ライフサイエンスコーパス: decarboxylation

1 adducts, demethylation, dehydrogenation, and decarboxylation).

2 bstrate hydrogen atom to initiate fatty acid decarboxylation.

3 acetyl-CoA is commonly generated by pyruvate decarboxylation.

4 ups, we propose an inner-sphere mechanism of decarboxylation.

5 s hydroxylation of fatty acids as opposed to decarboxylation.

6 to the free energy of activation for direct decarboxylation.

7 ganometallic complex, [(phen)M(CH3)](+), via decarboxylation.

8 transfer from the triplet state followed by decarboxylation.

9 transition state for the phosphite-activated decarboxylation.

10 the rate of biotin-independent oxaloacetate decarboxylation.

11 activity from decarboxylation-deamination to decarboxylation.

12 zymatic reactions such as transamination and decarboxylation.

13 ligation, carbon-skeleton rearrangement and decarboxylation.

14 that exhibits a high catalytic activity for decarboxylation.

15 o reactive iron-oxo species during substrate decarboxylation.

16 urther supporting a slowed rate of oxidative decarboxylation.

17 through Tet-catalyzed oxidation followed by decarboxylation.

18 by antibiotics, Lys-392 experiences N(zeta)-decarboxylation.

19 xylation, consistent with impaired oxidative decarboxylation.

20 hich serves to activate the substrate toward decarboxylation.

21 addition mechanism that underpins reversible decarboxylation.

22 ubstrates proceed through silver(I)-assisted decarboxylation.

23 involving ring fission, dehydroxylation and decarboxylation.

24 activates the biosynthetic intermediate for decarboxylation.

25 olylquinolines via [4 + 2] HDA and oxidative decarboxylation.

26 iety at the 3-OH position and (2) subsequent decarboxylation.

27 oth phenylacetate and p-hydroxyphenylacetate decarboxylation.

28 ion step, yet retains its ability to perform decarboxylation.

29 edure and current transition-metal-catalyzed decarboxylations.

30 ify residues responsible for differentiating decarboxylation AAADs from aldehyde synthase AAADs.

31 butyrate oxidation; faster leucine oxidative decarboxylation; accelerated glutamine conversion to glu

32 neering to improve catalysis or to introduce decarboxylation activity into P450s with different subst

33 B originates from a previously undetected 10-decarboxylation activity of DnrK.

34 mino acid decarboxylases changes the enzymes decarboxylation activity to a primarily decarboxylation-

35 n isochelidonic acid and indoles followed by decarboxylation afforded biologically important (E)-6-in

36 e, whose corresponding acid that is prone to decarboxylation, allowed for the synthesis of 5-bromo-1H

37 followed by a late-stage palladium-catalyzed decarboxylation-allylation procedure.

38 re characterized by a lower O/C ratio due to decarboxylation and a higher content of C=C bonds.

39 no acids they undergo Schiff base formation, decarboxylation and alpha-aminoketone condensation leadi

40 water molecule is essential to maintain the decarboxylation and aromatization activities and avoid r

41 These mutants were also defective in ICT decarboxylation and converted alphaKG to 2-hydroxyglutar

42 eviously proposed pathway involving separate decarboxylation and deamination enzymatic steps from tyr

43 Product release proceeds through decarboxylation and dehydration independent of the thioe

44 substrates undergo a palladium(II)-catalyzed decarboxylation and electron-deficient substrates procee

45 spholipids caused a shift of pyruvate toward decarboxylation and energy production away from the carb

46 nthesis have been reinvestigated, the Barton decarboxylation and Giese radical conjugate addition.

47 r a synergistic effect between the histidine decarboxylation and glycolytic pathways in acid stress s

48 allyl esters, in combination with subsequent decarboxylation and oxidative cleavage of the double bon

49 proteins are responsible for the subsequent decarboxylation and PEP regeneration steps has been elus

50 c oxindole derivative, isamic acid 1, led to decarboxylation and ring expansion to quinazolino[4,5-b]

51 he carbon-carbon bond formation precedes the decarboxylation and the reaction occurs in an outer-sphe

52 as a hydrogen atom donor in Barton reductive decarboxylations and to determine the scope of this proc

53 lyze the ring closure (i.e. condensation and decarboxylation) and dehydration steps, respectively.

