ライフサイエンスコーパス: catalyze

1 and the ADP-ribosylation reactions that they catalyze.

2 However, enzyme-catalyzed 1,3 dipolar cyclo-additions are unprecedented

3 Finally, we showed that Cu-catalyzed 1,3-dipolar cycloaddition is also chemically c

4 es Lhb gene expression directly and does not catalyze 5hmC at the gene promoter.

5 Carboxy-7-deazaguanine (CDG) synthase (QueE) catalyzes a key step in the biosynthesis of 7-deazapurin

6 50 enzyme in Mycobacterium tuberculosis that catalyzes a single intramolecular C-C cross-linking reac

7 ochrome P450 enzymes have been engineered to catalyze abiological C-H bond amination reactions, but t

8 at p53 K372 directly activates Tip60 for its catalyzed acetylation at p53 K120.

9 The data confirm that the disiloxanediol-catalyzed addition reaction is first order in catalyst o

10 and have important implications for other Pd-catalyzed aerobic C-H oxidation reactions.

11 the dihydrobenzodioxolone core by palladium-catalyzed aerobic dehydrogenation.

12 ures that have important implications for Pd-catalyzed aerobic oxidation catalysis: (1) The reaction

13 istic aspects of the N-heterocyclic carbenes catalyzed aerobic oxidation of aldehydes shares importan

14 stereoselectivity and regioselectivity in Zn-catalyzed allenylation reactions of N-protected l-alpha-

15 , selective, and highly controllable iridium-catalyzed allylbenzene isomerization is described, enabl

16 ong PLK family members, PLK3 is also able to catalyze alpha-syn phosphorylation and degradation in li

17 ild, oxidant-free, and selective Cp*Co(III) -catalyzed amidation of thioamides with robust dioxazolon

18 The Pd-catalyzed aminated intermediate was isolated and charact

19 amino functionalization and transition-metal-catalyzed arene C-H amination.

20 Combining a Rh(I)-catalyzed arylation followed by a Pd(0)-catalyzed C-N co

21 Pd-catalyzed arylation or benzylation of nitroazoles using

22 Enantioselective nickel-catalyzed arylative cyclizations of substrates containin

23 Among others, we identified sites catalyzed at faster rates with potential critical roles

24 This dynamic localization is driven by MinD-catalyzed ATP hydrolysis, stimulated by interactions wit

25 The CPC is activated by AURKB-catalyzed autophosphorylation on multiple subunits, but

26 , we combined Staudinger ligation and copper catalyzed azide alkyne cycloaddition (CuAAC) reactions t

27 The palladium(II)-catalyzed beta- and gamma-alkynylation of amide C(sp(3)

28 The first example of palladium(II)-catalyzed beta-C(sp(3))-H iodination of a wide range of

29 We report the Pd(II)-catalyzed, bidentate directing group (BDG)-assisted aryl

30 Under mild conditions, 1 catalyzes both hydrolysis of the nerve agent simulant, d

31 plays a critical role in steroid metabolism, catalyzing both the 17alpha-hydroxylation of pregnenolon

32 study of the oxygen reduction reaction (ORR) catalyzed by a cofacial porphyrin scaffold accessed in h

33 g the direct conversion of arylboronic acids catalyzed by a new ONO pincer-type Pd(II) complex under

34 asis for the normal and reverse prenylations catalyzed by a single enzyme, and it offers novel insigh

35 nantioselective direct Mannich-type reaction catalyzed by a sterically frustrated Lewis acid/Bronsted

36 intermediates, whereby at least one step is catalyzed by an enzyme.

37 The reaction is catalyzed by an iridium complex generated from [Ir(COD)O

38 e of the wide range of non-natural reactions catalyzed by ArMs, this was done using a functional-grou

39 not lean, mice, and this phosphorylation was catalyzed by casein kinase 2 (CK2), the levels of which

40 of the primary and secondary septa that are catalyzed by chitin synthase-II (Chs2) and chitin syntha

41 The cross-coupling of these radicals is catalyzed by copper via an out-of-cage mechanism in whic

42 ldiazo compounds and alpha-diazocarboximides catalyzed by copper(I) or dirhodium(II) have been develo

43 When catalyzed by Cu(I) or strain promotion, this cycloadditi

44 ium thioacetate (KSAc) and iodobenzene (PhI) catalyzed by CuI associated with 1,10-phenanthroline (ph

45 uoro-beta-iodoketones with silyl enol ethers catalyzed by fac-Ir(ppy)3 under blue LED irradiation wit

46 ) system, involves two consecutive reactions catalyzed by GLXI and GLXII.

