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1 tachlorophenol (PCP), but rather by the less chlorinated 2,3,5,6-tetrachlorophenol (2,3,5,6-TeCP), on
2 ith amino acid and eventual formation of the chlorinating agent in the form of the hydrochloride salt
3 it is not possible to preclude H2OCl(+) as a chlorinating agent, we were able to model our low-pH dat
7 remediation of groundwater contaminated with chlorinated aliphatic hydrocarbons such as perchloroethe
8 orm FeS, suggesting that, after oxidation by chlorinated aliphatics, FeS can be regenerated by additi
9 apid disinfection of the hospital WDS with a chlorinated, alkaline detergent and subsequent superchlo
11 ancomycin, exclusive conversion of vicinally chlorinated alkanes, and tolerance to short-term oxygen
13 moved toward alterative compounds including chlorinated alkyl and nonchlorinated aryl organophosphat
14 ions, N-chlorination and dechlorination of N-chlorinated amide links by hydroxyl ion are the two domi
15 ssion as a result of the hydrolysis of the N-chlorinated amidic N-C bond due to nucleophilic attack b
21 ce on calibration was not as significant for chlorinated and brominated substances as observed for hu
22 end=0.13; the ORs at the 95th percentile for chlorinated and brominated THMs were 1.77 (95% CI: 1.05,
23 xtracting nonvolatile and volatile DBPs from chlorinated and chloraminated drinking water to minimize
24 o experiments, this precursor is furthermore chlorinated and cyclized to merochlorin A and isomeric m
26 CNs), polychlorinated dibenzofurans (PCDFs), chlorinated and mixed brominated/chlorinated anthracenes
29 s from 16 California residents in 2011 for 6 chlorinated and nonchlorinated dialkyl or diaryl phospha
30 ransformations were intensively studied with chlorinated and simply structured compounds such as chlo
32 lationship between bladder cancer and total, chlorinated, and brominated trihalomethanes (THMs) throu
33 m a water utility was concentrated 136-fold, chlorinated, and provided as drinking water to Sprague-D
34 ss spectral patterns was applied to identify chlorinated- and brominated-containing substances with m
35 ns (PCDFs), chlorinated and mixed brominated/chlorinated anthracenes/phenanthrenes, and pyrenes/fluor
36 other halogen atom siblings, the utility of chlorinated arenes and (hetero)arenes are twofold: they
37 ed a substantial biodegradation capacity for chlorinated aromatic compounds at the oxic/anoxic interf
38 oPhenol catalyzed aza-Darzens reaction using chlorinated aromatic ketones as nucleophilic partners fo
39 dapted to survive in sites contaminated with chlorinated aromatics and may be useful for in situ bior
40 pea (Pisum sativum) seeds, the level of the chlorinated auxin, 4-chloroindole-3-acetic acid (4-Cl-IA
42 wo types of PCDD/F precursors, involving all chlorinated benzenes (CBz) and chlorinated phenols (CPh)
46 und to be strongly dependent on the ratio of chlorinated benzenes to chlorinated phenols and oxygen c
49 In this study, we describe the screening for chlorinated biomolecules by the use of mass isotope rati
52 ptor (AhR) agonist activities of a series of chlorinated, brominated, and mixed bromo/chlorocarbazole
53 hat allows for the simultaneous detection of chlorinated, brominated, or mixed halogen-substituted co
56 lic indices and the experimental profiles of chlorinated carbazole, phenoxazine, and phenazine sugges
57 was enriched and maintained using the highly chlorinated commercial PCB mixture Aroclor 1260 for orga
58 , and N2O emit chloroform and other volatile chlorinated compounds (VOCls) and are thus unsuitable in
60 vided information on the bioaccumulation for chlorinated compounds as well as for some polycyclic aro
62 ic isotope analysis (CSIA) is unsuitable for chlorinated compounds such as trichloroethene (TCE) and
64 nowledge, this is the first time such highly chlorinated compounds were studied with the LC-IRMS syst
66 he main precursors, namely acylglycerols and chlorinated compounds, on the formation yield of MCPD es
70 types were dominated by PCB 28/31 and higher-chlorinated congeners in both groups reflecting rapid me
72 usion of brominated congeners in addition to chlorinated congeners when computing the toxic equivalen
73 rs revolatilization is important, for higher-chlorinated congeners, the main processes are storage in
74 d analogs contributed 370% more TEQ than did chlorinated congeners, which indicates the need to inclu
77 s of groundwater samples containing BTEX and chlorinated contaminants at microgram per liter concentr
78 singly used to assess natural attenuation of chlorinated contaminants, in which anaerobic reductive d
80 to encode a new pathway to generate a novel chlorinated coumarin "non-natural" product in E. coli.
