ライフサイエンスコーパス: coordination number

1 tal size but strongly depended on the ligand coordination number.

2 even with small changes to first-shell Pt-Pt coordination number.

3 the uranium center in complexes with higher coordination number.

4 esembles a type II Cu(II) site with a higher coordination number.

5 count for their differences in heme-nitrosyl coordination number.

6 table choice of a structural property, water coordination number.

7 high spin Mn(III) in low symmetry and lower coordination number.

8 ation that occurs from a change in the metal coordination number.

9 were observed, consistent with an increased coordination number.

10 g that catalytic activity may correlate with coordination number.

11 ing relaxed coordination structures with low coordination number.

12 the catalytic reaction via changes in water-coordination number.

13 spin equilibrium occurs without a change in coordination number.

14 11 that occurs on the Pt atom with the lower coordination number.

15 nger adsorption of CO at Au sites with lower coordination numbers.

16 ates into spatial regions having much higher coordination numbers.

17 rs condense to form extended solids with low coordination numbers, 4 or 6.

18 The flexibility of Zn(II) ion's coordination number (5 and 6) as well as the formation o

19 e-nitrosyl function and reactivity is the Fe coordination number (5 or 6).

20 Shannon-Prewitt "effective ionic radii" (for coordination number 6) with mean absolute deviation of 0

21 exes the two metal atoms have formally a low coordination number and an also low electron count.

22 ds are strongly tied to oxidation state, the coordination number and crystallographic orientation of

23 in the variants correlate with the preferred coordination number and geometry of the metal ion.

24 structure (XANES) was used to determine the coordination number and geometry of the Ni site in the v

25 ws that the Ni site undergoes changes in the coordination number and geometry that are consistent wit

26 , chirality, porosity, etc. due to change in coordination number and geometry, dimensionality, interp

27 due to change in coordination number and geometry, dimensionality, interp

28 rticular, the red copper center has a higher coordination number and lacks the long Cu-S(Met) and sho

29 in ligands and one anion from the buffer, by coordination number and ligand selection.

30 g the systematic evaluation of the effect of coordination number and metal identity on M-Cl bond leng

31 binding of 15.1, is due to the nature of the coordination number and not the ligating group.

32 tipods (bi-, tri-, and tetrapods) of varying coordination number and patch angle in aqueous solution.

33 These results suggest that the coordination number and polarity may tune the electrophi

34 ng and Co(II)-substituted VanX have the same coordination number and that the metal ions are coordina

35 Furthermore, the coordination number and the arrangement of ligands obser

36 rature, the Cu(II)Cl complex favored a lower coordination number and the CuCl2 complex prevailed, whe

37 among strongly correlated parameters such as coordination number and the Debye-Waller factor.

38 h as a surprisingly large fluctuation in the coordination number and the detailed mechanism by which

39 After aging for two years, the coordination number and the distance to the first O shel

40 w the property can be predicted based on the coordination numbers and electronic structures of parama

41 igands to access main group complexes in low-coordination numbers and highly reactive bonding modes i

42 s in proteins is challenging due to the high coordination numbers and the incorporation of charged li

43 stablish a correlation between isomer shift, coordination number, and N/O composition.

44 emarkably independent of molecular charge or coordination number, and trends in values of d(PC) and n

45 nvironments with corresponding bond lengths, coordination numbers, and Debye-Waller factors for each.

46 wide diversity of packing fractions, average coordination numbers, and order as measured by standard

47 gle distributions, interatomic distances and coordination numbers are examined and lead to similar pr

48 The O-Ca and O-Al coordination numbers are similar in the eutectic 64 mol

49 particles-which contain metal atoms with low coordination numbers-are more active in catalysing oxida

50 Increasing the coordination number around Na(+) only partially accounts

51 hese carbene complexes to an increase of the coordination number around ruthenium is the insertion of

52 rent spatial location of water molecules and coordination numbers around the two CO2(-) groups.

