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1 attributed to isomerism of the methoxy-based chelates.
2 IRT) in addition to Fe(III)-phytosiderophore chelates.
3 macrocyclic GBCA chelates in lieu of linear chelates.
5 ate (DDC), a strong (64)Cu ligand, which can chelate (64)CuCl2 from the following injection to form t
6 active site, Asn211 is observed to directly chelate a hydrated divalent metal ion and Arg124, on the
8 ation of the highly conserved Gln-758, which chelates a nucleotide-associated Mg(2+) ion, eliminated
9 lgranulin B oligomer, MRP-8/MRP-14 oligomer) chelates a number of first-row transition metals, includ
12 ) radical scavenging activities, ferrous ion chelating abilities and reducing power results showed th
14 al scavenging capacity (50.18-86.79%), metal chelating ability (0.21-8.15%), ferric ion reducing powe
15 assay (67.66%), ABTS assay (78.81%), Fe(2+) chelating ability (51.20%), hydroxyl assay (60.95%) and
17 ty measurements, i.e. the reducing power and chelating ability measurements, for appropriate comparis
20 ckness, and the results demonstrate that the chelating action and dispersing effect of EDTA is critic
21 ylhydrazyl radical inhibiting and Fe(2+) ion chelating activities (IC50 25.05 and 350.7muM, respectiv
25 activity (IC50=39.33 +/- 3.2 mug/mL), metal chelating activity (IC50=56.51 +/- 3.6 mug/mL) and inhib
29 hocyanin content and 16.6-43.2% higher metal chelating activity than the cultivars grown in plains (9
39 been developed using the incorporation of a chelating agent in a common organic solvent, dimethyl su
40 or precursor cadmium complex that works as a chelating agent in order to increase optical and electri
41 suggests the importance of the alkali metal chelating agent in the reversibility of dinitrogen bindi
42 uman growth hormone, rhGH) modified with the chelating agent S-2-(4-isothiocyanatobenzyl)-1,4,7-triaz
45 ma mandarin fruits was extracted to obtain a chelating agent-soluble pectin fraction (ChSS), a dilute
49 ubstantially surpassing conventional Gd(III) chelating agents (r1 approximately 3 mM(-1)s(-1) at 4.7
50 ical "braking" system was achieved by adding chelating agents capable of sequestering the metal ion e
56 application of UV-Fenton processes with two chelating agents, nitrilotriacetic acid (NTA) and [S,S]-
57 ic acid, citrate, into the soil rhizosphere, chelating Al(3+) ions and thereby imparting Al-resistanc
58 re in rapid equilibrium with ethylene-opened chelates, (alpha-diimine)Ni(R)(C2H4)(+) complexes, the s
59 s how the new and rapidly expanding class of chelating ancillary ligands bearing 2,2'-bipyridyl, 1,10
60 Most bacteria have evolved mechanisms to chelate and transport ferric iron (Fe(3+)) via sideropho
61 nslocation velocities across a Cu(2+) HisTag-chelated and collagen-bound A1 single domain and A1A2A3
63 To synthesize two low-molecular-weight iron chelates and compare their T1 contrast effects with thos
64 interactions of multiple unstable lanthanide chelates and nonantenna ligands with sample leading to a
66 interactions of multiple unstable lanthanide chelates and selected chemicals within the sample leadin
71 ting the rearrangement via a lithium enolate chelate, and (3) imparting its influence on consecutive
72 ate that holomycin is an intracellular metal-chelating antibiotic that inhibits a subset of metalloen
76 e installation of other donors as the fourth chelating arm, while avoiding the formation of stereoiso
77 g a new class of planar tetradentate Mn(III) chelates assembled from a 1,2-phenylenediamido (PDA) bac
78 ntial for antimalarial activity supporting a chelate-based quinone methide mechanism involving metal
79 f photophysical titrations show this Eu(III) chelate behaves as an "on-off" luminescent switching pro
82 most preferred route begins with a bidentate chelate binding of deprotonated substrate to the Ni.
