ライフサイエンスコーパス: cyanide

1 lations in single cells without the need for cyanide.

2 e and two bd oxidases much less sensitive to cyanide.

3 yanoalanine synthase enzyme that metabolizes cyanide.

4 icate, 3 nM taurine, 3 nM sulfide, and 13 nM cyanide.

5 ensing in the presence of tetrabutylammonium cyanide.

6 trile into ICHO and ICOOH, thereby releasing cyanide.

7 a well-known source of endogenous biological cyanide.

8 tely nitrate < cyanate < azide < fluoride << cyanide.

9 tivated free radical rearrangement to benzyl cyanide.

10 can be reversed by the addition of potassium cyanide.

11 elective visual colorimetric response toward cyanide.

12 h: brefeldin A, latrunculin B, and potassium cyanide.

13 xide reduction are completely inactivated by cyanide.

14 change of the ancillary chloride ligand to a cyanide.

15 the toxicity of abundant components, such as cyanides.

16 ldehydes in combination with alpha-bromoacyl cyanides.

17 oformylation substrates vinyl acetate, allyl cyanide, 1-octene, and trans-1-phenyl-1,3-butadiene at l

18 luoro-11beta-hydroxy-16alpha-methylpregna-21-cyanide-1,4-diene-3,20-dion e), do not have the 17alpha-

19 block for further derivatizations, e.g., the cyanide 14.

20 dge (-26.9 +/- 1.5 per thousand), commercial cyanides (-26.0 +/- 3.0 per thousand), and their corresp

21 stable than delphinidin 3,5-di (Dp3,5dG) and cyaniding 3,5-diglucosides (Cy3,5dG).

22 he exception of P. spinosa samples, in which cyaniding 3-O-rutinoside and peonidin 3-O-rutinoside pre

23 argonidin-3-glucoside, cyanidin-3-glucoside, cyaniding-3,5-diglucoside and delphinidin-3-glucoside.

24 Cyaniding-3-rutinoside, cyaniding-3- glucoside and its equivalents were identifi

25 al flavonoids, total monomeric anthocyanins, cyaniding-3-glucoside and total proanthocyanidins.

26 in skin than in pulp (64-82 and 646-534mg of cyaniding-3-glucoside equivalents/100g skin and pulp, re

27 linear regression model from 0.05 to 50mg of cyaniding-3-O-glucoside L(-1) because it gave better fit

28 Cyaniding-3-rutinoside, cyaniding-3- glucoside and its e

29 chain, as confirmed by addition of carbonyl cyanide 4-(trifluoromethoxy) phenylhydrazone and potassi

30 , 6) poisoning (carbon monoxide, arsenic, or cyanide), 7) other toxins, and 8) combinations.

31 metal-loaded enzymes that are supplied with cyanide, a mimic of O2 (-) Studies with CDH and its isol

32 Cyanide accumulation and CYS-C1 gene expression are nega

33 bility of multiple, competing mechanisms for cyanide activation and reduction.

34 inyl ether to an alpha-chloro ether prior to cyanide addition in a pathway that proceeds through Bron

35 e constant (kon (CN)) but a much more stable cyanide adduct with 3 orders of magnitude slower koff (C

36 bromides, alpha-bromo diketones, alpha-bromo cyanides, alpha-bromoesters, and alpha-bromo ketoesters

37 Finally, potassium cyanide, an electron transport chain inhibitor, briefly

38 nel fluorogenic response toward fluoride and cyanide and also a selective visual colorimetric respons

39 kcat of 1475 s(-1) and Km of 10.1 +/- 1.7 mm Cyanide and azide inhibited the catalase activity with K

40 ei were inhibited by hydrogenase inhibitors (cyanide and carbon monoxide), but not by a formate dehyd

41 tei were inhibited by hypophosphite, but not cyanide and carbon monoxide.