47 a favorable crossover conformational shift, catalyzed by GTP hydrolysis, that converts the dimer fro

48 beling applied to 1-octene polymerization as catalyzed by hafnium-pyridyl amido precursors enables qu

49 ng the electrochemical reduction of dioxygen catalyzed by iron porphyrins in DMF as an example, decre

50 e oxidation of the same substrates with H2O2 catalyzed by manganese complexes, supporting the hypothe

51 groups with alpha-fluoro carbonyl compounds catalyzed by palladium complexes have been reported, but

52 The cycloisomerization of enynes catalyzed by Pd(OAc)2 and bis-benzylidene ethylenediamin

53 posttranslational modification in eukaryotes catalyzed by protein arginine methyltransferases (PRMTs)

54 transduction and deoxynucleotide production catalyzed by ribonucleotide reductases (RNRs).

55 n the biosynthesis of spinosyn A, a reaction catalyzed by SpnF enzyme, one of the most promising "tru

56 Biomethylation of As is catalyzed by the enzyme arsenite (As[III]) S-adenosylmet

57 onyl-CoA with S-propionyl-N-acetylcysteamine catalyzed by the Nan[KS1][AT1] didomain from module 1 of

58 and kinetic studies suggest the reaction is catalyzed by trace copper salts and that a Z- to E-hydra

59 quinone monoacetals (QMAs) with 2-naphthols catalyzed by triflic acid is reported.

60 as substrates in glycosaminoglycan synthesis catalyzed by various synthases.

61 nated to the Rh, whereas CS-L underwent a Rh-catalyzed C horizontal lineC isomerization to rac-C2-L,

62 origin of stereoinduction in asymmetric iron-catalyzed C(sp(2))-C(sp(3)) cross-coupling reaction betw

63 The palladium(II)-catalyzed C(sp(3) )-H alkynylation of oligopeptides was

64 his Review summarizes the advancements in Pd-catalyzed C(sp(3))-H activation via various redox manifo

65 Herein, we report a silver-free Pd(II)-catalyzed C(sp(3))-H arylation of saturated bicyclic and

66 Key steps were a palladium-catalyzed C(sp3)X-C(sp3)ZnX Negishi cross-coupling affor

67 A site-selective rhodium-catalyzed C-C activation of ring-fused cyclopentanones w

68 adicals are subsequently engaged in a nickel-catalyzed C-C bond-forming reaction with aryl halides.

69 e studied key aspects of the mechanism of Pd-catalyzed C-CN bond activation and intramolecular enanti

70 adiene or directing group-assisted ruthenium-catalyzed C-H activation of N-methoxybenzamide.

71 Ligand development for rhodium(III)-catalyzed C-H activation reactions has largely been limi

72 o overcomes the limitations of palladium(II)-catalyzed C-H amination reactions.

73 The mechanisms of Ni-catalyzed C-H arylation, alkylation, and sulfenylation w

74 Additionally, many transition-metal-catalyzed C-H bond additions to polarized pi bonds occur

75 Palladium(II)-catalyzed C-H carbonylation reactions of methylene C-H b

76 ctivity (including enantioselectivity) in Pd-catalyzed C-H functionalization reactions.

77 Electrochemical cobalt-catalyzed C-H functionalizations were achieved in terms

78 h(I)-catalyzed arylation followed by a Pd(0)-catalyzed C-N coupling, in a one-pot procedure, provides

79 Microorganisms catalyze carbon cycling and biogeochemical reactions in

80 synthetic protocol consists of sequential Pd-catalyzed carbon-nitrogen bond formation followed by Lew

81 Iron(III)-catalyzed carbonyl-olefin ring-closing metathesis repres

82 In particular, palladium-catalyzed carbonylation reactions have found broad appli

83 mplex molecules via various transition-metal-catalyzed carbonylation reactions.

