ライフサイエンスコーパス: cyclohexane

1 xidation by Fe(V)O of hydrocarbons including cyclohexane.

2 ether is a 4-substituted 1-(methoxymethylene)cyclohexane.

3 some cyclic 2-nitroalkanones was studied in cyclohexane.

4 ther was observed to selectively encapsulate cyclohexane.

5 t with their DeltaG(tr) values from water to cyclohexane.

6 over a multifunctional Pt/NbOPO4 catalyst in cyclohexane.

7 arent 1,2-BN cyclohexane, the BN-isostere of cyclohexane.

8 d the Phase I "plastic crystal" structure of cyclohexane.

9 acterized by UV-vis spectroscopy in MeCN and cyclohexane.

10 ly 2 x 10(12)-fold by transfer from water to cyclohexane.

11 um in this solvent relative to reaction with cyclohexane.

12 ydrogen and larger species such as argon and cyclohexane.

13 complexes that can preferentially halogenate cyclohexane.

14 ethane, and halobenzene solvents relative to cyclohexane.

15 form VB is slower than spin equilibration in cyclohexane.

16 ime of 1BpCMe is the same in cyclohexene and cyclohexane.

17 cycle with two substrates, benzphetamine and cyclohexane.

18 imes of 1BpCMe and 1BpCMe-d3 are the same in cyclohexane.

19 me of 1BpCH is shortened relative to that in cyclohexane.

20 ter correction for the one-half of the SE of cyclohexane.

21 in nonaromatic hydrocarbon solvents such as cyclohexane.

22 f 1 and 6 showed that they were monomeric in cyclohexane.

23 and examined all-cis 1,2,3,4,5,6-hexafluoro-cyclohexane.

24 onsted acid sites and the formation rate for cyclohexane.

25 tionalization selectivity of monosubstituted cyclohexanes.

26 ene derivatives to the corresponding all-cis-cyclohexanes.

27 etracyclic structure composed of fused chair cyclohexanes.

28 y are higher than expected for "strain-free" cyclohexanes.

29 ricted surrogates of trans-1,3-disubstituted cyclohexanes.

30 -1) s(-1)), water (4.0 x 10(6) M(-1) s(-1)), cyclohexane (1.8 x 10(5) M(-1) s(-1)), and several repre

31 R,2S,3R,4S,5S,6R)-5-(nonylamino)-6-(nonyloxy)cyclohexane-1,2,3,4-tetraol had a K(i) of 1 nM using iso

32 selective mono-N-pyridylation of trans-(R,R)-cyclohexane-1,2-diamine is described here.

33 Oligoureas (up to n=6) of meso cyclohexane-1,2-diamine were synthesized by chain extens

34 trans-Cyclohexane-1,2-diamine-a common component of chiral sal

35 The cyclohexane-1,2-diamine-based bisbinaphthyl macrocycles

36 use of copper(I) iodide (5 mol %) and trans-cyclohexane-1,2-diol as ligand under basic conditions an

37 In vivo labelling with 4-(3-azidopropyl)cyclohexane-1,3-dione (DAz-2) shows that Cys420 also for

38 lation of easily accessible 2-(2-bromobenzyl)cyclohexane-1,3-diones to provide the corresponding 2,3,

39 -Wittig reaction of 2-alkyl-2-(3-azidopropyl)cyclohexane-1,3-diones, delivering the highest ee's yet

40 ), 4, [Re(O)(NAr)(saldach)+] (saldach = N,N'-cyclohexane-1,3-diylbis(salicylideneimine)), 5, and [Re(

41 ermine whether they undergo cyclization to a cyclohexane-1,4-diyl anion structure by examining chemic

42 ituation is reversed, and reaction through a cyclohexane-1,4-diyl is favored.

43 ne for sp(3) centers causes reaction via the cyclohexane-1,4-diyl.

