ライフサイエンスコーパス: catalytic reaction

1 C/C-substrate interactions and stimulate its catalytic reaction.

2 s the key reason for stereoinduction in this catalytic reaction.

3 the formation of various products during the catalytic reaction.

4 chanism of a representative cooperative dual-catalytic reaction.

5 involved in spliceosomal activation and the catalytic reaction.

6 -S bond) is very labile during the multistep catalytic reaction.

7 t carbon monoxide is the only product of the catalytic reaction.

8 nds to 2D nanocrystals, even for a different catalytic reaction.

9 ield-dipole effect on the selectivity of the catalytic reaction.

10 e favorable to the three-phase heterogeneous catalytic reaction.

11 , consistent with the values obtained in the catalytic reaction.

12 wide range of species that could inhibit the catalytic reaction.

13 6) reveal k(H)/k(D) = 1.8(4) for the overall catalytic reaction.

14 ,8-dihydropterin pyrophosphokinase (HPPK) in catalytic reaction.

15 uggesting that loop>J may participate in the catalytic reaction.

16 itutes the initial step in the proposed LRAT catalytic reaction.

17 of trifluoroacetic acid is crucial for this catalytic reaction.

18 ies to fulfill the requirements of a defined catalytic reaction.

19 ficity of one such strand displacement-based catalytic reaction.

20 e use toehold exchange to construct a simple catalytic reaction.

21 her proposed intermediates in a hypothetical catalytic reaction.

22 te inhibits rather than enhances the rate of catalytic reaction.

23 es in the electrostatic potential during the catalytic reaction.

24 139 may also play important roles during the catalytic reaction.

25 hydroxyl from the substrate to initiate the catalytic reaction.

26 detection by analysis of the products of the catalytic reaction.

27 in combination for the first time to study a catalytic reaction.

28 of residues may play a dual role during the catalytic reaction.

29 idation is the turnover-limiting step of the catalytic reaction.

30 ing and bond-breaking events that occur in a catalytic reaction.

31 st that a loop-gating mechanism controls the catalytic reaction.

32 protocol with the purpose of expediting the catalytic reaction.

33 rotein dynamics and free energy landscape of catalytic reaction.

34 posing chains and how they contribute to the catalytic reaction.

35 nsible for the stereochemical outcome of the catalytic reaction.

36 rial is expected to find wide application in catalytic reactions.

37 of this special active site for a variety of catalytic reactions.

38 , which contain the active sites controlling catalytic reactions.

39 al surfaces, and the energetics of important catalytic reactions.

40 ides have important applications in numerous catalytic reactions.

41 s applicable at low temperatures for various catalytic reactions.

42 of the {111} and {100} facets for important catalytic reactions.

43 d olefins, one emerging application of these catalytic reactions.

44 opportunities for time-resolved analysis of catalytic reactions.

45 l platform for in situ monitoring of surface catalytic reactions.

46 ffective way to enhance their performance in catalytic reactions.

47 ty of active metal-promoter combinations and catalytic reactions.

48 ll allows the particles to be accessible for catalytic reactions.

49 a central, often vexing issue in any and all catalytic reactions.

50 le structure and chemical state in oxidation catalytic reactions.

51 has important implications for heterogeneous catalytic reactions.

52 (Bpin)(3), are likely intermediates in these catalytic reactions.

53 the rates and selectivities to those of the catalytic reactions.

54 alysts, supporting their intermediacy in the catalytic reactions.

55 ble the direct participation of the oxide in catalytic reactions.

56 of bimetallic nanoparticle catalysts during catalytic reactions.

57 limit their application in high-temperature catalytic reactions.

58 nanoclusters in size- and structure-specific catalytic reactions.

59 mportant implications for the use of TiIV in catalytic reactions.

60 particle size and structure effects on given catalytic reactions.

61 wards first-principles design based on novel catalytic reactions.

62 l center would facilitate the development of catalytic reactions.

63 and presents mechanistic studies of selected catalytic reactions.