54 o intermediates in a series of condensation, decarboxylation, and dehydration steps.

55 priming Fe(II) to react with O(2), oxidative decarboxylation, and substrate positioning.

56 droxy-acyl-ACP is followed by TE hydrolysis, decarboxylation, and sulfate elimination.

57 for investigating the catalytic mechanism of decarboxylation are complicated by the difficulty of ass

58 Two different conditions for decarboxylation are discussed for substrates with neutra

59 lase (OMPDC) with enhanced reactivity toward decarboxylation are reported: 1-(beta-d-erythrofuranosyl

60 ring cleavage, loss of carbamoyl group, and decarboxylation, as well as O-methylation.

61 Notably, the decarboxylation-assisted release of the catalyst enables

62 carboxylate group but also by its oxidative decarboxylation at the underlying poly(3-octylthiophene)

63 es significant contributions to lowering the decarboxylation barrier, while the enzyme active site pr

64 Decarboxylation by a convenient two-step protocol provid

65 endocrine tumors is mainly attributed to its decarboxylation by aromatic amino acid decarboxylase (AA

66 while addition of D-GAP enhanced the rate of decarboxylation by at least 600-fold.

67 he transport of this lipid to endosomes, and decarboxylation by PtdSer decarboxylase 2 (Psd2p) to pro

68 and ligand-free carbonylation/cycloaddition/decarboxylation cascade synthesis of sulfonyl amidines f

69 s in the presence of silver carbonate as the decarboxylation catalyst and copper acetate as the cross

70 The conserved Glu212 underwent decarboxylation concomitantly with an extensive rearrang

71 ymes decarboxylation activity to a primarily decarboxylation-deamination activity.

72 able of catalyzing either decarboxylation or decarboxylation-deamination on various combinations of a

73 primarily converts the enzymes activity from decarboxylation-deamination to decarboxylation.

74 ted group of examples is presented including decarboxylation, dehalogenation, nucleophilic addition,

75 tion appears to proceed via an unprecedented decarboxylation-dehydrogenation-monooxygenation cascade.

76 However, pyruvate decarboxylation during acetyl-CoA formation limits the t

77 mic acid during wort boiling or by enzymatic decarboxylation during fermentation.

78 on (Pmax ), but transcripts for archetypical decarboxylation enzymes phosphoenolpyruvate carboxykinas

79 ux of pyruvate to lactate, elevated pyruvate decarboxylation, ethanol accumulation, diminished pyruva

80 This remarkable transformation involves decarboxylation followed by an oxidation reaction enable

81 rate-limiting step from the chemical step of decarboxylation for the phosphite-activated reaction of

82 at the decomposition process is a reversible decarboxylation forming the corresponding N-heterocyclic

83 sodium borohydride and subsequent hydrolysis decarboxylation generated the corresponding 3-propanoic

84 alternative pathway is also found where the decarboxylation happens concertedly with an aryl migrati

85 cteria, oxaloacetate is subject to enzymatic decarboxylation; however, oxaloacetate decarboxylases (O

86 hat phenylacetate and p-hydroxyphenylacetate decarboxylation in complex cell-free extracts were catal

87 t a ca. 20 kcal/mol change in the barrier to decarboxylation in going from the gas phase to (SMD-simu

88 cycloaddition chemistry supports reversible decarboxylation in these enzymes.

89 Agmatine (AGM), a product of arginine decarboxylation, influences multiple physiologic and met

90 (pK(a) suppression); (b) detection of a pre-decarboxylation intermediate analogue using [C2,C6'-(13)

91 A reaction mechanism for the reversible decarboxylation involving an intermediate with a single

92 This TclP-mediated oxidative decarboxylation is a required step for the peptide to pr

93 now demonstrate that in extreme acidophiles, decarboxylation is carried out by two separate steps: pr

94 ave relevance to other ThDP enzymes in which decarboxylation is coupled to a ligation reaction.