44 oparticles, formulated from the polymer poly(cyclohexane-1,4-diylacetone dimethylene ketal) (PCADK),

45 ys(X)-OH, where MCC is 4-(N-maleimidomethyl)-cyclohexane-1-carbonyl and X is 1-((4-thiocarbonylamino)

46 ) by using succinimidyl-4-(N-maleimidomethyl)cyclohexane-1-carboxylate (SMCC) as a linker.

47 linker, N-succinimidyl-4-(N-maleimidomethyl)cyclohexane-1-carboxylate (SMCC), and the resulting ADC,

48 lar linker N-succinimidyl-4-(maleimidomethyl)cyclohexane-1-carboxylate (SMCC).

49 ogenase genes during syntrophic benzoate and cyclohexane-1-carboxylate growth, one of which (fdhA2) w

50 All three inhibitors halted syntrophic cyclohexane-1-carboxylate metabolism.

51 cyclohexane derivative cis-2-(carboxymethyl)cyclohexane-1-carboxylic acid [(1R,2R)-/(1S,2S)-2-(carbo

52 ylic acid [(1R,2R)-/(1S,2S)-2-(carboxymethyl)cyclohexane-1-carboxylic acid] has previously been ident

53 ,N'-bis(3,5-di- tert-butylhydroxybenzyl)-1,2-cyclohexane-(1R,2R)-diamine) exists as a temperature-inv

54 N,N'-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexane-(1R,2R)-diamine) with a non-innocent salen l

55 )(3)N)U(IV)}(2)(mu-eta(2):eta(1)-1,2-(CH)(2)-cyclohexane)] (2) and [{(((Ad)ArO)(3)N)U(IV)}(2)(mu-eta(

56 ne 22a and 2.0 kcal/mol for the formation of cyclohexane 22b.

57 xy triene 42, and the heavily functionalized cyclohexane 48.

58 oxy-7-formyl-4-methoxyspiro[benzofuran-2(3H)-cyclohexane] (5k)was found to be the most potent target

59 ied analogue 4-methoxyspiro[benzofuran-2(3H)-cyclohexane]-6-carboxylic acid (5a) exhibited an IC(50)

60 s strong as 100 kcal mol(-1) and reacts with cyclohexane a hundred- to a thousand-fold faster than mo

61 In cyclohexane, a (C5Me5)2Y(mu-eta(8):eta(1)-C8H7)Y(C5Me5)

62 ution of Grubbs first-generation catalyst in cyclohexane, a nonsolvent for PLA.

63 phologies were observed after treatment with cyclohexane, a selective solvent for PS, contact angle a

64 Cyclohexane adlayers form crystal-like faceted islands a

65 selectivities arise from differences in the cyclohexane adsorption enthalpies of these frameworks, w

66 Bu and (Ph(Me)2CO)2 at 100 degrees C without cyclohexane afforded N-methylphthalimide (Me-phth) from

67 onformationally restricted cis- or trans-1,4-cyclohexane alpha to the urea were prepared and tested a

68 In contrast, the cyclohexane analogue 2b treated with MeLi underwent a sm

69 dergo rearrangement by 4.0 kcal/mol than the cyclohexane analogues.

70 ingly, treatment of 1 with cyclohexene gives cyclohexane and 4 via a titanium-mediated transfer hydro

71 innamyloxy silanes has been examined in both cyclohexane and acetonitrile solvents.

72 lites produced C6-cyclic hydrocarbons (i.e., cyclohexane and benzene) most dominantly.

73 y to C6-cyclic products (62.4% and 28.6% for cyclohexane and benzene, respectively) without acyclic i

74 rrelated with the selectivity change between cyclohexane and benzene.