64 be sufficient for activating the systems for catalytic reactions.

65 xtendible to other nanoparticles and related catalytic reactions.

66 controlling the activity and selectivity of catalytic reactions.

67 positional resolved analysis of heterogenic catalytic reactions.

68 map, track, and fine-tune the performance of catalytic reactions.

69 osed could open up new opportunities for all catalytic reactions affected by water formation.

70 This catalytic reaction allows expedient syntheses of broadly

71 However, while FACLs perform a two-step catalytic reaction, AMP ligation followed by CoA ligatio

72 anorods at a temporal resolution of a single catalytic reaction and a spatial resolution of approxima

73 nanoclusters under conditions similar to the catalytic reaction and by detecting the R'-C identical w

74 ligand plays a key role in facilitating the catalytic reaction and enabling the aforementioned selec

75 dation of CO is the archetypal heterogeneous catalytic reaction and plays a central role in the advan

76 that Tyr 97 and His 138 are key residues for catalytic reaction and that a non-conserved beta3-beta4

77 ion between the decay of bromobenzene in the catalytic reaction and the predicted decay of bromobenze

78 stomize ILs with suitable pH (effective) for catalytic reactions and biotechnology applications such

79 atic series deal with the unusual aspects of catalytic reactions and electron transfer pathway organi

80 Therefore, it has been used to monitor catalytic reactions and is proposed to correlate the loc

81 ic understanding of several such cooperative catalytic reactions and the origin of cooperativity cont

82 based on a bi-molecular reaction motif with catalytic reactions and uniform reaction rates.

83 ighly selective oxide-metal interface during catalytic reaction, and the results demonstrate that cha

84 ructures, exhibit motility under appropriate catalytic reactions, and strongly adsorb to fluid-fluid

85 ingle-photon events with multielectron redox catalytic reactions, and such systems could have potenti

86 information about a variety of catalysts and catalytic reactions, and to also offer novel options for

87 major enantiomer and the selectivity of the catalytic reaction are related to the handedness and the

88 Mechanistic details of catalytic reactions are critical to the development of i

89 l design, functional framework synthesis and catalytic reactions are discussed along with some of the

90 ated precatalysts show that the rates of the catalytic reactions are independent of the identity and

91 robust approaches to quantitatively compare catalytic reactions are just beginning to appear.

92 Despite this, various aspects of catalytic reactions are not completely understood, such

93 The mechanisms for both catalytic reactions are proposed and supported by experi

94 quid sensing as well as on photochemical and catalytic reactions are reviewed.

95 are commonly measured in polar solvents but catalytic reactions are typically carried out in nonpola

96 Monitoring the catalytic reaction as a function of time revealed that b

97 the basis of kinetic studies on the overall catalytic reaction as well as each step in the catalytic

98 Hydrogenations of CO or CO2 are important catalytic reactions as they are interesting alternatives

99 l reaction scheme involving a proton-coupled catalytic reaction associated with proton-coupled electr

100 We quantify the turnover number of the catalytic reaction at the single soft nanoparticle level

101 al production is attributed primarily to the catalytic reactions at the nanoparticles' surface rather

102 To achieve high selectivity for catalytic reactions between two or more reactants on a h

103 Pd-Au, show superior performance in various catalytic reactions, but it has remained challenging to

104 In situ monitoring of the catalytic reaction by (1)H NMR spectroscopy coupled with

105 A highly potent inhibition of the peroxidase catalytic reaction by NO/SNO was seen in assays employin

106 gand substitutions may impact the outcome of catalytic reactions by modifying the acidities of the me

107 Here we show that such catalytic reactions can be achieved in cancer cells, off

108 fundamental studies on solvent extraction or catalytic reactions can lead to incorrect experimental d

109 uator networks, on-board fuel reservoirs and catalytic reaction chambers needed for movement are patt

110 Herein, we report an approach in which a catalytic reaction competes with a concomitant inactivat

111 The mild, catalytic reaction conditions are highly functional grou

112 M in dichloroethane (DCE), provides reliable catalytic reaction conditions for these rearrangements,

113 orinated intermediates were subjected to the catalytic reaction conditions, and it was concluded that

114 verages and are thus activated under typical catalytic reaction conditions.

