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1 equent conventional Pd-catalyzed coupling or cross-coupling reaction.
2 synthesized by the Pd-catalyzed Sonogashira cross-coupling reaction.
3 idine ligands were synthesized by the Suzuki cross-coupling reaction.
4 sides were synthesized using the Sonogashira cross-coupling reaction.
5 a versatile catalyst for the Suzuki-Miyaura cross-coupling reaction.
6 ytic efficiency and the base employed in the cross-coupling reaction.
7 l esters and amides through a Suzuki-Miyaura cross-coupling reaction.
8 the two positions toward the metal-catalyzed cross-coupling reaction.
9 a common intermediate using a silicon-based cross-coupling reaction.
10 amolecular enolate-driven palladium-mediated cross-coupling reaction.
11 as well as an alkenyl-alkenyl silicon-based cross-coupling reaction.
12 ti-substituted 3-fluorofurans using a Suzuki cross-coupling reaction.
13 , has been established in the Suzuki-Miyaura cross-coupling reaction.
14 unctionality was accomplished by Sonogashira cross-coupling reaction.
15 ydro-2H-pyrans as substrate in a Kumada-type cross-coupling reaction.
16 se cycloaddition reactions have been used in cross coupling reactions.
17 rins were synthesized through Suzuki-Miyaura cross coupling reactions.
18 idant-free Au(I)-catalyzed carbon-heteroatom cross-coupling reactions.
19 ials in the Suzuki, Sonogashira, and Ullmann cross-coupling reactions.
20 olithium reagents in the palladium-catalyzed cross-coupling reactions.
21 o competent catalysts for Kumada and Negishi cross-coupling reactions.
22 synthesis, but have rarely been employed in cross-coupling reactions.
23 d several intermediates were seen in Negishi cross-coupling reactions.
24 e highly effective in Suzuki-Miyaura and C-N cross-coupling reactions.
25 ally prepared through kinetically controlled cross-coupling reactions.
26 of the heterocyclic ring via Suzuki-Miyaura cross-coupling reactions.
27 es a well-defined pincer-Rh catalyst for C-S cross-coupling reactions.
28 ts for metal-free formal C(sp(2) )-C(sp(2) ) cross-coupling reactions.
29 es high catalytic activity for carbon-sulfur cross-coupling reactions.
30 use of organo-halide reagents in traditional cross-coupling reactions.
31 ed from the precursor iodide 7 using Negishi cross-coupling reactions.
32 method to use secondary alkyltin reagents in cross-coupling reactions.
33 atalytic performance in an eclectic array of cross-coupling reactions.
34 nsights into the mechanism of gold-catalyzed cross-coupling reactions.
35 re synthesized by double palladium-catalyzed cross-coupling reactions.
36 or exploited using versatile metal-catalysed cross-coupling reactions.
37 ion under the conditions of copper-catalyzed cross-coupling reactions.
38 kage and using multifold palladium-catalyzed cross-coupling reactions.
39 ification through S(N)Ar and metal-catalyzed cross-coupling reactions.
40 of chiral 4,4'-bipyridines by site-selective cross-coupling reactions.
41 on were further diversified via Pd-catalyzed cross-coupling reactions.
42 ersal partners (2 and 6) for metal-catalyzed cross-coupling reactions.
43 Diels-Alder cycloadducts were used in Hiyama cross-coupling reactions.
44 s such as arylboronic acids in Au(I)/Au(III) cross-coupling reactions.
45 ficiently be used as a precursor for Negishi cross-coupling reactions.
46 vinyl chlorides and subsequent Pd-catalyzed cross-coupling reactions.
47 e proposed key intermediates in Cu-catalyzed cross-coupling reactions.
48 abundance, and its ability to promote unique cross-coupling reactions.
49 ortant yet elusive objective for engineering cross-coupling reactions.
50 w turnover numbers relative to non-oxidative cross-coupling reactions.
51 only proposed as the active intermediates in cross-coupling reactions.
52 ve to traditional transition-metal-catalysed cross-coupling reactions.
53 lkyl groups to transition metal catalysts in cross-coupling reactions.
54 nate can serve to direct palladium-catalyzed cross-coupling reactions.
