ライフサイエンスコーパス: charge transfer

1 m (severe bulk charge recombination and slow charge transfer).

2 between triplet-triplet energy transfer and charge transfer.

3 acceptor, which inhibited the intramolecular charge transfer.

4 atures observed in systems with intervalence charge transfer.

5 serve as an efficient medium for long-range charge transfer.

6 otal length of the alkanethiol influence the charge transfer.

7 ate size and the energetic driving force for charge transfer.

8 resonant energy transfer and intermolecular charge transfer.

9 rest to explore ways to influence or enhance charge transfer.

10 is significantly affected by intramolecular charge transfer.

11 experiments such as photoinduced bimolecular charge transfer.

12 ers Ueff, the effective Coulombic barrier to charge transfer.

13 onductor bands, and finally impeding further charge transfer.

14 g a low-spin Co(3+) ion by an iron-to-cobalt charge transfer.

15 iratory chain, where they mediate long-range charge transfers.

16 relaxation from the singlet metal-to-ligand charge transfer ((1)MLCT) excited state into a quintet m

17 rs from a long-lived doublet ligand-to-metal charge-transfer ((2)LMCT) state that is rarely seen for

18 ticality of the oscillations, yielding rapid charge transfer across the interface.

19 Below a threshold voltage, charge transfer across the junction is suppressed.

20 pe semiconductive g-C3 N4 induces a vigorous charge transfer across the MoB/g-C3 N4 Schottky junction

21 ing the decomposition of Li2 O2 as a soluble charge-transfer agent between the electrode and the Li2

22 nzene motifs that promote a hairpin turn via charge-transfer-aided folding.

23 The impact of surface zinc vacancies on charge transfer and charge separation at donor/ZnO and a

24 We focus on the possible role of charge transfer and delocalized or excitonic states in t

25 Particularly, the charge transfer and dissolution steps occur sequentially

26 d TCBD unit results in strong intramolecular charge transfer and lowering of the LUMO energy level.

27 lectronic structure of CoO, assuring a rapid charge transfer and optimal adsorption energies for inte

28 ructure of cobalt selenide, assuring a rapid charge transfer and optimal energy barrier of hydrogen d

29 es straightforward placement of the internal charge transfer and photoinduced electron transfer (PET)

30 the crossed-beam ion imaging technique, from charge transfer and proton transfer to nucleophilic subs

31 yproduct of spray-coated SWCNTs that hinders charge transfer and stable CD4(+) T cell sensing.

32 and orbital states emerging from interfacial charge transfer and their connections to the modified ba

33 ing moieties, light-mediated ligand to metal charge transfer and/or reaction with siderophores.

34 The significant contributions from charge-transfer and the chiral imprint to the ICD demons

35 ffering in activation/deactivation kinetics, charge transfer, and sensitivity to EtOH.

36 -resonant excitonic coupling to nucleobases, charge-transfer, and resonant excitonic coupling between

37 The efficient charge transfer arises at the interface of electrolyte a

38 ediate between homogeneous and heterogeneous charge transfer as well as 2D to 0D electron transfer.

39 Our model is based on sequential charge transfer assisted by conformational changes which

40 p-probe spectroscopy to reveal the sub-45 fs charge transfer at a 2D/0D heterostructure composed of t

41 These results reveal the significant role of charge transfer at interfaces in improving large polariz

42 to control the potential-dependent rates of charge transfer at polymer/electrolyte interfaces remain

43 Electronic coupling and ground-state charge transfer at the C60 /ZnO hybrid interface is show

44 hene molecular orbitals, as a consequence of charge transfer at the diarylethene-graphene interface u

45 present films is proposed to result from the charge transfer at the La0.7 Sr0.3 MnO3 /PbTiO3 interfac

46 screening at the PZT/SNNO interface and the charge transfer at the SNNO/LSMO interface.

47 The efficient charge transfer at the WS2 /MoS2 heterointerface and lon

48 driving force and reorganization energy for charge transfer between a given donor/acceptor pair to t

49 the sensitivity of the yield of photoinduced charge transfer between a QD and a molecular probe to ev

50 Controlling the charge transfer between a semiconducting catalyst carrie

51 electrostatic nature with a modest amount of charge transfer between Ag(+) and Fe(CO)5.

