ライフサイエンスコーパス: chromophore

1 on the degree of electronic coupling of the chromophore.

2 r clearance of the photoisomerized rhodopsin chromophore.

3 action resulting in the mature protein-bound chromophore.

4 on is due to ruffling of the bacteriochlorin chromophore.

5 s suppressed owing to energy transfer to the chromophore.

6 ich is ubiquitous in mammalian tissues, as a chromophore.

7 ilable in mammalian cells biliverdin (BV) as chromophore.

8 e to track photoprotein and/or protein-bound chromophore.

9 similar or different) substrates from single chromophore.

10 n in the pyrone ring changing the molecule's chromophore.

11 e separation upon photoexcitation of the PDI chromophore.

12 often the photoisomerization of a conjugated chromophore.

13 and thus restored the fluorescence of BODIPY chromophore.

14 n isomerization of the protein-bound retinal chromophore.

15 , and this was reflected in solvation of the chromophore.

16 spectroscopic studies with R-state-specific chromophore.

17 ophore based on a bright red-emitting BODIPY chromophore.

18 hotoproduct of tryptophan and a powerful UVA chromophore.

19 and through betaME-mediated reduction of the chromophore.

20 well as mixed cages that contain both BODIPY chromophores.

21 states of the structurally different BODIPY chromophores.

22 notubes, and thereby restrict the motions of chromophores.

23 ctron can result in quenching of hundreds of chromophores.

24 ce of a significant but variable fraction of chromophores.

25 unoccupied molecular orbital gaps for local chromophores.

26 lity for detecting acetylated cellulosic key chromophores.

27 served in fluorophores but not in endogenous chromophores.

28 e of the stilbene donor/acceptor radical ion chromophores.

29 g the structure and function of the integral chromophores.

30 the results of structurally different BODIPY chromophores.

31 xcitation of 2-hydroxyperfluoroanthraquinone chromophore (1,2,3,4,5,6,7-heptafluro-8-hydroxyanthracen

32 In signalling photon absorption, the chromophore 11-cis retinal is first isomerized to all-tr

33 cle in vertebrates, through which the visual chromophore 11-cis-retinal (11-cis-RAL) is generated to

34 hydrogen atoms revealing protonation of the chromophore 4-hydroxybenzyl group in the ground state.

35 tructure in films of a model singlet fission chromophore, 6,13-bis(triisopropylsilylethynyl) pentacen

36 otein (GFP, Phif approximately 0.8), the GFP chromophore, a benzylidenedimethylimidazolinone (BDI) dy

37 Chromophores absorb light in photosensitive proteins and

38 , synthetic polymers, biopolymers, and other chromophores absorbing in the UV.

39 ng systems spatially organize densely packed chromophore aggregates using rigid protein scaffolds to

40 tramolecular conjugation as well as blocking chromophore aggregation, both of which prevent the typic

41 charge state of both quenched and unquenched chromophores allowed inference of multiple conformations

42 instead observed between at least two BODIPY chromophores along the edges of the cages, arising from

43 The chromophores also have favorable photophysics.

44 peptide derivatization with the ultraviolet chromophore AMCA yield peptides susceptible to 351 nm ul

45 ramolecular nanostructures formed by charged chromophore amphiphiles in salt-containing aqueous solut

46 n photosensitizing perylene monomimide (PMI) chromophore amphiphiles were found to show variation in

47 linecarboxylic acid repeat units, and of two chromophores, an N-terminal oligo(para-phenylenevinylene

48 achieved for structurally unconstrained GFP chromophore analogues (uGFPc).

49 eneration of mammalian green cone opsin with chromophore analogues such as 11-cis-6mr-retinal.

50 The dissociation produces a chromophore and dimers are reformed upon irradiation, th

51 BphP1 binds a heme-derived biliverdin chromophore and is reversibly photoconvertible between r

52 er reduction with a ruthenium trisbipyridine chromophore and molecular Ni(II) catalyst on NiO films w

53 porates a tris(bipyridine)ruthenium(II)-type chromophore and molecular ruthenium based water oxidatio

54 ructure effects, i.e., twisting of the enone chromophore and nonplanarity of the enone double bond ca

55 The thioether linkage between chromophore and protein is subject to positional ambigui

56 ends on the relative orientation of the aryl chromophore and the appended arsenic chelate: the fluore

