ライフサイエンスコーパス: cyclopropylamine

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1 for SET mechanisms in the P450 oxidation of cyclopropylamines.

2 gen abstraction at the N-H bond of secondary cyclopropylamines 1 gives a neutral aminyl radical which

3 The suicide substrate activity of N-benzyl-N-cyclopropylamine (1) and N-benzyl-N-(1'-methylcyclopropy

4 nism in the P450-catalyzed N-dealkylation of cyclopropylamines 2a and 2b, and argue strongly for the

5 ld, along with cyclopropanone hydrate (34%), cyclopropylamine (9%), benzaldehyde (6%), benzyl alcohol

6 n was attributable to high reactivity of the cyclopropylamine and azido moieties, respectively.

7 e scaffolds to include the chlorovinyl, endo-cyclopropylamine, and hydrazine-functionalities as LSD1

8 ate salts, boronic acids, cyclopropylarenes, cyclopropylamines, and cyclopropanols.

9 will provide a foundation for the design of cyclopropylamine-based inhibitors that are selective for

10 bitory scaffolds such as propargylamines and cyclopropylamines can serve as mechanism-based inactivat

11 s the discovery and biological activity of a cyclopropylamine containing inhibitor of Lysine Demethyl

12 studies should facilitate the application of cyclopropylamine-containing probes to reactions catalyze

13 racemic ring-substituted trans-2-(indol-3-yl)cyclopropylamine derivatives was synthesized and tested

14 hemically defined and densely functionalized cyclopropylamine derivatives.

15 Unlike aziridinyl and cyclopropylamine-derivatized histone H3 peptide substrat

16 The Ti(II) -mediated formation of cyclopropylamines from alkenes and amides, the Kulinkovi

17 e traps, N4-cyclopropylcytosine (CPC) and N2-cyclopropylamine-guanosine (CPG), incorporated in DNA du

18 echanism-based LSD1 inactivator whereas endo-cyclopropylamine-H3 does not show time-dependent inactiv

19 philic amines to yield highly valuable trans-cyclopropylamines in good yields and high diastereoselec

20 Cyclopropylamines inactivate cytochrome P450 enzymes whi

21 In contrast, the small molecule MAO cyclopropylamine inhibitor tranylcypromine is a time-dep

22 The cyclopropylamine moiety therefore appears to be a good s

23 e is a time-dependent LSD1 inhibitor but exo-cyclopropylamine-peptide substrate analogue is not.

24 Cyclopropylamine substituted bases, N4-cyclopropylcytosi

25 Because the cyclopropylamine-substituted bases decompose rapidly upo

26 In a de Meijere cyclopropylamine synthesis, a 3:1 mixture of N,N-dimethy

27 e minimum onset energy of photoionization of cyclopropylamine was calculated to be 201.5 kcal/mol (CC

28 signature metabolite" for SET oxidation of a cyclopropylamine, was observed for the first time in 57%

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