115 harge displacement that occurs along the KSI catalytic reaction coordinate.

116 ction analog has been developed to mimic the catalytic reaction cycle of Delta(5)-3-ketosteroid isome

117 During the catalytic reaction cycle, GroEL undergoes a series of al

118 overs to its original structure for the next catalytic reaction cycle.

119 served Thr-201, and its contributions to the catalytic reaction cycle.

120 The full catalytic reaction cycles can be completed energetically

121 Higher stratospheric temperatures accelerate catalytic reaction cycles, particularly those of odd-nit

122 This catalytic reaction demonstrates the feasibility of switc

123 Together, we offer new insight into the catalytic reaction dynamics and associated catalyst redo

124 tal catalyst (e.g., copper) for liquid-phase catalytic reactions (e.g., hydrogenation of biomass-deri

125 reversible binding to form complexes, and by catalytic reactions (e.g., phosphorylation and dephospho

126 A copper/borinic acid dual catalytic reaction enabled the enantioselective propargy

127 ectrochemical promotion effect of a chemical catalytic reaction ("EPOC").

128 d Pt catalysts exhibited during an exemplary catalytic reaction-ethylene hydrogenation.

129 Nano- and microscale motors powered by catalytic reactions exhibit collective behavior such as

130 The catalytic reaction exhibits a bimolecular rate law with

131 lows first-order kinetics, while the overall catalytic reaction follows the second-order kinetics wit

132 into an extremely efficient and powerful new catalytic reaction for the formation of tetrahydrofurans

133 ccurrence of hitherto unknown regulatory and catalytic reactions for the selective in situ replacemen

134 based on the nature of coke formation during catalytic reactions, from saturated status (e.g., alipha

135 or T4lec during ppGalNAc-T2 and ppGalNAc-T3 catalytic reaction had a clear inhibitory effect on GalN

136 rsibility of a dehydrogenation/hydrogenation catalytic reaction has been an elusive target for homoge

137 y of such oxidative addition products in the catalytic reaction has been gained.

138 hat can measure the produced oxygen gas, the catalytic reaction has never been used for diagnostic ap

139 A very large spectrum of catalytic reactions has been successfully disclosed, and

140 Catalytic reactions have played an indispensable role in

141 In the catalytic reaction, horseradish peroxidase (HRP) enzyme

142 of an enzyme during the essential steps of a catalytic reaction (i.e., enzyme-substrate interaction,

143 olefins based on (i) its isolation from the catalytic reaction, (ii) its stoichiometric regioselecti

144 conclude that the energetic difficulty of a catalytic reaction, imposed by gas-phase reactant proton

145 this study, spectral mapping of a multistep catalytic reaction in a flow microreactor was performed

146 inder of the enzyme and solvent disfavor the catalytic reaction in both cases.

147 n MIMS provides a method to characterize the catalytic reaction in cell suspensions by detecting the

148 cted that establish the kinetic order of the catalytic reaction in each component, determine the rest

149 ion were designed to consume products of the catalytic reaction in order to push the equilibrium and

150 r movie of the structural changes during the catalytic reaction in photosystem II.

151 at low temperature, not only in the classic catalytic reaction in solution but also, unexpectedly, i

152 s is likely to be the first observation of a catalytic reaction in which nanoparticles function as a

153 ating the capability of the cell for probing catalytic reactions in controlled gaseous environments.

154 aled two fundamentally different pictures of catalytic reactions in solution.

155 ous feedback loop between various exothermic catalytic reactions in the nutrient layer and the mechan

156 se), the development of novel preferentially catalytic reactions in which alcohols are converted into

157 en developed in the form of non-covalent DNA catalytic reactions, in which single-stranded DNA (ssDNA

158 facilitated by each of the components in the catalytic reaction, including the ligand, TsOH, DMSO, su

159 nd, which will reduce the energy barrier for catalytic reactions, including CO oxidation.