42 ase contains a 2Fe subcluster coordinated by cyanide and CO ligands as well as dithiomethylamine; the

43 nse induced by two NADH-oxidation inhibitors-cyanide and ethanol-are similar in Saccharomyces cerevis

44 e formed from the reaction of abundant vinyl cyanide and its radical or via cyano radicals reacting w

45 resumed to have been available from hydrogen cyanide and other nitrogenous species formed in Earth's

46 nsive nucleophiles (e.g., tetraalkylammonium cyanide and phenoxide salts) and fluorine-containing ele

47 ed by the reductive homologation of hydrogen cyanide and some of its derivatives, and thus that all t

48 o understand better the metabolic effects of cyanide and to discover novel cyanide antidotes, we deve

49 oxide itself, [(11)C]carbon monoxide, [(11)C]cyanide, and [(11)C]phosgene represent alternative react

50 ndicate that nucleophiles such as thiolates, cyanide, and hydride induce nonenzymatic reduction of th

51 activity towards glycolysis using potassium cyanide, and oxidative phosphorylation using hydrogen pe

52 of nucleophiles including hydrides, amines, cyanide, and protected enolates.

53 unts of insecticide residues (37 compounds), cyanide, and trypsin inhibitor, as well as Pb, Cd, nitra

54 drogen sulphide in the presence of copper(I) cyanide, and we therefore subjected ribose to these cond

55 ation of indoles using benzyl cyanide as the cyanide anion source is presented.

56 shown that aquohydroxocobinamide is a potent cyanide antidote in animal models of cyanide poisoning,

57 Current cyanide antidotes are administered by IV infusion, which

58 Improved cyanide antidotes are needed, but the ideal biological p

59 Currently available cyanide antidotes must be given by intravenous injection

60 lic effects of cyanide and to discover novel cyanide antidotes, we developed a zebrafish model of cya

61 The production of iso-propyl cyanide appears to require the addition of a functional

62 es, blast furnace operations, and commercial cyanide applications.

63 e optical responses of 3 toward fluoride and cyanide are distinctively different, thus enabling the d

64 muS/cm, limits of detection for sulfide and cyanide are in the submicromolar level, with a linear dy

65 The solid phases of gold(I) and/or silver(I) cyanides are supramolecular assemblies of inorganic poly

66 ) for chemical threat agents (CTAs), such as cyanides, are being investigated to provide an evidentia

67 Avoidance of hydrogen cyanide as a by-product also improves process safety and

68 echanistic approach was extended using tosyl cyanide as a radical trap, enabling the conversion of al

69 ial hydroxy group, benzoyl cyanide or acetyl cyanide as an acylating agent, and DMAP as a catalyst yi

70 nication focuses primarily on reactions with cyanide as nucleophile, preliminary experiments with oth

71 lective C3-cyanation of indoles using benzyl cyanide as the cyanide anion source is presented.

72 n of a substituted isoquinoline using benzyl cyanide as the second nitrile supports the postulated me

73 e synthase activity, the other enzyme in the cyanide assimilation pathway, suggesting that nitrilase

74 minimal affinity for fluoride and can detect cyanide at concentrations less than 1 mum.

75 heptane is opened by different nucleophiles (cyanide, azide, or acetate anions) to produce mixtures o

76 o be aposematic, forewarning of the animal's cyanide-based toxins, these results are contrary to apos

77 On the other hand, cyanide binding occurs at the Zn(II) core leading to dra

78 A 100-fold increase in the affinity of cyanide binding to the enzyme-substrate complex over the

79 a much stronger nucleophile than hydroxide, cyanide binds more rapidly and promotes oxidation of Ni(

80 literature results and suggest that hydrogen cyanide--"Blausaure"--was that feedstock.

81 Finally, the anionic cyanide-bound series reveals the highest degree of valen

82 rt a highly active phase of heterobimetallic cyanide-bridged electrocatalysts able to promote water o

83 Two structurally related and photoresponsive cyanide-bridged Fe/Co square complexes, {Fe2Co2}, are re

84 which was blocked by the Cu-Zn SOD inhibitor cyanide but not by azide, which inhibits Fe and Mn SODs.

85 leophile" coupling of the peptide and [(11)C]cyanide by temporal separation of nucleophile addition.