84 escribed applying a four-component palladium-catalyzed carbonylative coupling of aryl boronic acids t

85 ide synthase (GCS) is a rate-limiting enzyme catalyzing ceramide glycosylation, thereby regulating ce

86 C-H HAT step, with that of transition-metal-catalyzed chemistry (selective beta-hydrogen elimination

87 initiated by the PCGF3/5-PRC1 complex, which catalyzes chromosome-wide H2A lysine 119 ubiquitylation,

88 brils upon dephosphorylation by ALP, but CES-catalyzed cleavage of the ester bond on the molecules re

89 this bio-orthogonal amino acid using copper-catalyzed click chemistry, either before or after the si

90 s are used to study the Claisen-Schmidt base-catalyzed condensation of 6-hydroxy-1-indanone with subs

91 A nickel-catalyzed conjunctive cross-coupling between non-conjuga

92 The TET enzymes catalyze conversion of 5-methyl cytosine (5mC) to 5-hydr

93 he protein response, which involves thrombin-catalyzed conversion of a soluble plasma protein, fibrin

94 25 degrees C), and excellent activities for catalyzing conversion of CO2 into cyclic carbonate (conv

95 ation of 11beta-hydroxylase (CYP11B1), which catalyzes cortisol biosynthesis and is highly homologous

96 nabling chemoselective palladium- and nickel-catalyzed coupling sequences.

97 lenophene (IDSe), via a 2-fold and 4-fold Pd-catalyzed coupling with a 1,1-diborylmethane derivative.

98 lkyne, has been established by the copper(I)-catalyzed cross-coupling of 1,1-dibromoenamides with nit

99 Iron-catalyzed cross-coupling reactions using alkynyl nucleop

100 species are proposed key intermediates in Cu-catalyzed cross-coupling reactions.

101 Subsequent palladium-catalyzed cross-coupling with haloarenes furnished the d

102 hesis reaction, and THP formation via Pd(II)-catalyzed cyclization.

103 highly efficient and stereoselective Pt(IV)-catalyzed cycloaddition reactions of the corresponding q

104 s a landmark methodology in transition-metal-catalyzed cycloisomerization.

105 n embedded ladder polymers using a palladium catalyzed cyclopentannulation polymerization followed by

106 through a sequence of Rh2(OAc)4 (0.33 mol %)-catalyzed cyclopropanation, followed by ester hydrolysis

107 N-Cl-DCAM can, however, undergo acid-catalyzed decomposition to form the corresponding dichlo

108 eine (Cys) thiol group, followed by stepwise catalyzed degradation and eventual elimination along the

109 yl N-pivaloylhydroxamates undergo an Ir(III)-catalyzed diamination of the alkene with simple exogenou

110 ptor were synthesized by utilizing palladium catalyzed direct (hetero)arylation reaction.

111 [Pd]-catalyzed direct acylation of o-iodoketones with aldehyd

112 Palladium-catalyzed direct arylation of 4-(2-bromophenyl)-2-methyl

113 A rhodium catalyzed direct regioselective oxidative annulation by

114 into a series of Cp*Co(III)- and Cp*Rh(III)-catalyzed directed C-H bond functionalizations with diaz

115 ine (SAM) enzymes are widely distributed and catalyze diverse reactions.

116 The TnpA transposase of these elements catalyzes DNA breakage and rejoining reactions required

117 rase (Pol) beta maintains genome fidelity by catalyzing DNA synthesis and removal of a reactive DNA r

118 eIF2alpha to assemble a phosphatase complex catalyzing eIF2alpha dephosphorylation and resumption of

119 robes that inhabit the electrode surface and catalyze electron transfer in these systems remains larg

120 Here we show the cross-catalyzed emergence of a novel self-replicator from a dy

121 n cofactor (Ir(Me)-PIX) in place of the heme catalyze enantioselective intramolecular C-H bond aminat

122 A mechanistic study of the Pd-catalyzed enantioselective 1,1-diarylation of benzyl acr

123 Proteins in the hedgehog family undergo self-catalyzed endoproteolysis involving nucleophilic attack

124 Only a few natural enzymes catalyze even a formal [4 + 2] cycloaddition, and it rem

125 ase binds specifically to the Muta1 ends and catalyzes excision through double strand breaks (DSB) an

126 current exposure to inflammatory agents that catalyze fluctuations in the concentrations of acute-pha

127 to form 3-benzylated indoles and H2O that is catalyzed, for the first time, by a complex of earth-abu

128 port the serendipitous discovery of a borane-catalyzed formal C(sp(3))-CF3 reductive elimination from

129 a transcriptional repressor of factors that catalyze glycerol degradation.