53 This observation excludes low coordination number Au sites as being active alone in th

54 ks with central elements exhibiting variable coordination number can have the flexibility needed to a

55 fs, can use different combinations of phase, coordination number, cavity size, and rigidity (constrai

56 (XAS) at the Fe K-edge further supports this coordination number change with the binding of both cosu

57 ence spectroscopy, we found that a high Au-S coordination number (CN) and a high surface coverage res

58 the outer shell for all ions and an average coordination number (CN) for Ba that is higher than that

59 It is known that the coordination number (CN) of atoms or ions in many materi

60 Above 50 GPa, the estimated coordination number continuously increases from 6 to 6.8

61 ys metal-binding selectivity based solely on coordination number control and not on the chemical iden

62 Cation coordination numbers decrease with cation radius.

63 dent on the size of the lanthanide ions: the coordination number decreases from Pr (CN = 14) to Sm (C

64 olecules, thereby affecting observables like coordination number distributions of ions.

65 cise structural parameters (bond lengths and coordination number) extracted from the in situ PDF data

66 most bent monomers condense to form the high coordination number fluorite and PbCl(2) structure types

67 The coordination number for non-bonded interactions for each

68 superoxide dismutase indicating a change in coordination number for the metal complex at low tempera

69 We show that the change in ligand coordination number from 2 for aqueous Cu(+) to 5 for aq

70 a short Ni-O bond accounts for the change in coordination number from five to four that accompanies f

71 w that SiO2 first undergoes a change in Si-O coordination number from fourfold to sixfold between 15

72 s on metalloregulatory proteins suggest that coordination number/geometry and metal ion availability

73 that a given metal ion can adopt a preferred coordination number/geometry.

74 ne sites, as measured by the two-shell water coordination number, governs the kinetics of the oxidati

75 the average local structures (bond angle and coordination numbers), gradually transforming the a-GST

76 consistent with greater Ti 3d occupancy and coordination numbers greater than four, and 20-fold lowe

77 d the binding sites is tuned to sustain high coordination numbers (>6) around K+ ions, which otherwis

78 of the heme across multiple spin states and coordination number highlights the flexibility of the he

79 bond strength, determines the heme-nitrosyl coordination number in cytochromes c'.

80 mplexes indicated by a decrease in the Ir-Ir coordination number in ethene-rich feed.

81 The Zn(II) complexes change coordination number in response to the residue in positi

82 with NmtR uniquely capable of expanding its coordination number in the Ni(II) and Co(II) complexes b

83 hat we are capable of controlling the Cd(II) coordination number in these 2 sites solely by varying t

84 ovided a combined approach that revealed the coordination numbers in these systems.

85 mation of tetrairidium clusters as the Ir-Ir coordination number increased again.

86 n excess of Br(-1) ion is added, the bromide coordination number increases and the number of water mo

87 quids to fragile liquids by pressure-induced coordination number increases is demonstrated.

88 n states in water to states having different coordination numbers incurs a free energy cost.

89 zing the first atomic neighbor distances and coordination numbers inside the nanoalloy particles and

90 gold atoms: (a) one central gold atom whose coordination number is 12 (12 bonds to gold atoms); (b)

91 The fragmentation patterns indicate that the coordination number is 4 for this system.

92 n icosahedron around the central atom, whose coordination number is 6 (five bonds to gold atoms and o

93 inition, presents a nonselective medium, the coordination number is allowed to relax to suit the ion.

94 A new record coordination number is established, as AcHe17(3+) , ThHe

95 With oxidation state III, the coordination number is halfway between the coordination

96 e, and (1)H NMR spectra suggest that the low coordination number is maintained in solution.

97 ew atom) nanoparticles for which the average coordination number is much smaller than that in the bul

98 where the contribution of the protein to the coordination number is roughly constant in all four bind

99 Concomitant with the change in coordination number is the change of the spin state from

100 wiching a cobalt atom, which has the highest coordination number known heretofore in chemistry.

101 first isolable iron-hydride complexes with a coordination number less than 5.