86 esults obtained bring evidence that hydrogen cyanide can be adsorbed onto aerosol liquid water and ca

87 we show that inorganic nanowires of gold(I) cyanide can grow directly on pristine graphene, aligning

88 le alpha-carbanions to afford activated acyl cyanides capable of reacting with amine nucleophiles.

89 An integrated cyanide capture "apparatus", consisting of sample and cy

90 apture "apparatus", consisting of sample and cyanide capture chambers, allowed rapid separation of cy

91 termined the stable isotopic compositions of cyanide-carbon (CCN) and cyanide-nitrogen (NCN) in 127 c

92 y of weak acids (silicate, borate, arsenite, cyanide, carbonate, and sulfide) cannot only be separate

93 sing chain shuttling agents and double-metal cyanide catalysts.

94 ndogenous plant enzymes can release hydrogen cyanide causing potential toxicity issues for animals in

95 Here we report the detection of the complex cyanides CH3CN and HC3N (and HCN) in the protoplanetary

96 in comets, including 0.01 per cent of methyl cyanide (CH3CN) with respect to water, is of special int

97 Gold ore processing uses cyanide (CN(-) ), which often results in large volumes o

98 terrupting the electron transport chain with cyanide (CN(-)) alters ER NAD(P)H.

99 designed and successfully applied to detect cyanide (CN(-)) based on a Michael-type nucleophilic add

100 site with three carbon monoxide (CO) and two cyanide (CN(-)) ligands (e.g., in the oxidized state, Ho

101 site with three carbon monoxide (CO) and two cyanide (CN(-)) ligands in the active oxidized state (Ho

102 organic solvent to catalyze the reduction of cyanide (CN(-)), carbon monoxide (CO), and carbon dioxid

103 Hydrogen peroxide (HP) or cyanide (CN) are bacteriostatic at low-millimolar concen

104 conditions, but became markedly activated by cyanide (CN) or the known opener P1075 with a current de

105 Plants naturally produce cyanide (CN) which is maintained at low levels in their

106 e experiments demonstrating incorporation of cyanide cofactors and hydride substrate into [NiFe]-hydr

107 The [Au(CN)2](-) gold cyanide complex was detected in five of six waters from

108 tion of 11 and subsequent addition of benzyl cyanide, complex 9 is regenerated and the monomethylatio

109 Tracing the origin of iron-cyanide complexes in the environment is important becaus

110 o-hydroxyl, gold(I)-thiosulfate, and gold(I)-cyanide complexes.

111 n react with metal ions to form stable metal-cyanide complexes.

112 s is the first example of a heterobimetallic cyanide compound with such strong magnetic coupling.

113 The change with time of cyanide concentration, intermediates, and final products

114 promising tool for identifying the source of cyanide contamination.

115 tivars were used and the mean residual total cyanide content after steps 1, 2 and 3 was 28%, 12% and

116 type plants reveals that the high endogenous cyanide content of the cys-c1 mutant is correlated with

117 tion of CH4 and NH3 from a well-defined iron cyanide coordination complex, [SiP(iPr) 3 ]Fe(CN) (where

118 chemical environment change similar to gold-cyanide crystallization.

119 molecules and ions, notably carbon monoxide, cyanide, cyanate, and hydrogen sulfide, are potent inhib

120 radiation in oxygen-saturated toluene yields cyanide derivatives 3 and 4.

121 ase activity but enzyme kinetics showed that cyanide detoxification activity was strongly favored.

122 itrilase activity is the limiting factor for cyanide detoxification.

123 and a transcriptional regulator involved in cyanide detoxification.

124 Therefore, in a cyanide disaster, intramuscular (IM) injectable antidote

125 tion, the commercially relevant double-metal cyanide (DMC) catalyst systems are discussed.