52 Herein, we evaluate the kinetics of charge transfer between electrodeposited poly-(3-hexylth

53 n in these species occurs as a result of the charge transfer between low-lying orbitals located on th

54 -2000 cm(-1) and coupling of 2000 cm(-1) for charge transfer between neighboring sites, placing the s

55 ogen bonding and, thus, inhibits substantial charge transfer between solute and solvent.

56 control of efficient interfacial and surface charge transfer between the components.

57 The charge transfer between the conduction band of nAu and p

58 of voltammetric peaks owing to intervalence charge transfer between the ferrocenyl groups on the nan

59 er interactions, HVB and strong HB, involves charge transfer between the lone pair (n) of Y, and the

60 nsity functional theory calculations confirm charge transfer between the n-orbitals of the S atoms in

61 ircular dichroism spectroscopy, we show that charge transfer between two monolayers conserves spin-va

62 In photovoltaic blends, charge transfer can occur from the bound triplet pairs w

63 ances of 3.3-3.5 A wherein efficient spatial charge transfer can occur.

64 ains, broken symmetry, off-stoichiometry and charge transfer, can generate a rich spectrum of exotic

65 r electrochemical window and 70% higher CTC (charge transfer capacity) than Pt microelectrodes of sim

66 y corroborate the presence of intramolecular charge transfer character in TPEP.

67 hieve superior performance when they possess charge transfer character.

68 Upon photonic excitation, considerable charge-transfer character becomes apparent, which ration

69 Upon cage formation, the charge-transfer character exhibited by the bis(aminophen

70 protein fibers and yield suitable electrical charge transfer characteristics are highly desired.

71 on process for stabilizing and enhancing its charge transfer characteristics.

72 nor-acceptor1-acceptor2 conjugates and their charge-transfer characterization by means of advanced ph

73 erning the excited-state reactivity of these charge-transfer chromophores is needed.

74 Here we report supramolecular charge-transfer cocrystals formed by electron acceptor a

75 ide, which is more rigid due to the stronger charge transfer complex between chains, requires a great

76 s show that GA acts as an acceptor center in charge transfer complex formation which is supported by

77 proceed through a hydride transfer within a charge transfer complex.

78 onal studies suggest that a disulfide-olefin charge-transfer complex is possibly responsible for the

79 wider variety and larger number of absorbing charge transfer complexes are formed as functional group

80 citons and charge transfer states in organic charge transfer composites by using extended Su-Schrieff

81 concept of radical substitution directed by charge transfer could serve as the basis for the develop

82 method to organize two-dimensional molecular charge transfer crystals into arbitrarily and vertically

83 -doped inorganic semiconductors or molecular charge transfer crystals, this can be achieved by spatia

84 Excimer states having variable charge transfer (CT) character are frequently implicated

85 tate is however weak, suggesting weakness of charge transfer (CT) effect and Mott insulating ground s

86 urements, whereby the energy ordering of the charge transfer (CT) excited states and the local triple

87 How tightly bound charge transfer (CT) excitons dissociate at organic dono

88 etries, resulting in variable intermolecular charge transfer (CT) interactions in the solid.

89 Photoexcited intramolecular charge transfer (CT) states in N,N-diaryl dihydrophenazi

90 so be modulated by a combination of FRET and charge transfer (CT), and characterize the concurrent ef

91 ering interfacial energy-level alignment and charge transfer (CT).

92 The intramolecular charge-transfer (CT) dynamics of a rigid and strongly co

93 present a comprehensive investigation of the charge-transfer (CT) effect in weakly interacting organi

94 uatorial conformer on both donor sites, with charge-transfer (CT) emission close to the local triplet

95 Productive high-energy charge-transfer (CT) states are populated within 50 fs d

96 ion occurs upon population of intermolecular charge-transfer (CT) states formed at organic electron d

97 Dissociation of the exciton via the charge-transfer (CT) states is attributed to weak bindin

98 that are involved in the transition from the charge-transfer (CT) to the ground state, i.e., CR, but

99 This work provides the first use of helium charge transfer dissociation (He-CTD) tandem mass spectr

100 lations that allow for quantification of the charge-transfer distance.

101 rough judicious design of a Pt(II)-acetylide charge-transfer donor-bridge-acceptor-bridge-donor 'fork

102 p-type polymer memory achieved using n-type charge-transfer doping.