85 s of these complexes and their corresponding chlorinated derivatives have been characterized by NMR s
89 ed kinetic calculations for the formation of chlorinated dibenzothiophenes and chlorinated thianthren
90 cterized by a lower contribution of the less chlorinated dioxins in comparison with the furans, consi
91 hese applications include the measurement of chlorinated dioxins in soil samples, the identification
101 tion of methyltrioxorhenium (MTO) onto these chlorinated domains serves to activate it as a low tempe
103 nt "whole" mixture of DBPs representative of chlorinated drinking water, including unidentified DBPs
104 DCAM or, more broadly speaking, N-Cl-HAMs in chlorinated drinking waters is of significance because t
106 etailed parts of our analysis are focused on chlorinated drugs as a function of approval date, diseas
109 o a change in the ratio of electron donor to chlorinated electron acceptor in continuously stirred ta
113 We collected 95 groundwater samples across 6 chlorinated ethene-contaminated sites and searched for r
115 en in other hydrocarbon contaminants such as chlorinated ethenes and ethanes due to in situ degradati
116 ractionation was found to be smaller for the chlorinated ethenes and remarkably deviating from an inv
118 nes in flowing groundwater, mass transfer of chlorinated ethenes between mobile groundwater and stati
119 ed experimental results on dehalogenation of chlorinated ethenes both in well-mixed systems and in si
120 The nonexistent chlorine isotope effects of chlorinated ethenes in all aqueous OS-SET experiments co
121 model applied here accounts for transport of chlorinated ethenes in flowing groundwater, mass transfe
122 and unsuccessful reductive dechlorination of chlorinated ethenes in groundwater under different flow
123 hod to obtain high-frequency measurements of chlorinated ethenes in oak (Quercus rubra) and baldcypre
126 ment factors for microbial dehalogenation of chlorinated ethenes vary considerably we studied the pot
127 Consequently, competitive inhibition among chlorinated ethenes was examined and then added to the m
128 ta(13)C were from 2 to 60 mug/L (MTBE, BTEX, chlorinated ethenes, and benzenes) and 60-97 mug/L for d
136 al with known isotope composition, including chlorinated ethylene, chloromethane, hexachlorocyclohexa
137 hosphate esters (OPEs) and 45 brominated and chlorinated flame retardants (BFRs) were measured in par
139 able to effectively beta-brominate and beta-chlorinate for the first time cyclic enones with differe
140 HO-PCBs profile after weight loss with lower chlorinated HO-PCBs increasingly gaining importance.
142 ladium-based remediation method for reducing chlorinated hydrocarbons from marine environments by emp
143 eling study aims to reveal if degradation of chlorinated hydrocarbons in low permeability sediments c
145 mudstone; however, the carbon source for the chlorinated hydrocarbons is not definitively of martian
147 on and CSIA profiles were determined for the chlorinated hydrocarbons that had diffused into the clay
149 formation was promoted by UV254 exposure of chlorinated imidazole and guanidine compounds, which sug
150 d 1,4-dioxane is employed as a stabilizer of chlorinated industrial solvents and is a widespread envi
151 by UV/FC and SS/FC and minimal formation of chlorinated intermediates and disinfection byproducts.
152 After all free chlorine was consumed, the chlorinated intermediates autodecomposed slowly with a f
153 s results in the accumulation of the harmful chlorinated intermediates dichloroethene (DCE) and vinyl
155 3 min(-1); when a reductant was added, these chlorinated intermediates were then reduced back to BMAA
158 n contrast to North American marine mammals, chlorinated MBPs and DMBPs were more abundant than their
159 purification led to the isolation of several chlorinated metabolites, including two new natural produ
162 direct, mild, operationally simple, and safe chlorinating method is compatible with a range of nitrog
163 xy-brominated diphenyl ethers (MeO-BDEs) and chlorinated methyl- and dimethyl bipyrroles (MBPs and DM
165 p-nitrophenylisocyanate and the formation of chlorinated nitrile oxide were chosen as plausible mecha
166 oom temperature conversion of brominated and chlorinated nucleobases or nucleobase precursors as star
169 bited a low or nondetectable toxicity, lower-chlorinated OH-PCBs significantly inhibited the germinat
172 ool/spa waters were 1.8x more mutagenic than chlorinated ones; spa waters were 1.7x more mutagenic th
174 The composition profiles were dominated by chlorinated OPEs at the urban and rural sites and by non
175 studied for the reductive transformation of chlorinated or nitroaromatic compounds, no work exists e
178 efore, utilizing enzymes in the synthesis of chlorinated organic compounds is important, and providin
184 D), tetrabromobisphenol A (TBBPA), and three chlorinated organophosphate flame retardants (ClOPFRs),
185 base-induced aromatization of the resulting chlorinated oxanorborn(adi)enes 2 afford N-free-dihydroi
192 analyte signal of a polychlorinated alkanes (chlorinated paraffins) technical mixture that contains 7
194 ely revolatilized after deposition, a higher-chlorinated PCB congener is predominantly transferred to
201 ollowing initial hydroxylation of these less-chlorinated PCBs, metabolic sulfation to form PCB sulfat
202 oils were found to be a source of PAHs, high chlorinated PCBs, the majority of OCPs and PBDEs, and a
206 ngest CL was produced not by the most-highly chlorinated pentachlorophenol (PCP), but rather by the l
208 ammals, including mercury (whole blood), sum chlorinated pesticides (comprised of approximately 95% D
209 (PCBs) congeners, congener groups and three chlorinated pesticides [dichlorodiphenyldichloroethylene
210 ted biphenyl (PCB) congener groups and three chlorinated pesticides in a Native American population.
