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1 cids, sugars and nucleotides, are inherently chiral.
3 eptoid aromatic side chains, among which the chiral 1-naphthylethyl (1npe) group yielded the best res
4 ion of microbial strains that produce either chiral 2-methyl-3-hydroxy acids (1.1 +/- 0.2 g L(-1)) or
6 , sulfur, and fluorine nucleophiles afforded chiral 3,4-disubstituted 2-(trifluoromethyl)pyrrolidines
7 les, by (1) enabling in situ assembly of the chiral 3-amino-1,5-diene precursor, (2) facilitating the
9 s the best co-catalyst among the examined 28 chiral acids, for inducing the enantioselectivity of alp
11 how how odd viscosity in weakly compressible chiral active fluids can lead to density and pressure ex
12 or rapid and predictable assembly of complex chiral acyclic and cyclic nitrogen-containing motifs in
14 molecular chiral ensembles made out of small chiral adsorbates, and by adsorption of more complex chi
17 chemical isomerization in sterically crowded chiral alkenes is the driving force for molecular rotary
18 l JoSPOphos ligand, hydroamination generates chiral allylic amines with high regio- and enantioselect
20 cts could be further derivatized to valuable chiral alpha,alpha-disubstituted-beta-aminonitriles thro
21 a-2-azabicyclo[3.2.1]octane derivatives from chiral alpha-hydroxyaldehyde derivatives in one step.
24 ines can be derivatized to afford a range of chiral amine building blocks incorporating motifs readil
25 cal to reaction development was the use of a chiral amine catalyst, bearing a redox-active carbazole
28 ion of the molecular twist is achieved using chiral amino ligands (diastereomeric excess up to 77%, t
30 enantiomeric conformers able to recognize a chiral analyte and greatly amplify its chiroptical reado
31 rs only the simplest possible combination of chiral and achiral active stresses, yet this leads to an
32 icals and synthetic intermediates, including chiral and achiral drugs and metabolites, constitutional
33 eric mixtures, and of prochiral molecules on chiral and achiral model surfaces, especially on well-de
36 of 1 with its 2,3-dihydro isomer 2, which is chiral and racemic, by base-catalyzed olefin isomerizati
38 ncreased product selectivity resulted from a chiral anion dependent lowering of the activation barrie
39 of benzyl acrylates that is facilitated by a chiral anion phase transfer (CAPT) process is presented.
40 measurements provide strong evidence for the chiral anomaly of Weyl fermions-namely, the emergence of
47 r demonstrated through derivatization of the chiral aziridine products to obtain a diverse array of f
48 harmacaphore to nitroalkenes, delivering the chiral barbiturate derivatives in high yields and high e
50 r Josiphos ligand promotes the generation of chiral benzylic isomers, when combined with a Hantzsch e
52 nsformation provides access to highly useful chiral beta-alkynyl Meldrum's acid building blocks as de
53 ion in organocatalysis, the diastereomeric P-chiral beta-aminophosphine-based bifunctional thioureas
55 des are useful synthons for the synthesis of chiral beta-hydroxylated, beta-fluorinated, and beta-ary
56 the nature of its structure, the 5-membered chiral biaryl heterocyclic scaffold represents a departu
59 ositioned remote amide group in the designed chiral binaphthyl-based ligand plays the essential role
62 addition to sulfonyl hydrazones catalyzed by chiral biphenols to access enantioenriched allenes in a
63 hydrazines, and allylboronates, catalyzed by chiral biphenols, results in an asymmetric reductive tra
66 nthesis are the use of a Lewis acid assisted chiral Bronsted acid (chiral LBA) mediated cationic poly
68 a-amino acids, which are themselves valuable chiral building blocks for chemical synthesis and precur
69 sformations of the resulting multifunctional chiral building blocks highlight the potential for rapid
70 functionalization provides a direct path to chiral building blocks with a newly formed stereocentre
71 procedure was applied to the synthesis of (a)chiral bulky unsymmetrical unsaturated 2,6-diisopropylph
72 eaction of indoles leads to the formation of chiral C-N cross-coupled products with functional group
73 cyclic YbDO3A-trisamide complexes with delta-chiral carbons in the three pendant side-arms were exami
77 is work describes the first example of using chiral catalysts to control site-selectivity for the gly
78 h permutations of the enantiomers of the two chiral catalysts, all four stereoisomers of the products
80 preorganized and conformationally restricted chiral cavities of [2]rotaxanes to achieve enantioselect
81 imulation indicated hydrodynamic drag on the chiral cell shape caused rotation, and the predicted geo
88 d tetrahydroisoquinolines (THIQs) with three chiral centers in a step-efficient and selective manner
89 absolute configuration of the newly created chiral centers was definitively assigned for all the cor
90 t an investigation into the use of ultrafast chiral chromatography as a second dimension for 2D chrom
91 sampling, and comprehensive) using ultrafast chiral chromatography in the second dimension are succes
92 ved by coupling the azobenzene unit with two chiral clamps and with a further azobenzene switching un
97 e present the stereoselective synthesis of a chiral covalent organic cage consisting of three redox-a
101 with the electrons pairing with a p-wave or chiral d-wave symmetry, depending on the position of the
104 ium complex generated from [Ir(COD)OMe]2 and chiral dinitrogen ligands that we recently disclosed.
