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1 ization of geranylgeranyl diphosphate to (+)-copalyl diphosphate.
2 hosphate to the stable bicyclic intermediate copalyl diphosphate.
4 e monofunctional diterpene synthases for ent-copalyl diphosphate and ent-kaurene biosynthesis is simi
5 ctionally conserved, sequentially acting ent-copalyl diphosphate and ent-kaurene synthases (CPS and K
6 lgeranyl diphosphate to the intermediate (+)-copalyl diphosphate and the ionization-dependent cycliza
7 ization of geranylgeranyl diphosphate to (+)-copalyl diphosphate and the second for the cyclization o
8 onal class II active sites and converted (+)-copalyl diphosphate, but not GGPP, into isopimaradiene a
9 rpene cyclases that produce the intermediate copalyl diphosphate (CPP), along with the more surprisin
10 nd at least one allelopathic agent, from syn-copalyl diphosphate (CPP), representing the only known m
11 of the TPS-c subfamily were characterized as copalyl diphosphate (diterpene) synthases, and those bel
12 inorum diterpene synthases (diTPSs), the ent-copalyl diphosphate (ent-CPP) synthase SdCPS1, and the c
14 The class II terpene synthase producing syn-copalyl diphosphate from the universal diterpenoid precu
15 ations, of geranylgeranyl diphosphate and of copalyl diphosphate, in the formation of a mixture of ab
16 n of GGPP followed by rearrangement of a (+)-copalyl diphosphate intermediate at two discrete class I
17 y complement each other, suggesting that the copalyl diphosphate intermediate diffuses between the tw
18 abietadiene (a complex process involving the copalyl diphosphate intermediate) and then three to oxid
19 hase with geranylgeranyl diphosphate and (+)-copalyl diphosphate provided evidence for two functional
20 mics approach was utilized to identify a syn-copalyl diphosphate specific 9beta-pimara-7,15-diene syn
21 previously described and closely related ent-copalyl diphosphate specific cassa-12,15-diene synthase
25 biosynthesis is catalyzed in plastids by ent-copalyl diphosphate synthase (CPS), whose substrate, (E,
27 nally, our RNA sequencing analysis uncovered copalyl diphosphate synthase (SrCPS) and kaurene synthas
28 ck-outs of the relevant diterpene synthases (copalyl diphosphate synthase 4 (OsCPS4) and kaurene synt
29 ighly up-regulated genes, as was An2, an ent-copalyl diphosphate synthase associated with production
30 ces platensis CB00739 was verified as an ent-copalyl diphosphate synthase involved in the biosynthesi
34 part of the catalytic base group in the ent-copalyl diphosphate synthases found in all seed plants f
35 been utilized to identify two disparate ent-copalyl diphosphate synthases from rice (OsCPS1ent and O
36 geranyl diphosphate and the intermediate (+)-copalyl diphosphate to a nearly equal mixture of abietad
37 te and the second for the cyclization of (+)-copalyl diphosphate to diterpene end products, and demon
38 e class I terpene synthase that converts syn-copalyl diphosphate to the corresponding polycyclic hydr
39 tes encountered during the conversion of ent-copalyl diphosphate to the diterpenes beyerene, kaurene,
40 hate to the stable bicyclic intermediate (+)-copalyl diphosphate via protonation-initiated cyclizatio
41 the ionization-dependent cyclization of (+)-copalyl diphosphate, via a pimarenyl intermediate, to th
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