55 are particularly valuable in metal-catalyzed cross-coupling reactions.
56 of challenging C-C and C-X (X = heteroatom) cross-coupling reactions.
57 ign in facilitating challenging Pd-catalyzed cross-coupling reactions.
58 the transmetalation step in Pd/Cu-catalyzed cross-coupling reactions.
59 h electrophiles as well as Stille and Suzuki cross-coupling reactions.
60 : 1) Palladium-nanoparticle-catalyzed Suzuki cross-coupling reactions, 2) palladium- or silver-nanopa
61 of anomeric configuration make the glycosyl cross-coupling reaction a practical tool for the synthes
62 al Cu-catalyzed stereocontrolled sp(3)-sp(3) cross-coupling reactions allowed convergent assembly of
64 rivative was synthesized via the Sonogashira cross-coupling reaction and radiolabeled via the tricarb
65 synthesized by the Pd-catalyzed Sonogashira cross-coupling reaction and subsequent [2 + 2] cycloaddi
66 implications for the design of N-C(O) amide cross-coupling reactions and control of the molecular co
67 ecent findings in transition metal-catalysed cross-coupling reactions and detail several reports from
68 ladium nanoparticle-catalyzed Suzuki-Miyaura cross-coupling reactions and evaluated as human carbonic
69 rth-abundant" transition-metal catalysts for cross-coupling reactions and extraction and fractional c
70 ves through conventional palladium-catalyzed cross-coupling reactions and iodine-lithium exchange pro
71 lvement of organometallic Ni(III) species in cross-coupling reactions and oxidatively induced C-heter
72 derstanding the mechanisms of iron-catalyzed cross-coupling reactions and rational design of novel ir
73 e, Suzuki, Buchwald-Hartwig, and Sonogashira cross-coupling reactions) and lithium-halogen exchange t
74 reaction, a palladium-catalyzed Stille-Kelly cross coupling reaction, and a carbon monoxide-mediated
76 ely synthesized, using a palladium-catalyzed cross-coupling reaction, and identified as potent antipr
77 s alkynyl protecting groups, (2) Sonogashira cross-coupling reactions, and (3) the development of rin
78 nthetic transformations, including iterative cross-coupling reactions, and a Chan-Lam-type allyloxyla
79 (1) was prepared via two consecutive Suzuki cross-coupling reactions, and the three-dimensional stru
80 th the activity and regioselectivity of this cross-coupling reaction are correlated with the acidity
82 talyzed C(sp)-C(sp(2)) and C(sp(2))-C(sp(2)) cross-coupling reactions are accomplished with aryldiazo
87 arbon-halogen bond activation to achieve C-C cross-coupling reactions as well as reductive dehalogena
89 report a series of enantioselective C-O bond cross-coupling reactions based on remote symmetry breaki
90 ted a typically undesired elementary step in cross-coupling reactions, beta-hydride elimination, to a
91 diene was installed with a complex reductive cross-coupling reaction between a preformed Ti-alkyne co
92 a copper-catalyzed domino Michael/oxidative cross-coupling reaction between adenines and nitroolefin
93 ated the two-step, one-pot borylation/Suzuki cross-coupling reaction between aryl and heteroaryl hali
94 asymmetric iron-catalyzed C(sp(2))-C(sp(3)) cross-coupling reaction between Grignard reagents and al
96 erated through a palladium-catalyzed Ullmann cross-coupling reaction between o-iodonitrobenzene and a
97 Weinreb amides through a palladium-catalyzed cross-coupling reaction between organoboronic acids and
98 estigation of the palladium-catalyzed Kumada cross-coupling reaction between PhMgBr and (pseudo-ortho
99 Complex 3a was found to catalyze the Kumada cross-coupling reaction between PhMgCl and a range of br
100 prepared using a palladium-catalyzed Ullmann cross-coupling reaction between the appropriate 2-iodocy
101 is a mild, scalable, visible-light-promoted cross-coupling reaction between thiols and aryl halides
102 Here, we describe a metal-promoted reductive cross-coupling reaction between vinylcyclopropanes and a
103 s and have also been employed as partners in cross-coupling reactions between aromatic, alkenyl, alky
105 ss spectra suggests that there are extensive cross-coupling reactions between hydroxy-carbonyl produc
