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1 s (i.e., reactions with chloramines and free chlorine).
2 ers of magnitude lower than that of reactive chlorine.
3 O2 islands enhance the evolution of reactive chlorine.
4 months of exposure to monochloramine or free chlorine.
5 tergents containing strong oxidants, such as chlorine.
6 ies that promoted the autocatalytic decay of chlorine.
7 non-piped water, potentially due to residual chlorine.
8 the oxidation was performed with 1.5% active chlorine.
9 in seawater swimming pools disinfected with chlorine.
10 o remove cyanuric acid, a stabilizer for the chlorine.
11 as found to be very stable in the absence of chlorine.
12 elta(9)-tetrahydrocannabinol (THC-COOH) with chlorine.
13 ct (DBP) formation following the addition of chlorine.
14 s in most distribution systems that use free chlorine.
15 eeds to PCDD/F congeners with less than four chlorines.
16 (SRHA) at pH 5.1 +/- 0.2 using low doses of chlorine (0.1 to 0.50 mg free Cl2/L), with half-lives ca
17 e patterns containing sulfur, 187 containing chlorine, 14 containing bromine, one containing boron, o
19 aralyses by using 7-T sodium 23 ((23)Na) and chlorine 35 ((35)Cl) magnetic resonance (MR) imaging.
21 as nC60 suspensions) in the presence of free chlorine, a globally used chemical oxidant, in the absen
22 the modification of grain boundaries through chlorine accumulation, which leads an increase in the ca
25 rine with extensive covalent oxygen and even chlorine additions, and behave as soft (or loose) cluste
27 bined ultraviolet (UV) and free chlorine (UV-chlorine) advanced oxidation process that produces highl
28 ta set of PCDD/F congeners with four or more chlorines along with all 209 polychlorinated biphenyl (P
29 t compounds to contain Xe-Br bonds and their chlorine analogues are described in the present work.
30 entially alter the reaction pathways between chlorine and amino acids, resulting in the formation of
31 ringtime, unique halogen chemistry involving chlorine and bromine atoms controls the prevalence of vo
32 safe storage and transportation of elemental chlorine and bromine, which play critical roles in the c
34 a close association of N. fowleri with free chlorine and distance from treatment over the course of
35 iguously that a methyl appears bigger than a chlorine and gave the following order in size: CN > OMe
37 alyst heterogeneity following treatment with chlorine and hydrogen, using Mossbauer and X-ray absorpt
40 The effects of pH, disinfectant type (free chlorine and monochloramine), and chlor(am)ine residual
41 il today, concerning the selectivity between chlorine and oxygen evolution in chlorate and chlor-alka
42 e to association with other ligands, such as chlorine and sulphur, present in the original containers
43 ectron shuttle mechanism between Cr(III) and chlorine and the bypass of Cr intermediate formation.