130 er of zeste homolog 2 (EZH2), an enzyme that catalyzes H3 lysine trimethylation and associates with o

131 Histone acetyltransferase 1 (HAT1), which catalyzes H4K5ac and H4K12ac, was downregulated by ascor

132 The Pd-catalyzed Heck-type coupling (Matsuda-Heck reaction) of

133 ctivities, is secreted into macrophages, and catalyzes host lipid hydrolysis.

134 protein kinases comprising the human kinome catalyze hundreds of thousands of phosphorylation events

135 We report a Rh-catalyzed hydroamination of 1,3-dienes to generate homoa

136 tional studies on the mechanism of a rhodium-catalyzed hydroformylation that is selective for branche

137 Whereas most CCPs catalyze hydrolysis of alpha-carboxyl-linked glutamates,

138 d the change in the local pH produced by the catalyzed hydrolysis of urea.

139 e rings and the first example of a non-metal-catalyzed hydrosilylation of P-P bonds to produce silylp

140 or the synthesis of thiochromenes through Cu-catalyzed in situ incorporation of sulfur.

141 A silver-catalyzed intermolecular aminosulfonylation of terminal

142 an derivatives has been developed via Cu(II)-catalyzed intermolecular annulation of aryl ketones with

143 trogen bond formation followed by Lewis acid catalyzed intramolecular cyclization.

144 -1H-imidazol-3-ium bromides undergo a copper-catalyzed intramolecular direct C arylation under mild c

145 amides and related substrates undergo copper-catalyzed intramolecular sulfamidation at the benzylic m

146 process represents the first small-molecule catalyzed kinetic resolution of aliphatic amines.

147 A Bronsted acid catalyzed kinetic resolution of primary amines is descri

148 The utility of the nucleophile-catalyzed (Lewis base) aldol lactonization (NCAL) proces

149 We report the first enantioselective Rh-catalyzed Markovnikov hydroboration of unactivated termi

150 Finally, to show how this method can catalyze medical translation, we show that dosage time c

151 al collar at the neck of endocytic pits, and catalyzes membrane fission.

152 ochrome P450 enzyme by directed evolution to catalyze metal-oxo-mediated anti-Markovnikov oxidation o

153 nzymes (mouse and human) are also capable of catalyzing metal-dependent dual chemistry in vitro.

154 A recently reported Pd-catalyzed method for oxidative imidoylation of C-H bonds

155 ively review all asymmetric transition-metal-catalyzed methodologies that are believed to proceed via

156 protein glucosyltransferase 1 (UGGT1), which catalyzes monoglucosylation of N-glycans, and oppositely

157 uable data for a better understanding of OST-catalyzed N-glycosylation.

158 Linked N-acetylglucosamine transferase (OGT) catalyzes O-GlcNAcylation of target proteins and regulat

159 omer 2, which is chiral and racemic, by base-catalyzed olefin isomerization followed by kinetic resol

160 Zebrafish P450 17A2 catalyzes only the 17alpha-hydroxylations.

161 line vehicles, diesel vehicles equipped with catalyzed or additive DPF emit fewer particles but more

162 A Pd(II) -catalyzed ortho C-H alkoxycarbonylation reaction of aryl

163 e key is to merge soft enolization with a Pd-catalyzed oxidation process.

164 Palladium(II)-catalyzed oxidation reactions exhibit broad utility in o

165 nent flavin-dependent monooxygenase that can catalyze oxidative dechlorination of various CPs, and as

166 Although palladium catalyzed oxidative homocoupling of aryl boronic acids a

167 es were readily synthesized by palladium(II)-catalyzed oxidative macrocyclizations of bis(vinyl boron

168 The beta-gal catalyzed PAPG to an electroactive species p-aminophenol

169 talyzed reactions of alkynes, the mono Au(I)-catalyzed pendant to the radical dimerization of nonconj

170 Whereas ribosomes efficiently catalyze peptide bond synthesis by most amino acids, the

171 though all Type II restriction endonucleases catalyze phosphodiester bond hydrolysis within or close

172 stress-activated protein kinase 1/2 (MSK1/2)-catalyzed phosphorylation of histone H3 at serine 10 or

173 tide (NAD) kinase (NADK2, also called MNADK) catalyzes phosphorylation of NAD to yield NADP.