105 ecular architectures, thereby regulating the chiral directional "bonding" of gold nanorods decorated
108 ortant but previously unrecognized effect of chiral edge modes on the nuclear spin polarization.
112 two-dimensional semimetal that hosts unique chiral electron-optical effects due to its honeycomb cry
114 uminescence quenching due to the tendency of chiral enantiomers to form complexes with gamma-CD in di
115 namely, via the formation of supramolecular chiral ensembles made out of small chiral adsorbates, an
117 iral molecules capable of providing suitable chiral environments for reactants by themselves, via the
118 he triradical trianion of a shape-persistent chiral equilateral molecular triangle having three napht
119 eriments revealed that, while degradation of chiral fluoxetine (FL) in river water occurs via non-ena
122 dihydrofuran precursors gave rise to axially chiral furans with high enantiopurities accounting from
123 roxymethyl group with the epimerization of a chiral furanyl ether in a single transformation, high le
124 hyl-3-hydroxypentanoate methyl esters (8) by chiral GC-MS established that the BonMT2-catalyzed methy
125 ds composed of self-spinning objects such as chiral grains or colloidal particles subject to torques.
126 nding of chiral amino acids is proposed as a chiral growth mechanism, where a 'mother' subunit nanopa
128 Here we investigated the dissipation of the chiral herbicide S-metolachlor (SM) in soil in relation
129 propellers, have been achieved with various chiral HgS NC building blocks via distinct assembly mech
132 nM] was resolved into its two enantiomers by chiral HPLC, and the absolute configuration was establis
133 icryptophane host can be readily resolved by chiral HPLC, giving an easy access to the enantiopure mo
134 uted phenyl ring is expected to form axially chiral hydroxylated metabolites (OH-PCBs); however, the
135 ates from an intricate interplay between the chiral imprint of DNA, off-resonant excitonic coupling t
136 dependent electron transfer, indicating that chiral imprinting of the dots may lie at the origin of t
141 ynthetic systems involve the transmission of chiral information between the molecular-, meso- and mac
143 We also assess technological prospects of chiral inorganic materials with current front runners be
145 of both differences and similarities between chiral inorganic, organic, and biological nanostructures
147 thetic approaches utilize an advanced common chiral intermediate triflate from which all analogues co
148 types of handedness, resulting in different chiral interplays expressed as observables through mater
150 gest that structural perturbations caused by chiral inversions of amino acid side-chains may be espec
151 s and alkenes has been achieved using non-C2-chiral Josiphos digold(I) complexes as catalysts, by the
154 including a huge number of almost degenerate chiral Landau bands, implying pronounced magneto-transpo
155 a Lewis acid assisted chiral Bronsted acid (chiral LBA) mediated cationic polyene cyclization and a
159 rate that lower alkene amounts and/or higher chiral ligand concentration can minimize the deleterious
160 smox]12(OH2)3}.212H2O (1), where hismox is a chiral ligand derived from the natural amino acid l-hist
161 iral organocatalysts or metal complexes with chiral ligands are used, has become the most valuable me
162 y functional theory (DFT) based screening of chiral ligands for transition-metal-catalyzed reactions
166 veloped a one-step procedure to a variety of chiral lipophilic and conformationally rigid amines and
168 he diastereoselective addition of an axially chiral lithiated alkoxyallene to an enantiopure cyclic n
169 for chiral molecules, magnetic Skyrmions in chiral magnets and nonreciprocal carrier transport in ch
171 way towards the fabrication of thin films of chiral magnets that host certain spin whirls, so-called
172 hat suggest the existence of one-dimensional chiral Majorana fermion modes in the hybrid system of a
173 ical bonding renders 1,3-substituted allenes chiral, making them attractive targets for asymmetric sy
175 smart implementation of ferroelectricity in chiral metal-organic frameworks (MOFs): following a sing
177 In this paper, we propose a type of planar chiral metamaterial consisting of interconnected metal h
178 To fully leverage the innate duality of chiral metamaterials for future optical technologies, it
179 by manipulation of input powers incident on chiral metamaterials offers potential for active optics
180 novel stair-like and coil-like gold nanorod chiral metastructures, which is strongly affected by the
181 he platinum surface and their performance as chiral modifiers that impart enantioselectivity to the h
182 hesis, the Ca(2+) counterions of a preformed chiral MOF of formula Ca6(II){Cu(II)24[(S,S)-hismox]12(O
183 the quinoline and by introduction of simple chiral moieties, resulting in a combination of hydrophob
184 rating a judiciously chosen thermoresponsive chiral molecular switch into an achiral liquid crystalli
185 dsorbates, and by adsorption of more complex chiral molecules capable of providing suitable chiral en
186 , planarized nanophotonic interface to sense chiral molecules with inherently weak circular dichroism
187 ecules causes charge redistribution, and for chiral molecules, a Hall voltage is measured that indica
188 d approach to the stereochemical analysis of chiral molecules, especially in terms of process immedia
189 al phenomena such as circular dichiroism for chiral molecules, magnetic Skyrmions in chiral magnets a
195 the assembly architecture within a class of chiral nanoparticle superstructures is important for fin
197 iew will cover both experiment and theory of chiral nanostructures starting with the origin and multi
198 ility were achieved by combining achiral and chiral narrow-bore columns (2.1 mm x 100 mm and 2.1 mm x
202 a catalytic or stoichiometric amount of new chiral non-C2-symmetric iodoarenes(III) is reported.
