ライフサイエンスコーパス: congested

1 ale-free, such as random graphs, will become congested.

2 In this area, the microvasculature becomes congested.

3 ethods showed that the latter affords highly congested 1,8-diarylnaphthalenes in superior yields.

4 simultaneously simplify and resolve complex, congested (1)H NMR spectra with many overlapping spin mu

5 The highly strained and congested 11-membered macrocycle of coleophomones B (2)

6 ic alkylation to access a crucial and highly congested 3,3-disubstituted oxindole.

7 ned to 1.80 A resolution, revealing a highly congested active site region.

8 enantiospecific synthesis of the sterically congested all-cis 2,3,4,5-substituted pyrrolidines 4, 5,

9 The synthesis of the exceedingly congested amine tris(1,3-dihydroxy-2-propyl)amine, 9, wa

10 A short synthesis of exceedingly congested amines, with insertion of a rhodium carbenoid

11 midazole, while the somewhat more sterically congested analogue, N,N'-sulfurylbis-2-methylimidazole,

12 ions of ROESY spectra by moving them to less congested areas.

13 ry-tertiary stereocenters, the generation of congested arylic quaternary stereocenters, and hydroxyal

14 nsaturated gamma-butyrolactams to sterically congested beta-substituted cyclic dienones with high sit

15 y on C4-C11 bond constructions to access the congested bicyclic framework of these elusive natural pr

16 eaction allows for the rapid construction of congested bicyclic systems from remarkably simple alkyne

17 A flexible approach to construct sterically congested bicyclo-alkenedione frameworks is reported.

18 of this amphiphile, indicating a sterically congested, but stable, folded conformation of the inclus

19 lcohols by preferential cleavage of the less congested C(2)-O(1) bond.

20 ted Corey-Yu allylic oxidation at the highly congested C-12 position of the enfumafungin core.

21 The highly congested C-N bond generated in this coupling, in conjun

22 obviates the need to directly forge either a congested C-N or C-C bond at the new nitrogenous stereoc

23 ereoselective installation of the sterically congested C13 alkyl chloride and control of the wayward

24 mbly of two advanced fragments to secure the congested C3a-C3a' linkage in three steps, followed by a

25 ed, muscular arteries within alveolar septa; congested capillaries within alveolar walls; and congest

26 ested capillaries within alveolar walls; and congested capillaries within the walls of medium-size, m

27 vely DNMT1 activity within these complex and congested cellular samples.

28 ted syn-selective cyclizations to sterically congested chloro- and bromohydrins, while SnCl4, SnBr4,

29 sence of drug treatment for heart failure or congested circulation before surgery and the duration of

30 The photochemistry of the sterically congested complex 4 was demonstrated by C-C bond forming

31 These congested compounds exhibit two cofacial aniline rings t

32 ential IMS, TIMS not only is able to resolve congested conformational features but also can be used t

33 transfer through conversion of a sterically congested contact ion pair to a solvent-separated ion pa

34 h epimerizable stereocenters, and sterically congested coupling partners.

35 ift of a hydrogen atom out of the sterically congested cove region to the radical center, cyclization

36 mpared to the slowest average speed and most congested cycles, optimal emission rates could be 50% lo

37 H(8)BINOL-AM compounds with sterically less congested cyclic or acyclic amino methyl substituents we

38 romatic Nazarov cyclization to construct the congested cyclopentane core revealed an unanticipated el

39 polyribosomes, as well as phages, inside the congested cytosol of the infected cell.

40 It was found that once sterically congested Dbg is at the peptide N-terminus, further chai

41 ytically relevant amino acid residues in the congested diamagnetic envelope have been assigned.

42 e well-controlled construction of sterically congested dihydrobenzo[e]indazole derivatives.

43 al, and enantioselective route to the highly congested ent-kaurane diterpene maoecrystal V is present

44 species in a chemical system often creates a congested fluorescence spectrum that is difficult to int

45 , eight contiguous stereocenters, and highly congested functionality.

46 Congested heart failure causes increased plasma levels o

47 y diamondoid bromides gave highly sterically congested hydrocarbon (hetero)dimers with exceptionally

48 For the sterically congested ketenimine 1a, preferred hydroalumination of t

49 ally presented with a two-month history of a congested left eye.