75 ar ratios <or=1:1, the rate of metabolism of cyclohexane and benzphetamine is enhanced, whereas at hi

76 owever, when the reactions were performed in cyclohexane and cyclohexene, isomerization of 3 was favo

77 ring structures are most likely dominated by cyclohexane and cyclopentane rings and not larger cycloa

78 ium kinetic isotope effect from reactions of cyclohexane and d12-cyclohexane in separate vessels show

79 Separate reactions of cyclohexane and d12-cyclohexane with benzamide showed th

80 bicyclic fragment 22 consisting of the fused cyclohexane and dihydropyran rings was constructed via t

81 rapidly (t(1/2) approximately 0.2 h) to form cyclohexane and fluoride (F(-)) as the stable end produc

82 lifetime of 1BpCMe and 1BpCH are the same in cyclohexane and in cyclohexane-d12.

83 on reaction efficiencies for two substrates, cyclohexane and isopropyl alcohol, were measured for 23

84 Cyclohexane and methylcyclohexane can be also dehydrogen

85 chains) in nonpolar organic liquids such as cyclohexane and n-decane.

86 esicles in nonpolar organic liquids, such as cyclohexane and n-hexane.

87 er displayed superior affinity compared to a cyclohexane and phenyl linker.

88 ompany the placement of axial fluorines on a cyclohexane and the unusual property of a facially polar

89 5 orders of magnitude in nonpolar solvents, cyclohexane and toluene, resulting in a radical ion-pair

90 lectivities of C-H oxidations of substituted cyclohexanes and trans-decalins by dimethyldioxirane (DM

91 clopentane (MCP) to acyclic isomer, olefins, cyclohexane, and benzene.

92 econd pulses of UV light in acetonitrile, in cyclohexane, and in methanol.

93 imes of less than 300 fs in acetonitrile, in cyclohexane, and in methanol.

94 state of the diazo compound in acetonitrile, cyclohexane, and methanol with lambdamax = 490 nm and li

95 rmodynamics of the encapsulation of benzene, cyclohexane, and norbornadiene are compared.

96 redicted similar lifetimes for cyclopentane, cyclohexane, and, to a lesser extent, cycloheptane, sugg

97 cyclopropanes, cyclobutanes, cyclopentanes, cyclohexanes, and cycloheptanes, can thus be borylated.

98 energies for cyclopropane, cyclobutane, and cyclohexane are 3 to 4 kcal mol-1 too small and their pi

99 he heights of the second adlayers of THF and cyclohexane are measured to be 0.44 +/- 0.02 and 0.50 +/

100 ither 1-phth nor 1-phth2 reacted with excess cyclohexane at 100 degrees C without tBuOOtBu.

101 onium salt of neopentyl phosphate enters wet cyclohexane at concentrations sufficient to allow determ

102 The trithiane- and cyclohexane-based CBIs appear to be poor structural mimi

103 rium impacting the complex formation for the cyclohexane-based ligands is not significant.

104 which three thiourea groups are mounted on a cyclohexane-based scaffold.

105 s, including THF (BDE = 92 kcal mol(-1)) and cyclohexane (BDE = 99 kcal mol(-1)).

106 triplet ground state (3Fl) in acetonitrile, cyclohexane, benzene, and hexafluorobenzene.

107 pon irradiation of 2-diazoacenaphthenones in cyclohexane, benzene, and tetrahydrofuran.

108 iciencies of >95% were observed for propane, cyclohexane, benzene, isoprene, aerosol particle mass, a

109 ology for the synthesis of 4,4-disubstituted cyclohexane beta-keto esters from benzylic nitriles or e

110 tion of beta-1,2-dibromo-4-(1,2-dibromoethyl)cyclohexane (beta-TBECH).

111 O) and beta-1,2-dibromo-4-(1.2-dibromoethyl)-cyclohexane (beta-TBECH).

112 singlet-triplet gap that is close to zero in cyclohexane, but the triplet is the ground state.

113 ging of the dissolution process of urea in a cyclohexane/butanol solution with nanometer topographica

114 The oxidation of cyclohexane by 2 occurs at a rate comparable to that of

115 he catalytic reaction is the C-H cleavage of cyclohexane by a tert-butoxy radical.