95 s decarboxylated in mitochondria and whether decarboxylation is coupled to trafficking of PS.

96 stance and the Gibbs free energy barrier for decarboxylation is demonstrated.

97 dentified that in the preferred pathway, the decarboxylation is followed by a direct proton transfer

98 osynthetic strategy to facilitate acyl chain decarboxylation is of potential value as a route to hydr

99 e event involves sequential imine formation, decarboxylation, isonitrile insertion, and hydrolysis to

100 etic 2-myristoylmyristic acid showed similar decarboxylation kinetics in the absence of OleA.

101 ation to form beta-hydroxy acids, which upon decarboxylation led to hemiketal FR901464.

102 r reactions (e.g., oxidation, demethylation, decarboxylation) led to the formation of extremely polar

103 ylative coupling or tandem C-H arylation and decarboxylation occurred, leading to the formation of C2

104 kcal/mol for activation of ScOMPDC-catalyzed decarboxylation of 1-beta-d-erythrofuranosyl)orotic acid

105 two partially rate-determining steps in the decarboxylation of 1: transfer of the second carboxyl pr

106 The rate of decarboxylation of 2,4-dimethoxybenzoic acid (1) is acce

107 The decarboxylation of 2,4-dimethoxybenzoic acid (1) is acce

108 dicates that the free energy requirement for decarboxylation of 2,6-dimethoxybenzoic acid and especia

109 ere hydroxylation is driven by the oxidative decarboxylation of 2-OG, forming succinate and CO(2).

110 e the mechanisms underlying ring-opening and decarboxylation of 2-pyrones, including the degree of ri

111 of the transition state for the unactivated decarboxylation of 2.9 kcal/mol.

112 f l-arginine (l-Arg) driven by the oxidative decarboxylation of 2OG to form succinate and CO2.

113 fficient hydrolase but instead catalyzes the decarboxylation of 3-keto acids.

114 boxylase activity and catalyzed in vitro the decarboxylation of 4-hydroxy-3-prenylbenzoate with diffe

115 A chemical reaction mechanism for the decarboxylation of 5-carboxyvanillate by LigW was propos

116 c activity and the kinetic constants for the decarboxylation of 5-carboxyvanillate by the enzymes fro

117 hosphate decarboxylase (OMPDC) catalyzes the decarboxylation of 5-fluoroorotate (FO) with kcat/Km = 1

118 te (13)CO(2) at isocitrate dehydrogenase, or decarboxylation of [1-(13)C]pyruvate by PDH.

119 multiple mechanisms, including cataplerotic decarboxylation of [4-(13)C]oxaloacetate via phosphoenol

120 y studies suggest that the LA assists in the decarboxylation of a key iron formate intermediate and c

121 Oxidative decarboxylation of a lysine fragment of the luciferin su

122 nd a hydrogen atom donor in Barton reductive decarboxylation of a range of carboxylic acids was recen

123 ecarboxylase that catalyzes proton-dependent decarboxylation of a substrate amino acid to product and

124 of the transition state for OMPDC-catalyzed decarboxylation of a truncated substrate analog by bound

125 rough oxidative ring cleavage and subsequent decarboxylation of acridine, a well-known phototransform

126 rmationally rigid amines and heterocycles by decarboxylation of adamantane-oxazolidine-2-one.