126 Thus, the "cyanide effect" is due to dual hydrogen bonding of the a

127 ps were independently corroborated by HCA of cyanide elemental profiles and corresponded to countries

128 xazol-3-yl)-2-oxo-N'-phenyl-acetohydrazonoyl cyanide EPAC antagonists was synthesized and evaluated i

129 antidotes, we developed a zebrafish model of cyanide exposure and scaled it for high-throughput chemi

130 ve, and accurate method for the diagnosis of cyanide exposure is necessary.

131 erefore, a field sensor for the diagnosis of cyanide exposure was developed based on the reaction of

132 osulfate should rescue a human from a lethal cyanide exposure.

133 as a false positive or a false negative for cyanide exposure.

134 ded to countries each having one known solid cyanide factory: Czech Republic, Germany, and United Sta

135 ction of its iodophenyl precursor with (11)C-cyanide, followed by partial hydrolysis of the resulting

136 supernatant with phosphate buffer and sodium cyanide for derivatization in alkaline conditions.

137 NaHCO3 was used as an extraction solvent for cyanide formed after enzymatic hydrolysis of cyanogens.

138 etal formates, negative thermal expansion in cyanide frameworks, and the mechanics and processing of

139 trigonal CAP-Au(I) complexes, and displaces cyanide from [Au(CN)2](-) affording triangular [Au(CAP)3

140 apture chambers, allowed rapid separation of cyanide from blood samples.

141 The illness is attributed to exposure to cyanide from cassava foods, on which the population depe

142 Hydrolytically liberated endogenous cyanide from cyanogenic glycosides (CNp) reacts with ACC

143 rs and nitriles leads to displacement of the cyanide function.

144 isruption leads to release of toxic hydrogen cyanide gas, which can deter herbivore feeding.

145 nerating thiosulfate and from thiosulfate to cyanide generating thiocyanate.

146 irst-order kinetic equations with respect to cyanide, giving respectively activation energies of 108.

147 Further transformation of the cyanide group allowed the synthesis of an advance interm

148 Coal-carbonization-related cyanides had unique high mean delta(13)CCN values of -10

149 Because cyanogens and minor metabolites of cyanide have not induced konzo-like illnesses, SCN(-) re

150 icrometre-sized particles of frozen hydrogen cyanide (HCN ice).

151 ts in prebiotic chemistry implicate hydrogen cyanide (HCN) as the source of carbon and nitrogen for t

152 The chemistry of hydrogen cyanide (HCN) is believed to be central to the origin of

153 orine (and other halogens) can form hydrogen cyanide (HCN) or hydrogen chloride (HCl) and this can ca

154 We investigated if gaseous hydrogen cyanide (HCN) was a marker of BCC infection.

155 eroxide (H2O2), nitric acid (HNO3), hydrogen cyanide (HCN), hydroxymethyl hydroperoxide, peroxyacetic

156 hydroxynitrile that releases toxic hydrogen cyanide (HCN).

157 a chemical defensive strategy where hydrogen cyanide (HCN, hydrocyanic or prussic acid) is produced,

158 Nitryl cyanide holds promise as a high energy density material

159 ion of a branched alkyl molecule, iso-propyl cyanide (i-C3H7CN), with an abundance 0.4 times that of

160 Gold working electrode for detection of free cyanide in a chromatography system.

161 eter approach for the selective detection of cyanide in an aqueous micellar CTABr solution.

162 t test paper was conveniently used to detect cyanide in aqueous solution.

163 was successfully applied to the detection of cyanide in cassava (Manihot esculenta Crantz) roots, whi

164 the plant and leads to an increased level of cyanide in cys-c1 mutants as well as a root hairless phe

165 PAD) method for direct determination of free cyanide in drinking water has been reported.

166 ly developed method for the analysis of free cyanide in drinking water.

167 ction and rapid quantification of endogenous cyanide in fresh and processed cassava roots.

168 hloric acid, cyanogen chloride, and hydrogen cyanide in negative polarity are investigated.

169 similar stability of formamide and hydrogen cyanide in solution as well as their relatively facile i

170 The "heavy" use of cyanide in these industries, along with its necessary tr

171 th DOTAM derivatives display no affinity for cyanide in water, but respond to changes in fluoride con

172 fluorogenic chemosensor for the detection of cyanide in water, with detection limits of 1.9 x 10(-5)

173 st time on the measurement and speciation of cyanides in atmospheric aerosol.