44 ignificant oxidation in the presence of free chlorine and the oxidation reaction rates increase with
45 maceutically active natural products contain chlorine and thus, an understanding of the mechanism of
46 conditions, heteroelements like nitrogen or chlorine (and other halogens) can form hydrogen cyanide
48 xidation mediated by electrogenerated active chlorine, and the coupling between anodic and cathodic p
49 ents and compounds, such as zinc, potassium, chlorine, and water, provide key evidence for how Earth
50 ratio was approximately 20% for the UV/free chlorine AOP and approximately 35% for the UV/chloramine
55 ccur for membranes in treatment plants using chlorine as an upstream disinfectant and the extent and
56 s suggests that mediated oxidation by active chlorine, as well as by hydroxyl radicals resulting from
58 g that AgNPs are oxidized in the presence of chlorine at a much faster rate than observed in the pres
60 ance of a halogen bond interaction between a chlorine atom of the new class of 5-HT6 receptor antagon
61 ing of the C,N-cyclometalated ligand and the chlorine atom on increasing the electron withdrawing eff
63 nated biphenyls (PCBs) with lower numbers of chlorine atoms (LC-PCBs) due to their presence in both i
64 agation process and is capable of installing chlorine atoms at primary, secondary, and tertiary cente
65 uble fluorescent-labeled PAC with one or two chlorine atoms displaced from DTAF in alkaline pH via nu
66 Polychlorinated biphenyls (PCBs) with less chlorine atoms exhibit a greater susceptibility to metab
67 achloroquinoxalino[2,3-b]phenazine, with the chlorine atoms in the east and west positions) packs in
68 oroquinoxalino[2,3-b]phenazine) carrying its chlorine atoms in the peri-positions packs in a herringb
76 less genotoxic than the samples treated with chlorine-based disinfectants and was not significantly d
79 0.2 g L(-1)) in a reaction system containing chlorine, bromide, and CRW-BF-HPO enhances the formation
81 perties of the four halogen atoms (fluorine, chlorine, bromine, and iodine) and the diversity and che
82 ne the presence of certain elements (sulfur, chlorine, bromine, boron, and selenium) in the compound
83 do we make a false negative prediction; for chlorine, bromine, boron, and selenium, we make ten fals
85 ve analytical chemistry of spas treated with chlorine, bromine, or ozone, along with pools treated wi
87 ting four water contaminants - Cr(VI), total chlorine, caffeine, and E. coli K12 - at similar wavelen
89 tal chlorine (CaL/ClL), high CaCO3/low total chlorine (CaH/ClL), low CaCO3/high total chlorine (CaL/C
90 tal chlorine (CaH/ClL), low CaCO3/high total chlorine (CaL/ClH) and high CaCO3/high total chlorine (C
91 ted: a baseline group of low CaCO3/low total chlorine (CaL/ClL), high CaCO3/low total chlorine (CaH/C
92 scavenging of radicals participating in free chlorine chain decomposition and even free chlorine refo
93 olecules cm(-3), highlight the importance of chlorine chemistry in the degradation of volatile organi
94 he model results highlight the importance of chlorine chemistry participation in bromine radical cycl
95 Our observations reveal pollution-related chlorine chemistry that is both widespread and recurrent
96 he latter, conventional practices, including chlorine-chloramine disinfection, flushing of DWDS, nutr
100 When most reactive sites were consumed by chlorine, Cl-substituted functional groups (Cl-DOM) are
101 ic water CaCO3 (in milligrams per liter) and chlorine (Cl2; in milligrams per liter) concentrations f
102 ion followed by maintenance of residual free chlorine, combined with removal of redundant plumbing, w
103 in the water industry, and the residual free chlorine concentration in water distributed to the consu
104 oxidation reaction rates increase with free chlorine concentration while being inversely related to
105 loss actually decreased with increasing free chlorine concentration, suggesting scavenging of radical
108 fate in water of varying hardness levels and chlorine concentrations, rinsed, and covered with chambe
109 domestic water calcium carbonate (CaCO3) and chlorine concentrations, skin barrier dysfunction (incre
110 HAN concentrations depending on pH and free chlorine contact times (CTs), which can be applied as an
113 It is well established that anthropogenic chlorine-containing chemicals contribute to ozone layer
115 impacted by the presence of AgNPs because a chlorine-containing species is formed on OCl(-) decay th
117 DX analysis showed that ACFL550 had half the chlorine content (Cl%) relative to AC550, which makes AC
120 de of rapidly increasing available inorganic chlorine, coupled with observed temperatures, portend a
121 lack fundamental knowledge about how overall chlorine cycling is regulated in forested ecosystems.
