ライフサイエンスコーパス: carboxylation

1 brum homolog increased the enzyme's kcat for carboxylation.

2 of quercetin do not involve induction of MGP carboxylation.

3 cture from alpha-helix to beta-sheet through carboxylation.

4 nd/or inhibition of matrix Gla protein (MGP) carboxylation.

5 d the effects of vitamin K deficiency on MGP carboxylation.

6 s it critical to understand the mechanism of carboxylation.

7 e is posttranslationally modified by N(zeta)-carboxylation.

8 such a way as to ensure efficient, specific carboxylation.

9 levels of epoxidation but substantially less carboxylation.

10 to lipogenic acetyl-CoA occurs via reductive carboxylation.

11 tamin K-dependent enzyme, which mediates MGP carboxylation.

12 ures the extent of intracellular VKD protein carboxylation.

13 ng r-VKORC1 is functional for supporting fIX carboxylation.

14 roline is used to make citrate via reductive carboxylation.

15 catalyze the first two reactions of epoxide carboxylation.

16 min K to indirectly inhibit host VKD protein carboxylation.

17 exchange was higher than k(cat) for acetone carboxylation.

18 t advances in understanding the mechanism of carboxylation.

19 ere VKOR is the rate-limiting step for gamma-carboxylation.

20 tributes to lipid biosynthesis via reductive carboxylation.

21 ctor carboxylation but do not ameliorate MGP carboxylation.

22 ete against anaplerotic enzymes for pyruvate carboxylation.

23 in alkene hydrocarbon production or aryl (de)carboxylation.

24 atures that change as a function of backbone carboxylation (28, 40, 50, 60, 80, and 93 %) from other

25 an exceptionally high capacity for reductive carboxylation, a metabolic pathway that has recently gar

26 cleavage occurred independently of its gamma-carboxylation, a posttranslational modification that is

27 They identify pyruvate carboxylation, a reaction that enables glucose-derived c

28 P requires to be activated by gamma-glutamyl carboxylation, a vitamin K-dependent reaction, to serve

29 gamma-Carboxylation activity was measured by incorporation of

30 on could not reverse the defect in reductive carboxylation activity.

31 ation associated with CO2 hydration and PEPC carboxylations alone, such that the dark period mesophyl

32 Cellular gamma-glutamyl carboxylation also exhibited differential VKOR inhibitio

33 t significantly decreased coagulation factor carboxylation and abolished MGP carboxylation at the phy

34 boxylase/oxygenase (RuBisCO) do not catalyze carboxylation and are designated RuBisCO-like proteins (

35 eries of urinary metabolites including omega-carboxylation and beta-oxidation products, as well as N-

36 d vitamin K cofactor required for continuous carboxylation and causes decreased carboxylase catalysis

37 tase (VKOR) reduces vitamin K to support the carboxylation and consequent activation of vitamin K-dep

38 olism, initiated by IDH1-dependent reductive carboxylation and culminating in suppression of mitochon

39 ns (i.e. low CO2 availability at the site of carboxylation and high temperature) inducing Rubisco-lim

40 ake, increased use of glutamine in reductive carboxylation and increased use of glutamine in generati

41 bles quantitative analysis of gamma-glutamyl carboxylation and its antagonism in live cells.

42 us deficient in their capacity for reductive carboxylation and may be compromised in their ability to

43 ulated to simultaneously enhance the rate of carboxylation and minimize oxygenation, a competitive re

44 wer than that of the spinach enzyme, but the carboxylation and oxygenation kinetic constants are near

45 lished temperature responses of both Rubisco carboxylation and oxygenation kinetics from a C4 plant,

46 measure the temperature responses of Rubisco carboxylation and oxygenation kinetics, PEPc carboxylati

47 BisCOs) are promiscuous, catalyzing not only carboxylation and oxygenation of d-ribulose 1,5-bisphosp

48 s at ambient and low oxygen showed that both carboxylation and oxygenation of Rubisco acted as the ma

49 target is Rubisco because it catalyses both carboxylation and oxygenation reactions and the majority

50 The studies illustrate the complexity of carboxylation and potential importance of component stoi

51 However, this resulted in incomplete gamma-carboxylation and propeptide cleavage where both process

52 while the oxygenation reaction competes with carboxylation and reduces photosynthetic productivity.