174 The presence of cyanides in comets, including 0.01 per cent of methyl cy

175 on of benzylamines and decyanation of benzyl cyanides in one pot under metal-free conditions.

176 an even higher relative abundance of complex cyanides in the disk ice.

177 iocyanate (SCN(-) ), the major metabolite of cyanide, in the bodily fluids of konzo subjects is a con

178 FT (TD-DFT) calculations further support the cyanide-induced ESICT-ESIPT switching mechanism.

179 Riboflavin normalizes many of the cyanide-induced neurological and metabolic perturbations

180 "Cyanide inhibition" is easily reversed because it is sim

181 bservation originally made in the 1940s that cyanide inhibits microbial H2 oxidation and addresses th

182 The cyanide-insensitive alternative oxidase (AOX) is a non-p

183 Unmasking the addition products gives acyl cyanide intermediates that are intercepted by a variety

184 entations may involve the generation of acyl cyanide intermediates.

185 he oxidation of benzylic carbons (amines and cyanides) into corresponding benzamides using a catalyti

186 d sensitive probe for the optical sensing of cyanide ion (CN(-)) and 2-mercaptobenzothiazole (MBT) in

187 ess that involves a nucleophilic attack of a cyanide ion and a Brook rearrangement induced conjugate

188 tric detection of highly competitive H2S and cyanide ion in aqueous DMSO media.

189 Use of a chiral cyanide ion source, derived from KCN and quaternary ammo

190 A transketolase reaction was catalyzed by cyanide ion under prebiotic conditions instead of its mo

191 were probably initially performed instead by cyanide ion until its toxicity with metalloproteins beca

192 d a masked glyoxal equivalent catalyzed by a cyanide ion.

193 have been found to generate the nonvolatile cyanide ion.

194 Interestingly, cyanide ions (CN(-)) significantly inhibit the catalytic

195 Cyanide ions are shown to interact with lanthanide compl

196 Hydrogen cyanide is a ubiquitous gas in the atmosphere and a biom

197 h commonly known as a highly toxic chemical, cyanide is also an essential reagent for many industrial

198 As cyanide is capable of various kinds of hydrogen bonding

199 The affinity of ACCA sensor to cyanide is high, coordination occurs fast and the colori

200 s this new structure with respect to a mixed cyanide/isocyanide monolayer and propose a bonding schem

201 Removal of this "excess" gold by sodium cyanide leaching leaves the activity intact and the atom

202 We show that, in many cases, the cyanide leaving group is displaced preferentially in the

203 es carbon atom transfer from BAC to create a cyanide ligand along with the alkyne (i)Pr2N-C identical

204 3 [W(V) (CN)8 ] with concomitant loss of one cyanide ligand.

205 The two cyanide ligands in the assembled cluster of [FeFe] hydro

206 tion of the active site with diatomic CO and cyanide ligands.

207 te but with nitrosyl rather than carbonyl or cyanide ligands.

208 Chain extension reactions involving cyanide, lithium trimethylsilylacetylide, and a Wittig r

209 by the respiratory chain uncoupler, carbonyl cyanide m-chlorophenyl hydrazine (CCCP).

210 Herein, carbonyl cyanide m-chlorophenyl hydrazone (CCCP)-induced mitochon

211 induced by mitochondrial ionophore, carbonyl cyanide m-chlorophenyl hydrazone and other respiratory i

212 Although the uncoupler carbonyl cyanide m-chlorophenyl hydrazone inhibited AGT(P11LG170R

213 e to ATP or treatment with NH4Cl or carbonyl cyanide m-chlorophenyl hydrazone, indicating that SWEET1

214 reated with TNF or uncoupling agent carbonyl cyanide m-chlorophenyl hydrazone, suggesting an essentia

215 a or parkin-mediated mitophagy upon carbonyl cyanide m-chlorophenyl hydrazone-induced mitochondrial d

216 proton gradient was abolished with Carbonyl cyanide m-chlorophenyl hydrazone.

