in the cata

125 is due to a strong hydrogen bond between the carboxylate group and 2H of the quinolinium ring, in add

126 in addition to a 1,5-interaction between the carboxylate group and the CC triple bond.

127 triad, with the next nearest residue to the carboxylate group being Arg60.

128 ion of CO2 is reported based on activating a carboxylate group in amino acid ionic liquids.

129 By replacing the carboxylate group in peramivir with a phosphonate group,

130 channel in an inverted orientation, with the carboxylate group interacting with Tyr-385 and Ser-530 a

131 ylate and hydroxyl groups of lactate and the carboxylate group of acetate to give a three-dimensional

132 We find that N1 and the C7 carboxylate group of QA ligate to Fea in a bidentate fas

133 g site on the indicator cross-linker and the carboxylate group of the analyte was still operative upo

134 8R-LOX, and both residues likely tether the carboxylate group of the substrate.

135 s at around 1740 and 1630-1600cm(-1) (due to carboxylate group stretching) and the DM of pectin in mo

136 no group while simultaneously activating the carboxylate group to interact with CO2 very efficiently.

137 e tert-butyl protecting group of the pendant carboxylate group was removed using trifluoroacetic acid

138 u polypyridyl compounds with carboxylic acid/carboxylate group(s) revealed that some were photoacids

139 rsible substitution of an amide group with a carboxylate group.

140 Carboxylate groups are ubiquitous in bioactive molecules

141 atic interactions between negatively charged carboxylate groups in the peptide and positively charged

142 MOF are pyrenes linked to the nodes via the carboxylate groups of benzoates.

143 se the oxygen atoms with sulfur atoms in the carboxylate groups of sodium terephthalate which improve

144 th its phosphate group at the site where the carboxylate groups of W also bind.

145 hermal stability of the trapped OC is due to carboxylate groups within it bonding to Mn oxide surface

146 apture of chromatin-bound proteins via their carboxylate groups, leaving the DNA accessible for subse

147 tal-organic framework (MOF) to generate free carboxylate groups, which serve as Bronsted acid sites f

148 d (BINA), attached to TiO2 nanoparticles via carboxylate groups.

149 4 owing to the joint presence of carboxy and carboxylate groups.

150 polymeric chains of Fe centers complexed to carboxylate groups.

151 role, and 2-methylallylsilane) to coumarin-3-carboxylates has been developed to afford chromanone-3-c

152 ,4a,8a-tetrahydro-2H,5H-pyrano[2,3-b]pyran-7-carboxylates have been obtained in high diastereoselecti

153 esidue to promote anion-pi interactions with carboxylate headgroups in fatty acids.

154 s contacts comparable to those of the distal carboxylate in kainate.

155 h2(OAc)4 catalysis provides 4-aminopyrrole-3-carboxylates in good yields.

156 es has been developed to afford chromanone-3-carboxylates in high yields as a single diastereomer.

157 eceptors demonstrated a high affinity toward carboxylates in very competitive DMSO/water mixtures.

158 methyl 7-aryl-6H-pyrrolo[3,4-c]pyridazine-5-carboxylates, including unprecedented heterocyclic skele

159 measured hygroscopicity of the alkylaminium carboxylates increases with decreasing acid to base rati

160 ptimization led to the identification of non-carboxylate inhibitors derived from pyrido[3,4-d]pyrimid

161 g the discovery of cell penetrant pyridine-4-carboxylate inhibitors of the KDM4 (JMJD2) and KDM5 (JAR

162 position by the eta(1)-CO2 ligand leads to a carboxylate intermediate, which further reacts with the

163 a intramolecular deprotonation of an iminium carboxylate intermediate.

164 he transformation of methyl 4-aminopyrrole-2-carboxylate into the corresponding diazo compound, follo

165 red spectroscopy suggests the involvement of carboxylate ion, and sidechain carbon-oxygen of aspartat

166 The formation of a carboxylate ionic bond at the interface is characterized

167 The formation of hydrogen bonds and carboxylate ionic bonds at the interface are observed.

168 st {Mn31} cluster (1) has been prepared from carboxylate ions and the chelating/bridging ligand alpha

169 iometric and kinetic studies that a (PPh3)Ag-carboxylate is responsible for the C-H activation step i