127 transformations typically coupling oxidative decarboxylation of alpha-KG with hydroxylation of a prim

128 rate UMP, LipL is able to catalyze oxidative decarboxylation of alpha-KG, although at a significantly

129 can inactivate a class D enzyme by promoting decarboxylation of an active site lysine suggests a nove

130 Although the decarboxylation of aqueous phase PA through UV excitatio

131 hanism studies of a mild palladium-catalyzed decarboxylation of aromatic carboxylic acids are describ

132 n implicated in the non-oxidative reversible decarboxylation of aromatic substrates, and play a pivot

133 AgF2 induces decarboxylation of aryloxydifluoroacetic acids, and AgF,

134 Our data showed that the decarboxylation of aspartate was the only source of beta

135 vity, but it is able to efficiently catalyze decarboxylation of aspartate, cysteine sulfinic acid, an

136 Isotope effects in the decarboxylation of benzoylacetic acid support a transiti

137 mplex (BCKDC), which catalyzes the oxidative decarboxylation of branched-chain alpha-keto acids, is e

138 mammalian C5-MTases can catalyze the direct decarboxylation of caC yielding unmodified cytosine in D

139 lation mechanism via deformylation of fdC or decarboxylation of cadC.

140 Direct photolysis led to decarboxylation of CFD, CFX, and CFP.

141 Styrene is formed by the thermal decarboxylation of cinnamic acid during wort boiling or

142 ormation can be explained via acid triggered decarboxylation of cinnamic acid esters and subsequent i

143 known as methylenesuccinic acid) through the decarboxylation of cis-aconitate, a tricarboxylic acid c

144 Crude cell extracts synthesize ITA via decarboxylation of cis-aconitate, indicative of a novel

145 as 7-heptadecene, an isomer likely formed by decarboxylation of cis-vaccenic acid.

146 drogenase superfamily catalyze the oxidative decarboxylation of D-malate-based substrates with variou

147 dibromomethane, which could be generated by decarboxylation of dibromoacetic acid during ionization,

148 lmalate dehydrogenase catalyze the oxidative decarboxylation of different beta-hydroxyacids in the le

149 nto a deprotonated green fluorescent form by decarboxylation of E218 or into a bleached form with a d

150 wn mevalonate pathways involve ATP dependent decarboxylation of either mevalonate 5-phosphate or meva

151 The acceleration of the rate of decarboxylation of enzyme-bound LThDP in the presence of

152 xide-driven oxidase that catalyzes oxidative decarboxylation of fatty acids, producing terminal alken

153 n III via ferrochelatase HemH, and oxidative decarboxylation of Fe-coproporphyrin III into protohaem

154 zymatic reactions proceed in parallel to the decarboxylation of ferulic- and p-cumaric acid to 4-viny

155 The transition state for OMPDC-catalyzed decarboxylation of FO is stabilized by 5.2, 7.2, and 9.0

156 least three catalytic cycles, involving the decarboxylation of formic acid, hydration of the alkyne,

157 Herein, we report the catalytic decarboxylation of gamma-valerolactone (GVL) over Zn/ZSM

158 Elucidation of the mechanism for decarboxylation of indolecarboxylic acids over a wide ra

159 at catalyzes the NADP(+)-dependent oxidative decarboxylation of isocitrate (ICT) to alpha-ketoglutara

160 IDH1/2 normally catalyse the oxidative decarboxylation of isocitrate into alpha-ketoglutarate (

161 nd carbon kinetic isotope effects (CKIE) for decarboxylation of isomeric sets of heterocyclic carboxy

162 mumol min(-1) mg(-1) at 70 degrees C for the decarboxylation of l-aspartate was measured for the reco

163 tic isotope effects (KIEs) in the amino acid decarboxylation of L-Dopa catalyzed by the enzyme L-Dopa

164 to the open conformation that coincides with decarboxylation of LThDP and DXP release.

165 A-1, and undergo deacylation followed by the decarboxylation of Lys-70, rendering OXA-1 inactive.

166 nhibitor = 1:2000), OXA-24 was inhibited via decarboxylation of Lys-84; however, the enzyme could be

167 OXA-24 is no longer active and (ii) that the decarboxylation of Lys84 occurred during the first react

168 ME 1-4) to catalyze the reversible oxidative decarboxylation of malate in the presence of NADP.

169 method has been applied to the direct double decarboxylation of malonic acid derivatives, which allow

170 Decarboxylation of malonyl-CoA to acetyl-CoA by malonyl-

171 Decarboxylation of mandelylthiamin in aqueous solution i

172 The decarboxylation of mandelylthiamin is subject to general

173 mevalonate pathway, the Mg(2+)-ATP dependent decarboxylation of mevalonate 5-diphosphate (MVAPP), pro

174 hosphate, the classical MVA pathway involves decarboxylation of mevalonate diphosphate, while an alte

175 ternate pathway has been proposed to involve decarboxylation of mevalonate monophosphate.