102 ing, in WT and mutant proteins, the roles of coordination number, ligand selection, and residues in t

103 ) with local structure, including changes in coordination number, local geometry (bond distances and

104 Those of higher coordination numbers (mu-OH, mu3-OH) do not participate.

105 ors and the membrane normal and an isotropic coordination number (number of Mn neighbors to Sr) of 1

106 meters describing each particle, such as the coordination number, number of neighbors, and local pack

107 The pore size, pore throat size and coordination number obey normal distribution, and the av

108 The U-As coordination number of 1.6 implied that two uranyl arsen

109 The average Zn(II) coordination number of 4.5 in the resting enzyme appears

110 hydration of the adsorbed Hf complex up to a coordination number of 7, followed by the dissociation o

111 These results show that the low coordination number of a trigonal-planar geometry is imp

112 cture of cubic diamond silicon, although the coordination number of atoms of the SWSNTs is still four

113 Increasing the coordination number of iron from three to four through b

114 we report dynamic measurements of the water-coordination number of lanthanide triflate-based catalys

115 me of Earth's mantle the mean silicon-oxygen coordination number of magnesium metasilicate liquid cha

116 Here we show that the coordination number of network-forming structural motifs

117 s affinity switching was used to control the coordination number of Ni(2+).

118 ounds reveals that, in almost all cases, the coordination number of Pb is actually 5, 6, or 8.

119 ermochromic event corresponds to a change in coordination number of the active-site Mn(3+) ion from 6

120 n in the few known monomeric structures, the coordination number of the alkali metal is raised by bin

121 The increased coordination number of the antimony center in this anion

122 g values of 6.5, 4.2, and 2.0, and that the coordination number of the Co(II) is 5 or 6.

123 if equivalent constraints are imposed on the coordination number of the complex.

124 retaining the overall charge neutrality and coordination number of the Fe3+ center.

125 ount of water present for hydration, and the coordination number of the heme iron atom.

126 lectivity is not correlated with the overall coordination number of the ion entering the pore, but is

127 dation level, presence of alkali metals, and coordination number of the iron atoms are varied, to gai

128 ermore, the chelate mode is sensitive to the coordination number of the metal center; binding of a si

129 Significantly, reducing the coordination number of the metal centers appears to incr

130 ophenone, and nitrobenzene are involved, the coordination number of the proton (x) in [H(solvent)(x)(

131 rmine the effect of steric properties on the coordination number of the species that undergoes oxidat

132 uranate coordination environments where the coordination number of U is less than 8.

133 The coordination number of Zr is restricted to six in arylox

134 arious sets of collective variables, such as coordination numbers of the glycosidic oxygen, yielded a

135 sses, jammed solids and biopolymer gels have coordination numbers placing them at the edge of mechani

136 more brittle Cu46Zr54, where topological low coordination number polyhedra are still observed around

137 errous site, while in 3His-G4DFsc(Mut3), the coordination number remains the same and the substrate l

138 Analysis of the coordination number renders values that are almost const

139 Furthermore, we predict that low coordination numbers result in nonclassical nucleation b

140 thin the network extends beyond its chemical coordination number, resulting in a hyperconnected netwo

141 essful metalloprotein design that has a high coordination number (seven) metal-binding site construct

142 dicates the mutation does not alter the heme coordination number, spin state, or porphyrin deformatio

143 erogeneous catalysis of metal atoms with low coordination numbers, such as found at atomic steps and

144 he number of (N, O) ligands, with noninteger coordination numbers suggesting zinc site heterogeneity.

145 structural property, average two-shell water coordination number, that correlates well with measured

146 phase diagram predicting that, for the same coordination number, the density of monodisperse random

147 "NbO6" connectivity by extending the oxygen coordination number to 7 and 8.

148 quirement for topologically constraining the coordination number to a specific value.

149 with transition metals by maintaining a low coordination number to restrict the magnitude of the d-o

150 e shown promise in stabilizing unusually low-coordination number transition-metal complexes in low fo

151 fferences in the reactivity depending on the coordination number: tricoordinate boron azides behave a

152 The different coordination numbers, types of coordinating residues, an

153 in-group and transition-metal elements) with coordination numbers up to ten are discussed herein.

154 nce Raman spectra did not reveal a change in coordination number upon binding of isoniazid to KatG.

155 sing restraints that solely enforce specific coordination numbers, we find all models are K(+)-select

156 ligand field strength due to an increase in coordination number, whereas resonance Raman spectra ind

157 yer-Villiger insertions are favored by lower coordination numbers (x = 1 versus x = 2), earlier trans

158 Their stability depends critically on their coordination number z.