57 ing of charge transfer processes between the chromophore and the catalyst, and of the mechanism of wa

58 oth via the direct addition of betaME to the chromophore and through betaME-mediated reduction of the

59 ONOO(-) can readily bleach the chromophore and thus recover the luminescence, the prese

60 Bilin chromophores and bilirubin are involved in relevant biol

61 an be achieved in water with all-hydrocarbon chromophores and establish the use of the DNA scaffold t

62 We also determine that chromophores and growth factors can limit the range of a

63 hile DHBQ is one of the three key cellulosic chromophores and its degradation by H2O2 is well-establi

64 organic materials, applicable as functional chromophores and organic semiconductors.

65 IPM, and it promotes the removal of bleached chromophores and recycling in the nearby retinal pigment

66 tral bandwidths of the individual underlying chromophores and spectral proximity of the pump and prob

67 DOM are a result of multiple populations of chromophores and that their relative contribution is cha

68 synthesized with different light harvesting chromophores and transition metal binding bipyridyl (bpy

69 that both limiting the relative rotation of chromophores and tuning the energy difference between th

70 lean Search String: "dye OR Lake OR Stain OR chromophore" AND "tox$ OR terato* OR carcino$ OR Allerg$

71 agents, such as bleomycin, neocarzinostatin chromophore, and lomaiviticin A, in place of IR.

72 let energy is determined by the lower-energy chromophore, and the rate of SF is found to be relativel

73 s review outlines the rationale for surgical chromophore application, the weaknesses and risks in eac

74 formation and the resulting formation of the chromophore are controlled reversibly by varying the pH.

75 Light-induced structural changes in the chromophore are translated into global conformational ch

76 The absorption spectra of the BrC chromophores are influenced by the extraction solvent an

77 However, the energy gap law ensures such chromophores are rare, and molecular engineering of abso

78 here are complications in the use of organic chromophores arising from the instability of their oxidi

79 Three sets of tetrapyrrole-chromophore arrays have been examined that exhibit panch

80 cial photosynthetic systems based on organic chromophore arrays.

81 f polarized alkenes, employing the cinnamoyl chromophore as a retinal surrogate under UV-irradiation

82 al electronic spectroscopy to probe internal chromophores as a marker of quaternary structure.

83 Recently, the use of transition metal based chromophores as photo-induced single-electron transfer r

84 t modification of the UV-vis spectrum of the chromophore, as shown by time-resolved spectroelectroche

85 m investigation of complex systems with many chromophores, as opposed to averages.

86 Singlet exciton fission (SF) in organic chromophore assemblies results in the conversion of one

87 degrees C reveal the formation of a visible chromophore at 460 nm, which persists in a steady state

88 tenoid can approach any core phycocyanobilin chromophore at a distance that can promote efficient ene

89 cells recycle spent all-trans-retinol visual chromophore back to 11-cis-retinol.

90 ic characterization of a series of push-pull chromophores based on a novel coumarin scaffold in which

91 emission, the hybrid composite shows organic chromophore-based visible emission in the orange-red reg

92 scence indicated that the environment of the chromophores became more polar with opening of the exter

93 f a nanoliposome doped with a photoactivable chromophore (benzoporphyrin derivative, BPD) in the lipi

94 absorption and fluorescence spectra and the chromophore binding depend on the location of the Cys re

95 he room temperature crystal structure of the chromophore-binding domains of the Deinococcus radiodura

96 ary pocket of CRY1, analogous to the antenna chromophore-binding pocket of photolyase.

97 rrole (porphyrin, chlorin, bacteriochlorin), chromophore (boron-dipyrrin, perylene, terrylene), and a

98 e formation of Biliverdin IXalpha (BLA), the chromophore bound to Sandercyanin.

99 ed metal complexes combining the trimetallic chromophore [{(bpy)2Ru(dpp)}2Ru(dpp)](6+) (Ru3) with [Rh

100 ron donor-acceptor (D-A) substituted dipolar chromophore (BTPA-TCNE) is developed to serve as an effi

101 and rhodopsin, all of which exhibit similar chromophores but different isomerization yields and exci

102 Specifically, molecular chromophores (C), electron acceptors (A) and electron do

103 monstrate that the isolated deprotonated GFP chromophore can be trapped in the first excited state wh

104 Organic chromophores can be synthesized by established methods a

105 chemical properties of these multifunctional chromophores can easily be modified and adjusted to many

106 ) procedure for the preparation of molecular chromophore-catalyst assemblies on wide bandgap semicond

107 sorbing and catalytic properties of designed chromophore-catalyst assemblies.