103 an anomalous Hall response as the result of charge transfer driven interfacial ferromagnetism.

104 Both molecules are associated with charge transfer due to twisting in the lowest singlet ex

105 ed absorption, while that on C7 retarded the charge transfer due to twisting in the structure caused

106 id in the development of improved models for charge-transfer dynamics in donor-bridge-acceptor system

107 vibronic modes and their drastic effects on charge-transfer dynamics, thus setting paradigms for con

108 Here, the charge-transfer effect between two strongly correlated o

109 upled acceptors has been proposed to enhance charge transfer efficiency in functional organic electro

110 sfer picture, but instead exhibit a negative charge-transfer energy in line with recent models interp

111 ergies, thereby slowing nonradiative loss of charge-transfer energy.

112 ms these materials undergo an intramolecular charge-transfer event upon photoexcitation.

113 er activity does not depend on lutein nor on charge transfer events, whereas zeaxanthin was essential

114 both molecular Frenkel excitations (FE) and charge-transfer excitations (CTE) coupled nonadiabatical

115 characteristic of hybridization of local and charge transfer excited states.

116 ons (CASSCF), we define the ligand-field and charge-transfer excited states of [Mn(IV)(O)(N4py)](2+).

117 t transition-metal complexes with long-lived charge-transfer excited states.

118 Only the stable phase forms charge-transfer excitons upon exposure to visible light

119 e molecules were used to assess outer-sphere charge transfer (Fe(CN)6(4-)) and organic compound oxida

120 The sensor molecule is a charge-transfer fluorophore, DCM, which is strongly fluo

121 sence of intact vesicle by showing decreased charge transfer for the MUDA and AUT in the presence of

122 mically proportional increased resistance to charge transfer from a solution-based redox probe, due t

123 with a desorption mechanism based on direct charge transfer from a triboelectric probe to the adatom

124 such as graphene are uniquely responsive to charge transfer from adjacent materials, making them ide

125 viour is strong evidence for field dependent charge transfer from charge reservoirs with exceptionall

126 For example, charge transfer from I(-) to I2 gives rise to the linear

127 th monolayer and bilayer MoS2 as a result of charge transfer from MoS2 to epitaxial graphene under il

128 gy transfer (TET) by suppressing competitive charge transfer from QDs to molecules.

129 y, size-dependent plasmons and excitons, and charge transfer from semiconductors to molecules and vic

130 /cm(2) was necessary to induce a significant charge transfer from SiC to WSe2, where a reduction of v

131 ered by the catalyst, which thereby enhances charge transfer from the diene to the imine.

132 three kinds of thermoelectromagnetic effect: charge transfer from the magnetic inclusions to the matr

133 The heterostructure exhibits interfacial charge transfer from Ti to Ni sites, giving rise to an i

134 the double perovskite A 2VFeO6 a 'complete' charge transfer from V to Fe leads to a non-bulk-like ch

135 cal nonlinearity, namely, (i) intramolecular charge transfer, greatly enhanced by increased electron

136 Single-atom mutations that inhibit this charge transfer hinder primase initiation without affect

137 e resulting in switching off, intramolecular charge transfer (ICT) from pyrene moiety to the phenolic

138 phore pi-backbone the highest intramolecular charge transfer (ICT) is observed.

139 ophilic addition reaction and intramolecular charge transfer (ICT) mechanism.

140 uced electron transfer (PET), intramolecular charge transfer (ICT), aggregation-induced emission (AIE

141 sign carbon-supported catalysts.Control over charge transfer in carbon-supported metal nanoparticles

142 g augmented by dispersion, polarization, and charge transfer in competition with destabilizing Pauli

143 r states and predict the field dependence of charge transfer in excellent agreement with experimental

144 examine exciton recombination, energy-, and charge transfer in multilayer CdS/ZnS quantum dots (QDs)

145 has allowed for investigation of energy and charge transfer in numerous photoactive compounds and co

146 In particular, charge transfer in the 1,8-isomer is likely to occur bet

147 the carbocation intermediate, the degree of charge transfer in the transition states, and, in certai

148 colloidal template and studies photoinduced charge transfer in them.

149 ks in which the molecules are positioned for charge-transfer in face-to-face and edge-to-face orienta

150 he doping mechanism is identified as partial-charge-transfer induced trap filling.