84 I) metal complexes possessing two tridentate chelates (bis-tridentate) are known to be more robust co
85 been prepared from carboxylate ions and the chelating/bridging ligand alpha-methyl-2-pyridine-methan
86 into strands through silver ions, which are chelated by the amine functions of one open cage and bou
92 system resulted in high levels of dispersed "chelated" calcium; conversely, disodium phosphate additi
94 tal complex stability, we evaluated the zinc-chelating capacity and stability of zinc complexes of wh
95 pectin (>/=58%), probably due to its higher chelating capacity of pro-oxidative metal ions (Fe(2+)),
97 and peroxyl radicals, the reducing power and chelating capacity were, in general, in the decreasing o
99 als of Y. luopingensis indicates that simple chelate claspers in males are plesiomorphic for horsesho
100 0 000 administrations compared with the same chelate classification without protein binding, at 5.2 (
101 he two chiral twisted-boat conformers of the chelated COD included in the already chiral cavity of th
102 the two cyclochiral conformers of the Ir(I) chelated COD was 5 kcal mol(-1) higher as an included or
104 s they facilitate a mononuclear six-membered chelate complex via the displacement of two hydroxo/aquo
105 method is based on the formation of anionic chelate complexes of Al(III) and Cr(VI) with o-hydroxy a
106 wed a significant decrease in the gadolinium chelate concentration in amniotic fluid compared with th
107 ted imaging; and-before and after gadolinium chelate contrast enhancement-T1-weighted 3-dimensional s
108 pieces were connected via a highly efficient chelate-controlled addition of a vinyl zincate to an alp
109 (allosteric) cooperativity, intramolecular (chelate) cooperativity and interannular cooperativity an
112 This system is evaluated in batch mode via chelating copper at the active site of tyrosinase and in
113 f detection: 0.019microM and 0.008microM for chelating copper at the active site of tyrosinase and th
114 onverting enzyme inhibitor that operates via chelating copper at the active site of tyrosinase and th
115 ,6-iPr2C6H3)}2](n) (n = 0 to -4), (dadi)(n), chelates Cr and Fe to give [(dadi)M] ([1Cr(thf)] and [1F
118 3))-H activation, including requirements for chelating directing groups and high reaction temperature
119 of non-exchangeable protons from macrocyclic chelates (e.g., DOTP(8-)) complexed with paramagnetic th
126 erimental protocols to assess the ability to chelate Fe(2+) and Cu(2+) using 96-well microplates, we
128 e further show that ICDH-Coumarin is able to chelate Fe(3+) to switch off RssAB signaling, triggering
129 ulate matter such as biomass burning aerosol chelate Fe(II), but the effect on ROS formation in the p
130 sults suggest that siderophores could partly chelate Fe(III) in cloud waters and thus potentially imp
131 n combination with a colorimetric screen for chelated Fe(III)-NTA reduction with NADH as electron don
133 e starting to question the use of gadolinium chelates for clinical magnetic resonance (MR) imaging.
136 These materials can degrade into smaller chelating fragments at rates proportional to the level o
138 allenge have generated a range of innovative chelate-free radiolabeling methods that exploit intrinsi
139 TdTs facilitate utilization of iron or iron chelates from host-derived proteins, including transferr
140 phyla of the tested strains and the type of chelating functional groups (i.e., hydroxamate, catechol
144 t herein a novel allysine-binding gadolinium chelate (GdOA), that can non-invasively detect and quant
145 erately higher concentrations, however, iron chelates generated similar contrast effects at T1-weight
147 extrapolated to substrates bearing a single chelating group, providing further insight into the reac
149 s as ligands that combine two distinct metal-chelating groups, lipoic acid and imidazole, for the sur
155 time points, the distribution of gadolinium chelate in the fetus was comparable to that expected in
156 ntrations of multiple linear and macrocyclic chelates in a rat model to better understand the scope a
157 sequences of the bite angle of five-membered chelates in cubic tetramers and resulting solvation numb
160 xpression and stability of Al(3+) and Fe(3+) chelates in pH 6-7 were evaluated by spectrophotometry (
161 demonstrating that the pharmacophores of the chelating inhibitors (S)-10a, (R)-10a, and 10b were bind
163 the auxiliary, with the metal cation (K(+)) chelated into the malonate six-membered hole as a Z-enol
165 Molecular analysis revealed that Ent can chelate intracellular labile iron that is required for n
168 tor, deferiprone, is well tolerated, able to chelate iron from various brain regions and improve PD s
169 ly compromised the ability of transferrin to chelate iron, as iron chelation combined with sodium bic
171 er than deferasirox, but rapidly donates the chelated iron to deferasirox, consistent with a shuttlin
173 actors linked to AD pathogenesis, namely by: chelating iron, copper and zinc; scavenging reactive oxy
174 valuate whether administration of gadolinium chelates is necessary for evaluation of pediatric tumors
177 its two terminal aryls to afford a bidentate chelating ligand (CN(tBu)Ar3NC) that is able to stabiliz
178 o-Vanillidine-2-amino-p-cresol was used as a chelating ligand and 1-undecanol was selected as an extr
180 of the phenyl ring of 2-phenylbenzimidazole chelating ligand of the ruthenium (3a-g) and iridium com
181 anism for homogeneous catalysts in which the chelating ligand plays a key role in facilitating the ca
183 lvent, extraction time, concentration of the chelating ligand, salt effect, centrifugation time and s
184 rifluoromethylation of unprotected bidentate chelating ligand, xanthine alkaloids, nucleosides, and r
185 n fluorophores with heterobiaryl N,O- or N,N-chelate ligands were prepared and photophysically charac
189 adding clustering agents, such as calcium or chelating ligands, favor the lateral cis adhesion of the
190 noline), O,O (diketonate), or S,S (dithione) chelating ligands, have been characterized by X-ray crys
193 proton relaxitivities compared with other Gd-chelates, making them the promising contrast agents for
195 titution generally increased lambdamax of Cy chelates: malonic acid monoacylation<triglycosylated Cy<
197 ns of the phosphonate group of the alpha-CNP chelate Mg(2+), mimicking the chelation by the beta- and
201 extrin (beta-CD) and ferrocene (Fc) and iron chelating moieties composed of deferoxamine (DFO) into t
203 ll-L-serine- (MAS3) and all-D-serine- (mas3) chelating moieties were evaluated in parallel, and a kit
206 wo contrast agents: a clinically approved Gd chelate, Multihance((R)) (gadobenate dimeglumine), and a
207 of both Evans blue dye (EBD) and Gadolinium-chelated N-(2-hydroxypropyl)methacrylamide (HPMA) copoly
208 ll, renal clearable, silica based gadolinium chelated nanoparticles (SiGdNP) provide simultaneous MR
209 iotics and emphasizes the potential of metal-chelating natural products in antimicrobial therapy.