108 hese oligopyrroles of interest as functional chromophores, charge-storage materials, and tectons for

109 lt of the broad and strong absorption of the chromophore compared with ytterbium's intrinsic absorpti

110 e QDs are the only band-gap-tunable infrared chromophore composed entirely of elements with atomic nu

111 The more demanding chromophore concept generates a complete pi-electron sys

112 to evaluate acute hepatotoxicity in vivo by chromophore-conjugated upconversion nanoparticles.

113 Chromophore-containing molecules feature extensively in

114 monoxide-releasing molecules based on BODIPY chromophores (COR-BDPs) activatable by visible-to-NIR (u

115 st dynamics of electronically excited BODIPY chromophores could lead to further advances in these are

116 lecule consists of a perylene electron donor chromophore (D) bound to a pyromellitimide acceptor (A),

117 CP made of strong and fully conjugated donor chromophore DBD (M4) shows the highest hydrogen producti

118 cellent models for localized bacteriochlorin chromophore deformations that are suggested to also be r

119 ctrochemically addressable films with a high chromophore density.

120 small family of suitable materials, and new chromophore design principles are needed.

121 Retinal (vitamin A1) was the only chromophore detected in the retina.

122 These include single-chromophore emission states for each of the three covale

123 standing of the structure around the twisted chromophore enabled the design of a mutant that displays

124 uctor nanocrystals interfaced with molecular chromophores, enabling potential applications of their c

125 s is essentially diffusive because intrinsic chromophore energetic disorder is comparable to chromoph

126 many efforts have been devoted into the BDI chromophore engineering for fluorescence recovery, limit

127 ; (ii) the alpha-dicarbonyl tether acts as a chromophore enhancer, extending the conjugation chain an

128 we resolve the discrepancy by measuring the chromophore exchange rate of the bound 11-cis-retinal ch

129 es such as spectroelectrochemistry and model chromophore experiments such as photoinduced bimolecular

130 spectral domain absorptivities of M-(PM')n-M chromophores far exceed those of classic coordination co

131 Photoreceptor membranes synthesize 11cRAL chromophore faster under blue light than in darkness.

132 rated instead with a six-carbon-ring retinal chromophore featuring a C(11)=C(12) double bond locked i

133 epted that the protein environment makes its chromophore fluoresce, whereas the fluorescence is compl

134 ght-activated cis-trans isomerization of the chromophore followed by light-independent strand dissoci

135 t that cone opsins, but not R-opsin, require chromophore for proper folding and trafficking to the ph

136 receptors, including the recycling of visual chromophore for the opsin visual pigments.

137 light-driven oxygen production by an organic chromophore for up to 1 h of operation has been demonstr

138 Consistently, levels of 11-cis-retinal, the chromophore for visual pigments, were significantly lowe

139 f pi-extended porphyrins a valuable class of chromophores for 2P applications.

140 citons, is crucial to the development of new chromophores for efficient fission-sensitized solar cell

141 known example of a side chain self-assembled chromophore formed due to protein aggregation.

142 vitro) have suggested that rhodopsin and its chromophore-free apoprotein, R-opsin, may indeed exist a

143 the lipid bilayer of bicelles stabilized the chromophore-free opsin over the long timescale required

144 how that isomerization of the 11-cis retinal chromophore generates strong steric interactions between

145 romophore thiophene rings and (ii) a twisted chromophore geometry, producing a manifold of close-lyin

146 imaginary part, with the highest twist angle chromophore giving |Re(gamma)/Im(gamma)| approximately 1

147 erties of light interacting with the retinal chromophore has remained largely unexplored.

148 Boron-dipyrromethene (BODIPY) chromophores have a wide range of applications, spanning

149 e electronic interactions that enhance SF in chromophores having strong intra- and intermolecular CT

150 the OCP carotenoid to within 5-10 A of core chromophores; however, alteration of the core structure

151 mino acid residues surrounding the rhodopsin chromophore identified both close and distant sites affe

152 toreceptor degeneration and increased visual chromophore in 1-y-old AAV-CRRY-treated STGD1 mice.