151 The intermolecular charge-transfer interaction in the long-range ordered su

152 effect derives from an intrinsic directional charge-transfer interaction that can ultimately be progr

153 TCBD-aniline showed significant ground-state charge transfer interactions between the H12SubPc macroc

154 ansfer state and in the other via a distinct charge-transfer intermediate.

155 The results exclude charge transfer, intermixing, epitaxial strain, and octa

156 s and a chemical trajectory (nuclear motion, charge-transfer, intersystem crossing, etc.) dictates th

157 c transitions of mixed ligand-to-metal-metal-charge-transfer (IPr --> AuM2) and interligand (IPr -->

158 Charge transfer is a fundamental process that underlies

159 bstrates and reagents and activating them by charge transfer is also commented.

160 Photoinduced interfacial charge transfer is at the heart of many applications, in

161 Metal-to-ligand charge transfer is involved in both the formation of Pu3

162 X-ray absorption spectroscopy shows that the charge transfer is thwarted by hybridization effects tun

163 The degree to which intervalence charge transfer (IVCT) occurs, dependent on the degree o

164 Intervalence charge-transfer (IVCT) bands in the near-IR are observed

165 sorption to the HER2 analyte as well as high charge transfer kinetic properties of the applied rGO-Ch

166 he challenges related to the optimization of charge transfer kinetics in both oxides are highlighted.

167 moiety improves coordination (and, in turn, charge transfer kinetics) to the platinum co-catalyst an

168 al energy storage and conversion due to fast charge transfer kinetics, highly accessible surface area

169 cting and therefore possesses less efficient charge transfer kinetics.

170 R molecules that host LiCl salt exhibit fast charge-transfer kinetics and as much as five-times highe

171 Then the electrochemical stability and the charge-transfer kinetics of the electrocatalysts were ev

172 Due to its more efficient graphene-mediated charge-transfer kinetics, the as-grown Mo2 C-on-graphene

173 excited state sufficiently to realize a long charge-transfer lifetime of 100 picoseconds (ps) and roo

174 onentially on the energy for ligand-to-metal charge transfer (LMCT) and the functional Lewis acid str

175 Ligand-to-metal charge transfer (LMCT) excitation of [BiI6](3-) yielded

176 (III) reduction occurs via a ligand-to-metal charge transfer (LMCT) pathway.

177 entation can occur after the ligand-to-metal charge transfer (LMCT) via a complex reaction mechanism.

178 -assembly, may serve as potential long-range charge-transfer materials for photovoltaic applications.

179 We then analyse the charge transfer mechanism through the protection layers

180 on bands at 252 and 321nm due to an internal charge transfer mechanism.

181 unique electrotrophic behavior and propose a charge-transfer mechanism from CdS to M. thermoacetica T

182 In cases of coherent charge-transfer mechanism in biaryl compounds the rates

183 through ligand-to-metal and metal-to-ligand charge-transfer mixing pathways.

184 orm-to-naphthyridine, metal/ligand-to-ligand charge-transfer (ML-LCT) excited states were observed in

185 the ligand scaffold to tune the metal ligand charge transfer (MLCT) bands of these materials from the

186 DFT calculations confirm the metal to ligand charge transfer (MLCT) character of the low-lying electr

187 tates are reminiscent of the metal to ligand charge transfer (MLCT) states of ruthenium and iridium p

188 into question the wide applicability of the charge-transfer model for explaining organic matter opti

189 optical properties have been attributed to a charge-transfer model in which donor-acceptor complexes

190 ochromic effects arising from intramolecular charge transfer, moderate fluorescence quantum yields in

191 velop a Langmuir-Blodgett method to organize charge transfer molecular heterostructures with external

192 ntersystem crossing (rISC) in donor-acceptor charge transfer molecules, where spin-orbit coupling bet

193 Recent advances in emissive charge-transfer molecules have pioneered routes to reduc

194 oss the c-Si/a-B interface systems where the charge transfer occurs mainly from the interface Si atom

195 Excited state dynamics and photo-induced charge transfer of dye molecules have been widely studie

196 rease of Fe2MnAl originates from the unusual charge transfer of Fe and Mn and bond populations rearra

197 xyl terminal group can efficiently block the charge transfer of free nanoparticles in an aqueous solu

198 perties, optical absorption, and interfacial charge transfer of g-C3N4-based heterostructured nanohyb

199 y of metal oxides and the restricted 2D mass/charge transfer of graphene render these hybrid catalyst

200 This result could be explained by charge transfer on the MoS2 channel and Schottky contact

201 r on the basis of tunneling or superexchange charge transfer operating over small distances which pro

202 ll as purely quantum mechanical effects like charge-transfer or exciton-coupling, are included.

