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1 lecular insights into malonate decarboxylase catalysis.
2 intermediates remains an enigma in chemical catalysis.
3 g the CN(-) ligands on FTIR spectroscopy and catalysis.
4 y that is opposite to traditional acid-based catalysis.
5 oles of these critical residues in PI3Kalpha catalysis.
6 ologies is accessible to small molecules for catalysis.
7 e Fe2+ in place of Mg2+ as a cofactor during catalysis.
8 s in potential applications in magnetism and catalysis.
9 dues participate in substrate binding and/or catalysis.
10 understanding the fundamentals of biological catalysis.
11 triction of the substrate may play a role in catalysis.
12 donuclease Cas9 during its activation toward catalysis.
13 h-energy conformation that is on-pathway for catalysis.
14 gy a real opportunity for the future of (bio)catalysis.
15 ons, notably in the science of heterogeneous catalysis.
16 tial residues used for substrate binding and catalysis.
17 s, optoelectronics, topological devices, and catalysis.
18 ding geometry that explains the slow rate of catalysis.
19 cond monomer provides residues essential for catalysis.
20 e the performances of MOFs in adsorption and catalysis.
21 iology and function in electron transfer and catalysis.
22 s decouple, proton pumping from the chemical catalysis.
23 de or H2O2 from the outset strongly enhances catalysis.
24 nctionalization of 1,3-dienes via Rh-hydride catalysis.
25 cific tasks, such as chemical separations or catalysis.
26 e purported correlation between dynamics and catalysis.
27 reported through the use of allyl-palladium catalysis.
28 es, that bind metal ions is important in RNA catalysis.
29 ajor electrostatic contribution to enzymatic catalysis.
30 nitro groups but are strongly activating for catalysis.
31 diseases, including signaling and enzymatic catalysis.
32 ication as electrodes for energy storage and catalysis.
33 s for various applications in bioimaging and catalysis.
34 n of grain-boundary effects in heterogeneous catalysis.
35 oting new reactivity paradigms in base-metal catalysis.
36 Mobius-type molecular hosts for sensing and catalysis.
37 nactive, additional factors are required for catalysis.
38 amically coupled to the chemical step during catalysis.
39 s, and diazo carbonyl compounds under Rh(II) catalysis.
40 tures that might be uniquely associated with catalysis.
41 5 phosphate termini of the strand breaks for catalysis.
42 sidues involved in substrate recognition and catalysis.
43 nt of heterogeneous asymmetric hydrogenation catalysis.
44 ins with aryl electrophiles using Pd and CuH catalysis.
45 transformation as well as its translation to catalysis.
46 , alleviating CO poisoning and promoting the catalysis.
47 icient hydrogen wave function overlap during catalysis.
48 POUT family, suggesting a novel mechanism of catalysis.
49 g GME in a variety of applications including catalysis.
50 cognition determinant that may favor RNase E catalysis.
51 illary ligands in homogeneous polymerization catalysis.
52 the N-terminal domain of Hsp90 required for catalysis.
53 e xenobiotics via not only binding, but also catalysis.
54 such as fuel cells, batteries, sensors, and catalysis.
55 otoredox, nickel, and hydrogen atom transfer catalysis.
56 nhTMEM16, except for changes at the site of catalysis.
57 the pyrophosphate leaving group for in-line catalysis.
58 al role in enantioselective transition-metal catalysis.
59 /support interface sites that play a role in catalysis.
60 ed to the desired allenes under CdI2 or ZnI2 catalysis.
61 hiral racemic reactants via transition metal catalysis.
62 energy pathways under water or sulfuric acid catalysis.
63 e mass-dependent vibrational modes linked to catalysis.
64 corporate the biological cofactor heme-B for catalysis.
65 the activity, and Mn(2+) alone also supports catalysis.
66 diazomalonyl)indolin-2-one under rhodium(II) catalysis.
67 strate binding (Cys96-Cys97) are involved in catalysis.
68 realigns active-site residues, accelerating catalysis.
69 poorly explored as the use of fullerenes in catalysis.