116 nitrile ylide (lambdamax = 370 nm), and with cyclohexane by C-H insertion 1-20 ns after the laser pul

117 reaction barriers for H-atom abstraction of cyclohexane by the ground state of 7-coordinate CNTs and

118 ange of geminal C H bonds of the methane and cyclohexane C H sigma adducts, is observed before loss o

119 f ring strain energies (RSEs) of substituted cyclohexanes c-C6H(x)R(12-x) (R = F, Cl, Me; x = 0, 2, 4

120 c dehydrogenation reactions of high-pressure cyclohexane (C(6)H(12)) on the Pt(111) crystal surface i

121 Derivative 5-bromo-3'-(cyclohexane carbonyl)-1-methyl-2-oxospiro[indoline-3,2'-

122 tion of RLi/TMEDA to the N-isopropylimine of cyclohexane carboxaldehyde and the RLi/TMEDA-mediated al

123 xyphenyl) piperazin-1-yl]ethyl-N-(2-pyridyl) cyclohexane carboxamide ((18)F-FCWAY) PET and CMRglc mea

124 h R-(+)-trans-N-(4-pyridyl)-4-(1-aminoethyl)-cyclohexane carboxamide (Y27632) can markedly reduce the

125 phenyl)-1-piperazinyl)ethyl)-N-(2-pyridinyl) cyclohexane carboxamide] [WAY100635] 0.5 mg/kg, intraven

126 IAB) and 1-biotinamido-4-(4'-[maleimidoethyl-cyclohexane]-carboxamido)butane (BMCC).

127 key steps involved in benzoate breakdown and cyclohexane carboxylate formation are unclear.

128 ydro-furan-2-yl)-9H-purin-2-yl]-prop-2-ynyl]-cyclohexane carboxylic acid methyl ester (ATL146e; 0.05-

129 s a reactive surface intermediate during the cyclohexane catalytic conversion to benzene at high pres

130 of cyclohexyl is a rate-limiting step in the cyclohexane catalytic conversion to benzene.

131 y diffraction reveals some distortion of the cyclohexane chair conformation in the solid state.

132 Crude 4-MCHM is comprised of several major cyclohexane components, four of which have distinct isom

133 the water molecules surrounding benzene and cyclohexane computed previously from molecular dynamics

134 t with100-fold (k = 0.15 +/- 0.05 s(-1)) and cyclohexane congruent with10-fold (k = 2.5 +/- 0.35 s(-1

135 uinoline (compound 3) rings around a central cyclohexane core for use in molecular recognition of mon

136 incorporating a cis,cis-1,3,5-trisubstituted cyclohexane core.

137 th model linear (propane, n-PrH) and cyclic (cyclohexane, CyH) alkanes may proceed via classical Ir(V

138 nt to cleave C-H bonds as strong as those in cyclohexane (D(C-H) = 99.3 kcal mol(-1)).

139 ysis of (eta(5)-Me(5)C(5))(2)LaCH(TMS)(2) in cyclohexane-d(12) at 120 degrees C rapidly releases CH(2

140 -5-norbornenyl-2-oxychlorocarbene [(S)-8] in cyclohexane-d(12) gives approximately 20% (S)-endo-2-chl

141 in hydrocarbon solvents such as pentane and cyclohexane-d(12).

142 )D(6) > mesitylene-d(12) > n-decane-d(22) >> cyclohexane-d(12).

143 and 1BpCH are the same in cyclohexane and in cyclohexane-d12.

144 tes benzene or benzene-d6 and dehydrogenates cyclohexane-d12.

145 ix different amine scaffolds: linear acenes, cyclohexane, decalin, triptycene, adamantane, and [2.2]p

146 10 mol %, the SFG signals for 1-hexanol and cyclohexane decrease with increasing concentration of 1-

147 a completely unactivated C(sp(3))-H bond of cyclohexane demonstrate the broad implications of this m

148 character of carbene 22a as compared to the cyclohexane derivative 22b.

