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1 ure to hydrogen gas in the presence of Raney cobalt.
2 are example of a side-on dioxygen complex of cobalt.
3 ment for water oxidation is 10 +/- 1 ions of cobalt, 13 +/- 4 ions of iridium, and 11 +/- 3 ions of n
4 ependent charge transport properties of a 2D cobalt 2,3,6,7,10,11-triphenylenehexathiolate framework.
6 an interfacial layer of elemental nickel and cobalt, a few nanometres in thickness, whose moments are
7 EO800-PESn[Co2(CO)6]x ABA triblock copolymer/cobalt adducts (10-67 wt % PEO) were subsequently prepar
9 16 using dihydogen in the presence of Raney cobalt afforded compound 17 (60%) that could be elaborat
11 odetermining with no evidence for erosion of cobalt alkyl stereochemistry by competing beta-hydrogen
12 g., iron, cobalt, nickel, copper, and nickel-cobalt alloy), accomplished by a facile low-temperature
16 the wire changes with the transition between cobalt and cobalt oxide controlled by a voltage applied
19 ecies with conjugated dienes using a unified cobalt and iridium catalytic system in order to access a
21 ighly crystalline, electrochemically active, cobalt and naphthalene diimide-based MOF that is an effi
24 report self-assembled growth of c-BN NDs on cobalt and nickel substrates by plasma-assisted molecula
25 phase-pure cobalt-doped SnO2 (Co/SnO2) and a cobalt and nitrogen co-doped SnO2 (Co-N/SnO2) nanocrysta
27 he essential but high-cost alloying elements cobalt and titanium with inexpensive and lightweight alu
29 ators includes metal sensors that respond to cobalt and/or nickel (RcnR, InrS) or copper (CsoR) plus
32 report the development of second-generation cobalt- and maleimide-based liposomes that have improved
34 substrates containing inert C-H bonds using cobalt as catalyst is currently a topic attracting signi
35 ertically aligned two-dimensional layers and cobalt atoms doping demonstrated a high hydrogen evoluti
36 proach we deliberately place single iron and cobalt atoms in either of two different coordination env
38 imultaneous installation of multiple diverse cobalt-based active sites, including FeCo alloys and Co4
40 talytic performances ranks this new class of cobalt-based complexes among the most promising CO2-to-f
41 to create a new highly efficient and durable cobalt-based electrocatalyst for the oxygen evolution re
44 and O2-adsorption strength, we conclude that cobalt-based moieties bind O2 too weakly for efficient O
47 n under inert and aerobic conditions, with a cobalt-based turnover number (TON(Co)) of up to 420.
50 esign of highly robust, active, and reusable cobalt-bipyridine- and cobalt-phenanthroline-based metal
51 on of an alkynylboronate to a Co-B bond of a cobalt boryl complex to form a vinylcobalt intermediate.
53 evaluation and experimental validation on a cobalt-C3N4 catalyst with a desired molecular configurat
59 e to the intermediacy of Co(IV)-O species in cobalt-catalysed oxidation of organic substrates as well
60 pressure and mild conditions using a simple cobalt catalyst and extends to diverse tosylate and dien
61 ality with a C1-symmetric bis(imino)pyridine cobalt catalyst is described and has been applied to the
64 eme for the hydrogen evolution reaction by a cobalt catalyst, revealing unique information for the de
67 ho-to-fluorine selectivity observed with the cobalt catalysts was maintained in the presence of a ben
68 red the next generation of 4-substituted PNP cobalt catalysts with electron donating and sterically b
70 otoredox catalysis in tandem with low-valent cobalt catalysts, new methods by which functionalities m
71 bstitution patterns were synthesized using a cobalt-catalyzed [2 + 2 + 2] cycloaddition and subsequen
72 ir efficient construction was the photo- and cobalt-catalyzed [2 + 2 + 2] cycloaddition reaction betw
73 ein, we disclose the first light-controlled, cobalt-catalyzed [2+2+2] cycloaddition via a dual cobalt
76 he mechanism of bis(phosphino)pyridine (PNP) cobalt-catalyzed C-H borylation of 2,6-lutidine using B2
79 1,1-triborylalkanes was accomplished through cobalt-catalyzed hydroboration of 1,1-diborylalkenes wit
83 veals that O2 binds end-on to each framework cobalt center in a 1:1 ratio with a Co-O2 bond distance
84 ntial radiological dispersal devices (RDDs), cobalt, cesium, and strontium, were studied by DMS to de
85 p of urine metals including barium, cadmium, cobalt, cesium, molybdenum, lead, antimony, thallium, tu
86 omprising a redox-active, atomically precise cobalt chalcogenide cluster wired between two nanoscopic