70 stability in air and water, an advantage for catalysis.
71 s storage and separation, ion conduction and catalysis.
72 he conformational changes implicit in rotary catalysis.
73 adical pathway, glutathione fully suppresses catalysis.
74 ich may lead to the discovery of new f-block catalysis.
75 lities are realized mostly through enzymatic catalysis.
76 gle metal center is directly involved in the catalysis.
77 lower the potentials for oxidation steps and catalysis.
78 Space and time are the essence of enzyme catalysis.
79 ired for correct lipid substrate binding and catalysis.
80 transfer pathways and mechanism of Na(+)-NQR catalysis.
81 used to test the role of protein dynamics in catalysis.
82 e of electron orbital filling in metal oxide catalysis.
83 chemistry, materials science, and industrial catalysis.
84 associated with metabolism of synthesis and catalysis.
85 esting it is a plausible intermediate of the catalysis.
86 s such as nanoelectronics, photovoltaics and catalysis.
87 ic insights in the arena of enantioselective catalysis.
88 merging ligand class for enantioselective Ni catalysis.
89 kely to be found in other examples of enzyme catalysis.
90 electromagnetic interference shielding, and catalysis.
91 lications for Pd-catalyzed aerobic oxidation catalysis: (1) The reaction tolerates heterocycles that
92 ll historical period of asymmetric oxidation catalysis (1970 to the present day) is covered; both tra
95 in harnessing the power of antibody-mediated catalysis against microbial antigens for host defense.
96 ized LPMO could support its desorption after catalysis and allow hydrolases to access the cleavage si
98 resent examples of indenylmetal complexes in catalysis and compare their reactivity to their cyclopen
101 ning attractive features of both homogeneous catalysis and enzymatic catalysis, led to a resurgence o
106 e transformation relies on the use of nickel catalysis and proceeds using sterically hindered tri- an
107 in, we provide a more detailed study of MftC catalysis and report a revised mechanism for MftC chemis
109 . without the Ubl2 domain, is sufficient for catalysis and stability in vitro with utility to evaluat
110 e several residues around the active site in catalysis and substrate binding, and support a structura
113 d by visible light photoredox initiated hole catalysis and the in situ Bronsted acid activation of th
114 lytically competent Cas9, which is prone for catalysis and whose experimental characterization is sti
121 and TERS in fields such as electrochemistry, catalysis, and SM electronics, which all benefit from th
122 mbly of the division complex, independent of catalysis, and that its biochemical activity in septum f
123 modifications, conformational fluctuations, catalysis, and transient protein-protein interactions.
126 ueprint toward the development of photoredox catalysis as a generic platform to target other redox-ac
127 ically, we demonstrate the use of photoredox catalysis as a platform to selectivity wherein the discr
128 es, which lend themselves to applications in catalysis as well as novel fundamental stoichiometric re
129 he elegant ligand design in heterobimetallic catalysis as well as sustainable photo-induced C-H trans
130 However, it remains an unsolved problem in catalysis, as typically it involves expensive or corrosi
132 ime in view of their diverse applications in catalysis; as anion, cation, and neutral substrate recep
133 which are scarcely used in enantioselective catalysis because of their sensitivity and lack of acces
134 ng supported nanocatalysts for heterogeneous catalysis because of their uniform particle sizes, contr
135 ns of light absorption, charge transport and catalysis between the colloidal semiconductor and molecu
143 leading to the suggestion that nucleophilic catalysis by triflate may be more common than generally
146 recise regulation of the DNAzyme's oxidative catalysis can be achieved by external stimuli (i.e., add
148 elease and enhanced dynamics associated with catalysis compensate for entropic losses from substrate
149 ently introduced synergistic gold(I)-silicon catalysis concept capable of producing simultaneously ca
150 as applications related to water splitting, catalysis, corrosion protection, degradation of pollutan
151 ftA* is the major product formed during MftC catalysis could have implications for the further elucid
152 in cells with abundant glucose, whereas the catalysis-defective D34S aldolase mutant, which still bi
153 Biochemical and structural studies show that catalysis depends on a Lys-Tyr-Asn-Tyr tetrad that emerg
154 le metal compounds have long been central in catalysis, Earth-abundant metal-based catalysts have in
155 lated with the nature of substrate including catalysis effect, lattice-mismatch-induced strain, and r
156 cesses such as crystal growth, heterogeneous catalysis, electrochemistry, or biological function.