170 The kappa value for all alkylaminium carboxylates is in the range of 0.06-1.37 derived from t

171 mino acid, (R)-5,5-dimethyl thiazolidinium-4-carboxylate (L-DMTC) with simple Bronsted acid TFA is re

172 Diffusion studies of the carboxylate ligand into MOF-5 indicate that diffusion is

173 The structure suggests that a carboxylate ligand of the diiron centre may trigger homo

174 m a nucleophilic attack at a terminal eta(2)-carboxylate ligand of the zirconium catalyst, followed b

175 ction pathway, wherein a sterically hindered carboxylate ligand orchestrates an amine attack on a pal

176 re found to be activated by reduction of the carboxylate ligand to the corresponding alkoxide followe

177 The use of DAF in combination with other carboxylate ligands (CF3CO2(-) or tBuCO2(-)) also result

178 luster is completely passivated by bidentate carboxylate ligands exhibiting predominantly bridging bi

179 consistent with the loss of iron-complexing carboxylate ligands were observed, including decreases i

180 gle-crystal X-ray diffraction structure of a carboxylate-ligated indium phosphide magic-sized nanoclu

181 ization proceeds via intermediates that have carboxylate ligation in common, and a secondary cycle in

182 ainers constructed from divalent metal ions, carboxylate linkers, and sulfonylcalix[4]arene-based con

183 ) aptamer was first covalently conjugated to carboxylated-magnetic beads (MBs) using the succinimide

184 The structure reveals tyrosine- and carboxylate-mediated contacts acting as pH switches to r

185 which leads to an altered positioning of the carboxylate metal ligand, a resulting twisted peptide bo

186 sma levels of uncarboxylated MGP (ucMGP) and carboxylated MGP (cMGP) than controls.

187 found that the motion of negatively charged, carboxylated microspheres in mucus from pregnant patient

188 Both Mo-pic and (NEt4)[MoO(S2)2pyrimidine-2-carboxylate] (Mo-pym) are shown to be homogenous electro

189 e similarity but distinct differences in the carboxylate modes, indicating that the second electron r

190 h epoxy-/sulfate beads (85-86%), followed by carboxylate-modified beads (76-78%) and aldehyde-/sulfat

191 ies to epoxy-/sulfate, aldehyde-/sulfate, or carboxylate-modified beads with or without poly(ethylene

192 The carboxylate-modified beads with PEG provided the highest

193 lar SN2-type C-C bond formation in which the carboxylate moiety acts as a relay is disclosed.

194 hyperconjugation and pi-resonance within the carboxylate moiety is operative in TS.

195 s an oxidizing species that incorporates the carboxylate moiety.

196 lic acids are negatively charged nine-carbon carboxylated monosaccharides that often cap glycans on g

197 ures composed of gamma-Fe2O3 (maghemite) and carboxylated-multi walled carbon nanotube (cMWCNT) were

198 engineer this immunosensor, uniform layer of carboxylated multiwall carbon nanotubes (MWCNT) was depo

199 thylene green as electron transfer mediator, carboxylated-multiwall carbon nanotubes as electron tran

200 old nanoparticle based strip biosensors, the carboxylated MWCNTs were selected as the labeling substr

201 yloyloxy)-3-formylphenyl)-4-methylthiazole-5-carboxylate (NL-AC) was designed and synthesized as a co

202 R', R' = n-butyl, n-hexyl, n-octyl) (</=0.01 carboxylates nm(-2)).

203 c, amide, carboxylate) C; amide and anionic (carboxylate) O; and amide and cationic N-were determined

204 e, carbon dioxide, and sometimes pyrroline-5-carboxylate occurs.

205 nce of the strong reductant, dithionite, the carboxylate of 6-CP is esterified to generate 6-carboxyp

206 -hexahydro-4-((E)-pent-2-enyl)-2H-chromene-6-carboxylate of polyketide origin, with activity against

207 om hydrogen bond directly with the aspartate carboxylate of the E446D variant.

208 teraction between the Lewis-basic C-terminal carboxylate of the peptides with the distal arene of the

209 t between the Schiff base and the C-terminal carboxylate of the substrate, a position indicative of a

210 etal ion in the A site is coordinated by the carboxylate of two highly conserved acidic residues, wat

211 results in the attachment of the C-terminal carboxylate of ubiquitin to a lysine side chain in the p

212 ion of homogalacturonan, indicating that the carboxylates of galacturonic acid are key specificity de

213 o unknown chemical class, dihydroxymagnesium carboxylates [(OH)2MgO2CR](-), in meteoritic soluble org

214 able packing of oleates compared to branched carboxylates on the (100) facets of CdSe quantum dots.