91 intervention (PCI) with fluoropolymer-based cobalt-chromium everolimus-eluting stents (PCI group, 94
92 polymer drug-eluting stents: the thin-strut cobalt-chromium sirolimus-eluting Orsiro stent and the s
94 etal is lost from the taper junction between Cobalt-Chromium-Molybdenum (CoCrMo) and Titanium (Ti) co
97 rowth of h-BN films on mechanically polished cobalt (Co) foils using plasma-assisted molecular beam e
98 r in controlling Se as well as vanadium (V), cobalt (Co), nickel (Ni), zinc (Zn), and aluminum (Al) c
100 thesis and characterization of a hexanuclear cobalt complex 1 involving a nonheme ligand system, L1,
101 With this information, we identify a soluble cobalt complex that mimics the structure and reactivity
102 proceed in the presence of 0.25 mol % of the cobalt complex with 0.75 mol % of the alkylating agent t
103 tion catalyzed by a tetradentate macrocyclic cobalt complex with the formula [LCo(III)Cl2](+) (L = ma
108 A series of mononuclear pseudomacrocyclic cobalt complexes have been investigated as catalysts for
109 fluence of bound cations on the reduction of cobalt complexes of redox active ligands and explored th
111 id nanostructures combining amorphous nickel-cobalt complexes with 1T phase molybdenum disulfide (MoS
112 catalysts have been prepared by pyrolysis of cobalt complexes with nitrogen ligands on different inor
113 d been alleviated, the addition of cobalt or cobalt-containing vitamin B12 could further enhance chlo
114 stable for high iron concentration or for a cobalt content up to about 0.3 atom per formula unit.
115 after thermal activation under O2 to open a cobalt coordination site and to oxidize Co(II) to Co(III
116 d with systematically varied low loadings of cobalt (CoOx), manganese (MnOx), and nickel oxides (NiOx
119 Aryl-substituted bis(imino)pyridine iron and cobalt dihalide compounds, when activated with alkyl alu
123 (T c = 23 to 25 K) by precipitating-out the cobalt dopants and giving larger overall a-lattice param
124 conducting-ordering temperature in optimally cobalt-doped BaFe2As2 crystal (T c = 23 to 25 K) by prec
125 ability of bacterially synthesized zinc- and cobalt-doped magnetite nanoparticles for biomedical appl
128 cate that molybdenum disulfide with moderate cobalt doping content possesses the optimal activity.
134 ved for magnetically compacted (MC) Zr doped cobalt ferrite (x = 0.2) ( 4.3 x 10(-9) A(-1)m) compared
137 Magnetic solid phase extraction (MSPE) with cobalt ferrite nanoparticles coated with oleic acid is d
139 9) A(-1)m) compared to that of unsubstituted cobalt-ferrite ( 1.24 x 10(-9) A(-1)m), while a fivefold
140 lambda/dH was observed in Zr-doped (x = 0.2) cobalt-ferrite ( 4.3 x 10(-9) A(-1)m) compared to that o
142 n (MC) has been employed to process Zr-doped cobalt ferrites, Co1+xZrxFe2-2xO4 (0 </= x </= 0.4), to
146 ic atmospheres of RbCl, SrCl2, and CoHexCl3 (cobalt hexamine chloride) around a B-form DNA molecule.
148 ctrocatalysts for H2 production, but the key cobalt hydride intermediates are frequently difficult to
149 solation of and open environments around the cobalt-hydride catalytic species at Zr8-SBUs are respons
150 Despite having very different ligands, the cobalt hydrides of both catalysts possess nearly identic
151 e-step synthesis of well-dispersed amorphous cobalt hydroxide/oxide-modified graphene oxide (CoOxH-GO
153 , the reaction of the diketiminate-supported cobalt(I) complex L(tBu) Co with O2 gives a rare example
154 structure of one-dimensional single-crystal cobalt (II) oxide (CoO) nanorods by creating oxygen vaca
155 mple and efficient assembly of permanganate, cobalt(II) acetate, and pyridine to form the cubane oxo
156 -((iPr)PNP)Co(H)2BPin (1) and the air-stable cobalt(II) bis(pivalate) 4-Me-((iPr)PNP)Co(O2C(t)Bu)2 (2
157 enerates coordinatively unsaturated low-spin cobalt(II) centers that exhibit a strong preference for
158 es from DNA damage and cell death induced by cobalt(II) chloride hexahydrate (CoCl2.6H2O) and the ant
160 rain engineering of the outermost surface of cobalt(II) oxide nanorods can turn them into efficient e
161 structure properties and the activity of the cobalt(II) oxide surface, which results in the creation
164 verify a clocklike transition for the hosted cobalt(II) spins in the framework [(TCPP)Co0.07Zn0.93]3[
165 and electrochemical techniques on monomeric cobalt(II) tetra(meso-4-pyridyl)porphyrinate (CoTPyP) an
169 n of acylazirines combined with a subsequent cobalt(II)-catalyzed ring expansion with 1,3-diketones.