108 ting group, which otherwise does not allow a cross-coupling reaction, by transformation to the N-oxid
109 ized aryl iodides are introduced, subsequent cross coupling reactions can be used for further modific
110 ed that an enolate-driven palladium-mediated cross-coupling reaction can be accomplished by a copper-
112 fective room-temperature palladium-catalyzed cross-coupling reactions (CCRs) of aryl and heteroaryl c
113 a directing group for C(sp(2))-H activation/cross-coupling reactions, circumventing the extra steps
114 o-metabolites, develop a mild Suzuki-Miyaura cross-coupling reaction compatible with cell growth and
116 n and the sulfanyl group by Liebeskind-Srogl cross-coupling reaction, demonstrating the orthogonality
117 spectroscopic studies suggest that this C-S cross-coupling reaction does not involve a Ni(0)-species
119 This method represents the first catalytic cross-coupling reaction employing a nonallylic and nonbe
120 ide N-C(O) bonds are generally unreactive in cross-coupling reactions employing low-valent transition
123 w compounds are also scaffolds for selective cross-coupling reactions, enabling further molecular div
124 ity of these intermediates is exemplified by cross-coupling reactions, enabling regiocontrolled synth
125 an important role in a range of Ni-catalyzed cross-coupling reactions, especially those involving alk
127 The explication of how this new class of cross-coupling reactions evolved from problem formulatio
128 ve been shown to undergo selective amide N-C cross-coupling reactions, feature a significantly decrea
129 eature the development of the B-alkyl Suzuki cross-coupling reaction for direct access to (E)-cyclono
130 ound to be the resting state in Pd-catalyzed cross-coupling reactions for a range of aryl halides and
132 method complementary to the Stille or Suzuki cross-coupling reactions for the synthesis of cyclic or
134 s have been synthesized by a modified Suzuki cross-coupling reaction from 3,4-dibromo-N-benzylmaleimi
135 lizing sequential, orthogonal Suzuki-Miyaura cross-coupling reactions from two late-stage intermediat
137 t is noted that the one-pot pinacol boronate cross-coupling reaction generally provides products in h
139 Bronsted acid catalyzed dearomatizing redox cross coupling reaction has been realized, in which aryl
140 s in a challenging asymmetric Suzuki-Miyaura cross-coupling reaction has enabled enantioenriched (up
141 ant first-row metals, especially nickel, for cross-coupling reactions has attracted significant inter
142 he development of transition metal-catalysed cross-coupling reactions has greatly influenced the mann
143 e equivalents for transition metal-catalyzed cross-coupling reactions has the potential to substantia
147 tility of these compounds is demonstrated in cross-coupling reactions, highlighting the potential of
148 sters was obtained via a palladium-catalyzed cross-coupling reaction (Hirao coupling) of dialkyl phos
149 This elementary reaction enables a powerful cross-coupling reaction in which a chiral Pd catalyst me
150 nts 2a and 2b were prepared and subjected to cross-coupling reactions in the presence of a nickel cat
151 amental characterization of the key steps in cross-coupling reactions, including C-C bond-forming red
152 stration of three mild Pd/Cu-mediated Stille cross-coupling reactions, including the use of a one-pot
153 he useful two-step directed ortho metalation/cross-coupling reaction involving cryogenic temperature
155 ribe the use of MOFs as catalysts to promote cross-coupling reactions involving organometallic reacti
161 effect of unprotected azoles on Pd-catalyzed cross-coupling reactions is described based on evidence
163 of gold as the organizing metal in homo- and cross-coupling reactions is explored in this paper combi
167 ugh an efficient palladium-catalyzed Ullmann cross-coupling reaction, is reductively cyclized under c
168 commercially available starting materials by cross-coupling reactions, many desirable and otherwise d
170 yl: A significant development in alkyl-alkyl cross-coupling reactions, namely the nickel-catalyzed de