122 (tpy) ligands modified by fluorine (dftpy), chlorine (dctpy), or bromine (dbtpy) substitution at the
124 pled with the electron stimulated removal of chlorine demonstrated in the UHV experiments, the Auger
125 asured reaction rate constants, kexp, for 22 chlorine-derived inorganic radical reactions in the UV-c
126 This is the first comprehensive study on chlorine-derived radical reactions, and it provides mech
127 genated radicals, the reaction mechanisms of chlorine-derived radicals have not been elucidated due t
128 erated echovirus 11 (E11) with resistance to chlorine dioxide (ClO2) by experimental evolution, and w
130 er environmentally relevant oxidants (ozone, chlorine dioxide, and phosphate and carbonate radicals)
131 likely increased N. fowleri's resistance to chlorine disinfection compared to that of the laboratory
133 ionally carcinogenic compounds formed during chlorine disinfection in water treatment processes aroun
138 ovide opportunities for improved modeling of chlorine distribution and cycling in terrestrial ecosyst
139 with OVA and the photosensitizer tetraphenyl chlorine disulphonate (TPCS2a) and administered intrader
141 Solution pH, chloride concentration, and chlorine dose were systematically varied in order to ass
143 his complex undergoes a clean photoreductive chlorine elimination reaction which produces [Cl2Sb(IV)P
145 altitude-dependent distribution of inorganic chlorine established in the same coordinate system as th
147 to appear chemically identical, whereas the chlorine exchange presents diffusion-limited exchanges p
148 diates were found to further react with free chlorine, exhibiting a second-order rate constant k3 = 1
152 chlorine was quantified at a variety of free chlorine exposure times, concentrations, and pH and rins
156 These molecules are found to undergo further chlorine-fluorine exchange reactions by treatment with s
159 delivery of two public health interventions: chlorine for water purification and multivitamins for mi
160 Marcus analysis afforded an estimate of the chlorine formal reduction potential E degrees (Cl(*/-))
165 thway involving electrochemical evolution of chlorine gas followed by Cl2-mediated electrophilic dich
166 casions found "compelling confirmation" that chlorine gas has been used against civilians in northern
167 The inactivation of PR772 and HAdV by free chlorine had similar kinetics that could be represented
170 nd mechanisms of Cr(III) solids oxidation by chlorine in drinking water and associated Cr(VI) formati
172 gest that the oxidation of Cr(III) solids by chlorine in water distribution systems can contribute to
178 recommendation of a 15 min exposure to 0.5% chlorine, independently of chlorine type, surface, pre-c
182 ssolution of silver nanoparticles (AgNPs) by chlorine is investigated in this work, with results show
183 orresponding dichloroacetic acid (DCAA) when chlorine is present, although those acidic conditions th
184 entified as DCAM, because its nitrogen-bound chlorine is readily reduced by most commonly used quench
186 sitions are the most toxic, removal of these chlorines is advantageous, but previous studies have onl
189 usand to -11.9 per thousand), but negligible chlorine isotope effects (epsilonCl = -0.12 per thousand
192 estigated for the first time both carbon and chlorine isotope fractionation for three different engin
195 in previous approaches using ICP methods for chlorine isotopes, isobaric interference of the (36)ArH
196 ,1,2-trichlorethane (K0 = 2.31 cm(2)/(V s)), chlorine (K0 = 2.24 cm(2)/(V s)), and nitrogen dioxide (
203 igh calcium levels of hard water and/or high chlorine levels, is a compelling mechanism for this incr
208 with a fixed chain length (n) and number of chlorines (m) are referred to as a "congener group" CnCl
209 tains (i) metallic potassium, (ii) elemental chlorine made of covalently bonded Cl2 molecules held to
212 ion (PTM) of proteins by endogenous reactive chlorine, nitrogen, and oxygen species is implicated in
215 estimates that incorporated subsequent free chlorine or chloramine scavenging by the (*)Cl and (*)OH
216 WWTPs with different disinfection processes (chlorine, peracetic acid (PAA), and ultraviolet light (U
218 gram, this mechanism reduces the quantity of chlorine procured by 60 percentage points, but reduces t
219 removal, anodes designed to enhance reactive chlorine production are more effective than those design
221 the CARIBIC airborne dataset, for extensive chlorine radical chemistry associated with Asian polluti
222 lectron oxidation, leads to elimination of a chlorine radical in what amounts to the sequential captu
224 erve as both cross-coupling partners and the chlorine radical source for the alpha-oxy C(sp(3))-H ary
225 ighly reactive hydroxyl radicals (HO(*)) and chlorine radicals (Cl(*)) is an attractive alternative t
226 tform enabled by the catalytic generation of chlorine radicals by nickel and photoredox catalysis.
