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1 an effective catalyst for the Huisgen [3+2] cycloaddition reaction.
2 ed using the copper-catalyzed sydnone-alkyne cycloaddition reaction.
3 hesis of bicyclic adduct through Diels-Alder cycloaddition reaction.
4 y through a copper(I)-catalyzed azide-alkyne cycloaddition reaction.
5 methane, a C-C or N-C coupling, and a formal cycloaddition reaction.
6 bromo-ethylmalonate and a retro-Diels-Alder cycloaddition reaction.
7 cation via the copper-catalyzed azide-alkyne cycloaddition reaction.
8 solely committed to the catalysis of a [4+2] cycloaddition reaction.
9 olymerization and azide-alkyne [3+2] Huisgen cycloaddition reaction.
10 eration of the copper-catalyzed azide-alkyne cycloaddition reaction.
11 ted for its ability to promote a Diels-Alder cycloaddition reaction.
12 omplexes using the CuI-mediated azide-alkyne cycloaddition reaction.
13 ough a novel Bronsted acid catalyzed [5 + 2] cycloaddition reaction.
14 ies through a copper catalyzed 3 + 2 Huisgen cycloaddition reaction.
15 r and may involve a Diels-Alder-type [4 + 2] cycloaddition reaction.
16 nds for the copper(I)-catalyzed azide-alkyne cycloaddition reaction.
17 use of a bulky vinyl ether in the key [4+2] cycloaddition reaction.
18 the asymmetric organocatalysis of the 4 + 3 cycloaddition reaction.
19 BO-NOTA) via copper-free Huisgen-1,3-dipolar cycloaddition reaction.
20 her understand the mechanism of this [3 + 2]-cycloaddition reaction.
21 enantioselective triple cascade 1,3-dipolar cycloaddition reaction.
22 G-II through a copper-catalysed azide-alkyne cycloaddition reaction.
23 socyanides to nitrile N-oxides via a [3 + 1] cycloaddition reaction.
24 o our knowledge, of an enzymatic 1,3-dipolar cycloaddition reaction.
25 en enol ether systems can participate in the cycloaddition reaction.
26 quence over the alternate hetero-Diels-Alder cycloaddition reaction.
27 an unsaturated aldehyde-allene for a [2 + 2] cycloaddition reaction.
28 ly prepared by enantioselective formal [3+2] cycloaddition reactions.
29 etrazine inverse electron demand Diels-Alder cycloaddition reactions.
30 reactivity of pentafulvenes in a plethora of cycloaddition reactions.
31 insertion, and [2 + 2], [3 + 2], and [4 + 2] cycloaddition reactions.
32 ioselectivities in nucleophilic addition and cycloaddition reactions.
33 ve as substrates for SN2, SN2', and aldehyde cycloaddition reactions.
34 preformed 5-membered rings, based mainly on cycloaddition reactions.
35 ic questions regarding ketene-alkene [2 + 2] cycloaddition reactions.
36 which is faster than recent strain-promoted cycloaddition reactions.
37 eactions, and intermolecular [2 + 2 + 1 + 1] cycloaddition reactions.
38 versatility in both Diels-Alder and dipolar cycloaddition reactions.
39 gration of propargylic esters in a number of cycloaddition reactions.
40 s hitherto unknown during phosphine-promoted cycloaddition reactions.
41 substitution, thiol addition, or 1,3-dipolar cycloaddition reactions.
42 eactions afford cycloheptadienes via [4 + 3] cycloaddition reactions.
43 esityl oxide, do not undergo selective [2+2] cycloaddition reactions.
44 incorporation of probes via copper-mediated cycloaddition reactions.
45 s of this type were made via copper-mediated cycloaddition reactions.
46 products of synthetic and biosynthetic [4+2] cycloaddition reactions.
47 Alder and 1,3-dipolar tritylazomethine ylide cycloaddition reactions.
48 oducts were all obtained from simple [2 + 2] cycloaddition reactions.
49 a key role in determining the outcome of the cycloaddition reactions.
50 ving as electron-rich dienophiles in [4 + 2] cycloaddition reactions.
51 for subsequent copper-catalyzed azide-alkyne cycloaddition reactions.
52 t of its reactivity in Michael, radical, and cycloaddition reactions.
53 embered anionic heterocycles in formal [2+2] cycloaddition reactions.