170 O2 adducts in Co-BTTri are best described as cobalt(II)-dioxygen species with partial electron transf
172 rbon nanotubes with the cobalt(II) porphyrin/cobalt(III) corrole system are promising alternatives fo
173 unds of choice were cobalt(II) porphyrin and cobalt(III) corrole-both characterized by a high stabili
175 TEMPOH) to form a structurally characterized cobalt(III)-hydroperoxo complex, Co(III)(BDPP)(OOH) (4)
176 Co(III)-O(*) species and stabilization of a cobalt(III)-oxyl/propane transition state as the Lewis a
180 question, we considered the substitution of cobalt in AdoCbl with rhodium to generate the rhodium an
182 gistic interplay between tungsten, iron, and cobalt in producing a favorable local coordination envir
183 no evidence of redox cycling of manganese or cobalt in the enzymatic reactions and suggest that struc
184 osure can be confirmed by the measurement of cobalt in the serum, but serum levels of the ion are not
185 muPADs for instrument-free determination of cobalt in waters using distance-based readout, with exce
186 e volume variation from 10 to 110 cm(3)/g by cobalt insertion in the MoS2 crystallographic lattice, w
187 thesized as a stable salt and transferred to cobalt introduces potential new routes to magnetic mater
190 ore, in our case Calcein Blue, quenched by a cobalt ion is add to the first one (4-MUP), and, in pres
191 theoretically demonstrated that the divalent cobalt ion reaches 90% of the [Formula: see text] value
192 icant intramolecular interaction between the cobalt ions across the 1,1'-bis(boratabenzene) unit.
193 aterial only comprising atomically dispersed cobalt ions and identify with X-ray absorption spectrosc
196 ochemical detection of femtomolar amounts of cobalt, iridium, nickel, and iron ions in solution by el
198 helatases, CbiK(P) and CbiK(C) , that insert cobalt/iron into the tetrapyrrole macrocycle but are tho
200 -edge structure spectra were obtained on the cobalt K edge and Re L3 edge of the working catalyst.
201 -based multilayered thin fi lms in which the cobalt layer is sandwiched between two heavy metals and
202 xistence of ultrathin superdense nonmagnetic cobalt layers in a polycrystalline cobalt thin film.
203 excitations in KCoF3 single crystals at the cobalt M2,3-edge at FERMI FEL (Elettra-Sincrotrone Tries
204 his work, we report the synthesis of ternary cobalt manganese phosphide nanoparticles from the soluti
205 Perhydroquinoline 4, the product of a Raney-cobalt mediated reductive cyclization reaction, was read
210 gate the internal distribution of engineered cobalt nanoparticles (Co NPs) in exposed individuals of
211 ive core-shell formation process in platinum-cobalt nanoparticles at elevated temperature under oxyge
213 ped carbon by using chloride, while metallic cobalt nanoparticles encased in protective graphite laye
215 Among the as-synthesized materials, the cobalt/nanoporous N-doped carbon composites have demonst
216 the growth of hierarchical supercrystals of cobalt nanorods have been studied by in situ tandem X-ra
217 The specific/mass activities of the platinum-cobalt nanowires for oxygen reduction reaction are 39.6/
218 ategy for synthesizing hierarchical platinum-cobalt nanowires with high-index, platinum-rich facets a
219 se of earth-abundant metals, including iron, cobalt, nickel and manganese, and represents a generic p
220 libration curves at the femtomolar level for cobalt, nickel, and lead ions on carbon ultramicroelectr
221 hese results, the limits of quantitation for cobalt, nickel, and lead ions were reported at 10 s of f
222 g trace metals, including arsenic, chromium, cobalt, nickel, and lead, likely due to the microbial pr
223 on of diverse transition metals (e.g., iron, cobalt, nickel, copper, and nickel-cobalt alloy), accomp
225 been obtained on the catalyst dominated with cobalt-nitrogen sites, confirmed by the advanced spectro
226 ectronic ground state of the pentacoordinate cobalt nitrosyl complexes, [CoX2 (NO)(PMePh2 )2 ] (X=Cl,
230 itation had been alleviated, the addition of cobalt or cobalt-containing vitamin B12 could further en