215 and presence of additional negative charges (carboxylates) on the chelator, promoting renal clearance

216 egrees C, and the oxidation of 2-propanol to carboxylates only occurs in the presence of oxygen above

217 mpared to those stabilized by adsorbed metal carboxylate or phosphonate complexes or by ion pairs.

218 using a judiciously designed rigid octatopic carboxylate organic linker allowed the construction of e

219 A storage reduces ACC (1-aminocyclopropane-1-carboxylate) oxidase activity, ethylene production and r

220 elate with an upfield shift of the substrate carboxylate oxygen resonances.

221 A SAM carboxylate-oxygen is an M(+) ligand, and EPR and circul

222 (both ribose hydroxyls interacting with the carboxylate oxygens), to the angle between the carboxyla

223 -dependent reduction of Delta(1)-pyrroline-5-carboxylate (P5C) to proline.

224 A tetra(carboxylated) PCP pincer ligand has been synthesized as

225 s used as an internal standard and the three carboxylate peaks were resolved with baseline separation

226 magnitude lower than those of perfluoroalkyl carboxylates (PFCA) and perfluoroalkanesulfonates (PFSA)

227 Long-chained perfluoroalkyl carboxylates (PFCAs) in arctic foxes decreased with avai

228 sulfonates (PFSAs) and C7-14 perfluoroalkyl carboxylates (PFCAs) in snow but limited to the transite

229 ulfonamide (FOSA), and C8-C14 perfluoroalkyl carboxylates (PFCAs) were the most-recurrent analytes.

230 cluded four types of strongly ionized acids (carboxylates, phenolates, sulfonates, and sulfates), thr

231 Here, we utilized the carboxylate platform and chain elongation to produce n-b

232 Carboxylated polystyrene particles with a density and su

233 Carboxylate precatalysts were found to be activated by r

234 difluoro-4-azaspiro[2.4]hepta-1,4,6-triene-1-carboxylate, presumably via the corresponding ketenimine

235 tive sites were engineered using pyrrole and carboxylated pyrrole that was one-step electropolymerize

236 oordinates the active site metal via its C-4 carboxylate rather than the C-1 carboxylate/C-2 keto gro

237 Pyrroline-5-carboxylate reductase (PYCR) is the final enzyme in prol

238 Pyrroline-5-carboxylate reductase 1 and 2 (PYCR1, PYCR2) were identi

239 However, the fraction of total MGP that was carboxylated (relative cMGP concentration = cMGP/[cMGP +

240 rease in the equivalents of the nucleophilic carboxylate required for full conversion.

241 They uniquely retain the two carboxylate residues that define the vectorial proton pa

242 zhydryl aryl/alkyl carbonates and benzhydryl carboxylates reveal that a given carbonate solvolyzes ov

243 purine, cholesterol, microbiome, pyrroline-5-carboxylate, riboflavin, branch chain amino acid, peroxi

244 forms the pore entrance, which features two carboxylate rings; based on the ring dimensions and func

245 rugs with additional ester promoiety(ies) on carboxylate(s) were examined for their ability to delive

246 The copper isoquinoline-1-carboxylate salt was precipitated from the solution and

247 Palladium(II) carboxylate salts have been shown to catalyze the oxidat

248 rdination chemistry of DAF and palladium(II) carboxylate salts.

249 olyl 5-chloro-2-[ethylsulfonyl] pyrimidine-4-carboxylate [SBI-115]), and (3) a combination of SBI-115

250 By introducing two sulfur atoms to a single carboxylate scaffold, the molecular solid reaches a reve

251 Allene carboxylates, scarcely used as Michael acceptors, serve

252 ighly polar containing a phosphonate and two carboxylates, severely limiting its oral bioavailability

253 ilized within the conjugated uranium oxalate-carboxylate sheet.

254 and closed conformations plus an Asp residue carboxylate shift between monodentate and bidentate coor

255 esent Rossmann ribose-binding interaction: a carboxylate side chain at the tip of the second beta-str

256 active site, a conformational change of the carboxylate side chain metal ligand to allow for hydroge

257 drophobic residues (I170 and L230), over the carboxylate side chain of E165.