54 n, ylide formation, Wolff rearrangement, and cycloaddition reactions.
55 o be used in tandem with other bioorthogonal cycloaddition reactions.
56 DM2 RNA dysfunction by a Huisgen 1,3-dipolar cycloaddition reaction, a variant of click chemistry.
57 serve as conduits to three-component [4 + 2] cycloaddition reactions accessing structurally and stere
58 hiral catalyst that effectively promotes the cycloaddition reaction and can be recycled (five cycles)
59 mixture at 60 degrees C for 6 h promoted the cycloaddition reaction and provided the desired product
61 pha,beta-unsaturated ketone to undergo [1+4] cycloaddition reactions and afford [Cp*(IXy)(H)2 RuSn(ka
62 rated in this fashion are highly reactive in cycloaddition reactions and display a scope of reactivit
64 ly regio- and stereoselective intramolecular cycloaddition reactions and organometallic additions to
66 of independent (nontethered) bis-1,3-dipolar cycloaddition reactions and the characterization of 5 ne
67 (ii) the thermal stability toward the retro-cycloaddition reaction, and (iii) the effect of changing
68 more fully understand the mechanism of this cycloaddition reaction, and to guide efforts to extend i
69 dition reactions, intermolecular [2 + 2 + 2] cycloaddition reactions, and intermolecular [2 + 2 + 1 +
72 pha-Hydroxy-gamma-pyrone-based oxidopyrylium cycloaddition reactions are useful methods for accessing
73 itution and the participation of corroles in cycloaddition reactions as 2pi or 4pi components (coveri
74 und at 0 degrees C resulted in a retro [4+2] cycloaddition reaction, as observed by gel permeation ch
75 Baylis-Hillman, imino-ene, Mannich-type, and cycloaddition reactions, as well as hydrogenation and re
77 s electron density at Cu(I) that assists the cycloaddition reaction, (b) the three-armed motif bearin
78 as assembled by an internal azomethine ylide cycloaddition reaction based on silver ion-assisted intr
80 the regio- and enantioselective 1,3-dipolar cycloaddition reaction between 4-acetamidobenzonitrile N
81 fied TNA nucleosides (2'-NH2-TNA) based on a cycloaddition reaction between a glycal and an azodicarb
82 ates its own synthesis through a 1,3-dipolar cycloaddition reaction between a nitrone component, equi
84 esized through a ruthenium-catalyzed [2+2+2] cycloaddition reaction between a propargylic alcohol and
85 and led to the discovery of a Paterno-Buchi cycloaddition reaction between acetone and an angular me
88 ted monolayers were formed through a Huisgen cycloaddition reaction between an alpha-helical peptide
89 pyridyl-modified nucleotides, accelerates a cycloaddition reaction between anthracene and maleimide
92 Cl(4) was found to catalyze a formal [3 + 2] cycloaddition reaction between C(3)-substituted indoles
93 e of the decarbonylative [4 + 2] Diels-Alder cycloaddition reaction between ethynyl and tetraphenylcy
94 ilizing a regioselective copper(I)-catalyzed cycloaddition reaction between in situ generated nitrile
96 perimental and computational studies for the cycloaddition reaction between N-(3-pyridyl)aldimines an
97 crystal by a photochemically induced [4 + 4] cycloaddition reaction between neighboring monomers in w
99 Theory indicates that a pi2 + pi2 + sigma2 cycloaddition reaction between SO3 and HCOOH is a plausi
100 the photo- and cobalt-catalyzed [2 + 2 + 2] cycloaddition reaction between the corresponding naphthy
101 al resolution in cells via a Cu(I)-catalyzed cycloaddition reaction between the terminal alkyne group
102 It is found that the AlCl3-catalyzed [4 + 2]-cycloaddition reaction between these dienes and N-methyl
103 id synthesis utilized a novel hetero-[2 + 2]-cycloaddition reaction between two aryl ynol ethers to y
104 th 1 and 2 are effective catalysts for [3+2] cycloaddition reactions between alkynes and azides (i.e.