203 current, peak separation, and resistance to charge transfer over traditional carbon electrodes.

204 anisotropic interfacial coupling between the charge transfer pairs is demonstrated.

205 This particular through-space charge transfer pathway might be generally important in

206 rstood on the basis of a simple through-bond charge transfer pathway model.

207 pathway mechanism: a high quantum efficiency charge-transfer pathway to H2ase generating H2 as a mole

208 is characterized by a significant degree of charge transfer permitted by the pi-stacking that occurs

209 y, and the role of spin-orbit coupling under charge-transfer perturbations.

210 aterials do not obey a conventional positive charge-transfer picture, but instead exhibit a negative

211 ation of significantly different dipolar and charge transfer plasmon (CTP) resonances, respectively.

212 scope and the transition between coupled and charge-transfer plasmons is directly observed in the sub

213 Here we find that intercalation charge transfer proceeds through highly variable current

214 PEC) is a great challenge due to its complex charge transfer process, high overpotential, and corrosi

215 frared spectroscopy for the understanding of charge transfer processes between the chromophore and th

216 ated photoinduced electronic transitions and charge transfer processes.

217 provide evidence for cascades of short-range charge-transfer processes, including reductive charge sh

218 eep trap states, a more than 10 times faster charge transfer rate and nearly three times higher condu

219 and where distinctly different heterogeneous charge transfer rate constants (k(0) values) apply at th

220 Moreover, it was determined that charge transfer rate constants are reliable for the esta

221 photoluminescence, relate the dependence of charge transfer rate on the spatial extent of the initia

222 implication of this finding in non-coherent charge-transfer rates is being investigated.

223 to enhance the dopant/organic semiconductor charge transfer reaction by exposing the pi-electrons to

224 etween observed voltage changes and specific charge-transfer reactions, which includes an explicit de

225 ortant roles as intermediates in biochemical charge-transfer reactions.

226 base pairs was performed to investigate the charge transfer resistance (RCT ) of metal-modified DNA.

227 pedance spectroscopy (EIS) via comparison of charge transfer resistance (Rct) values before and after

228 TBHQ photocurrent about 13-fold higher and a charge transfer resistance 62-fold lower than observed f

229 h concurrently improve specific capacitance, charge transfer resistance and cycling stability.

230 udocapacitance to over 300 F g(-1), reducing charge transfer resistance as low as 3 Omega, and provid

231 e binding event results in a decrease of the charge transfer resistance at the working electrode/elec

232 he incorporation of In into SnO2 reduces the charge transfer resistance during cycling, prolonging li

233 ce spectroscopy indicating three times lower charge transfer resistance for the GN anode.

234 The charge transfer resistance in the impedimetric measureme

235 Increasing rotating speed reduces the charge transfer resistance resulting in the lower detect

236 erformance of ACP is attributed to its lower charge transfer resistance than ABP.

237 The charge transfer resistance was decreased which was obser

238 aded RuNPs/GC shows a linear increase in the charge transfer resistance with an increase in As(III) c

239 py (EIS) study revealed a great reduction of charge transfer resistance with forced convective flow o

240 of the improved photocurrent and diminished charge transfer resistance, the all-V continuous-flow PE

241 This leads to a decrease in charge transfer resistance, which prevents the formation

242 y between two distinct states with different charge transfer resistance.

243 edance determination showed a relatively low charge-transfer resistance (17.44 Omega) and a long life

244 cterized with respect to surface morphology, charge-transfer resistance and P450 BM3 immobilization a

245 Overall, the charge-transfer resistance decreased after antibody bind

246 Charge transfer results in an induced ferromagnetic-like

247 Because the charge-transfer satellites were also resolved in the HER

248 centimeter-sized free-standing (BEDT-TTF)C60 charge-transfer single crystal is demonstrated.

249 arvesting relies on transport of excitons to charge-transfer sites.