211 lycyclic aromatic hydrocarbons (PAHs), three chlorinated pesticides, and five metals in Norwegian wat
212 s, a new poster showcasing the structures of chlorinated pharmaceuticals was created specifically for
217 edominantly from chlorinated benzenes, while chlorinated phenols are responsible for majority of PCDD
218 em was demonstrated for the determination of chlorinated phenoxyacetic acid herbicides in spiked rive
221 coides mccartyi strain JNA detoxifies highly chlorinated polychlorinated biphenyl (PCB) mixtures via
223 Subsequent diverse transformations of the chlorinated products demonstrate the versatility of meta
224 d through monitoring of formation of HMF and chlorinated products under pyrolytic conditions using gl
226 eport the invention of a new guanidine-based chlorinating reagent, CBMG or "Palau'chlor", inspired by
227 onditions, this compound outperforms typical chlorinating reagents for organic synthesis, facilitates
229 s of ClO2 on C. parvum oocyst infectivity in chlorinated recreational water venues (e.g., pools).
230 rination for inactivating Cryptosporidium in chlorinated recreational water venues, but further studi
232 the transformation products of oxybenzone in chlorinated seawater swimming pools; especially that use
234 of the long term health effects of the lower-chlorinated, semi-volatile PCBs in the indoor environmen
236 hloride in surface soils, and the ability to chlorinate soil organic matter (SOM) appears widespread
237 advantage of this approach is the use of non-chlorinated solvent and small amounts of organic solvent
241 tificially contaminated by a three component chlorinated solvent mixture (tetrachloroethene (PCE) 45
242 dation by bacterial pure cultures exposed to chlorinated solvent mixtures as well as in environmental
244 set of sites, there was little evidence that chlorinated solvent remedial efforts (e.g., chemical oxi
247 ous film-forming foams (AFFFs) to extinguish chlorinated solvent-fueled fires has led to the co-conta
248 euterated) and nonlabeled isotopologues) and chlorinated solvents (trichloroethene, TCE, and cis-dich
251 study investigated the impacts of individual chlorinated solvents and their mixtures on aerobic 1,4-d
252 cles can contribute to the transformation of chlorinated solvents and various other contaminants into
253 ane bioremediation strategies at sites where chlorinated solvents are present as co-contaminants.
255 ion that abiotic natural attenuation (NA) of chlorinated solvents can be important has created demand
256 ng reactants for reductive dechlorination of chlorinated solvents due to high reaction rates and the
257 erovalent iron (Fe(0)) in the degradation of chlorinated solvents in subsurface environments is of in
259 ation approaches for sites contaminated with chlorinated solvents requires a fundamental understandin
262 es used for the bioremediation of co-mingled chlorinated solvents such as trichloroethene (TCE).
263 ition of 1,4-dioxane biodegradation rates by chlorinated solvents was attributed to delayed ATP produ
265 are a common photoisomerization mechanism in chlorinated solvents with notable differences in kinetic
267 bacterium involved in the bioremediation of chlorinated solvents, reveal homologous genes encoding a
268 s 1-7 exhibit moderate-to-good solubility in chlorinated solvents, such as 1,2-dichlorobenzene and ch
275 ed to a stronger interaction between MTO and chlorinated surface regions, as well as extensive deplet
278 o-beta-aminoketone intermediates featuring a chlorinated tetrasubstituted stereocenter can be isolate
280 rmation of chlorinated dibenzothiophenes and chlorinated thianthrenes that could be applied to predic
281 r, concerns about the potential formation of chlorinated transformation products require an understan
282 n, the antimicrobial agent in handsoaps, and chlorinated triclosan derivatives (CTDs, formed during d
283 kidneys, levels of HOCl-derived oxidized and chlorinated tryptophan residues W(28) and W(192) are sig
284 acute coronary syndrome had higher levels of chlorinated tyrosine 192 and oxidized methionine 148 com
286 The absence of lysine increased yields of chlorinated tyrosines and decreased yields of brominated
287 HOCl is present, the SiF fluorophores become chlorinated, via an intermediate halohydrin, resulting i
288 oroaldehydes, kinetic resolutions of complex chlorinated vinyl epoxide intermediates, and Z-selective
289 excess of 4% decreased the decomposition of chlorinated VOCs as a result of ozone and nitrogen oxide
292 atment aimed predominantly at remediation of chlorinated volatile organic compounds (cVOCs) and perfl
294 ted, e.g., chloromethane (CH3Cl), and higher chlorinated VOX compounds such as trichloromethane (CHCl
295 ing may lead to higher DBP concentrations in chlorinated water with lower distribution system tempera
298 vated DBP formation during transportation of chlorinated waters in copper-containing distribution sys
299 ncluding BrCl, Br2, BrOCl, Br2O) can form in chlorinated waters, albeit at generally lower concentrat
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