217 e to global mitochondrial damage by carbonyl cyanide m-chlorophenylhydrazine (CCCP) requires active g

218 The uncoupler carbonyl cyanide m-chlorophenylhydrazone (CCCP) inhibited Hyd-2-d

219 r mitochondrial depolarization with carbonyl cyanide m-chlorophenylhydrazone (CCCP), Flag-gp78 induce

220 tion to mitochondria in response to carbonyl cyanide m-chlorophenylhydrazone treatment.

221 otects mitochondria from actions of carbonyl cyanide m-chlorophenylhydrazone, an inhibitor of oxidati

222 Unlike the protonophore carbonyl cyanide m-chlorophenylhydrazone, which activates the mit

223 rsts after high-dose treatment with carbonyl cyanide m-chlorophenylhydrazone.

224 The reaction utilizes a masked acyl cyanide (MAC) reagent, which enables the one-pot prepara

225 Masked acyl cyanide (MAC) reagents are shown to be effective umpolun

226 Masked acyl cyanide (MAC) reagents are shown to be effective umpolun

227 In all tested conditions, cyanide mimicked the functional effect of sulfide on bac

228 e from acidic electrolytes both on bare, and cyanide-modified Pt(111).

229 orresponds to the expected complex with four cyanide moieties bound.

230 one another by having C21-thiomethyl and C21-cyanide moieties, respectively.

231 ations with sodium thiosulfate and potassium cyanide monitored by NMR and EPR.

232 Cyanide monolayers on Au{111} restructure from a hexagon

233 roid distance (2.786(3) A), occurring with a cyanide N atom located almost above the centroid of the

234 The elusive nitryl cyanide, NCNO2, has been synthesized and characterized.

235 pic compositions of cyanide-carbon (CCN) and cyanide-nitrogen (NCN) in 127 contaminated solids and 11

236 The metabolic effects of cyanide observed in zebrafish were conserved in a rabbit

237 uatorial and an axial hydroxy group, benzoyl cyanide or acetyl cyanide as an acylating agent, and DMA

238 e reactions between the ferric proteins with cyanide or H2O2 were accelerated.

239 These models were treated with potassium cyanide or hydrogen peroxide as controls, and epidermal

240 ating the iron with carbon monoxide (CO) and cyanide (or equivalent) groups.

241 ges were inhibited by l-Trp, the heme ligand cyanide, or free radical scavengers.

242 natural toxic substances (nitrate, nitrite, cyanide, oxalate, phytate, and trypsin inhibitor) in tub

243 Moreover, in the presence of carbonyl cyanide-p-trifluoromethoxyphenylhydrazone (FCCP), we sho

244 ives (chloride, bromide, thiocyanate, azide, cyanide, phenylsulfinate) by anion exchange.

245 referred to as nitrocobinamide) that rescues cyanide-poisoned mice and rabbits when given by intramus

246 , the sensor was 100% accurate in diagnosing cyanide poisoning for acutely exposed rabbits.

247 potent cyanide antidote in animal models of cyanide poisoning, but it is unstable in solution and po

248 ealized in the structural chemistry of these cyanide polymers.

249 action in HydG-catalyzed carbon monoxide and cyanide production from tyrosine.

250 addresses the interesting mechanism by which cyanide promotes the formation of Ni-B.

251 gical relevance (fluoride, chloride, iodide, cyanide, pyrophosphate, bicarbonate, hydrosulphide, pero

252 Cyanide reacts rapidly with [NiFe]-hydrogenases (hydroge

253 er the conventional use of halides and toxic cyanide reagents.

254 studies, are plausible intermediates of the cyanide reductive protonation to generate CH4 and NH3 .

255 , the structures of gold(I) and/or silver(I) cyanides reflect the phase behaviour of triangular XY ma

256 fluoromethoxy) phenylhydrazone and potassium cyanide, respectively, in intact mitochondria.