153 nstead of npi* excited state of the carbonyl chromophore in a "transposed Paterno-Buchi" reaction is

154 The flavin chromophore in blue-light-using FAD (BLUF) photoreceptor

155 cycle provides cones exclusively with 11-cis chromophore in both salamander and mouse and show that t

156 ficient binding of the endogenous biliverdin chromophore in cultured neurons and in the mammalian bra

157 ability to utilize an endogenous biliverdin chromophore in eukaryotes (including mammals), and its s

158 t-translational modifications, including the chromophore in GFP, as well as the three phosphopantethe

159 ow that the hydroxybenzylidene imidazolinone chromophore in one of the excited states assumes a near-

160 The light absorbing chromophore in opsin visual pigments is the protonated S

161 eps in the trans-to-cis isomerization of the chromophore in photoactive yellow protein.

162 orientation and interactions of the retinal chromophore in the active metarhodopsin II intermediate.

163 1,4]-naphthoquinone (DHNQ) is one of the key chromophores in cellulosic materials.

164 surgically relevant classification system of chromophores in current use, which facilitates risk/bene

165 New applications for chromophores in diagnostics and operative treatment expl

166 ers (HBPs) with decorated donor and acceptor chromophores in different domains were constructed to de

167 derivatives have found widespread utility as chromophores in fluorescent applications, but little is

168 Coupling among chromophores in molecular assemblies is responsible for

169 ctated by the nature of interactions between chromophores in this dense, nanoscale multichromophoric

170 A significant contributor is a chromophore-induced reduction in the configuration inter

171 onstrated that the structure of the coumarin chromophore influences the rate of the uncaging process,

172 omophore energetic disorder is comparable to chromophore inhomogeneous broadening.

173 The chromophore is a dinitro derivative of bisstyrylthiophen

174 e intensity required to optically saturate a chromophore is a molecular property that is determined b

175 tional scaffold approach an already existing chromophore is coupled with other components to give a c

176 photoreceptors in which the reactivity of a chromophore is enhanced by its molecular environment to

177 t energy transfer from (1)(T1T1) to a nearby chromophore is essential for producing free triplets.

178 n biliverdin-bound fluorescent proteins, the chromophore is noncovalently bound to the protein.

179 ic assay coupled to formation of fluorescent chromophore is presented.

180 orescence is completely lost when the native chromophore is taken out of GFP.

181 The 11-cis retinal chromophore is tightly packed within the interior of the

182 The disulfide bridge between the two chromophores is cleaved upon exposure to bisulfide, resu

183 port within ordered assemblies of pi-stacked chromophores is essential for developing molecular photo

184 ed-state reactivity of these charge-transfer chromophores is needed.

185 The oxidized form of one of the chromophores is sufficiently stable to exhibit reversibl

186 of well-understood and inexpensive molecular chromophores is therefore paramount.

187 tween two phenyl-extended viologen (ExV(2+)) chromophores is varied systematically using a pair of o-

188 pigment, in which the chromate ion acts as a chromophore, is related to its chemical composition (PbC

189 talytic incorporation of linear tetrapyrrole chromophores make phytochromes attractive molecular temp

190 oerythrobilin (PEB) or phycocyanobilin (PCB) chromophore, matched the lines in reconstructed STORM im

191 e chain of elementary reactions resulting in chromophore maturation in the green fluorescent protein

192 lysyl residue in EGFP that is essential for chromophore maturation, and is also an efficient deacety

193 on of tensile forces on a simplified retinal chromophore model provokes a substantial and regular inc

194 The properties of organic chromophores necessary for successfully driving water ox

195 Most chromophores observed during the event were attributed t

196 ons, and the resulting twisted, unaggregated chromophores, occur in these solids: (i) the electron-re

197 t the photo-induced proton transfer from the chromophore occurs through water-mediated proton relay i

198 A chlorin, the core chromophore of a chlorophyll, is a dihydroporphyrin macr

199 om typical arylboronic acids and esters, the chromophore of pnGFP is unreactive to millimolar concent

200 -retinal and 9-cis-retinal, a functional iso-chromophore of the visual pigments, led to alleviation o

201 related compounds were especially important chromophores of BBOA.