160 er(III) is commonly invoked as a key step in catalytic reactions, including the century-old Ullmann r

161 Experiments on the catalytic reaction indicated that NaOt-Bu was necessary

162 The catalytic reaction induces thereby conformational change

163 ajor mechanisms have been proposed for these catalytic reactions: inner-sphere syn-addition and outer

164 species formed from ionic Cu in solution via catalytic reaction intermediated by reduced Cu(I) specie

165 A rapidly emerging set of catalytic reactions involves intermediates that contain

166 achieved by a new palladium-assisted tandem catalytic reaction involving N-tosylhydrazones, halo-sub

167 chiometric reactions and elementary steps of catalytic reactions involving cooperative participation

168 hase peptide radicals is analogous to enzyme catalytic reactions involving His and acidic amino acid

169 ied in situ, during oxidizing, reducing, and catalytic reactions involving NO, O2, CO, and H2 by x-ra

170 Many catalytic reactions involving small molecules, which are

171 The catalytic reaction is a true multicomponent condensation

172 The catalytic reaction is consistent with substrate water mo

173 The energetics of the catalytic reaction is first evaluated by density functio

174 ble complex, yet the major enantiomer of the catalytic reaction is formed from the more stable diaste

175 A mechanistic model for the catalytic reaction is presented.

176 tion; with a bulky substituent (R=tBu), this catalytic reaction is shut down, but the complex becomes

177 The proposed mechanism explains why the catalytic reaction is slower for unhindered substrates a

178 The catalytic reaction is terminated via the facile formatio

179 howed that the turnover-limiting step in the catalytic reaction is the C-H cleavage of cyclohexane by

180 e absence of excess amine (at the end of the catalytic reaction) is conversion to a metallacyclic spe

181 nine NG-hydroxylation (the first half of the catalytic reaction) is proposed in this Perspective.

182 an elevated K(m) for tetrahydropterin in the catalytic reaction, is reduced by tetrahydropterins with

183 ructure of certain DNA regions might promote catalytic reactions, leading to genomic instability.

184 ching the desired adducts through asymmetric catalytic reactions leads to a single carbon-carbon bond

185 Picolinate, the product of the physiological catalytic reaction, matches the properties deduced for t

186 the molecular dynamics simulations, a novel catalytic reaction mechanism for plant PPOs is proposed.

187 ese highly unusual aspects of the long-range catalytic reaction mediated by MauG.

188 ving oxygen atom exchange are fundamental in catalytic reactions mediated by metal oxides.

189 This catalytic reaction not only affords high enantioselectiv

190 Catalytic reaction occurring on S-AuNPs changes its perm

191 adical anions occur in solution, whereas the catalytic reaction occurs on the surface of lithium, whi

192 are inverse order in alpha-olefin; thus the catalytic reaction occurs, in part, because isomerizatio

193 observed in aldolase A, its function in the catalytic reaction of aldolase has not been demonstrated

194 onclude that Arg260 is not essential for the catalytic reaction of BS.

195 TyrOH + TyrO(*), to mimic a key step in the catalytic reaction of class Ia ribonucleotide reductase

196 acy of an alkyl radical was evidenced by the catalytic reaction of cyclohexane with benzamide in the

197 The effect of distant mutations on the catalytic reaction of dihydrofolate reductase (DHFR) is

198 The catalytic reaction of ethyl 3-(trimethylsilyl)propiolate

199 Therefore, the overall catalytic reaction of FRP-alphabeta without any FMN addi

200 led study of the eight-electron/eight-proton catalytic reaction of nitrogenase has been hampered by t

201 A new mechanism for the catalytic reaction of oxoanions with CO2 has also been p

202 duce interference of the GAF ligand with the catalytic reaction of PDE.