106 copper(I) complexes catalyzed multicomponent cycloaddition reactions between diazo compounds, pyridin
107 (F)CF2CF2-)(PPh2Me) in the first examples of cycloaddition reactions between perfluoroalkenes and met
108 the INI unit were synthesized by 1,3-dipolar cycloaddition reactions between pyrido[2,1-a]isoindole (
110 e first general method for catalysis of such cycloaddition reactions by using solvent hydrogen bondin
111 hree-step sequence involving the Diels-Alder cycloaddition reaction can be employed as advanced inter
112 cular, we show that the azide-alkyne Huisgen cycloaddition reaction catalyzed by copper(I) is fully c
113 reaction sequence proceeds via a Diels-Alder cycloaddition reaction catalyzed by dimethylaluminum chl
114 zetidinone and a variety of diynes undergo a cycloaddition reaction catalyzed by Ni/IPr to give dihyd
116 5-shift precursor, a copper-mediated dipolar cycloaddition reaction ("click") with azide partners is
121 s show why the catalytic, asymmetric (4 + 3)-cycloaddition reaction developed in the Harmata laborato
122 performing Sonogashira coupling and Huisgen cycloaddition reactions directly to the CTV core for the
123 several constrained agonists generated by a cycloaddition reaction displayed high selectivity (223-
124 to CuPRT via a Cu(I)-catalyzed azide-alkyne cycloaddition reaction failed as a result of dethreading
125 -membered ring trans-alkenes underwent [4+2] cycloaddition reactions faster than a trans-cyclooctene.
126 ed in good yields presumably through [4 + 2] cycloaddition reactions followed by hydrogen migrations.
127 echanistic insights into the thermal [3 + 2] cycloaddition reaction for such substrates, they were al
129 les are found to proceed through retro-(3+2)-cycloaddition reactions, generating the experimentally r
131 metal-free highly diastereoselctive [3 + 2] cycloaddition reaction has been developed between N-phen
133 the boron substituted cycloadducts of those cycloaddition reactions have been used in cross coupling
134 able linker via Cu(I)-catalyzed azide-alkyne cycloaddition reaction; (iii) enrichment of the biotin-t
137 reacts with the C(001) surface via a [2 + 2] cycloaddition reaction in a manner similar to nonpolar m
138 spectively, which were used in a Diels-Alder cycloaddition reaction in the synthesis of the correspon
139 the power of the intramolecular hetero [4+2] cycloaddition reaction in the total synthesis of complex
140 reference to an intramolecular Type-II 4 + 3 cycloaddition reaction in trifluoroethanol and hexafluor
143 onventional chemical approaches to achieving cycloaddition reactions in synthesis and uncover enantio
146 tions, other intermolecular and transannular cycloaddition reactions included intermolecular Pauson-K
147 on-metal-free applications of arynes include cycloaddition reactions, insertion reactions and multico
148 Pauson-Khand reactions, transannular [4 + 2] cycloaddition reactions, intermolecular [2 + 2 + 2] cycl
149 een successfully synthesized through [4 + 2] cycloaddition reaction involving in situ arynes as dieno
151 ies of multicomponent [4 + 2]/[3 + 2] domino cycloaddition reactions involving nitroindole derivative
152 plets (ca. 5 mum diameter) and find that the cycloaddition reaction is accelerated even further (by a
156 We find that the precursor of this [2 + 2] cycloaddition reaction is the singlet doubly pi(2)pi*(2)
159 exes are employed as catalysts for a [4 + 2] cycloaddition reaction leading to alkylidenecyclohexenes
160 lves at room temperature via a retro-[2 + 2]-cycloaddition reaction, leading to an original NHC-stabi
161 polarophiles in a 1,3-dipolar intramolecular cycloaddition reaction, leading to the corresponding iso
163 f the in situ protein-templated azide-alkyne cycloaddition reaction occurring at a localized, sequest
164 repared by a one-pot three-component [3 + 2] cycloaddition reaction of (E)-3-arylidene-1-phenyl-pyrro
165 , obtained by a Rh(II)-catalyzed 1,3-dipolar cycloaddition reaction of 1-(2-benzenesulfonyl-2-diazoac
166 or the formation of C(60) involves a [2 + 2] cycloaddition reaction of a cyclopolyyne to form a tetra
167 The technique illustrated here involves a cycloaddition reaction of a lactone with the in situ-gen