202 en-bonding network that surrounds the flavin chromophore on the nanosecond time scale, while the dark

203 om the oligoquinoline bridge to the acceptor chromophore on the picosecond time scale.

204 of excitons moving on a grid of biomolecular chromophores on typical timescales [Formula: see text]10

205 This process relies on multiple chromophores per reaction centre to quickly generate the

206 o be photoactive yellow protein (PYP), whose chromophore photoisomerizes from trans to cis in the pre

207 Their chromophore, phycocyanobilin (PCB), was cleaved from the

208 pment, using the linear tetrapyrrole (bilin) chromophore phytochromobilin (PPhiB).

209 e 2,5-thienylene moiety is embedded into the chromophore pi-backbone the highest intramolecular charg

210 the relative orientation of the catalyst and chromophore plays an important role in determining the d

211 ange in conformation and coordination in the chromophore pocket as being responsible for Dathail's ph

212 This chromophore possesses a zwitterionic resonance structure

213 optical properties of the individual pigment chromophores present in light-harvesting antenna complex

214 ugh blue light photoactivation of the FlicR1 chromophore presents a challenge for applications that r

215 Surprisingly, a large fraction of the chromophore produced by dihydroceramide desaturase-1, th

216 -cis pigments to identify the isoform of the chromophore produced by the visual cycle of the intact r

217 fluorescence is traced back to an intrinsic chromophore property, and by improving excited-state tra

218 d can distinguish the influence of different chromophore protonation states in experimental results.

219 The chromophore quench-labeling agents do not react with the

220 Chromophore quench-labeling applied to 1-octene polymeri

221 a model in which the GtCCR2 retinylidene SB chromophore rapidly deprotonates to the Asp-85 homolog,

222 Many strains can alter phycoerythrin chromophore ratios to optimize photon capture in changin

223 ally slows pigment dephosphorylation, visual chromophore recycling, and ultimately photoreceptor dark

224 Consistently, exogenous chromophore reduces rod responses at bright background.

225 ominant-negative mutant of RPE65 that delays chromophore regeneration.

226 n that activates transducin (Gt) followed by chromophore release.

227 roduced functional S-pigment upon subsequent chromophore restoration.

228 These aligned and more extended chromophores, resulting from the high stretching rate an

229 zation-dehydration-oxidation sequence of the chromophore's maturation reactions.

230 te residues that occupy the positions of the chromophore Schiff base proton acceptor and donor, a hal

231 face on nanometer length scale and different chromophore-semiconductor binding interactions under cha

232 hniques, which are insensitive at very short chromophore separations.

233 insensitive to the interplanar angle between chromophores, since rotation about sigma bonds negligibl

234 ector domain (NTD) and a ketocarotenoid; the chromophore spans the two domains in the ground state an

235 The retinal chromophore sterically constrained inside rhodopsin prot

236 This compound consists of a chromophore substructure 1,7-diazaheptamethin.

237 lled spatial relationships between the acene chromophore subunits.

238 r, using photoreceptors, which rely on bound chromophores such as retinal, flavins, or linear tetrapy

239 pical of conventional Ru(II) bis(terpyridyl) chromophores, suggesting new opportunities in light-driv

240 Chromophore supply by the retinal Muller cells (retina v

241 in possesses the largest electron-conjugated chromophore system among linear tetrapyrroles, BphPs exh

242 bilaterally and selectively eliminated using chromophore-targeted laser photolysis.

243 Hemiindigo is a long known chromophore that absorbs in the blue part of the spectru

244 It is also a chameleon-like chromophore that can be transformed into different highl

245 They all contain an aromatic chromophore that is formed in the periplasm by intramole

246 aqueous solution yields a strongly absorbing chromophore that undergoes efficient photodissociation t

247 ded to reflect its interaction with cellular chromophores that act as photosensitisers.

248 its set of electronically coupled two level chromophores that are each linearly coupled to dissipati

249 The detection of individual chromophores that contribute to the overall discoloratio

250 f versatile and abundant naturally occurring chromophores that produce different hues in nature, espe

251 on in a thin film, binary mixture of organic chromophores that provides a pathway to overcoming the a

252 Realizing chromophores that simultaneously possess substantial nea

253 f apparent conjugation between the component chromophores, the validity of the ISA should never be ta

254 ) and 1,4,5,8-naphthalenetetrone, are potent chromophores themselves.