203 formational change process that precedes the catalytic reaction of the enzyme dihydrofolate reductase

204 The catalytic reaction of UGDH is thought to involve a Cys n

205 highlights the cases where stereocontrol in catalytic reactions of 1-alkenes is high enough to be us

206 e choice of NHC initiator, stoichiometric or catalytic reactions of bis(cyclooctatetraene)iron [Fe(CO

207 However, monitoring of catalytic reactions of dienes by (31)P NMR spectroscopy

208 quently invoked as reactive intermediates in catalytic reactions of epoxides using nickel, but have n

209 ta showing that CcdB does indeed inhibit the catalytic reactions of gyrase by stabilization of the cl

210 x', but it has not been shown to inhibit the catalytic reactions of gyrase.

211 of nonlinear effects and stoichiometric and catalytic reactions of isolated (PyOx)Pd(Ph)I complexes

212 Asymmetric, catalytic reactions of oxocarbenium ions are reported.

213 s can provide an environment for enzyme-like catalytic reactions of small-molecule guests.

214 The catalytic reactions of these products generate approxima

215 ne insertion and the regioselectivity of the catalytic reactions of vinylarenes.

216 Competing pathways in catalytic reactions often involve transition states with

217 Hence, we can indirectly monitor catalytic reactions on a single nanohalo under DFM, on t

218 ace species involved in ALD and, ultimately, catalytic reactions on these support materials.

219 reaction progress data over the course of a catalytic reaction opens up a vista that provides mechan

220 t nanocatalytic systems for high-temperature catalytic reactions or surface chemical processes, and t

221 In the context of the catalytic reaction, our findings reveal the importance o

222 mido radical is a viable intermediate in the catalytic reaction pathway.

223 Finally, theoretical catalytic reaction pathways were explored, revealing tha

224 In these catalytic reactions, Pd(I) mu-allyl dimer formation is a

225 The catalytic reaction plausibly proceeds via the cobaltacyc

226 These catalytic reactions proceed in excellent yields with a b

227 t role during catalysis in ensuring that the catalytic reaction proceeds in a forward direction.

228 The simulations reveal that the catalytic reaction proceeds in two steps, starting with

229 This catalytic reaction proceeds on lipid-water interfaces an

230 provide multiple lines of evidence that the catalytic reaction proceeds through the intermediate for

231 The catalytic reaction proceeds via an intermediate that alr

232 e demonstrate by methanolysis study that the catalytic reaction proceeds via the formation of a react

233 aterials that exhibit improved diffusion and catalytic reaction properties compared to conventional z

234 These simple-to-run catalytic reactions provide practical and economical pro

235 This catalytic reaction provides a new disconnection for the

236 This catalytic reaction provides practical access to a wide r

237 Identifying such relationships in asymmetric catalytic reactions provides substantial insight into th

238 ding the role of elastic strain in modifying catalytic reaction rates is crucial for catalyst design,

239 The large currents resulting from the fast catalytic reaction result in significant potential losse

240 r comparison to steady-state kinetics of the catalytic reaction reveal that the observed intermediate

241 The catalytic reactions reveal (i) a novel selectivity for s

242 Mechanistic studies of this rare catalytic reaction revealed a dynamic mixture of resting

243 Mechanistic studies on this rare catalytic reaction revealed a resting state that is the

244 within the framework of different plausible catalytic reaction schemes including appropriate approxi

245 phthol catalyst and the vinylboronate in the catalytic reaction sequence.

246 imental and DFT computational studies of the catalytic reaction, show that Cu(OTf)2 activates the Pd(

247 Using sulfide ions as inhibitors, the catalytic reaction slows down, resulting in a delay in t

248 Examples from a variety of catalytic reactions spanning two decades of the author's

249 Using gas-phase catalytic reaction studies and in situ sum-frequency gen

250 ity pattern serves as a platform for various catalytic reactions such as C-H borylation and hydrogena

251 bridging allyl ligands have been detected in catalytic reactions, such as cross-coupling, and discuss

252 ous efficient, site-, and/or stereoselective catalytic reactions, such as cross-metathesis or proto-b

253 ogen bonding in different stoichiometric and catalytic reactions, such as hydrogen exchange, alcoholy

254 ached the market stage, while for some other catalytic reactions, such as reforming processes, photoc

255 cess in which light energy was used to drive catalytic reactions, such as the Suzuki coupling, with m

256 Three arguments are consistent with the catalytic reactions taking place inside the pores.

257 of localized assembly of the product of the catalytic reaction that is screened for.