149 The cyclohexane derivative cis-2-(carboxymethyl)cyclohexane-

150 ketones affords functionalized 3,5-dihydroxy cyclohexane derivatives as the kinetically controlled pr

151 cyclopropane affords either cyclopentane or cyclohexane derivatives in which the C6F5 and B(C6F5)2 a

152 ical shifts in chair conformationally locked cyclohexane derivatives readily secured from a mixture o

153 .2 kcal/mol for dioxane and 6.4 kcal/mol for cyclohexane derivatives than for the formation of the bi

154 stricted surrogates of cis-1,4-disubstituted cyclohexane derivatives.

155 goethylene functionalized benzaldehyde and a cyclohexane-derived trishydrazide--in the presence of ac

156 In cyclohexane, DHNA shows the lowest lying S0 -->S1 (pi-pi

157 e (1,2,3-propanetricarboxylate), or CDA (1,1-cyclohexane diacetate) at pH values between 7 and 8 yiel

158 from triphenyl amine-based trialdehydes and cyclohexane diamine building blocks utilizing the dynami

159 ates of pentetic acid (Fe-DTPA) and of trans-cyclohexane diamine tetraacetic acid (Fe-tCDTA) were syn

160 In 2002, the plasticizer 1,2-cyclohexane dicarboxylic acid diisononyl ester (DINCH) w

161 Crotepoxide (a substituted cyclohexane diepoxide), isolated from Kaempferia pulchra

162 2008, 47, 7321) with cyclohexane, dihydroanthracene (DHA), and xanthene (Xan)

163 id side-chain as represented by its water-to-cyclohexane distribution coefficient, and this relations

164 h side-chain, as represented by its vapor-to-cyclohexane distribution coefficient.

165 reaction mechanism is stepwise, involving a cyclohexane diyl intermediate.

166 r activation barrier for ring inversion than cyclohexane due to BN/CC isosterism.

167 t appears to be the reductive elimination of cyclohexane during the hydrogenation process.

168 e opening of hydroxyl protected forms of the cyclohexane epoxides cyclophellitol and 1,6-epi-cyclophe

169 lar to that afforded by the nonpolar solvent cyclohexane (epsilon = 2).

170 onstants (e.g., benzene, epsilon of 2.27, or cyclohexane, epsilon of 2.02) as studied via emulsion dr

171 pesticides were extracted from the sample by cyclohexane-ethyl acetate mixture (1:1 v/v) and cleaned

172 rogenated by transient A, and in the case of cyclohexane, ethylene (1 atm) can trap the [(PNP)Ti(CH2(

173 ericyclic transition state is reported for a cyclohexane featuring opposing methylene and a vinyliden

174 s the first reported parental BN isostere of cyclohexane featuring two BN units, is thermally stable

175 and TL205 (a mixture of mesogens containing cyclohexane-fluorinated biphenyls and fluorinated terphe

176 placement of the aromatic ring of Phe1579 by cyclohexane, for example, strongly reduces use-dependent

177 ively smaller B/L ratio is effective for the cyclohexane formation, whereas more Bronsted acidic zeol

178 Synthetic access to the fully charged BN cyclohexane fuels will now enable investigations of thes

179 ation of 2 with sec-butyllithium (s-BuLi) in cyclohexane gave poly-2 in quantitative yield, with a na

180 ric HIV-1 protease inhibitors that contain a cyclohexane group at P1 and/or P1'.

181 We also demonstrate that 1,2-BN cyclohexane has a lower activation barrier for ring inve

182 The SE of cyclohexane has been estimated to be 2.2 kcal/mol at the

183 tereodivergent synthesis of tetrasubstituted cyclohexanes has been achieved using modularly designed

184 cal shift perturbations in deuterium-labeled cyclohexanes have been identified and quantified.