176 ol stabilization of the transition state for decarboxylation of OMP provided by OMPDC represents the

177 ncrease in (k(cat))(obs) for OMPDC-catalyzed decarboxylation of OMP, and the 4 kcal/mol of binding en

178 total transition-state stabilization for the decarboxylation of orotidine 5'-monophosphate can be acc

179 of pyruvate, enhances the rate of enzymatic decarboxylation of oxaloacetate in the carboxyl transfer

180 The same reaction mechanism promotes decarboxylation of oxaloacetate.

181 ted in situ in a tandem mass spectrometer by decarboxylation of oxo[4-(trimethylammonio)phenyl]acetic

182 Ferulic acid decarboxylase catalyzes the decarboxylation of phenylacrylic acid using a newly iden

183 mitochondrion and parasitophorous vacuole by decarboxylation of phosphatidylserine (PtdSer) and in th

184 ay to identify malaria genes involved in the decarboxylation of phosphatidylserine.

185 A similar pathway is proposed for decarboxylation of propionate 4, but with a lysine resid

186 boxylase (YPDC) carries out the nonoxidative decarboxylation of pyruvate and is mechanistically a sim

187 ority of alanine enters into the pathway via decarboxylation of pyruvate in promastigotes, whereas pa

188 The decarboxylation of pyruvate loses a carbon equivalent, a

189 onents and coenzymes, performs the oxidative decarboxylation of pyruvate to acetyl-CoA and is central

190 rd of sugar carbon is lost to CO2 due to the decarboxylation of pyruvate to acetyl-CoA and limitation

191 ormate lyase (PFL)-enzymes that catalyze the decarboxylation of pyruvate to form acetaldehyde and for

192 ]pyruvate is caused exclusively by oxidative decarboxylation of pyruvate via the pyruvate dehydrogena

193 olved in energy generation through oxidative decarboxylation of pyruvate.

194 reaction proceeding via a mild photoinduced decarboxylation of redox-activated aromatic carboxylic a

195 Decarboxylation of rifamycin provides salinisporamycin,

196 ing ubiX and ubiD, which are responsible for decarboxylation of the 3-octaprenyl-4-hydroxybenzoate pr

197 Decarboxylation of the amino acid sarcosine resulted in

198 mine is a biogenic compound derived from the decarboxylation of the amino acid tyrosine, and is there

199 cadaverine, which are generated by bacterial decarboxylation of the basic amino acids ornithine and l

200 this cluster, MftC, catalyzes the oxidative decarboxylation of the C-terminal Tyr of the substrate p

201 been shown that MftC catalyzes the oxidative decarboxylation of the C-terminal tyrosine (Tyr-30) on t

202 ne and uguenenazole, via two-step hydrolysis-decarboxylation of the corresponding 2,5-diaryloxazole-4

203 corresponding maleic anhydride, followed by decarboxylation of the diacid leads to the pathway's fin

204 and a bicyclic enamine derived from in situ decarboxylation of the diastereomeric tricyclic beta-lac

205 f FEO is not limited by the chemical step of decarboxylation of the enzyme-bound substrate.

206 the methoxypyridine, accompanied by in situ decarboxylation of the intermediate carbamic acid, gave

207 Decarboxylation of the intermediate occurs spontaneously

208 A mechanism for the decarboxylation of the kinetically stable carboxyl group

209 : (1) The orotate binding domain carries out decarboxylation of the orotate ring.