53 Enzymes related to the C4 shuttle, the carboxylation and regeneration phase of the Calvin cycle

54 ose) polymerase inhibitor protects reductive carboxylation and RPE viability from excessive oxidative

55 -VKORC1 expression increased the rate of fIX carboxylation and the extent of secreted carboxylated fI

56 and therefore overestimate CO2 available for carboxylation and underestimate photosynthetic responsiv

57 nation, arylation, alkylation, halogenation, carboxylation, and carbonylation), each representing a d

58 metformin via glutamine-dependent reductive carboxylation, and display reduced sensitivity to metfor

59 ydroquinone (KH(2)) epoxidation to drive Glu carboxylation, and one of its critical roles is to provi

60 he stabilization of intermediates, substrate carboxylation, and product release.

61 lase uses vitamin K epoxidation to drive Glu carboxylation, and the two half-reactions are coupled in

62 uch as tryptophan bromination, glutamic acid carboxylation, and threonine glycosylation.

63 y for achieving alkene 1,2-amino-acylation, -carboxylation, -arylation, -vinylation, and -alkynylatio

64 min K epoxide to support vitamin K-dependent carboxylation as efficiently as does VKORC1.

65 n for lipogenesis, in part through reductive carboxylation, as has been found previously in other cel

66 ation factor carboxylation and abolished MGP carboxylation at the physiological concentration of vita

67 t functionally critical substrates for gamma-carboxylation, at least in the developing embryo and neo

68 of oxaloacetate by phosphoenolpyruvate (PEP) carboxylation became evident from the patterns in de nov

69 nt in mammalian cells, and to understand why carboxylation becomes saturated, we developed an approac

70 can restore up to 60% of coagulation factor carboxylation but do not ameliorate MGP carboxylation.

71 in a C-terminal extension that directs gamma-carboxylation but is not found on the mature conotoxin.

72 O vs D(2)O) isotope effect (1.7) for acetone carboxylation but no discernible substrate (H(6)- vs D(6

73 ase (2-KPCC), the terminal enzyme of epoxide carboxylation, but not by addition of epoxyalkane:CoM tr

74 dition of the epsilon-subunit stimulated the carboxylation by 3.2- and 6.3-fold, respectively.

75 Reductive carboxylation by IDH1 was potently inhibited by NADP(+)

76 Supporting reductive carboxylation by supplementation with an NAD(+) precurso

77 mutant subunit did not inactivate reductive carboxylation by the wild-type subunit.

78 elationship for inhibition of gamma-glutamyl carboxylation by warfarin metabolites, observing toleran

79 saturated photosynthesis (A(sat), P = 0.09), carboxylation capacity (V(c,max), P = 0.82), or maximum

80 ed to determine the effect of temperature on carboxylation capacity (Vc,max ) and the light- and CO2

81 t intensity of 600 mumol m(-2) sec(-1) , the carboxylation capacity, electron transport capacity and

82 small subunits, which can also influence the carboxylation catalytic efficiency and CO(2)/O(2) specif

83 ssion is limited in vivo, possibly because a carboxylation component like the redox protein becomes s

84 Analysis in insect cells lacking endogenous carboxylation components showed that r-VKORC1 reduces KO

85 ycle, in which glutamine-dependent reductive carboxylation cooperates to the production of lipids and

86 the steric factor plays a major role in the carboxylation/decarboxylation process.