157 the emergence of novel applications such as catalysis, electronics, nanomaterial synthesis and biose
158 ally important material with applications in catalysis, emissions control and solid-oxide fuel cells.
160 ce MXene-based materials for energy storage, catalysis, environmental, and biomedical applications.
162 examining the common principles that govern catalysis for different electrochemical reactions, we de
163 of the state of the art in heterobimetallic catalysis for sustainable organic syntheses (SOS), highl
165 function as a catalyst and show maximum NiPd catalysis for the hydrolysis of ammonia borane (H3 NBH3
166 ins a challenge for addressing key issues in catalysis, for example, the efficiency of catalysts due
170 lytic protocol using both Pd and isothiourea catalysis has been developed for the enantioselective sy
172 actions has been successfully disclosed, and catalysis has been examined for each metal starting with
174 widespread application of this technology in catalysis has been limited by the relatively poor chemic
178 ials are important in many fields, including catalysis, imaging, and drug delivery, mainly due to the
181 anisms underlying thermoadaptation of enzyme catalysis in adenylate kinase using ancestral sequence r
187 ing the one-electron chemistry of photoredox catalysis in tandem with low-valent cobalt catalysts, ne
188 chieve an appropriate conformation for lyase catalysis in this system that is precluded in the conven
189 state and transition state effects in enzyme catalysis in unprecedented detail, providing a molecular
190 ng organic base was eliminated by performing catalysis in water owing to the change in mechanism.
191 latter include examples of remarkable enzyme catalysis including an unusual cytidilation reaction and
194 lustrating the unexpected Pb(2+)-accelerated catalysis, intrinsic tertiary interactions, and molecula
195 ing in thicker bilayers, suggesting that BAM catalysis involves lowering of the kinetic barrier impos
196 ormed, which are consistent with auto-tandem catalysis involving atom-transfer radical cyclization fo
200 atalyst, a MAD1:C-MAD2 tetramer, but how the catalysis is executed and regulated remains elusive.
203 e of the terpenoid cyclase as a template for catalysis is paramount to its function, and protein engi
204 Based on these observations, a model of GenK catalysis is proposed wherein free rotation of the radic
207 in solid oxide fuel cells, electrolysis and catalysis, it is desirable to obtain a better understand
208 )) and rate constants of overall homogeneous catalysis (kobs) determined from rotating ring-disk expe
209 of both homogeneous catalysis and enzymatic catalysis, led to a resurgence of interest in ArMs start
210 and Mn(III) in solution, and also inhibiting catalysis, likely through binding at or near the active
212 miting step of electrochemical CO2 reduction catalysis mediated by planar polycrystalline Au surfaces
213 c main group and transition metal chemistry, catalysis, medicinal chemistry and materials science.
215 fields in which spin-state is key, including catalysis, metallo-enzyme modeling studies, and host-gue
218 ment of organocatalysis and transition-metal catalysis, neither field has provided an adequate soluti
221 This Communication describes the photoredox catalysis of a C-C coupling reaction between 1-phenylpyr
222 ractions between particles chosen to allow a catalysis of a specific six-particle cluster from a spec
223 the chemical and/or physical environment or catalysis of an exergonic reaction, drives the system aw
224 t only visualizes the active site poised for catalysis of APOBEC3A, but pinpoints the residues that c
225 rtance of accessing CT states for photoredox catalysis of atom transfer radical polymerization lies i
227 sequentially concealed or revealed, enabling catalysis of both steps of a tandem reaction process.