210 etical simulations reveal that the efficient decarboxylation of the primarily generated phenyl cation

211 a nonaqueous solvent, led to the spontaneous decarboxylation of the sialic acid residues as determine

212 the entire effect of these mutations on the decarboxylation of the truncated neutral substrate 1-(be

213 Reaction profiles for the direct decarboxylation of trichloroacetate were generated with

214 5'-monophosphate decarboxylase catalyzes the decarboxylation of truncated substrate (1-beta-D-erythro

215 phan 2-monooxygenase catalyzes the oxidative decarboxylation of tryptophan to yield indole-3-acetamid

216 me PaaA catalyzes the double dehydration and decarboxylation of two glutamic acid residues in the 30-

217 to an almost fully axial position, ideal for decarboxylation of UDP-4-keto-D-glucuronic acid in the s

218 UDP-xylose synthase (UXS) catalyzes decarboxylation of UDP-D-glucuronic acid to UDP-xylose.

219 ylose into glycans and is synthesized by the decarboxylation of UDP-glucuronic acid (UDP-GlcA).

220 order rate constants for the OMPDC-catalyzed decarboxylations of FEO (10 M(-)(1) s(-)(1)) and 1-(beta

221 The OMPDC-catalyzed decarboxylations of FEO and EO are both activated by exo

222 The experimentally observed decarboxylations of these molecules are found to proceed

223 ttributed to pyroglutamic acid formation and decarboxylation on the primary structure of the mAb thro

224 AD) enzymes are capable of catalyzing either decarboxylation or decarboxylation-deamination on variou

225 Understanding mechanisms that favor decarboxylation over fatty acid hydroxylation in OleTJE

226 The flux through the histidine decarboxylation pathway in cells grown at physiological

227 tterns suggest the existence of an alternate decarboxylation pathway in which an unstable intermediat

228 The histidine decarboxylation pathway of Streptococcus thermophilus CH

229 of excess ZnCl2 , thus avoiding the typical decarboxylation pathway of these substrates.

230 Degradative amino acid decarboxylation pathways in bacteria generate secondary

231 ogen bonds play roles in promoting oxidative decarboxylation, priming Fe(II) to bind O(2), and positi

232 slowing the decarboxylation process and likewise the overall decompo

233 amined including a newly developed catalytic decarboxylation process.

234 ctor plays a major role in the carboxylation/decarboxylation process.

235 uric acid ring hydrolytically and subsequent decarboxylation produces carbon dioxide and biuret.

236 The decarboxylation product, 14-heptacosanone, did not react

237 lular accumulation of the amino acid and its decarboxylation product.

238 No decarboxylation products of (18)F-l-FEHTP were detected

239 alladium-catalyzed reaction through a tandem decarboxylation, proton abstraction, and nucleophilic ad

240 two solvents, this compound suffers a rapid decarboxylation/protonaton reaction, forming 1,3-dimethy

241 ence for hemiketal biosynthesis by oxidative decarboxylation rather than the previously hypothesized

242 (2+) photocages that utilizes a light-driven decarboxylation reaction in the metal ion release mechan

243 ate salts by employing an interrupted Barton decarboxylation reaction is reported.

244 The decarboxylation reaction provides a route for the produc

245 f both the labeling conditions, to drive the decarboxylation reaction to completion and the CE-LIF pa

246 The free energy profile for the decarboxylation reaction was traced, assuming equilibriu

247 oduct and thereby accelerating the enzymatic decarboxylation reaction.

248 the presence or absence of base catalysis in decarboxylation reactions are consistent with the associ

249 ate-determining process, intrinsic CKIEs for decarboxylation reactions are typically greater than 1.0

250 from sugar fermentations are limited by the decarboxylation reactions involved in Embden-Meyerhof-Pa

251 inetic evidence suggests that acid-catalyzed decarboxylation reactions of aromatic carboxylic acids c

252 te C-13 are consistent with that observed on decarboxylation reactions of other PLP-dependent enzymes

253 Patterns in the observed catalysis of decarboxylation reactions required us to conclude that t

254 yruvate carboxylation followed by subsequent decarboxylation reactions.

255 re synthesized by cross coupling followed by decarboxylation reactions.