87 Loss of reductive carboxylation disrupts redox balance and increases RPE s

88 ic ether serves as an auxiliary for oxindole carboxylation (dr 5.2:1.0) that sets C10 configuration i

89 The resultant enzyme has decreases in carboxylation efficiency and CO(2)/O(2) specificity, des

90 This unprecedented carboxylation event is characterized by its simplicity,

91 The reductive carboxylation flux accounted for 90% of all flux of glut

92 bitor studies were compatible with reductive carboxylation flux through mitochondrial isocitrate dehy

93 lustrate a potential application, we use C-H carboxylation followed by protonation to convert 2-furoi

94 pyruvate dehydrogenase rather than pyruvate carboxylation followed by subsequent decarboxylation rea

95 The crucial role of PEP carboxylation for growth of S. suis in the host was supp

96 tion of free primary hydroxyls to carboxyls (carboxylation; HTT </= 500 degrees C), and their subsequ

97 onstrate that PRGP2 undergoes gamma-glutamyl carboxylation in a manner that is both dependent upon th

98 glycolysis and glutamine-dependent reductive carboxylation in cancer cells.

99 the presence of warfarin, vitamin K rescued carboxylation in HEK293 cells but not in AV12 cells.

100 n K epoxide reductase (VKOR-Y139F) supported carboxylation in HEK293 cells when fed KO in the presenc

101 te that entered mitochondrial metabolism via carboxylation in human islets was only 20-30% that in ra

102 These data support a role for glutamine carboxylation in maintaining citrate synthesis and cell

103 r show that VKORC1 is required for OCN gamma-carboxylation in osteoblasts, whereas its paralogue, VKO

104 water molecule may play an important role in carboxylation in OXA-24 (an analogous water molecule is

105 bility of reduced vitamin K may also control carboxylation in r-VKD protein-expressing cells, where t

106 The capacity for reductive carboxylation in RPE exceeds that of all other cells tes

107 tantly, knocking down NNT inhibits reductive carboxylation in SkMel5 and 786-O renal carcinoma cells.

108 sing by soluble rFurin did not preempt gamma-carboxylation in the ER and therefore was compartmentali

109 steps featuring a palladium-catalyzed phenyl carboxylation in the last step.

110 ces below the stomata to the site of initial carboxylation in the mesophyll.

111 NHC-CO(2) adducts were obtained by carboxylation in THF of related free NHCs (2), while the

112 lting in decreased KO reduction in cells and carboxylation in vitro.

113 hat r-VKORC1 reduces KO to efficiently drive carboxylation, indicating KH2 production.

114 We investigated how MGP carboxylation influences the risk of calciphylaxis in ad

115 The regiochemistry of the N2 carboxylation is controlled by the ansa-cyclopentadienyl

116 VKD protein carboxylation is inefficient in mammalian cells, and to

117 er microsomes, reduced RNase-triggered gamma-carboxylation is inhibited by the PDI inhibitor bacitrac

118 expression levels of VKD proteins, and where carboxylation is not improved by overexpression of r-car

119 The first structural rationale for acetone carboxylation is presented here, focusing on the 360 kDa

120 of enzyme inhibitors, the rate of acetyl-CoA carboxylation is the main determinant of the malonyl-CoA

121 d fIX approximately 2-fold, which shows that carboxylation is the rate-limiting step in fIX turnover

122 carboxylation and oxygenation kinetics, PEPc carboxylation kinetics, and the activity and first-order

123 st, anaerobic activation of naphthalene by a carboxylation-like mechanism by strain NaphS6 was linked

124 n (aCO2 ), with leaf photosynthesis strongly carboxylation-limited.

125 e, suggesting that deficiencies of reductive carboxylation may contribute to RPE cell death.

126 circumstantial evidence suggests that gamma-carboxylation may inhibit OCN endocrine functions, genet

127 on from substomatal cavities to the sites of carboxylation) may increase photosynthetic and water use

128 than with the changes in hexanal and protein carboxylation measured in the lamb cuts kept under prote

129 dependent upon the vitamin K-dependent gamma-carboxylation modification of MGP.

130 segues the ER targeted enhancement of gamma-carboxylation needed to biomanufacture coagulation prote

131 reactions such as halogenation, formylation, carboxylation, nitration, sulfonation, and others are di

132 evolutionary emphasis on increased rates of carboxylation observed in bacterial homologues.