185 For deuterium-labeled cyclohexanes held in a chair conformation at -80 degrees

186 covered oxidative esterification reaction of cyclohexane hexacarboxylic acid with phosphorus pentachl

187 l CO 520 (nonionic head group) in 50/50 wt % cyclohexane/hexane are prepared to have the same diamete

188 materials for the preparation of substituted cyclohexanes; however, the synthetic tools available for

189 (BpCCF3) which absorbs strongly at 385 nm in cyclohexane, immediately after the 300 fs laser pulse.

190 yridine in water as well as acetonitrile and cyclohexane in 1,2-dichloroethane (DCE).

191 Mixtures of 40% benzene or 40% cyclohexane in 50% isopropanol and 10% water showed no b

192 2 undergo selective ionic hydrogenation with cyclohexane in CF3SO3H-SbF5, HBr-AlBr3-CH2Br2, or HCl-Al

193 HCN products of reaction of CN radicals with cyclohexane in chlorinated organic solvents exhibit pref

194 ccommodating guests such as cyclopentane and cyclohexane in its internal cavity (red).

195 effect from reactions of cyclohexane and d12-cyclohexane in separate vessels showed that the turnover

196 underwent selective ionic hydrogenation with cyclohexane in the presence of aluminum chloride.

197 rbene BpCCOCH3 has a singlet ground state in cyclohexane, in dichloromethane, and in acetonitrile and

198 roperties of these molecules in deoxygenated cyclohexane, including their absorption spectra, steady-

199 on subnanometre length scales across a water-cyclohexane interface.

200 1,2-BN cyclohexane is an air- and water-stable compound that cl

201 at the turnover-limiting step for the ODC of cyclohexane is C-H bond cleavage.

202 f 1-hexanol, consistent with the notion that cyclohexane is excluded from the interfacial region whil

203 f their side-chains from neutral solution to cyclohexane (K(w > c)).

204 for the stereoselective construction of the cyclohexane-lactone C,D-rings.

205 These data on the ODC of cyclohexane led to preliminary investigation of copper-c

206 ction structure reveals that 1 0 has a chair-cyclohexane-like core and a [6]radialene structure.

207 e that the transfer energetics of alkanes to cyclohexane measure the release of these shells.

208 flat to most likely tilted, suggesting that cyclohexane mediates the adsorption of 1-hexanol via int

209 2 Despite the high relative concentration of cyclohexane, minimal quantities of borylated cyclohexane

210 nol and 10% water showed no bound benzene or cyclohexane molecules, but did reveal bound isopropanol.

211 performed well with acids, bases, alcohols, cyclohexane, n-heptane, and toluene but not with chlorin

212 rphyrin) were trapped in a mixed benzene (or cyclohexane) oil-in-water emulsion using an ionic liquid

213 y thin adlayers of tetrahydrofuran (THF) and cyclohexane on atomically flat mica substrates, thus per

214 ial beta-C-Y bonds in oxa-, thia- and selena-cyclohexanes, only the homoanomeric n(X)(ax) --> sigma(C

215 nt is close to Theta-conditions, e.g., PS in cyclohexane or PPO/PEO in water.

216 01 [(S)-1] by phenyl, or by ortho,meta-fused cyclohexane, or especially by ortho,meta-fused benzene p

217 ted toward 2 in the highly nonpolar solvent, cyclohexane, or toward 3 in the more polar solvents.

218 Mixtures of 1-hexanol in cyclohexane over the (0001) alpha-Al(2)O(3) surface were

219 methoxy- and 4-hydroxyspiro[benzofuran-2(3H)-cyclohexane] partial analogues (5) of the complement inh

220 water were sources of hydrogen in the final cyclohexane product.

221 cyclohexane, minimal quantities of borylated cyclohexane products are observed.

222 rovides beta-lactone-fused cyclopentanes and cyclohexanes readied for further transformations.