227 Significantly faster reaction rates allow chlorine radicals to expedite oxidation of hydrocarbons,
228 red from hydrocarbon relationships show that chlorine radicals were regionally more important than hy
236 eholds whose stored water tests positive for chlorine residual by only one percentage point, substant
238 confirmed Dispenser use (as measured by free chlorine residual) ranged from 5 to 87%, and effective u
242 ination performance and aggressive shear and chlorine resistance of these scalable graphene-based mem
243 ovel hybrid-layered membranes exhibit better chlorine resistance than pure graphene oxide membranes.
245 queous chlorine could promote degradation of chlorine-resistant and photochemically stable chemicals
249 Therefore, the low-cost, hand-drawn free chlorine sensor is of great significance for water quali
250 echanism that combines the free provision of chlorine solution for water treatment with a small nonmo
257 xidation of chloride anions to electrophilic chlorine species reacting with arenes in aromatic substi
258 xamine the roles that two largely overlooked chlorine species, Cl2 and Cl2O, may play in the chlorina
261 chers have attributed these reactions to two chlorine species: HOCl (at circum-neutral and high pH) a
264 provide a data set of carbon, hydrogen, and chlorine stable isotope ratios (delta(13)C, delta(2)H, d
265 , we observed that PR772 inactivated by free chlorine still attached to host cells, and viral DNA syn
266 s inactivated at levels up to 99.99% by free chlorine still attached to host cells; however, viral DN
267 d for bacterial aggregates and, similarly to chlorine, stimulated the selection of ARGs during the in
269 glycolipids featuring aliphatic chains with chlorine substituents and C-glycosyl moieties, is report
270 biphenyl (PCB) congeners with multiple ortho chlorine substituents and their metabolites exist as sta
271 n+3Hn-2SO4(-); n = 5, 7, 9, 11, 13, and 15), chlorine substituted perfluorocarboxylates (ClCnF2nCO2(-
273 ation to final perovskite grains and partial chlorine substitution can accelerate the crystalline nuc
276 erogeneous catalytic conversion of inorganic chlorine to free radical form on ubiquitous sulfate-wate
277 released bromide is reoxidized (recycled) by chlorine to HOBr, leading to further electrophilic subst
278 omplex Ir(IV)(mu-oxo)2Ir(IV), can react with chlorine to release O2 by the oxidation of oxygen ions w
279 he mean stiffness of monochloramine- or free-chlorine-treated biofilms was 4 to 9 times higher than t
280 aeruginosa was simulated using pristine and chlorine-treated thin-film composite polyamide membranes
281 exposure to 0.5% chlorine, independently of chlorine type, surface, pre-cleaning practices, and orga
286 fischerindole and hapalindole alkaloids with chlorine via late-stage aliphatic C-H group functionaliz
287 e rapid oxidation of Cr(III) solid phases by chlorine was accompanied by Cr(VI) formation and an unex
288 d less than median levels of CaCO3 and total chlorine was constructed: a baseline group of low CaCO3/
292 verse osmosis membrane upon exposure to free chlorine was quantified at a variety of free chlorine ex
294 ion of compound-specific isotope analysis of chlorine was thus far limited by the availability of sui
296 food factory is frequently disinfected with chlorine, which originates disinfection by-products: hal
297 Strategies that minimize application of free chlorine while preventing nitrification are needed to co
298 These results suggest that the presence of chlorine will mitigate AgNP toxicity by forming less-rea
300 s are readily formed in the presence of free chlorine with extensive covalent oxygen and even chlorin
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