168 a Ru- or Rh-catalyzed [5 + 2] intramolecular cycloaddition reaction of an alkyne and a vinylcycloprop
169 ynthesis consists of an intramolecular [3+2]-cycloaddition reaction of an alpha-diazo indoloamide whi
170 The key step is an intramolecular [3 + 2]-cycloaddition reaction of an in situ generated azomethin
174 ion, transphosphorylation, and a 1,3-dipolar cycloaddition reaction of diazoalkylphosphonates in a pe
175 ure, we found that the rate constant for the cycloaddition reaction of DIFBO with an azide exceeds th
176 ater, is a regioselective hetero-Diels-Alder cycloaddition reaction of enol ethers to 4-phosphinyl or
180 d CHO-(Fl)(n)-CHO precursors via 1,3-dipolar cycloaddition reaction of in situ generated azomethine y
181 s the formal inverse electron demand [4 + 2] cycloaddition reaction of in situ-generated cationic ary
183 iiodide ions, which collectively mediate the cycloaddition reaction of organic azide and terminal alk
187 A regioselective dearomative aza-(3 + 2) cycloaddition reaction of substituted indoles with alpha
190 as accomplished through mono- and bis[3 + 2]-cycloaddition reactions of (2E,4E)-ethyl 5-(phenylsulfon
192 l ylide formation-intramolecular 1,3-dipolar cycloaddition reactions of 2-diazo-3,6-diketoesters show
193 ng the first systematic study of the [4 + 2] cycloaddition reactions of 3,6-diacyl-1,2,4,5-tetrazines
194 ffolds is presented, which exploits multiple cycloaddition reactions of a carbohydrate-derived nitron
196 an be achieved for either [4 + 2] or [4 + 3] cycloaddition reactions of allene-dienes catalyzed by go
201 tene substrates are derived from acylnitroso cycloaddition reactions of cyclopentadiene, followed by
203 ino esters are formed catalytically by [3+2] cycloaddition reactions of enecarbamates with electrophi
207 , synthesis of small-ring compounds, (2 + 2) cycloaddition reactions of halogenated ethylenes, assist
210 re investigated and paralleled with selected cycloaddition reactions of nitro- and nitrosobenzene wit
216 etailed account regarding formal aza-[3 + 3] cycloaddition reactions of tetronamides with alpha,beta-
217 was produced via two intramolecular [2 + 2] cycloaddition reactions of the benzannulated enyne-allen
218 ficient and stereoselective Pt(IV)-catalyzed cycloaddition reactions of the corresponding quinone met
219 catalyzed highly diastereoselective (3 + 2) cycloaddition reactions of the synthesized spiro-cyclopr
221 sensitivity by using a copper (I)-catalyzed cycloaddition reaction (often referred to as "click" che
222 cation of intramolecular 1,3-dipolar nitrone cycloaddition reaction on carbohydrate-derived precursor
223 ent complexation is much more favorable than cycloaddition reactions on interior bonds of graphene.
225 and 2 do not undergo heat- or light-induced cycloaddition reactions or Friedel-Crafts acylations.
226 rs for the biosynthetic relevance of [4 + 2] cycloaddition reactions, other cycloadditions have recei
227 On the basis of the strain-promoted [3 + 2] cycloaddition reaction performed at ambient temperature,
230 lectivity was observed in the intramolecular cycloaddition reaction producing 5 to 7-membered rings.
231 sess the viability of nitrone-alkene (3 + 2) cycloaddition reactions proposed to occur during the bio
233 s and 1,4,2-dioxazolidines revealed that the cycloaddition reaction takes place through a concerted m
234 we report an unprecedented overall 4pi + 2pi cycloaddition reaction that generates a different, highl
235 , the result is a sequential [5 + 2]/[4 + 2] cycloaddition reaction that provides sp(3)-rich products
236 des have proven to be versatile reagents for cycloaddition reactions that allow highly efficient cons
237 idized to Cu(I) , catalyzes the azide-alkyne cycloaddition reactions that result in the efficient syn
238 n other transformations, such as 1,3-dipolar cycloaddition reactions, that provide these products.
239 A DFT study explains the polar nature of the cycloaddition reaction, the observed reactivity and sugg
241 ymers, which are generated via retro-[4 + 2] cycloaddition reactions, the first-order kinetic coeffic
242 spite the widespread use of copper-catalyzed cycloaddition reactions, the mechanism of these processe
244 ed as an isomer formed via an internal 2 + 2 cycloaddition reaction; the triplet lifetime (8.4 +/- 0.