50 orithm that can be used to deconvolve highly congested mass spectra for heterogeneous ion populations

51 Synthesis of a sterically congested metallacyclobutene complex has led to the firs

52 Although these polycycles are sterically congested, molecular dynamics simulations indicate that

53 rived polycarbonate from the sterically less congested monomer, methyl 3,4-epoxybutanoate, displayed

54 The congested N,C-biaryl bond establishes an axis of chirali

55 that will show normal stability; more highly congested naphthalenes will prefer to exist as the corre

56 , the critical C4-C5 bond of this sterically congested natural product could never be forged.

57 ely underestimates the network throughput of congested networks, and a rich phenomenology of path flo

58 provided internal protection for the highly congested nitrogen atom during side-chain elaboration.

59 Sterically congested o-terphenyl crown ethers with alkoxy substitue

60 mass spectra of these ions are often highly congested, obfuscating determination of charge state, to

61 ic examination of rims (portal inflammation, congested or compressed sinusoids, cell atrophy) correla

62 rd and scaleable synthesis of the sterically congested pheromone of the longtailed mealybug, with two

63 sentative of the broader class of sterically congested polyphenylenes.

64 red, suggesting the furan ring is bound in a congested portion of the binding pocket.

65 sible at low temperatures even at sterically congested positions, thus permitting formation and also

66 f the sunspot (3200 K) gave rise to a highly congested pure rotational spectrum in the 10-micrometer

67 vatives involving axial asymmetry around the congested pyrimidine C5-N5 bond.

68 0a by initial construction of the sterically congested quaternary center at C-3, followed by elaborat

69 stereoselective construction of a sterically congested quaternary center embedded in the densely func

70 g and outdated vehicle fleet and to famously congested roads.

71 experimental technique distributes normally congested rotational-vibrational peaks along a series of

72 ability to separate and sort these normally congested rotational-vibrational peaks.

73 of the intermediate ketyl to the sterically congested Sm(III)HMPA both stabilizes the intermediate a

74 tational/vibrational states, yielding highly congested spectra that are difficult to assign.

75 reveal the underlying features of the highly congested spectral profiles associated with the complexe

76 features of the bound pigments in the highly congested spectral profiles from these light-harvesting

77 .0.0(2,8)]decanone 5 efficiently install the congested spirooxindole functionality of gelsemine.

78 rcembranoid natural products are a family of congested, stereochemically complex, and extensively oxy

79 presence of sensitive functional groups and congested structural environments.

80 PM3 calculations of 2 and 3 suggest a highly congested structure exhibiting two parallel acridyl moie

81 The rigid, highly congested structure of 1,8-diacridylnaphthalenes has bee

82 of stereocontrol for reactions of sterically congested substrates that lie outside of the traditional

83 f rich club regions were significantly under-congested, suggesting that macaque connectivity actively

84 developed a method for preparing sterically congested sulfonylureas based on N,N'-sulfuryldiimidazol

85 ed by the singlet, while in these sterically congested systems, the triplet led to di-pi-methane reac

86 teric hindrance to isomerization in a highly congested T-shaped transition state.

87 ng partners in order to establish the highly congested tetracyclic core structure.

88 ese systems, in fact, linear spectra are too congested to be used to disentangle the many coupled vib

89 ibutable to asphyxiation brought on by fluid-congested tracheal tubes.

90 erivative spectroscopy for disentangling the congested transient absorption spectra of LH1 and LH2 co

91 ve Heck cyclization, to rapidly assemble the congested tricyclic core of the indoxamycins.

92 adione and alphaEE showed foci of tumor with congested tubules and atrophic glomeruli.

93 ng for the observation and interpretation of congested vibrational structure.

94 Highly congested vicinal stereocenters comprised of tertiary an

95 were observed in association with 1 or more congested vortex veins ampullas, suggesting that outflow

96 Subduction zones become congested when they try to consume buoyant, exotic crust

97 and has: iron deposition; immature sinusoids congested with blood; persistent erythropoietic elements

98 stituted allylic alcohol are shown to afford congested Z alkenes with high diastereoselectivity.