223 /mol in water, dichloromethane, benzene, and cyclohexane, respectively, and (b) significantly reduce

224 etimes are 200 and 77 ps in acetonitrile and cyclohexane, respectively, and are controlled by intersy

225 ith hydrocarbons R-H (R-H = ethylbenzene and cyclohexane) reveals inefficient stoichiometric C-H amin

226 ound to be consistent with a model where the cyclohexane ring adopts a distorted twist-boat conformat

227 ne atoms at the 3, 4, and 5-positions of the cyclohexane ring and calculations suggest that these sta

228 cocrystal structure with gp120 revealed the cyclohexane ring buried within the gp120 hydrophobic cor

229 on reactions until full aromatization of the cyclohexane ring is achieved.

230 ostulate that the constraints imposed by the cyclohexane ring of OX affect the DNA conformations expl

231 ive study of the conformational landscape of cyclohexane ring of TFC and DFCs revealed that TFC is a

232 e-dependent dioxygenase that closes the core cyclohexane ring of the aryltetralin scaffold.

233 According to the model, the central cyclohexane ring of the linker connecting the two NDI un

234 s did not affect membrane leakage, whereas a cyclohexane ring reduced leakage by an additional 40 %.

235 cture-activity relationship (SAR) within the cyclohexane ring showed the cis-isomers to be more poten

236 was simplified even further by replacing the cyclohexane ring with an isobutyl group attached either

237 y could be replaced by a simpler, less rigid cyclohexane ring without compromising the S1P receptor a

238 equatorial disposition of the proton on the cyclohexane ring, (b) syn versus anti orientation of the

239 mino-4-hydroxybenzoic acid core component, a cyclohexane ring, two triene polyketide chains, and a 2-

240 ts because of the constraints imposed by its cyclohexane ring, which may explain the negligible bindi

241 n in these helical foldamers is coupled with cyclohexane ring-flipping, and results in a reversal of

242 moiety, O-demethylation, hydroxylation, and cyclohexane ring-opening were identified as major reacti

243 e ortho versus para position on the pyrylium cyclohexane ring.

244 gle conformation by the adjacent trans-fused cyclohexane ring.

245 Although carboxylic acid groups in cyclohexane rings are generally believed to be far more

246 In cyclohexane rings with alpha-substituents the net effect

247 s are more favored for cyclopentane than for cyclohexane rings.

248 preferences of the pyrrolidine and the fused cyclohexane rings.

249 ete single bond (in DMSO) or double bond (in cyclohexane) rotation can be induced by visible light.

250 similarity between the spiro[3.3]heptane and cyclohexane scaffolds.

251 orientation preference, whereas those around cyclohexane show a weaker tendency.

252 mechanism of oxygenated organic species from cyclohexane solution at the liquid/solid interface of op

253 In methyl cyclohexane solution, the same polymer exhibits an inten

254 nd in aqueous, dichloromethane, benzene, and cyclohexane solutions using B3LYP/6-311+G(d,p)//B3LYP/6-

255 f methane with bis-pinacolborane (B2pin2) in cyclohexane solvent at 150 degrees C under 2800 to 3500

256 1-hexanol is an orientational change of the cyclohexane solvent from flat to most likely tilted, sug

257 CCSD(T)/cc-pVTZ//B3LYP/6-311+G(3df,2p)+ZPE), cyclohexane solvent-field relative energies (IPCM-MP2/6-

258 ation of methane using bis(pinacolborane) in cyclohexane solvent.

259 a diverse series of carbamates at C6 of the cyclohexane spiroepoxide.

260 The structure and stereochemistry of the cyclohexane substituents of analogues of arterolane (OZ2

261 ed by UV light in acetonitrile, benzene, and cyclohexane (Tables 1-4).

262 l mixture of 1,2-dibromo-4-(1,2-dibromoethyl)cyclohexane (TBECH or DBE-DBCH) and the pure beta-TBECH

263 ound EFR was 1,2-dibromo-4-(1,2 dibromoethyl)cyclohexane (TBECH or DBE-DBCH), which was found in near

264 cane (HBCD), 1,2-dibromo-4-(1,2-dibromoethyl)cyclohexane (TBECH), and hexachlorocyclopentadienyl dibr

265 ha- and beta-1,2-dibromo-4-(1,2-dibromoethyl)cyclohexane (TBECH), beta-1,2,5,6-tetrabromocyclooctane

266 s (i.e., CO2, O2, NO2, NO, SO2, H2O, H2, and cyclohexane, tested at the same concentration as SO2).

