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1 oduct and thereby accelerating the enzymatic decarboxylation reaction.
2 he C-terminal Mn(II) center can catalyze the decarboxylation reaction.
3 rate independently during the ThDP-dependent decarboxylation reaction.
4 roperties of this residue are crucial in the decarboxylation reaction.
5 tures indicate a plausible mechanism for the decarboxylation reaction.
6 hree excited states controls the rate of the decarboxylation reaction.
7 it as a proton sink during an intracellular decarboxylation reaction.
8 hydrogen-bonded network that facilitates the decarboxylation reaction.
9 thioester carbonyl of malonyl-CoA during the decarboxylation reaction.
10 ance of His303 and Asn336 in the malonyl-CoA decarboxylation reaction.
11 tion without having any marked effect on the decarboxylation reaction.
12 ragmentation, native peptide hydrolysis, and decarboxylation reactions.
13 ovel transition metal-dependent nonoxidative decarboxylation reactions.
14 yruvate carboxylation followed by subsequent decarboxylation reactions.
15 ting enzymes including hydroxylation-coupled decarboxylation reactions.
16 re synthesized by cross coupling followed by decarboxylation reactions.
17 form complementary functions in catalysis of decarboxylation reactions: (1) The orotate binding domai
18 lation/C4'-protonation mechanism for the AIB decarboxylation reaction, and rapid equilibrium quinonoi
19 the presence or absence of base catalysis in decarboxylation reactions are consistent with the associ
20 ate-determining process, intrinsic CKIEs for decarboxylation reactions are typically greater than 1.0
22 -360 to Ala or Ser reduces the k(cat) of the decarboxylation reaction by 50- and 1000-fold, respectiv
23 within the active site to participate in the decarboxylation reaction by orienting the carboxylate gr
24 and an unusually effective formal oxidative decarboxylation reaction cascade initiated by a Curtius
25 vinyl anion intermediate; the Mg2+-dependent decarboxylation reaction catalyzed by KGPDC involves the
27 esidue Cys-82 may be the proton donor of the decarboxylation reaction catalyzed by S-adenosylmethioni
28 ysis of the pH dependence of the malonyl-CoA decarboxylation reaction catalyzed by wild-type CHS and
31 (2+) photocages that utilizes a light-driven decarboxylation reaction in the metal ion release mechan
32 nt enzyme containing a covalently bound, pre-decarboxylation reaction intermediate analogue and shoul
33 from sugar fermentations are limited by the decarboxylation reactions involved in Embden-Meyerhof-Pa
35 duces a blue bioluminescence by triggering a decarboxylation reaction of protein-bound hydroperoxycoe
36 inetic evidence suggests that acid-catalyzed decarboxylation reactions of aromatic carboxylic acids c
37 minobutane) activates the autoprocessing and decarboxylation reactions of human S-adenosylmethionine
38 te C-13 are consistent with that observed on decarboxylation reactions of other PLP-dependent enzymes
39 reactions and the nonproductive "uncoupled" decarboxylation reactions of this enzyme family, as demo
43 lyzed all of the isomerization and oxidative decarboxylation reactions required to form 2-oxoadipate,
45 s reported that the rate of the light-driven decarboxylation reaction strongly depends on the excitat
46 er propose a photochemical mechanism for the decarboxylation reaction, supporting a role for the GFP
48 ubated with benzaldehyde, the product of the decarboxylation reaction thus confirming its presence on
49 f both the labeling conditions, to drive the decarboxylation reaction to completion and the CE-LIF pa
50 phosphoribosyl transfer that is linked to a decarboxylation reaction to form the NAD precursor nicot
51 nover experiment, the initial product of the decarboxylation reaction was shown to be CO(2) not HCO(3
53 ysis and oxidation of 38 to 40, an oxidative decarboxylation reaction was used to provide the C(2)(-)
54 in diphosphate (ThDP)-dependent nonoxidative decarboxylation reaction, was studied with the chromopho
55 ion and the pH dependence of the malonyl-CoA decarboxylation reaction were used to evaluate the poten
56 serve as the basis for future studies of the decarboxylation reaction which is unique among the acyl-
57 of bacterial species utilizing an activation-decarboxylation reaction which yields formate and CO2.
58 vative in a thiamine PPi-dependent oxidative decarboxylation reaction with reduction of ferredoxin.
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