133 he first formal evidence to prove that gamma-carboxylation occurs as a post-translational rather than

134 t copper-catalyzed oxidative dehydrogenative carboxylation (ODC) of unactivated alkanes with various

135 nzymes, catalyzes the reductive cleavage and carboxylation of 2-ketopropyl-coenzyme M [2-(2-ketopropy

136 Acetone carboxylase catalyzes the carboxylation of acetone to acetoacetate with concomitan

137 tone carboxylase catalyzes the ATP-dependent carboxylation of acetone to acetoacetate with the concom

138 , the cytosol and mitochondria, and although carboxylation of acetyl-CoA is the known mechanism for g

139 oA carboxylases (ACC1 and ACC2) catalyze the carboxylation of acetyl-CoA to form malonyl-CoA, an inte

140 ction in de novo synthesis of fatty acids is carboxylation of acetyl-CoA to form malonyl-CoA, catalyz

141 acetyl-CoA carboxylase, which catalyzes the carboxylation of acetyl-CoA to malonyl-CoA, the first an

142 cetyl-CoA carboxylase (ACC), which catalyzes carboxylation of acetyl-CoA to malonyl-CoA, the first an

143 ed by the enzyme gamma-carboxylase for gamma-carboxylation of all vitamin K-dependent (VKD) proteins.

144 novel Ni-catalyzed regiodivergent reductive carboxylation of allyl esters with CO2 has been develope

145 ender units are biosynthesized via reductive carboxylation of alpha, beta-unsaturated thioesters cata

146 ios) accompanied by an increase in reductive carboxylation of alpha-ketoglutarate (increased concentr

147 In addition, reductive carboxylation of alpha-ketoglutarate by isocitrate dehyd

148 ate cancer cells, SRC-2 stimulated reductive carboxylation of alpha-ketoglutarate to generate citrate

149 everse reaction of isocitrate dehydrogenase (carboxylation of alpha-KG to isocitrate).

150 aKG) and the NADPH/CO(2)-dependent reductive carboxylation of alphaKG to ICT.

151 nines were unable to carry out the reductive carboxylation of alphaKG.

152 toredox catalyst effects the selective alpha-carboxylation of amines that bear various functional gro

153 terocyclic carbene) catalytic system for the carboxylation of aromatic and heteroaromatic C-H bonds w

154 a significant progress has been made for the carboxylation of aryl and benzyl halides with CO2, becom

155 )-catalyzed reaction protocol for the direct carboxylation of benzoic and phenylacetic acid derivativ

156 A novel Ni-catalyzed carboxylation of benzyl halides with CO(2) has been deve

157 otin carboxylase catalyzes the ATP-dependent carboxylation of biotin and is one component of the mult

158 component, which catalyzes the ATP-dependent carboxylation of biotin using bicarbonate as the carboxy

159 component, which catalyzes the ATP-dependent carboxylation of biotin using bicarbonate as the donor.

160 rboxylases and catalyzes the MgATP-dependent carboxylation of biotin, using bicarbonate as the CO(2)

161 xylase component catalyzes the ATP-dependent carboxylation of biotin.

162 he carboxyphosphate intermediate for optimal carboxylation of biotin.

163 Rapid and direct: the carboxylation of boronic acid esters with (11)CO(2) prov

164 rein, we report on the enzyme-catalyzed para-carboxylation of catechols, employing 3,4-dihydroxybenzo

165 oxylase utilizes four substrates to catalyze carboxylation of certain glutamic acid residues in vitam

166 ality of this method was demonstrated by the carboxylation of estrone and by the synthesis of an unsy

167 Maximal gamma-glutamyl carboxylation of F9CH required vitamin K supplementation

168 ts with mutations in GGCX critical for gamma-carboxylation of gla-proteins.

169 The carboxylation of glutamic acid residues to gamma-carboxy

170 The reductive carboxylation of glutamine is part of the metabolic repr

171 CoA is produced via another route, reductive carboxylation of glutamine-derived alpha-ketoglutarate (

172 xia rely almost exclusively on the reductive carboxylation of glutamine-derived alpha-ketoglutarate f

173 The increased IDH2-dependent carboxylation of glutamine-derived alpha-ketoglutarate i

174 eased glutaminolysis but decreased reductive carboxylation of glutamine-derived alpha-ketoglutarate.