267 The rate of WR of BpCCOCH3 is faster in cyclohexane than in dichloromethane and acetonitrile bec

268 ted structure containing a penta-substituted cyclohexane that is generated by oxidative cleavage of t

269 c cores (triazenes, pyrimidines, trithianes, cyclohexanes) that mimic the tether sites of the three l

270 ields in solution and in the solid state: in cyclohexane the value are 14 and 36%, but in the thin fi

271 is and characterization of the parent 1,2-BN cyclohexane, the BN-isostere of cyclohexane.

272 For cyclohexane, the deuterium kinetic isotope effect (k(H)/

273 3-Sc can initiate tosylamination of cyclohexane, thereby suggesting Cu(II)N(*)Ts cores as vi

274 lycol) diacrylate (PEGDA) hydrogel sample in cyclohexane to create two-dimensional images with high c

275 in the lifetimes of the sigma-complexes from cyclohexane to cycloheptane was predicted to be due to t

276 Here, the oxidation of cyclohexane to cyclohexanol and cyclohexanone is used as

277 tic performance achieved in the oxidation of cyclohexane to cyclohexanone/cyclohexanol (100 degrees C

278 e 2b reacts with the unactivated CH bonds of cyclohexane to form adduct 8b in 46% yield.

279 lyzed oxidative dehydrogenative amination of cyclohexane to generate a mixture of N-alkyl and N-allyl

280 city, spanning an overall range from 363 nm (cyclohexane) to 595 nm (acetonitrile).

281 ion energies ranging from 99.3 kcal mol(-1) (cyclohexane) to 84.5 kcal mol(-1) (cumene).

282 ications and demonstrates the possibility of cyclohexane-to-benzene conversions under relatively mild

283 e) in solvents of widely varying polarities: cyclohexane, toluene, 1,2-dichloroethane, ethyl acetate,

284 hobicity, but when free energies of vapor-to-cyclohexane transfer (corresponding to size) are taken i

285 with DBU, followed by hydrogenation, gave a cyclohexane triflate, which, on fluorination, gave the a

286 ) model complexes produces 6-membered FeS2C3 cyclohexane-type rings that produce substantial distorti

287 nd 97.5% selective for hydrodeoxygenation to cyclohexane under mild conditions in a batch reaction; t

288 and tetramethylethylene in water, DMSO, and cyclohexane using novel 3-dimensional potentials of mean

289 1-(Chloromethylidene)-4-tert-butyl-cyclohexane was also coupled with thiols, giving the tar

290 duct selectivity than their constituents; no cyclohexane was produced, while benzene was the dominant

291 nsistent with product studies (ethanol-OD in cyclohexane) which indicate that there is an approximate

292 eacts with solvents such as acetonitrile and cyclohexane, while t-butyloxycarbonylnitrene undergoes a

293 served for the C-H bonds of cyclopentane and cyclohexane, while the tertiary C-H bond of methylcyclop

294 essed in the catalytic C-H etherification of cyclohexane with (t)BuOO(t)Bu at rt employing [Cu(I)] (5

295 This generates a cyclohexane with a high molecular dipole (mu = 6.2 D), u

296 l was evidenced by the catalytic reaction of cyclohexane with benzamide in the presence of CBr4, whic

297 Separate reactions of cyclohexane and d12-cyclohexane with benzamide showed that the turnover-limi

298 idation of the substrates, benzphetamine and cyclohexane, with rate constants of 18 +/- 2 and 29 +/-

299 s catalytic activity toward the oxidation of cyclohexane, with turn-over numbers, to the best of our

300 ination of a variety of hydrocarbons such as cyclohexane without the need of prefunctionalization or