256 form complementary functions in catalysis of decarboxylation reactions: (1) The orotate binding domai

257 edivoxetine is also described using this new decarboxylation-recombination protocol.

258 on, can subsequently undergo metal insertion-decarboxylation-recombination to generate Csp(2)-Csp(3)

259 We postulate that decarboxylation requires formation of a ternary complex

260 Increased amino acid uptake and subsequent decarboxylation result in the intracellular accumulation

261 oesters with aldehydes followed by reductive decarboxylation results in unnatural alpha-amino acids i

262 es as CO or CO(2) through decarbonylation or decarboxylation routes, respectively, that use C-atoms p

263 ranssulfuration (cystathionine), and glycine decarboxylation (serine and glycine).

264 The carboxylic acid, which is removed by decarboxylation, serves as a traceless activating group,

265 computational study here of a beta-ketoacid decarboxylation shows how the distinction between the tw

266 The decarboxylation stage of this tandem sequence is envisio

267 This decarboxylation step is coupled to a proton transfer fro

268 a proton to C5 of the substrate prior to the decarboxylation step.

269 o)aryl bromides followed by an acid-mediated decarboxylation step.

270 ential role for the follower sequence in the decarboxylation step.

271 is unique process, termed the lysine N(zeta)-decarboxylation switch, arrests the sensor domain in the

272 uce the experimental rate constant show that decarboxylation takes place with a non-negligible free e

273 (TclIJN) is followed by C-terminal oxidative decarboxylation (TclP).

274 in diphosphate (LThDP), which has subsequent decarboxylation that is triggered by d-glyceraldehyde 3-

275 uciferin substrate, followed by an oxidative decarboxylation that ultimately produces light.

276 yze two key steps during light-period malate decarboxylation that underpin secondary CO(2) fixation i

277 adaptation to acidic environments, as lysine decarboxylation to cadaverine.

278 eased the availability of 6-PG for oxidative decarboxylation to D-ribose-5-phosphate, which is essent

279 collision-induced dissociation, 4 undergoes decarboxylation to form 5.

280 dative radical followed by rearrangement and decarboxylation to form an aryl radical anion which is t

281 of tartrates to oxaloacetate and an ensuing decarboxylation to form pyruvate are known processes tha

282 The adducts could further undergo hydrolysis/decarboxylation to generate the products which are equiv

283 on of self-assembled diacids with subsequent decarboxylation to give polymeric bisnaphthyl-Cu species

284 d with fructose to form a Schiff base before decarboxylation to produce acrylamide without Amadori re

285 sodium azide, undergo a tandem ring-opening decarboxylation to produce gamma-azidobutyric acids in g

286 oxidation, the carboxylate undergoes radical decarboxylation to site-specifically generate radical in

287 and photoredox catalysis to affect a facile decarboxylation to the CF3 radical.

288 esters but also were the key to avoid facile decarboxylation to the parent drugs from the carboxylic

289 the 5'-deoxyadenosine followed by oxidative decarboxylation to the product.

290 e putative dehydrogenase EryC and subsequent decarboxylation to yield triose-phosphates.

291 ino acids at their rim, undergo photoinduced decarboxylations to give baskets 4-6 forming a solid pre

292 th asparagine to form the Schiff base before decarboxylation, to generate acrylamide without the Amad

293 red both in the Michaelis complex and at the decarboxylation transition state.

294 ontal lineCH(COO-t-Bu) with enynal undergoes decarboxylation under the [Au]/[Ag] catalysis and forms

295 During this exploration, a facile decarboxylation was noted and was exploited as a novel p

296 independent reaction of 2-KPCC (acetoacetate decarboxylation) was not decreased for any of the aforem

297 2] cycloaddition with amides and subsequent decarboxylation, which liberates the desired sulfonyl am

298 alation has a comparably high barrier as the decarboxylation, which was previously believed to be sol

299 n ascorbate peroxidase is essential for both decarboxylations, while a lysine that salt bridges to pr

300 rboxylase catalyzes two sequential oxidative decarboxylations with H2O2 as the oxidant, coproheme III