175 extend beyond that of a cofactor for the VKD carboxylation of glutamyl residues (Glus) to carboxylate

176 We also demonstrated that gamma-carboxylation of ligands is essential for the full activ

177 of reduced vitamin K are sufficient for full carboxylation of low, but not high, expression levels of

178 ates vitamin K hydroquinone to sustain gamma-carboxylation of many blood coagulation factors.

179 an essential cofactor for the gamma-glutamyl carboxylation of many clotting factors.

180 lyketide antibiotics are assembled by direct carboxylation of medium chain acyl-CoA thioesters.

181 reaction conditions are also amenable to the carboxylation of N-phenyl pyrrolidinones.

182 specific gene inactivation models that gamma-carboxylation of OCN by GGCX inhibits its endocrine func

183 nd esters that could not be generated by the carboxylation of organomagnesium compounds.

184 A Pd(II)-catalyzed reaction protocol for the carboxylation of ortho-C-H bonds in anilides to form N-a

185 The catalytic mechanism proposed for the carboxylation of oxamate is similar to that proposed for

186 , with the canonical UbiD catalyzing the (de)carboxylation of para-hydroxybenzoic acid-type substrate

187 conclude that the energy required for gamma-carboxylation of proteins is provided by dithiol-depende

188 talyzes the bicarbonate- and MgATP-dependent carboxylation of pyruvate to oxaloacetate, an important

189 Increased carboxylation of pyruvate via cytosolic malic enzyme (ME

190 In addition, the reverse reaction (reductive carboxylation of pyruvate) is also modulated by fumarate

191 oxamate is similar to that proposed for the carboxylation of pyruvate, which occurs via the formatio

192 red photosynthetic capacity (maximal rate of carboxylation of Rubisco (Vcmax ), and the maximum rate

193 and provides vitamin K hydroquinone for the carboxylation of select glutamic acid residues of the vi

194 A nickel-catalyzed reductive carboxylation of styrenes using CO2 has been developed.

195 The VKD gamma-carboxylation of the 5 essential VKD proteins in the liv

196 Carboxylation of the common substrate ribulose-1,5-bisph

197 stitutions of these residues perturbed gamma-carboxylation of the Gla-TxXI peptide.

198 ollowed by a second, slower nickel-catalyzed carboxylation of the in situ formed organozinc reagent.

199 tial for substrate recognition, that epsilon-carboxylation of the lysine of the stem peptide was not

200 ied into (PLGA)(n)-b-(carboxylated bPEI) via carboxylation of the primary amines.

201 plex, biotin carboxylase (BC), catalyzes the carboxylation of the protein-bound biotin moiety of anot

202 wn to trigger reduction of Vit.K>O and gamma-carboxylation of the synthetic gamma-carboxylase peptide

203 The bionanoconjugates were fabricated by carboxylation of the two-dimensional graphene oxide nano

204 Vitamin K is involved in the gamma-carboxylation of the vitamin K-dependent proteins, and v

205 -friendly Ni-catalyzed reductive cyclization/carboxylation of unactivated alkyl halides with CO2 is d

206 A Ni-catalyzed carboxylation of unactivated primary alkyl bromides and

207 A catalytic carboxylation of unactivated primary, secondary, and ter

208 ction conditions are also applicable for the carboxylation of vinyl C-H bonds.

209 Carboxylation of vitamin K-dependent (VKD) proteins is r

210 Gamma-carboxylation of vitamin K-dependent proteins is depende

211 amma-carboxylase in post-translational gamma-carboxylation of vitamin K-dependent proteins.

212 the substrate, 2-ketopropyl-coenzyme M, and carboxylation of what is thought to be an enzyme-stabili

213 rected mutagenesis did not affect either the carboxylation or epoxidation activity when the small FLE

214 l redox-dependent reactions of 2-KPCC (2-KPC carboxylation or protonation).

215 f organic acids, evolved to become the major carboxylation pathway for succinate production.