174 mm(2) The initial corrosion proceeds as self-catalyzed pitting, visualized by the sudden appearance o

175 n sulfotransferases (TPSTs) are enzymes that catalyze post-translational tyrosine sulfation of protei

176 This palladium-catalyzed process provides direct access to alkyl silane

177 A Bronsted acid-catalyzed process using TfOH formed in situ was ruled ou

178 The focus is on transition-metal-catalyzed processes that are triggered by C-C bond activ

179 rnover frequencies (TOF) of these Lewis pair catalyzed processes were as high as 119 h(-1) at ambient

180 Purified human telomerase catalyzes processive repeat synthesis, which could resto

181 zDHHC S-acyltransferases are enzymes catalyzing protein S-acylation, a common post-translatio

182 The rate of the water-catalyzed proton transfer shows a prominent H/D kinetic

183 A cobalt-catalyzed proton-coupled electron transfer (PCET) mediat

184 We have developed a method for palladium-catalyzed, pyrazole-directed sp(3) C-H bond arylation by

185 second-order rate constants for general-base-catalyzed racemization that are usefully accurate.

186 t starting materials for simple, thermal, Ni-catalyzed radical formation and subsequent trapping with

187 indicate that the final product of the ALD1-catalyzed reaction is enaminic 2,3-dehydropipecolic acid

188 )-C(sp(3) ) bond formation in the copper(I)-catalyzed reaction of cyclopropanols with diazo esters.

189 An efficient dual-metal catalyzed reaction of electron-deficient o-chlorovinylpy

190 mechanism-inspired enantioselective rhodium-catalyzed reaction of gamma-substituted enoldiazoacetami

191 arboxamidothiazoles 1 by an yttrium-triflate-catalyzed reaction of thiocarboxylic acids 2 with isocya

192 The synthesis is highlighted by an enzyme-catalyzed reaction to access 3,4,5-trifluoro-(S)-phenylg

193 Here, we reconstitute the CysS-catalyzed reaction, on p-aminobenzoate thioester substra

194 To gain mechanistic insight into the CYP121-catalyzed reaction, we tested the peroxide shunt pathway

195 e-binding event that occurs during the MDDEF-catalyzed reaction.

196 Kinetic data suggest thioether-Pd-catalyzed reactions can be as much as 800x faster than c

197 In addition, a cascade of three aldolase-catalyzed reactions enables one-pot assembly of gamma-ni

198 Despite the myriad of Au(I)-catalyzed reactions of alkynes, the mono Au(I)-catalyzed

199 iflate/double-sidearmed bisoxazoline complex catalyzed reactions of beta-triisopropylsilyl-substitute

200 e global chemicals that are produced by acid-catalyzed reactions that involve the formation of carboc

201 ening of chiral ligands for transition-metal-catalyzed reactions with well-defined reaction mechanism

202 verning the selectivity of the cooperatively catalyzed reactions.

203 This process, referred to as Fe(2+)-catalyzed recrystallization, can influence water quality

204 mplished with quinone diazides under Rh(III)-catalyzed redox-neutral conditions.

205 An asymmetric Ni-catalyzed reductive cross-coupling has been developed to

206 Lewis acid catalyzed ring closure with a thiophene dialcohol in 2%

207 A Bi(OTf)3-catalyzed ring-opening cyclization of (hetero)aryl cyclo

208 d polymer produced commercially by the metal-catalyzed ring-opening polymerization of lactide.

209 is an essential, multi-subunit complex that catalyzes RNA turnover, maturation, and quality control

210 A ruthenium-catalyzed sequence for the formal two-carbon scission of

211 curs through the action of four ASATs, which catalyze sequential addition of acyl groups to the R2, R

212 Because PutAs catalyze sequential reactions, they are good systems for

213 substrates, and demonstrate that it not only catalyzes sequential methylations of a methyl group to f

214 tic studies are ongoing, we propose that CuH-catalyzed silylation of unsaturated acids occurs to acce

215 ism (PAO) enrichment cultures are capable of catalyzing simultaneous biological N and P removal coupl

216 They can catalyze site-specific RNA cleavage, and as a result, th

217 exahydropyrrolo[2,3-b]indoles via Lewis acid-catalyzed SN2-type ring opening of activated aziridines

218 , termed APEX-RIP, which combines peroxidase-catalyzed, spatially restricted in situ protein biotinyl

219 (Plu2236) from Photorhabdus luminescens that catalyzes stilbene epoxidation.