171 alyst under commonly employed conditions for cross-coupling reactions, noninhibitory byproduct releas
173 Formation on demand: An organocatalytic cross-coupling reaction of aldehydes with N-hydroxyimide
175 versal of regioselectivity in a Pd-catalyzed cross-coupling reaction of an aryl chloro triflate with
177 atalyzed synthesis of diaryl selenides via a cross-coupling reaction of diaryl diselenides with aryl
181 approach is based on the palladium-catalyzed cross-coupling reaction of halogenated azines with organ
183 wn that the efficiency of the Suzuki-Miyaura cross-coupling reaction of nitroimidazoles is slightly l
184 sis was performed for the k(c) values of the cross-coupling reaction of nitroxides with tert-butoxylc
186 conditions were found for the Suzuki-Miyaura cross-coupling reaction of potassium cyclopropyl- and cy
187 is of (+)-ileabethoxazole (1) using a Stille cross-coupling reaction of propargylic stannanes with 5-
188 irst Negishi nickel-catalyzed stereospecific cross-coupling reaction of secondary benzylic esters is
189 al and highly stereoselective iron-catalyzed cross-coupling reaction of stereodefined enol carbamates
190 were prepared via the Liebeskind-Srogl (L-S) cross-coupling reaction of the Biellmann BODIPYs (1a,b)
191 the sp(2) C-H bond in water also allows the cross-coupling reaction of two different C-H bonds in th
192 l for the palladium-catalyzed Suzuki-Miyaura cross-coupling reaction of unprotected haloimidazoles is
193 This method relies on a palladium-catalyzed cross-coupling reaction of various brominated PAHs with
194 , are shown to serve as suitable partners in cross-coupling reactions of (activated) secondary alkyl
196 of our ongoing effort to expand the scope of cross-coupling reactions of alkyl electrophiles, we have
197 xanediol ligand facilitated the Cu-catalyzed cross-coupling reactions of alkyl, aryl, or heterocyclic
200 stereochemical course of palladium-catalyzed cross-coupling reactions of an enantioenriched, alpha-su
201 eavage of inert C(sp(2))-O bonds relevant to cross-coupling reactions of aromatic ethers catalyzed by
204 t adducts containing Si-O-Pd linkages in the cross-coupling reactions of arylsilanolates has been una
205 leoside triphosphates (dNTPs) by the aqueous cross-coupling reactions of biarylboronates is reported.
206 Pd-catalyzed Suzuki-Miyaura and Sonogashira cross-coupling reactions of cyclic 1,3-diones in the syn
207 or 168 different Pd/Cu-catalyzed Sonogashira cross-coupling reactions of five arylacetylenes (phenyla
208 phosphorylation of nucleosides or by aqueous cross-coupling reactions of halogenated dNTPs is discuss
211 tematic study of titanium-mediated reductive cross-coupling reactions of internal alkynes with termin
212 d Suzuki, Negishi, Sonogashira, and Heck C-C cross-coupling reactions of iodo derivatives 1c, 1d, and
213 ickel-based catalysts have been reported for cross-coupling reactions of nonactivated alkyl halides.
214 t adducts containing Si-O-Pd linkages in the cross-coupling reactions of organosilanolates has been u
218 e pyri(mi)dyl bromides and then Pd-catalyzed cross-coupling reactions of the amines and precursor bro
221 subsequent TBAF-assisted/Pd-catalyzed Hiyama cross-coupling reactions of those Diels-Alder adducts.
224 l step was also possible by Liebeskind-Srogl cross-coupling reaction on the previously introduced C-2
226 tions can be used directly in Suzuki-Miyaura cross-coupling reactions or isolated as air-stable potas
231 fluorinated amide, this palladium-catalyzed cross-coupling reaction provides a versatile platform to
232 ing of each module using palladium-catalyzed cross-coupling reactions provides both mono- and disubst
233 eboronative mechanisms with implications for cross-coupling reactions, regioselective deuteration/tri
234 secondary and tertiary alkyl nucleophiles in cross-coupling reactions remains a challenge because of
235 ication of C(sp3)-hybridized nucleophiles in cross-coupling reactions remains an unsolved challenge i
236 combining amination and palladium-catalyzed cross-coupling reactions, such as reductive dehalogenati