216 xylation and energy production away from the carboxylation pathway that leads to glucose production.

217 the citric acid cycle, whereas the reductive carboxylation pathway travels in reverse of the citric a

218 e the summed unit costs of transpiration and carboxylation' predicts leaf-internal/ambient CO2 ratios

219 eported copper-, silver-, and gold-catalyzed carboxylation processes of terminal alkynes are studied

220 ructurally diverse lipids generated from the carboxylation products of acetyl-CoA and propionyl-CoA.

221 We also developed C-H olefination and carboxylation protocols, demonstrating the applicability

222 only used organic halides as counterparts in carboxylation protocols.

223 tion, reduction and oxidation, substitution, carboxylation, radical-mediated, and rearrangements, whi

224 s(-1)) and ribulose-1:5-bisphosphate limited carboxylation rate (Jmax 213 mumol CO2 m(-2) s(-1)) unde

225 The maximum photosynthetic carboxylation rate (Vcmax ) is an influential plant trai

226 t CO2 ratios (ci /ca ) and slopes of maximum carboxylation rate (Vcmax ) or leaf nitrogen (Narea ) vs

227 ypically need a specification of the maximum carboxylation rate (Vcmax ).

228 or can be corrected by adjusting the maximum carboxylation rate (Vmax ) specified for tropical forest

229 eitol, VKOR overexpression increased the fIX carboxylation rate 14-fold, showing r-VKORC1 is function

230 tion, the lowest g NIL had 27% lower maximum carboxylation rate and 23% lower photosynthetic electron

231 thesis, in particular the parameters maximum carboxylation rate and maximum electron transport rate a

232 higher energy of activation than the maximum carboxylation rate and the CO2 compensation point in the

233 ree leaf traits (specific leaf area, maximum carboxylation rate at 25 degrees C, and maximum electron

234 n of non-native forms of Rubisco with higher carboxylation rate constants in vascular plants and the

235 is positively correlated with the mass-based carboxylation rate of mature leaves.

236 ut accounting for CO2 effects on the maximum carboxylation rate of photosynthesis and specific leaf a

237 e found to vary with [CO2 ] were the maximum carboxylation rate of photosynthesis and specific leaf a

238 tic efficiency as represented by the maximum carboxylation rate of Rubisco (Vmax), the maximum electr

239 nd six small subunit mutations that improved carboxylation rate, efficiency, and specificity.

240 Despite a doubling in the carboxylation rate, the photorespiratory flux increased

241 To achieve high carboxylation rates, psychrophilic diatoms increased Rub

242 tochondria use glutamine-dependent reductive carboxylation rather than oxidative metabolism as the ma

243 enerate citrate and lipids through reductive carboxylation (RC) of alpha-ketoglutarate (alphaKG).

244 A silanol-directed, palladium-catalyzed C-H carboxylation reaction of phenols to give salicylic acid

245 The described carboxylation reaction proceeds under mild conditions (a

246 ith the source(s) of NADPH for the reductive carboxylation reaction remaining unexplored.

247 loenzyme subunit, which catalyzes the second carboxylation reaction, have been solved in free form an

248 lizes the enolate biotin intermediate in the carboxylation reaction.

249 the proposed overall mechanism reveals that carboxylation reactions in acidic solutions will proceed

250 ing CO2 for heterogeneous C-H activation and carboxylation reactions on MOFs, and opens a new avenue

251 hesis of biotin, a vitamin required for many carboxylation reactions, is a variable trait in Saccharo

252 Propionibacterium shermanii that couples two carboxylation reactions, transferring CO(2)(-) from meth

253 rticipates in processes other than classical carboxylation reactions.

254 between donor and acceptor molecules during carboxylation reactions.

255 notoxins indicates the presence of the gamma-carboxylation recognition site within the postpeptide an

256 on involves a recognition element, the gamma-carboxylation recognition site, typically located within

257 e of OXA-24 can lower the energy barrier for carboxylation significantly.

258 boxylate proteins, osteoclasts determine the carboxylation status and function of osteocalcin.