220 phile cycloaddition and subsequent palladium-catalyzed substitution with nonstabilized lithium enolat

221 have established that two molecules of LarE catalyze successive thiolation reactions by donating the

222 Recently, the first palladium-catalyzed Suzuki-Miyaura and Buchwald-Hartwig cross-coup

223 lizing a recently discovered precatalyst, Pd-catalyzed Suzuki-Miyaura and Buchwald-Hartwig reactions

224 usly unappreciated role in mediating surface-catalyzed synthesis in the prebiotic milieu.

225 e acyltransferases (DGATs), the enzymes that catalyze TAG production.

226 The synthetic route features iodine-catalyzed tandem isomerization followed by C-O and C-C b

227 Here we report that RA95.5-8 variants catalyze the asymmetric synthesis of gamma-nitroketones

228 Thioesterases catalyze the cleavage of thioester bonds within many act

229 ox-active pyridine dialdimine (PDAI) ligands catalyze the cycloaddition of two terminal alkynes and o

230 Pectin methylesterases (PMEs) catalyze the demethylesterification of pectin, one of th

231 lated Fe(II) PNP pincer complex was shown to catalyze the methylation of 2-naphtol rather than its am

232 LTs catalyze the non-hydrolytic cleavage of the bacterial pe

233 cresol methylhydroxylase flavoprotein family catalyze the oxidation of para-substituted phenols.

234 Lytic polysaccharide monooxygenases (LPMOs) catalyze the oxidative cleavage of glycosidic bonds in r

235 The enzymes that catalyze the oxygenation of AA begin by abstracting hydr

236 dependent phosphatidic acid phosphatases and catalyze the penultimate step of triacylglycerol synthes

237 Tomato ASATs catalyze the sequential esterification of acyl-coenzyme

238 nsable, or whether their main function is to catalyze the splitting reaction, which necessarily prece

239 e energy of ATP hydrolysis, ABC transporters catalyze the trans-membrane transport of molecules.

240 Consistent with this finding, FosDH2 catalyzed the interconversion of the corresponding trike

241 Recombinant Glt1 catalyzed the same reaction, confirming that it directly

242 ithin the prolipoprotein signal sequence and catalyzes the addition of diacylglycerol to an invariant

243 coded phosphatidate phosphatase (PAP), which catalyzes the committed step for the synthesis of triacy

244 Coproporphyrinogen III oxidase (CPO) catalyzes the conversion of coproporphyrinogen III into

245 the expression of aromatase, the enzyme that catalyzes the conversion of testosterone to estradiol.

246 UDP-galactopyranose mutase (UGM) catalyzes the conversion of UDP-galactofuranose (UDP-Gal

247 conserved Rad51/RecA family of recombinases catalyzes the DNA strand invasion reaction that takes pl

248 Cinnamyl alcohol dehydrogenase (CAD) catalyzes the final step in monolignol biosynthesis, red

249 icity for arginine in the P1 position, which catalyzes the first enzymatic reaction of the amplificat

250 evolved pgi knockouts of Escherichia coliPgi catalyzes the first reaction in glycolysis, and its loss

251 ver, the gene coding for hexokinase-2, which catalyzes the first step of glycolysis, was significantl

252 delta-aminolevulinate synthase (ALAS), which catalyzes the first step of heme synthesis.