228 lithium-ion batteries, sodium-ion batteries, catalysis of hydrogen evolution, oxygen evolution, CO2 r
229 role in surface reactions and heterogeneous catalysis of metal atoms with low coordination numbers,
230 may be used to significantly improve the HER catalysis of MoS2 in all kinds of environments from acid
231 ricted to pyoverdine-producing bacteria, its catalysis of periplasmic transaminations is most likely
232 ent at C10 of AA play a critical role in the catalysis of prostaglandin and thromboxane synthesis.
234 to this important class of compounds, their catalysis of Si-O bond hydrolysis and condensation was i
235 xygen reduction to evaluate the laccase-like catalysis of the materials, among which gamma-MnO2 exhib
236 way) with a branched-chain fatty acid by the catalysis of the putative enzyme capsaicinoid synthase.
237 ransfer is involved in preventing accidental catalysis of the reverse reaction, as conditions that de
238 onsequences of increased or decreased Pol II catalysis on gene expression in Saccharomyces cerevisiae
240 the possibility of light-activated chemical catalysis on surfaces of strongly plasmonic metal nanopa
243 ll also open new possibilities in metal-free catalysis or organic crystal engineering, where double-H
244 could enable protein engineering to improve catalysis or to introduce decarboxylation activity into
245 nomy, but it is almost impossible by thermal catalysis owing to the significant thermodynamic barrier
248 chloroform at 100 degrees C under Rh2(OAc)4 catalysis provides 4-aminopyrrole-3-carboxylates in good
251 determination of ancillary ligand effects on catalysis rate and, in some cases, even provide mechanis
252 mization under uncertainty for heterogeneous catalysis reaction networks using surrogate models that
253 determination of rate constants in the total catalysis regime is a prerequisite for the rational benc
255 ndamental challenge in surface chemistry and catalysis relates to the determination of three-dimensio
259 pplications of MOFs, such as in gas storage, catalysis, sensing and drug delivery, electrical semicon
260 organic frameworks (COFs) are promising for catalysis, sensing, gas storage, adsorption, optoelectri
262 Nanoscience has revolutionized the world of catalysis since it was observed that very small Au nanop
265 ty issues in view of recent findings on LPMO catalysis, such as the involvement of H2O2 Our results s
269 ectrophile over the average turnover time of catalysis, the in situ formed neutral mono- and bis-alky
272 ntaining modified tetrapyrrole that promotes catalysis through a methyl radical/Ni(ii)-thiolate inter
273 the conditions and solvent dependence of the catalysis through NMR monitoring, with mechanistic insig
274 diverse effects of the TL basic residues on catalysis through their effects on positioning reactants
275 factant removal to obtain clean surfaces for catalysis through traditional approaches (such as solven
277 rer-type transformation using phase-transfer catalysis to deliver enantioenriched sulfur-bearing hete
280 dolase RA95.5-8, for example, exploits amine catalysis to promote mechanistically diverse carboligati
282 herefore be used, with nickel- or iron-based catalysis, to extract carbon dioxide from a carboxylic a
283 aromatic and vinyl halides, under palladium catalysis, to produce 4-substituted homopropargyl alcoho
284 icrocomposite also displays high performance catalysis towards electroreduction of H2O2 with a high s
285 n iterative application of asymmetric copper catalysis towards the synthesis of six distinct oligomer
286 ch as conformational fluctuations, multistep catalysis, transient interactions, folding, and alloster
287 lthough perovskites have been widely used in catalysis, tuning of their surface termination to contro
289 we demonstrate excited-state organometallic catalysis via such an activation pathway: Energy transfe
293 catalyst is redox inert before the onset of catalysis, which coincides with the formation of Fe(4+)
294 ns utilizes a unique non-catalytic triad for catalysis, which could be exploited for therapeutics.
295 only the prFMN(iminium) form is relevant to catalysis, which requires transient cycloaddition betwee
296 connects high atom-efficiency C-H/C-H green catalysis with dye-sensitized solar cell applications.
298 dase, to determine the kinetics of complex I catalysis with ubiquinones of varying isoprenoid chain l
299 ble, to describe the enzymatic mechanisms of catalysis within the context of their synthetic counterp
300 Mechanistic studies show 3 acts directly in catalysis without any ligand dissociation and DFT calcul
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