231 at concentrations only slightly higher, and cobalt or Zn(II) shock triggers mal-responses that match
233 y chain (HC) transfer), HA-oligosaccharides, cobalt, or Si bikunin prevented TSG-6 activity, preventi
236 study the active surfaces of layered lithium cobalt oxide (LCO) for the oxygen evolution reaction (OE
237 is coupled with a water oxidation phosphate cobalt oxide anode in a home-made electrolyzer by means
238 er with good cyclability of a 4-volt lithium cobalt oxide cathode and operation as low as -60 degrees
240 anges with the transition between cobalt and cobalt oxide controlled by a voltage applied to the top
241 mical properties for a manganese center in a cobalt oxide environment, and provides a molecular model
242 el the oxygen evolution reaction activity of cobalt oxide nanoislands and show that the nanoparticle
244 cathode layers based on graphite and lithium cobalt oxide, respectively, on thin flexible current col
245 segregation of a thin platinum, rather than cobalt oxide, surface layer occurs concurrently with ord
249 brid catalyst consisting of sulfur-deficient cobalt oxysulfide single crystals and nitrogen-doped gra
250 both oxygen-vacancy-rich, nonstoichiometric cobalt oxysulfides and edge-nitrogen-rich graphene nanom
251 s including skyrmions in an exchange-coupled cobalt/palladium multilayer at room temperature with Lor
252 active, and reusable cobalt-bipyridine- and cobalt-phenanthroline-based metal-organic framework (MOF
254 atoms around the vacancies in the resulting cobalt phosphoselenide favorably change the electronic s
255 es a novel ternary electrocatalyst of porous cobalt phosphoselenide nanosheets prepared by a combined
256 catalyst material based on pyrite-structured cobalt phosphosulfide nanoparticles grown on carbon nano
257 Nanocomposite molecular material based on cobalt phthalocyanine (CoPc) and multiwalled carbon nano
259 fying a screen-printed carbon electrode with cobalt phthalocyanine, graphene and an ionic liquid (CoP
262 riles to primary amines using a bench-stable cobalt precatalyst under 4 atm of H2 is reported herein.
263 nd induction of heme oxygenase-1 (HO-1) with cobalt protoporphyrin (CoPP) markedly attenuated the dev
266 ection, HO-1 induction with metalloporphyrin cobalt protoporphyrin IX significantly reduces the loss
267 eudomallei Pharmacological administration of cobalt protoporphyrin IX to mice resulted in an enhanced
269 pharmacologic induction of HMOX-1 in vivo by cobalt protoporphyrin-IX treatment eradicated intestinal
270 admium (Ptrend = 0.35), 1.21 (0.85-1.72) for cobalt (Ptrend = 0.59), 1.31 (0.90-1.91) for cesium (Ptr
275 ecially, exhibit complex behavior because of cobalt's ability to adopt various valence and spin state
276 ng the illness and exhibit other evidence of cobalt's effects on the body (eg, polycythemia and goite
277 ic biosensor based on an ionic liquid tagged cobalt-salophen metal complex (Co-salophen-IL) immobiliz
280 favorably change the electronic structure of cobalt selenide, assuring a rapid charge transfer and op
281 ymium, neodymium, promethium, and samarium), cobalt, silver, tungsten, heavy rare earth elements (ytt
282 oordinates water and more open access to the cobalt site has higher electrocatalytic activity than CT
285 minary mechanistic studies indicate that the cobalt species is reduced to Co(0) during the reaction.
287 lysis showed that the amount of redox-active cobalt-species in the film is small, less than 10% of to
290 eport a catalyst derived from earth-abundant cobalt that enables preparation of cyclobutanones, with
292 spin-dependent reflectivity measurements on cobalt thin films intercalated at the graphene/Ir(111) i
296 nthetically useful selectivity observed with cobalt was applied to an efficient synthesis of the anti
298 ls (platinum, palladium, copper, nickel, and cobalt) were synthesized with average particle sizes fro
301 ese substrate and similar divalents iron and cobalt, with several small amino acid replacements still
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