255 ormation of an sp(3)-hybridized boron in the chromophore, thereby tuning the reactivity of pnGFP with

256 electron density and reduced aromaticity at chromophore thiophene rings and (ii) a twisted chromopho

257 the ultrafast dynamics of halogenated BODIPY chromophores through applying two-dimensional electronic

258 ned, synthesized, and applied a rhodol-based chromophore to a molecular wire-based platform for volta

259 ypical photoreceptors employing a prosthetic chromophore to capture photons, LITE-1 strictly depends

260 rhodopsin (Rh) contains 11-cis-retinal as a chromophore to convert light energy into visual signals.

261 one opsin (S-opsin) in rods and also lacking chromophore to exploit the fact that cone opsins, but no

262 orption of light converts the 11-cis-retinal chromophore to its all-trans configuration in both rod a

263 facilitate attachment of linear tetrapyrrole chromophores to Cys-155 of phycobiliprotein beta-subunit

264 ntenance and cellular homeostasis, including chromophore turnover.

265 ation of a long peptide chain along with the chromophore unit of PVD generates a converging cleft for

266 odd-even effect regarding the number of PBI chromophore units was observed in steady-state and time-

267 ench the fluorescence of hundreds of polymer chromophore units.

268 re based on the changes in photophysics of a chromophore upon dimer formation.

269 a)/Im(gamma)| approximately 100, making such chromophores very promising for all-optical-switching ap

270 ce, S-opsin in these transgenic rods without chromophore was mislocalized; in R-opsin's presence, how

271 d PhiCpeT.PEB complex was very stable as the chromophore was not lost during chromatography and displ

272 based on the Disperse Red nonlinear optical chromophore was synthesized according to a simple and ef

273 Using sensitizer models for DOM chromophores, we show that halogen radicals are formed p

274 hiols, meso-(4-pyridinyl)-substituted BODIPY chromophore were displaced and released from the AuNP su

275 microbeads conjugated with a light-sensitive chromophore were made in MGBv, and, following retrograde

276 al composition and optical properties of BrC chromophores were investigated using a high performance

277 varied ring size containing two to nine PBI chromophores were synthesized in a one-pot reaction and

278 4, C15=N double-isomerization of the retinal chromophore, whereas the intracircular photoconversion o

279 Phenylmethylenepyrans are organic chromophores which are well suited for such purposes sin

280 t by a network of light-absorbing molecules (chromophores), which are also responsible for the subseq

281 These molecules contain a chromophore, which can be switched between two configura

282 They utilize biliverdin (BV) as a chromophore, which is a heme degradation product, and th

283 is initiated by light absorption by its FAD chromophore, which is most likely fully oxidized (FADox)

284 r use of phycourobilin and phycoerythrobilin chromophores, which are attached to antennae proteins ca

285 ly variable quenching behavior of one of the chromophores, which should inform future studies of high

286 me, the linear tetrapyrrole biliverdin, as a chromophore whose level in neurons is poorly studied.

287 t aromaticity the new octaphyrin is a potent chromophore with a vis-NIR absorption profile strongly i

288 lized QDs, which produces a stable hydrazone chromophore with a well-defined optical signature.

289 A purple chromophore with characteristic 550 nm absorption is for

290 ical tweezers and simultaneously probing the chromophore with fluorescence.

291 re exchange rate of the bound 11-cis-retinal chromophore with free 9-cis-retinal from Rho in an in vi

292 In YFPs, the pi-stacking of the chromophore with Tyr203 reduces its electron-donating ab

293 ron-rich thiophene-containing donor-acceptor chromophores with condensed pi-systems and sterically re

294 gioselective postfunctionalization of BODIPY chromophores with different functional groups.

295 evelop within DNA strands and become optical chromophores with diverse electronic spectra and wide-ra

296 ron-donor capacity, in order to assemble new chromophores with high molar extinction coefficients (ep

297 is(thiophen-2-yl)diketopyrrolopyrrole (TDPP) chromophores with methyl (Me), n-hexyl (C6), triethylene

298 All target chromophores with systematically varied pi-linker struct

299 xBox(4+) depends on the distance between the chromophores within the cyclophanes, while in the weak i

300 URFP), covalently attaches a biliverdin (BV) chromophore without a lyase, and has 642/670-nm excitati