246 .1]-5-undecen-9-one; and (iii) a Diels-Alder cycloaddition reaction to construct the third ring found
247 we report the use of the Huisgen 1,3-dipolar cycloaddition reaction to generate triazole-stapled BCL9
248 ped by an alkene dipolarophile via a [2 + 3] cycloaddition reaction to give the corresponding isooxaz
249 plication of the ruthenium-catalyzed [2+2+2] cycloaddition reaction to highly substituted indene syst
251 ntioselective azomethine ylide (1,3)-dipolar cycloaddition reaction to set the absolute and relative
252 tions via a UV-irradiation-initiated [2 + 2] cycloaddition reaction to yield the corresponding cyclob
253 ites-that react pairwise through 1,3-dipolar cycloaddition reactions to create a network of four leng
254 n regio- and stereo-selective intramolecular cycloaddition reactions to give adducts, for example, 15
255 The regio- and stereoselective control of cycloaddition reactions to polyconjugated systems has be
256 also underwent strain-promoted alkyne-azido cycloaddition reactions to provide access to fluorescent
257 anes were shown to undergo efficient [3 + 2] cycloaddition reactions to provide azabicyclo[n.2.1]alka
258 zido fluorophore, via copper catalyzed [3+2] cycloaddition reactions, to produce the corresponding tr
259 e use of tandem, cobalt-mediated [2 + 2 + 2] cycloaddition reactions, two synthetic routes have been
260 hat underwent exquisite intramolecular [4+2] cycloaddition reactions under thermal conditions to prov
262 ggering of the metal-free azide to acetylene cycloaddition reaction was achieved by masking the tripl
263 isoxazoline complex as the catalyst, a [3+3]-cycloaddition reaction was achieved with excellent yield
266 oles formed via strain-promoted azide-alkyne cycloaddition reactions was investigated by density func
267 Brummond-Chen thermal intramolecular (2 + 2)-cycloaddition reactions were examined using density func
272 C) and featured a novel [2 + 2] photoinduced cycloaddition reaction which occurred with complete regi
273 onjugated aromatic system would be broken by cycloaddition reactions, which are therefore rarely appl
274 Cu(I) significantly accelerate azide-alkyne cycloaddition reactions while Bipy-containing SCPNs liga
275 functionalized by the four reagents through cycloaddition reactions, while the interior regions cann
276 cially available amide base and trapped in a cycloaddition reaction with furan in moderate to good yi
277 Br2-induced chelation-controlled 1,3-dipolar cycloaddition reaction with N-hydroxyphenylglycinol as a
278 alyzed dearomative trimethylenemethane [3+2] cycloaddition reaction with simple nitroarene substrates
281 y reported asymmetric Diels-Alder and Ficini cycloaddition reactions with 2,3-disubstituted butadiene
282 reversible, recognition-mediated 1,3-dipolar cycloaddition reactions with a stoppering maleimide grou
285 at N-malonylimidates undergo catalyzed [3+2] cycloaddition reactions with aldehydes, imines, and acti
289 s have been sought as substrates for Cu-free cycloaddition reactions with azides in biological system
290 )-ligated dirhodium carboxylates for [3 + 3]-cycloaddition reactions with both acyclic and cyclic nit
291 roenamines and their use in Zn(II)-catalyzed cycloaddition reactions with commercial alpha,beta-unsat
293 nters can be generated via completed (3 + 2) cycloaddition reactions with full regio- and diastereoco
294 ntities via N-chlorosulfonylisocyanate (CSI) cycloaddition reactions with functionalized alkenes; pre
295 rans linked by a rigid tether undergo tandem cycloaddition reactions with high stereoselectivity.
296 prepared in situ, is exemplified by dipolar cycloaddition reactions with nitrones to give highly sub
297 o react readily in [n + 2] (n = 6, 4, 2 + 2) cycloaddition reactions with norbornadiene and quadricyc
298 uranoside were also subjected to 1,3-dipolar cycloaddition reactions with six azidopyranosides under
299 shown to undergo characteristic ketene [2+2] cycloaddition reactions with tethered alkenes and extern
300 ognition site can participate in 1,3-dipolar cycloaddition reactions with two maleimides that differ
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