253 -N-acetylglucosaminyltransferase 1 (POMGNT1) catalyzes the first step toward other various glycan str

254 Agmatine N-acetyltransferase (AgmNAT) catalyzes the formation of N-acetylagmatine from acetyl-

255 man methionine S-adenosyltransferase (MAT2A) catalyzes the formation of S-adenosylmethionine (SAM) fr

256 It catalyzes the glutathione (GSH)-dependent dealkylation o

257 Neutrophil myeloperoxidase (MPO) catalyzes the H2O2-dependent oxidation of chloride anion

258 A chiral rhodium complex catalyzes the highly enantioselective coupling of arylbo

259 We also found that B(C6F5)3 catalyzes the homodehydrocoupling of primary phosphines

260 Lipoyl synthase (LipA) catalyzes the last step in the biosynthesis of the lipoy

261 Bam complex, an essential heteroligomer that catalyzes the membrane insertion of OMPs.

262 mental cytosolic biotransforming enzyme that catalyzes the N-methylation of endogenous and exogenous

263 (ALDH2), one of 19 ALDH superfamily members, catalyzes the NAD(+)-dependent oxidation of aldehydes to

264 Peptidoglycan O-acetyltransferase B (PatB) catalyzes the O-acetylation of PG in Gram (-) bacteria,

265 he topologically conserved C-terminal domain catalyzes the oxidation of polyunsaturated fatty acids,

266 nylcysteine carboxylmethyltransferase (ICMT) catalyzes the post-translational modification of RAB GTP

267 yl hydroperoxide reductase subunit F (AhpF), catalyzes the rapid reduction of the redox-active disulf

268 ASS1 catalyzes the rate-limiting step of arginine synthesis i

269 acteria a simple version of this photoenzyme catalyzes the reduction of a quinone molecule, accompani

270 Nitrogenase catalyzes the reduction of dinitrogen (N2) to two ammoni

271 is a mitochondrial 1-Cys peroxiredoxin that catalyzes the reduction of endogenously generated H2O2 P

272 Furthermore, we found that tafazzin catalyzes the remodeling of cardiolipin by combinations

273 osphate (FBP) aldolase, a glycolytic enzyme, catalyzes the reversible and stereospecific aldol additi

274 bic methanogenic and methanotrophic archaea, catalyzes the reversible production and consumption of t

275 -phosphate (PLP)-dependent transaminase BioA catalyzes the second step in the biosynthesis of biotin

276 Lipase AS catalyzes the selective hydrolysis of the rear foot of m

277 ed the "gatekeeper" of glycolysis because it catalyzes the step committing glucose to breakdown.

278 lar stomatitis virus (VSV) and rabies virus, catalyzes the transfer of 5'-phospho-RNA (pRNA) from 5'-

279 us diacylglycerol acetyltransferase (EaDAcT) catalyzes the transfer of an acetyl group from acetyl-Co

280 Munc13 catalyzes the transit of syntaxin from a closed complex

281 nal flavoenzyme proline utilization A (PutA) catalyzes the two-step oxidation of proline to glutamate

282 lasma serine palmitoyltransferase, an enzyme catalyzing the first and rate-limiting step in sphingoli

283 rotein family HemW/RSAD1 is a heme chaperone catalyzing the insertion of heme into hemoproteins.

284 rotein superfamilies in all domains of life, catalyzing the movement of diverse substrates across mem

285 nzyme of the general phenylpropanoid pathway catalyzing the nonoxidative elimination of ammonia from

286 When catalyzing the ORR, FeNx Cy moieties are more selective

287 The selection of oxide materials for catalyzing the oxygen evolution reaction in acid-based e

288 etabolism of anaerobic bacteria and archaea, catalyzing the reversible synthesis of acetyl-CoA from C

289 zirine, which is compatible with Ph3PAuNTf2, catalyzing the second step.

290 GS) plays an essential role in metabolism by catalyzing the synthesis of glutamine from glutamate and

291 on of 8-oxogeranial is clearly enzymatically catalyzed, the cyclization step appears to be subject to

292 made enzyme-like catalyst that is capable of catalyzing this reaction.

293 ift promoting signals mostly impair the EF-G-catalyzed translocation step of the two tRNALys and the

294 tRNA in the small subunit P site during EF-G-catalyzed translocation.

295 ncluding base excision repair where Pol beta catalyzes two key enzymatic steps: 5'-dRP lyase gap trim

296 one of the first targets identified for PKB, catalyzes two previously unreported phosphorylation even

297 us to dissect the concerted process of E1-E2-catalyzed Ub conjugation in order to separately characte

298 s such as 20 were prepared using a palladium-catalyzed Ullmann cross-coupling reaction between the ap

299 These enzymes have been shown to catalyze unconventional reactions, such as methyl transf

300 The TBAF-catalyzed VMMR afforded high anti-diastereoselectivity i