257 d with using anion impurities for matching a cyanide sample to its factory using our current cyanide

258 six reported countries of origin resulted in cyanide samples clustering into three groups, independen

259 the colorimetric and ratiometric fluorescent cyanide-selective chemodosimeter can be created based on

260 E. coli has three respiratory oxidases, the cyanide-sensitive heme-copper bo3 enzyme and two bd oxid

261 mice increased pH sensitivity while reducing cyanide sensitivity.

262 (15)NCN values seemed to be indicative for a cyanide source in the blast furnace.

263 on of aryl halides using a relatively benign cyanide source, K4[Fe(CN)6], is described.

264 be independently prepared using NaCN as the cyanide source, while reaction with B(C6F5)3 provides th

265 echanisms based on the generation of radical cyanide species (CN.) for the synthesis of nucleobases.

266 HCA of anion impurity profiles from multiple cyanide stocks from six reported countries of origin res

267 nide sample to its factory using our current cyanide stocks.

268 The concentration of cyanides strongly correlates with concentration of total

269 also involved in regulating the thiosulphate:cyanide sulphurtransferase activity of TstT.

270 0852) belongs to a new class of thiosulphate:cyanide sulphurtransferases.

271 In contrast, commercial cyanides tend to have lower delta(15)NCN values of -5.6

272 ensification, the large scale degradation of cyanide to below European emission limits is achievable.

273 lant over TiO2, with the target of degrading cyanide to below its allowable emission threshold set by

274 diate the six-electron reductive cleavage of cyanide to CH4 and NH3 .

275 , cupric ions may catalyse the conversion of cyanide to EC.

276 Here we employed sodium cyanide to probe the metal-ligand exchange of the enzyme

277 which indicate favorable hydrogen bonding of cyanide to the most acidic axial hydroxy group supported

278 Finally, using anion profiles to classify cyanides to a specific stock or stock group for a subset

279 B12 was extracted in the presence of sodium cyanide, to transform all forms of cobalamin into cyanoc

280 simplicity and inherent stability of nitryl cyanide, together with the known multitude of nitriles i

281 f the tstRT operon was found to increase the cyanide tolerance of L. brevis and Escherichia coli.

282 (2) Cyanide totally inhibits CO oxidation, but its effect on

283 Because the onset of cyanide toxicity is fast, a rapid, sensitive, and accura

284 ebrafish were conserved in a rabbit model of cyanide toxicity.

285 , we discovered 4 novel antidotes that block cyanide toxicity.

286 Metabolomic profiling of cyanide-treated zebrafish revealed changes in bile acid

287 inium photoredox catalyst and trimethylsilyl cyanide under an aerobic atmosphere.

288 e [5Fe-5S] cluster, which on incubation with cyanide, undergoes loss of the labile iron to yield a [4

289 for activity and are inhibited by azide and cyanide underscoring their common chemical imperatives.

290 afe-to-handle potassium thiocyanate releases cyanide units that are trapped in the presence of co-oxi

291 inal species able to undergo substitution by cyanide upon treatment with TMSCN (TMS=trimethylsilyl).

292 urtransferase activity of human rhodanese to cyanide versus sulfite and might be important in differe

293 Cyanide was actually a better catalyst than was TPP in s

294 anomethylation of N-tritylisatin with benzyl cyanide was obtained by DFT calculations.

295 ogen concentrations were lower, the resulted cyanide was separated by microdiffusion in a Conway cell

296 ver, for CYP71A12, indole-3-carbaldehyde and cyanide were identified as major reaction products.

297 selectively labeled tyrosine substrates, the cyanides were isotopically labeled via a recently develo

298 The results showed that strongly bound cyanides were present in all aerosol samples at a concen

299 ects is a consequence of dietary exposure to cyanide, which follows intake of poorly processed cassav

300 We hypothesize that cyanide, which is transiently accumulated during avirule

301 This simple system allows the detection of cyanide, with high sensitivity and specific selectivity,

302 tion of naphthalene dialdehyde, taurine, and cyanide, yielding a fluorescent beta-isoindole.