259 MGP carboxylation status was not determined.

260 boxylase for some use other than VKD protein carboxylation, such as using the strong vitamin K base t

261 VKOR is the rate-limiting step in the gamma-carboxylation system and demonstrate successful engineer

262 The vitamin K-dependent gamma-carboxylation system in the endoplasmic reticulum membra

263 The vitamin K-dependent gamma-carboxylation system is responsible for post-translation

264 overexpress various components of the gamma-carboxylation system of the cell, to determine whether i

265 significantly impaired in the in vitro gamma-carboxylation system prepared from warfarin-resistant ra

266 tic cell harbors a vitamin K-dependent gamma-carboxylation system that converts the proteins to gamma

267 In this work, an in vitro gamma-carboxylation system was designed and used to understand

268 ning a recombinant vitamin K-dependent gamma-carboxylation system with enhanced capacity for gamma-ca

269 cing of calumenin, an inhibitor of the gamma-carboxylation system, enhances production of functional

270 cing enzyme of the vitamin K-dependent gamma-carboxylation system, produced 2.9-fold more functional

271 However increased activity of the gamma-carboxylation system, where VKOR provides the reduced vi

272 ed to also overexpress proteins of the gamma-carboxylation system.

273 understanding the vitamin K-dependent gamma-carboxylation system.

274 uggests human islets depend less on pyruvate carboxylation than rodent models that were used to estab

275 ry of a mild, operationally simple alternate carboxylation that occurs with a wide substrate scope em

276 RuBisCO has homologues that do not catalyze carboxylation; these are designated RuBisCO-like protein

277 de from lignocellulose, CO3(2-)-promoted C-H carboxylation thus reveals a way to transform inedible b

278 results in a reduction of matrix gla protein carboxylation, thus allowing peripheral mineralization t

279 provide carbon for anaplerosis and reductive carboxylation to citrate.

280 rgo dehydrogenation, reductive cleavage, and carboxylation to form acetoacetate in a three-step metab

281 dies, we show that biosynthesis occurs via N-carboxylation to form an initial N-carboxy-aminoacyl-S-P

282 KPC), which undergoes reductive cleavage and carboxylation to produce acetoacetate.

283 ity of wild type and mutant VKORs to support carboxylation, using intact membranes from cells coexpre

284 s greater CO(2)/O(2) specificity but a lower carboxylation V(max) than Chlamydomonas Rubisco, the hyb

285 These are the maximum rates of carboxylation (V(c,max)), whole-chain electron transport

286 al rates of RuBP (ribulose-1,5-bisphosphate) carboxylation (Vcmax ) and electron transport (Jmax ) at

287 e acclimation of the maximum rate of Rubisco carboxylation (Vcmax ), the maximum rate of electron tra

288 gher maximum velocity of phosphoenolpyruvate carboxylation, velocity of phosphoenolpyruvate regenerat

289 imum rate of phosphoenolpyruvate carboxylase carboxylation (Vpmax ), and foliar dark respiration (Rd

290 However, the k cat for H160A carboxylation was 8-9-fold lower than the wild-type enzy

291 mitochondrial pyruvate metabolism, pyruvate carboxylation was suppressed, and anaplerotic oxaloaceta

292 Ci-Gla1 undergoes gamma-glutamyl carboxylation when expressed in CHO cells and is homolog

293 ending on the degree of substitution (DS) of carboxylation, where [CMA] is the concentration of polym

294 stimulate glutamine oxidation and reductive carboxylation, whereas it inhibits glucose catabolism in

295 VKD proteins are activated by Glu carboxylation, which depends upon the oxygenation of vit

296 tial impact of quality control components on carboxylation, which occurs in the endoplasmic reticulum

297 acid cycle travels to citrate via reductive carboxylation while the remainder is oxidized through su

298 an essential enzyme for vitamin K-dependent carboxylation, while the physiological function of its p

299 These organocopper compounds will undergo carboxylation with CO(2) to form the corresponding coppe

300 The product of the initial acetyl-CoA carboxylation with CO2, malonyl-CoA, is further reduced