258 Efficient catalytic reactions that can generate C-C bonds enantios

259 Catalytic reactions that enable the formation of new bon

260 The synaptic complex is a prerequisite for catalytic reactions that occur during the transposition

261 rred but remains challenging, especially for catalytic reactions that occur in water.

262 From the catalytic reactions that sustain the global oxygen, nitr

263 IR data showed that at the start of the catalytic reaction, the acac ligand of the Ru(acac)(C2H4

264 We detected two alternative forms of the catalytic reaction, the first requiring a reorientation

265 The key step in the second half of the NOS catalytic reaction, the internal electron transfer betwe

266 The reversibility of catalytic reactions, the influence of an adsorption pre-

267 During the course of all catalytic reactions, the resting state of the catalyst w

268 As a prototypical example of homogeneous catalytic reactions, the Wacker process poses serious ch

269 heterogeneous catalysts to known homogeneous catalytic reactions through the design and synthesis of

270 des sufficient basicity (and buffer) for the catalytic reactions; thus, the addition of base is not r

271 onor to the electrode surface, allowing this catalytic reaction to serve as a proxy for the rate of i

272 steps require most commercial heterogeneous catalytic reactions to be run at relatively high tempera

273 This approach can be used for catalytic reactions to identify transition states and ad

274 and local flexibility, and thus balance all catalytic reactions to maximize enzyme activity.

275 s that require coordinative unsaturation for catalytic reactions to occur on such surfaces.

276 ies that compare the enantioselectivities of catalytic reactions to those of stoichiometric reactions

277 information on the elementary steps of this catalytic reaction (transmetalation --> oxidative additi

278 ur knowledge, this is the first example of a catalytic reaction triggered in response to molecular pi

279 transferability from the model study to the catalytic reaction under practical conditions.

280 ersion of biomass-derived molecules involves catalytic reactions under harsh conditions in the liquid

281 ld also be applied in the promotion of other catalytic reactions under mild conditions.

282 dies, can be used for monitoring interfacial catalytic reactions under well-defined experimental cond

283 Preliminary findings on the development of catalytic reactions using these reagents are detailed, a

284 unveil mechanistic information regarding the catalytic reaction via changes in water-coordination num

285 reveal that Ni(I) species are formed in the catalytic reaction via two different pathways: (i) the p

286 P enzyme, and the emission of light from the catalytic reaction was detected by underlying flexible p

287 The rate law for the catalytic reaction was determined to be nearly unimolecu

288 (2)O(3)) and anatase (TiO(2)) NPs as a model catalytic reaction, we discovered that the catalytic and

289 atalyst active site and the mechanism of the catalytic reaction were revealed by joint experimental a

290 Catalytic reactions were effected using single-phase rea

291 undamental understanding of the mechanism of catalytic reactions which can be achieved by the detaile

292 cations, but most notably when investigating catalytic reactions which occur on the surfaces of nanos

293 manure biodegradation likely through enzyme catalytic reactions, which may enhance antibiotic attenu

294 Because kinase signaling can be amplified by catalytic reaction, why CaMKII exists in such a large qu

295 ffective reversible potential, Eeff(0)) to a catalytic reaction with a substrate in solution (pseudo-

296 Consistent with suggested hypotheses, catalytic reactions with a Cu complex, derived from an N

297 the (3 + 2) annulation reaction and multiple catalytic reactions with excellent overall yield.

298 t platform for investigating the kinetics of catalytic reactions with SERS.

299 Similar selectivities for stoichiometric and catalytic reactions with two different iodoarenes and fa

300 reveals strong geometric conservation of the catalytic reaction, with APE1 catalytic side chains posi