258 tional significance of the observed patch of carboxylate side chains and resulting metallocluster for

259 The selectivity filter is lined by the carboxylate side chains of a functionally important glut

260 The formation of Pb, Zn, and Cu carboxylates (soaps) has caused visible deterioration in

261 Chain elongation into medium-chain carboxylates, such as n-caproate and n-caprylate, with e

262 To completely displace the carboxylate surface ligands from cadmium selenide nanocr

263 tudy, we examined the phototransformation of carboxylated SWCNTs and associated amorphous carbon impu

264 The second-order rate constant for carboxylated SWCNTs reacting with (*)OH was estimated to

265 We found that while carboxylated SWCNTs were rather unreactive with respect

266 l characteristics similar to those of parent carboxylated SWCNTs whose amorphous carbon was removed b

267 Further studies using carboxylated SWCNTs with and without base washing indica

268 Delta-1-pyrroline-5-carboxylate synthase gene1 (P5CS1) is the key gene invol

269 he stress and ABA-induced Delta1-PYRROLINE-5-CARBOXYLATE SYNTHETASE1 (P5CS1) gene was previously show

270 nds to FBXO31 by tucking its free C-terminal carboxylate tail into an open cavity of the C-terminal F

271 f the thermodynamically less favored gaseous carboxylate tautomer or the thermodynamically more favor

272 Negatively charged carboxylate-terminated CDs (CD-CO2(-)) displayed little

273 with lead oleate at 60-150 degrees C to form carboxylate-terminated PbSe nanocrystals in quantitative

274 r and over the earlier transition state than carboxylate that produces an anion of similar stability.

275 in the B site is coordinated by the same two carboxylates that are affixed to the A metal ion as well

276 ntagonist ligands contain negatively charged carboxylates that interact with two key positively charg

277 Here, we show that LarB carboxylates the pyridinium ring of nicotinic acid adeni

278 s alkyl 4-alkoxy-5-amino-3-methylthiophene-2-carboxylates through the one-pot sequential reaction of

279 addition of 2-oxazoline- and 2-thiazoline 4-carboxylate to a nitroalkene proceeded to give either th

280 eacted with N-benzyl-cis-3-phenylaziridine-2-carboxylate to give the corresponding 4-methylenepyrroli

281 involve donation of electron density of the carboxylate to the C horizontal lineC bond as well hydro

282 ategy for catalytic vinyl transfer from enol carboxylates to activated secondary alcohol C-H bonds is

283 A novel rearrangement of 2-vinyl aziridine 2-carboxylates to unusual chiral cyclic sulfoximines is de

284 limidazole), is developed via the typical Zn-carboxylate type of linkage.

285 surface determinant system), it produces two carboxylate-type siderophores staphyloferrin A and staph

286 hyl (POC) while keeping the alpha- and gamma-carboxylates unsubstituted.

287 ze the selectivity switch of benzothiazole-2-carboxylates versus benzazine-3-ones/benzazine-2,3-dione

288 um leads to the formation of benzothiazole-2-carboxylates via the 5-endo-trig process contrary to Bal

289 ers of different end-terminal functionality (carboxylated vs. pyrrolidonated) by two phenotypically d

290 Glycosyl isoquinoline-1-carboxylate was developed as a novel benchtop stable and

291 oxide by an intermediate comprising multiple carboxylates was found to be rate-determining.

292 one such complex, N,N-dimethylimidazolium 2-carboxylate, was remarkably sensitive to solvent polarit

293 POC groups on both the phosphonate and alpha-carboxylate, we synthesized Tris-POC-2-PMPA (21b), which

294 stigate the functional role of the catalytic carboxylates, we generated mutant proteins catalysing me

295 verse ethyl 1,2,3,4-tetrahydroisoquinolone-3-carboxylates were accessible in good to excellent yields

296 4-Aminopyrrole-3-carboxylates and pyrazine-2-carboxylates were synthesized from 5-alkoxyisoxazoles an

297 2(mu-npCOO)2 (npCOO(-) = 1,8-naphthyridine-2-carboxylate), were synthesized and characterized.

298 was designed by bringing together coumarin-3-carboxylates with indoles and amines to afford indolylma

299 rved, independent of the supplied alcohol or carboxylate, with a strain related to Clostridium kluyve

300 8) conferred resistance to NAIs (oseltamivir carboxylate, zanamivir, or peramivir) as determined usin