203 nantioselective APKR could provide access to chiral, nonracemic alpha-acyloxy and alpha-hydroxy cyclo
204 bolites (OH-PCBs); however, the formation of chiral OH-PCBs from prochiral PCBs has not been demonstr
206 of achiral molecules and racemic mixtures of chiral ones form flat films and show uniform textures be
209 region are consistent with the existence of chiral ordering in a temperature range above the Curie t
210 lid metal catalysts is their modification by chiral organic compounds, as most prominently represente
211 e spin-selectivity by coating the anode with chiral organic semiconductors from helically aggregated
215 he effective removal of two electrons from a chiral organocuprate R2CuLi, by i-propyl 2,4-dinitrobenz
216 ly reported the synthesis of polysubstituted chiral oxazepanes in three steps from commercially avail
220 substituents within the same bay region, the chiral peropyrene adopts a twisted backbone with an end-
221 '',6,6''-tetrayne derivatives as precursors, chiral peropyrenes were formed after a 4-fold alkyne cyc
223 expression related to selective toxicity in chiral pesticide, nor on epigenetic changes, such as DNA
224 y be used to design and understand nanoscale chiral phenomena and highlight important recent advances
225 tuted enol esters using Rh catalysts bearing chiral phosphine-phosphite ligands (P-OP) has been studi
228 ryption of the transition states involved in chiral phosphoric acids catalyzed addition of nucleophil
231 iginally assigned absolute configurations of chiral polyacetylenes from Atractylodes macrocephala sho
235 al rejection through Gly-cisPro motif during chiral proofreading underlies the inability of D-aminoac
237 ties for the stereoselective generation of a chiral quaternary carbon center in the alkaloid scaffold
239 ternary carbon stereocenters from achiral or chiral racemic reactants via transition metal catalysis.
241 een space occupancy, guest conformation, and chiral recognition based purely on dispersion forces and
242 hod based on d-DNP NMR spectroscopy to study chiral recognition is described for the first time.
247 followed by kinetic resolution of 2 with the chiral rhodium catalyst realized the present dynamic kin
249 MD) simulation experiments revealed that the chiral rotaxane cavity significantly enhances enantiodis
250 interestingly, the spontaneous resolution of chiral S-isomer of the 1-SH adduct occurred during cryst
252 x 50 mm columns packed with highly efficient chiral selectors (sub-2 mum fully porous and 2.7 mum fus
253 ization switching is achieved by adsorbing a chiral self-assembled molecular monolayer on a gold-coat
254 rein, we constructed helical fibrils through chiral self-assembly of nucleobase-peptide conjugates (N
255 ng (also known as chiral self-recognition or chiral self-discrimination) is fundamental for creating
263 ion studies, we demonstrate director-encoded chiral shape actuation in thin-film nematic polymer netw
265 ccurately map the nonlinear crossover to the chiral soliton lattice regime from the chiral helimagnet
268 e study the effects of distortions caused by chiral springs and helices on the colloidal self-organiz
270 logical features and predict the presence of chiral squeezed fluctuations at the edges in some parame
271 The overall synthetic approach stems from chiral starting material benzyl (S)-2-methyl-4-oxopiperi
272 of chiral separations has limited the use of chiral stationary phases (CSPs) as the second dimension
273 ous evidence of superconductivity reflecting chiral structure in which the forward and backward super
276 ol ethers derived from arylmethyl ketones to chiral sulfinimines in excellent yield and selectivity.
277 , best promoted by a Cu-based complex with a chiral sulfonate-containing N-heterocyclic carbene, are
279 At the same time, distinct similarities with chiral supramolecular and biological systems also emerge
280 can programmably self-assemble into various chiral supramolecular architectures, thereby regulating
282 and imaginary fields on a lattice exhibiting chiral symmetry, which form two strands that interleave
285 the population of a specific enantiomer of a chiral terpene could be enhanced relative to the other e
290 sulators, the quantum anomalous Hall effect, chiral topological superconductors, helical topological
294 port on wholly synthetic, water-soluble, and chiral tubules that incorporate photoswitchable building
298 plane films are generally expected to be non-chiral, we show that right-handed spin rotations are str
300 e first detailed investigation of the use of chiral XB rotaxanes for this purpose, extensive (1)H NMR
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