237 TTF building block using palladium-catalyzed cross-coupling reactions, such as the Suzuki reaction.
238 different chemoselectivity than conventional cross-coupling reactions, such as the Suzuki-Miyaura, St
239 Moreover, 4,4'-bipyridine 2 was submitted to cross-coupling reactions (Suzuki and Sonogashira) which
243 In the area of transition metal-catalyzed cross-coupling reactions the C-S bond cleaving reactions
244 se apart from their effectiveness in Negishi cross-coupling reactions, they show more resistance to a
245 f styrene, followed by a palladium-catalyzed cross coupling reaction to install an electron donating
247 uctions to build the polyol domain, a Stille cross-coupling reaction to assemble the polyene, and an
248 re used in a stereospecific nickel-catalyzed cross-coupling reaction to form C(sp(3))-C(sp(3)) bonds.
249 ynthesis features the stereoselective Stille cross-coupling reaction to set up the whole carbon frame
250 an also be accessed by harnessing the Suzuki cross-coupling reaction to the isomerization/N-acylimini
251 equent high yielding stereoretentive Negishi cross-coupling reactions to allow structural diversity t
252 for subsequent oxidation, halogenation, and cross-coupling reactions to deliver benzylamine and aryl
253 triflate products can be elaborated through cross-coupling reactions to generate synthetically usefu
257 lete conversions of aryl chlorides in Suzuki cross-coupling reactions under Pd(I) dimer conditions.
258 The late-stage alkenyl-alkenyl silicon-based cross-coupling reaction uniting the core alkenyl iodides
259 adium-catalyzed, enantioselective, aryl-aryl cross-coupling reaction using 1-naphthyldimethylsilanola
261 thway is important in further development of cross-coupling reactions using different catalysts.
262 n the absence of Pd-catalyzed or Ni-mediated cross-coupling reactions, using 1,4-diketones as surroga
263 been synthesized by exploiting Pd-catalyzed cross-coupling reaction via C-H activation as a key step
267 ruglike electrophiles (informers) in Negishi cross-coupling reactions was evaluated by high-throughpu
270 oronic acid (p-tolyl-B(OH)2) in this type of cross-coupling reaction were evaluated (eg, ethyleneglyc
275 ther been incorporated into a dual catalytic cross-coupling reaction, which requires both the supramo
278 ting oxidative additions upon d(0) metals or cross coupling reactions with cobalt(iii) without metal
279 siloxane ring, followed by an intramolecular cross-coupling reaction with a pendant alkenyl iodide.
280 Palladium-catalyzed Suzuki-Miyaura (SM) cross-coupling reaction with allylboronic acid pinacol e
281 anomeric stannanes undergo a stereospecific cross-coupling reaction with aromatic halides in the pre
282 l anion equivalents in a palladium-catalyzed cross-coupling reaction with aryl bromides to give unsym
283 es undergo a stereospecific nickel-catalyzed cross-coupling reaction with aryl Grignard reagents (see
286 these copper-rich complexes on the yields of cross-coupling reactions with an alkyl halide was tested
288 rate both the importance of Fe(I) in Negishi cross-coupling reactions with arylzinc reagents and the
289 ter for onward reactivity as demonstrated in cross-coupling reactions with benzoyl chloride that prod
290 unds served as starting materials for Suzuki cross-coupling reactions with electron-poor arylboronic
291 ed the development of elusive amide bond N-C cross-coupling reactions with organometallic reagents, a
292 is demonstrated to be effective in selective cross-coupling reactions with secondary alkyl reagents a
294 ondary alkyltrifluoroborate reagents undergo cross-coupling reactions with stereospecific inversion o
295 ant implications for the design of new amide cross-coupling reactions with the N-C(O) amide bond clea
296 boronate in nickel-catalyzed Suzuki-Miyaura cross-coupling reactions with the two C-O electrophiles,
297 phine ligands for efficient room temperature cross-coupling reactions with unactivated aryl chlorides
298 (N-methylheteroaryl)borates and their use in cross-coupling reactions with various aryl and heteroary
299 philic addition followed by Liebeskind-Srogl cross-coupling reaction yielded unprecedented aryl intro
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