211 A-modified somatropins as well as to gallium chelated NOTA-functionalities (Ga-10:1 NOTA-somatropin);
216 set up an original method of screening metal chelating peptides in a hydrolysate using Surface Plasmo
219 operation between iridium(III) and a 1,3-N,O-chelating phosphoramidate ligand has been used to develo
220 tage of time-resolved luminescence of Tb(3+)-chelated phosphotyrosine-containing peptides, which faci
223 ce; however, only the aspartic acid modified chelates produced an amide proton-based PARACEST signal.
224 strategy that enables to modulate the metal chelating properties of hydroxamic acid groups by bioort
229 biological coordination chemistry of Ni(II)-chelating proteins in nature and provide a foundation fo
231 ariety of strategies were explored to form a chelated radical intermediate en route to xiamycin A, in
232 (2H7), with the other arm of the FP an anti-chelated radiometal trap for a radiolabeled ligand (yttr
233 using 1-(2-Pyridylazo)-2-naphthol (PAN) as a chelating reagent and detection by electrothermal atomic
236 rstly synthesized and characterized as a new chelating reagent for determination of some metals.
238 ice were incubated with excess Cu or with Cu-chelating reagents; effects on cell fat content and ATP7
241 of FRO2 transcript levels, as well as ferric chelate reductase activity, and is causal for a portion
242 d by an impaired ability to boost the ferric chelate reductase activity, which is an essential proces
243 through the analysis of expression of ferric chelate reductase, iron-regulated transporter, and putat
244 ed in iron-regulated transporter1 and ferric chelate reductase2 knockout mutants and was prioritized
246 ycidyl methacrylate (GMA) based terpolymeric chelating resin was synthesized for the separation and p
248 , volume of the sample and eluent, amount of chelating resin, and interference of ions were examined.
253 conformers associated with the five membered chelate rings (lambda/delta), alignment modes of the C-C
256 m citrate either alone or as part of a mixed chelating salt system resulted in high levels of dispers
257 pite its simplicity, was a good indicator of chelating salt-calcium interactions in rennet casein dis
258 tudy elucidates the critical role of calcium chelating salts in modulating casein hydration and dispe
260 is study investigated the effects of calcium chelating salts on calcium-ion activity (ACa(++)), calci
265 nufacture of the matrices containing calcium chelating salts; with approximately 23% of total calcium
266 or each type of oxygen-donor present in such chelating (Section 1) or bridging (Section 2) hybrid lig
268 st-effective material with a high density of chelating sites designed for mercury capture and therefo
269 ude hierarchical porosity, a high density of chelating sites, and the material's robustness, which im
270 only those proton donors that coordinate or chelate strongly to Sm(II) promote anthracene reduction
271 he feasibility of highly selective non-metal chelating, substrate-competitive inhibitors of the JmjC
275 (oxygen nanosensors) and a pH sensitive BF2-chelated tetraarylazadipyrromethene dye (aza-BODIPY) was
276 nsing materials are based on fluorescent BF2-chelated tetraarylazadipyrromethene dyes (aza-BODIPYs) d
280 emokine with CXCR1 (1-350) containing Mn(2+) chelated to an unnatural amino acid assists in the chara
281 in which imine acts as a directing group by chelating to the metal center, affords a potential route
284 very generally entails chemotypes capable of chelating two divalent metal ions in the RNase H active
288 ng within the MMP-13 active site, the Zn(2+) chelating unit was replaced with nonchelating polar resi
289 contrast agent with a single gadolinium (Gd) chelate using a quantitative MRI T1 mapping technique in
293 dified to form a bifunctional chelator and 4 chelates were conjugated to a fibrin-specific peptide to
294 cts of hydroxycinnamic acids on cyanidin and chelates were investigated by addition of the acids to t
296 H2 binding enthalpy of 5 linkers which were chelated with 11 different transition metals (Tm), inclu
297 C inhibitors contain hydroxamate moiety that chelates with zinc ion to become the cofactor of HDAC en
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