250 ation of highly polar twisted intramolecular charge-transfer species in the excited state and is base

251 bases for the repair points to a long-living charge transfer state between G and A to be responsible

252 served for the first time the formation of a charge transfer state between the COF subunits across th

253 e-on to the acceptor interface have a higher charge transfer state energy and less non-radiative reco

254 substituent creates a twisted intramolecular charge transfer state that causes a large Stokes shift a

255 enium-polypyridyl dyes whose metal-to-ligand charge-transfer state (MLCT) energetics are tuned throug

256 in both molecules, in one case via a virtual charge-transfer state and in the other via a distinct ch

257 nsfer reaction coordinates between a triplet charge-transfer state and lower lying charge-separated a

258 locally excited state of the flavin, and the charge-transfer state associated with electron transfer

259 scribe a terrylenediimide dimer that forms a charge-transfer state in a few picoseconds in polar solv

260 The resulting charge-transfer state is surprisingly long lived and lea

261 s electronically excited singlet and triplet charge-transfer state lifetimes more than 2 orders of ma

262 ent absorption spectroscopy (fsTA) reveals a charge-transfer state preceding a 190% T1 yield in films

263 ons is excitation from the ground state to a charge-transfer state; the long charge-transfer-state li

264 d state to a charge-transfer state; the long charge-transfer-state lifetimes typical for complexes of

265 d that low-lying energy dark states, such as charge transfer states and polaron pairs, play an import

266 d to smaller electronic coupling between the charge transfer states and the ground state, and lower a

267 report the spin polarization of excitons and charge transfer states in organic charge transfer compos

268 large hyperpolarizability of intermolecular charge transfer states, naturally aligned at an organic

269 hannel of photoexcited DNA leads to reactive charge transfer states.

270 to describe the formation of species such as charge-transfer states and polaron pairs.

271 These results clearly establish the role of charge-transfer states in singlet fission and highlight

272 energy gaps between the locally excited and charge-transfer states suggest that electron transfer fr

273 en by excited-state mixing between pi-pi*and charge-transfer states, affording new insight into rever

274 0 fs, and (ii) coherence between exciton and charge-transfer states, the reactant and product of the

275 verned by the energy gap between singlet and charge-transfer states, which change dynamically with mo

276 to that proposed for twisted intramolecular charge-transfer states.

277 mine neurons of the SNc, leading to a higher charge transfer through L-type channels during pacemakin

278 that, based on structural data, the path for charge transfer through the [4Fe4S] domain of primase is

279 The biosensing platform facilitated charge transfer through the microwire-bridged IDEs, whil

280 Efficient charge transfer, tighter pi-pi stacking, and strong inte

281 from both structural integrity and enhanced charge transfer to achieve efficient and very stable cyc

282 tacene-C60 DA interface, we confirm that the charge transfer transition is strongly aligned orthogona

283 The results highlight a charge transfer transition that leads to changes in the

284 locally excited state and an intramolecular charge-transfer transition, respectively.

285 is likely attributable to an intramolecular charge-transfer transition.

286 moieties acting as the primary acceptors in charge-transfer transitions within these samples.

287 Charge transfer/transport in molecular wires over varyin

288 This twisted and rehybridized intramolecular charge transfer ("TRICT") state decays back to the plana

289 kbones and the possibility of intramolecular charge transfer upon excitation.

290 e illustrate the approach by calculating the charge transfer upon membrane insertion of the HIV gp41

291 antly impact the magnitude of the electronic charge transferred upon excitation.

292 s evolution reactions, offers a two-electron charge transfer via Mn(2+)/Mn(4+) redox couple, and prov

293 actual atmospheric discharge events, such as charge transferred, voltage, and action integral.

294 a new realization of the SIT by interfacial charge transfer, we developed extremely thin superlattic

295 h rates of substrate turnover and electronic charge transfer with an electrode, is a centrally import

296 t with experiments, indicating near complete charge transfer within a timescale of 100 fs.

297 This enhancement is driven by ultrafast charge transfer within the molecule, which refills the c

298 R-induced electric fields result in a direct charge transfer within the molecule-adsorbate system.

299 t that visible-light-promoted intermolecular charge transfer within the thiolate-aryl halide electron

300 f Ca(2+) and Mg(2+) inhibited intramolecular charge-transfer within photoexcited NOM, leading to subs