ライフサイエンスコーパス: dehydrogenation

1 steam reforming) or CO (by complete methanol dehydrogenation).

2 balanced competition between elimination and dehydrogenation.

3 prior to the intramolecular oxidative cyclo-dehydrogenation.

4 ves approximately 1,000,000 turnovers for FA dehydrogenation.

5 that isobutene inhibits the rate of n-butane dehydrogenation.

6 validated activity in cholesterol side chain dehydrogenation.

7 n product, formed from triple C-H activation/dehydrogenation.

8 ogen production through their catalytic deep dehydrogenation.

9 gages in C(sp(3) )-H bond activation-induced dehydrogenation.

10 +) which is rather unreactive toward further dehydrogenation.

11 ansformed to the corresponding indolizine by dehydrogenation.

12 sequential acetylene additions coupled with dehydrogenation.

13 ioxolone core by palladium-catalyzed aerobic dehydrogenation.

14 he degree to which elimination competes with dehydrogenation.

15 diimine (DPDI), undergoes specific levels of dehydrogenation (-1 H2 or -3 H2) depending on the nature

16 yl addition (+16 Da), alcoholic oxidation or dehydrogenation (-2 Da), and elimination of sulfate (-80

17 The catalysis of acceptorless alcohol dehydrogenation (AAD) is an important area of research.

18 The different types of acceptorless alcohol dehydrogenation (AAD) reactions are discussed, followed

19 respectively, through catalytic acceptorless dehydrogenation (AD).

20 ent efficiency of 3.7% was achieved for BnOH dehydrogenation, an enhancement of ~10 compared to TiO2.

21 ng the Ullmann coupling reaction followed by dehydrogenation and C-C coupling, we have developed a fi

22 adical partitions roughly equally between C3-dehydrogenation and C4-dehydration.

23 le many catalysts exist for both formic acid dehydrogenation and carbon dioxide reduction, solutions

24 with high atom efficiency via a sequence of dehydrogenation and condensation steps that give rise to

25 with high atom efficiency via a sequence of dehydrogenation and condensation steps which give rise t

26 Dehydrogenation and dehydrocoupling processes are partic

27 Dehydrogenation and dissociation pathways that can compe

28 asing the number of conformations predicting dehydrogenation and facilitating the identification of s

29 e significant improvement of the kinetics of dehydrogenation and hydrogenation compared to commercial

30 gand efficiently catalyzes both acceptorless dehydrogenation and hydrogenation of N-heterocycles.

31 n-hexane, a reaction requiring hydrogenation/dehydrogenation and moderate to strong Bronsted acid sit

32 was detected from the release of HCl in the dehydrogenation and subsequent reaction with IrCl(CO)(ra

33 insic activation energies, most strongly for dehydrogenation and terminal cracking, resulting in incr

34 It also effects dehydrogenations and other oxidations.

35 complex pathway including aldol-condensation/dehydrogenation, and a Bronsted acidic site-catalyzed ac

36 ., water- and oxygen-adducts, demethylation, dehydrogenation, and decarboxylation).

37 is shown to yield regioselective oxidation, dehydrogenation, and fragmentation of alkanes.

38 The reaction rate, extent of dehydrogenation, and reaction mechanism vary as a functi

39 high rates and turnover numbers for n-alkane dehydrogenation, and yields of terminal dehydrogenation

40 etics of n-butane monomolecular cracking and dehydrogenation are investigated for eight zeolites diff

41 ysis, hydrogen evolution, hydrogenation, and dehydrogenation, are discussed.

42 to the corresponding tetrahydrocarbazole and dehydrogenation (aromatization) of this to give the targ

43 uted benzofurans via 1,2-alkyl migration and dehydrogenation (aromatization).

44 lyst is robust, delivering several cycles of dehydrogenation at high [AB] without loss of catalytic a

45 As a consequence of dehydrogenation, B-N-containing oligomeric/polymeric mat

46 computational study reveals that ethyl group dehydrogenation begins with activation of a primary C-H

47 or of this potential material to improve its dehydrogenation behavior further and also to make rehydr

48 e formation of 4 is thermoneutral due to the dehydrogenation being concerted with the donor coordinat

49 ine co-catalyst was found to be critical for dehydrogenation but was not effective as a stoichiometri

50 Pt/CeO2 catalysts are stable during propane dehydrogenation, but are not selective for propylene.

51 This process involves alkane dehydrogenation by a pincer-ligated iridium complex and

52 Primary alcohol dehydrogenation by a PNP-Ru(II) catalyst was probed by l

53 E241 in ChsE2 is required for catalysis of dehydrogenation by ChsE1-ChsE2.

54 AB dehydrogenation by lithium and potassium triethylborohyd

55 ion sequence comprising a Cu-catalyzed cross dehydrogenation C-N coupling and an Ullmann C-C bond for

56 action, as indicated by the observation that dehydrogenation can take place in the absence of an exte

57 e [2 + 2 + 2] termolecular cycloaddition and dehydrogenation cascade to yield selectively the E-isome

58 lex is shown to be a competitive alternative dehydrogenation catalyst for the transformation of diami

59 A comparison of the effect of various dehydrogenation catalysts and reaction conditions is als

60 trasubstituted olefins via aerobic oxidative dehydrogenation catalyzed by Cu(OAc)2.

61 The compatibility of the dehydrogenation conditions additionally allows for effic

62 f single phenylene units in combination with dehydrogenation cross-linking reactions within the polym

63 Cycle A, the dehydrogenation cycle, produces an enone intermediate.

64 aSintdouble dagger for terminal cracking and dehydrogenation decrease for a given channel topology.

65 ntly, selectivities to terminal cracking and dehydrogenation decrease relative to central cracking be

66 osilylation, C-C bond cleavage, acceptorless dehydrogenation, dehalogenation/hydrogen transfer, oxida

67 HTT </= 500 degrees C), and their subsequent dehydrogenation/dehydroxylation (HTT > 500 degrees C) co

68 Thus, a one-pot dehydrogenation/direct arylation cascade reaction betwee

69 ses the peroxyflavin-independent oxygenation-dehydrogenation dual oxidation of a highly reactive poly

70 Routine and rapid calculations of arene dehydrogenation energies and aryne angle distortion pred

71 Dehydrogenation, epoxidation, and demethylation of the l

72 ion-to-ethane and the parallel hydrogenation-dehydrogenation ethylidyne-producing route are considere

73 Pi]/[ATP] provides feedback to the substrate dehydrogenation flux over the entire range of respirator

74 ydrogenation to -CH2O; a following oxidative dehydrogenation forms CHO; CHO is transformed to product

75 under a N(2) atmosphere established transfer dehydrogenation from an isopropyl aryl substituent to ei

76 der additions, two decarbonylations, and two dehydrogenations, giant biaryl bisquinones (compounds 13

77 Reversibility of a dehydrogenation/hydrogenation catalytic reaction has bee

78 Moreover, meso-11 was found to undergo clean dehydrogenation in solution at 50 degrees C to provide 6

79 The most likely reaction mechanisms involve dehydrogenation induced by O and/or OH surface species r

80 s and related enzymes perform O(2)-dependent dehydrogenations initiated at unactivated C-H groups wit

81 The dehydrogenation is assisted by N-methylindole, which act

82 nding that the transition-state geometry for dehydrogenation is bulky and resembles a product state,

83 reaction sequence cycloaddition/elimination/dehydrogenation is described.

84 Large ring-forming dehydrogenation is initiated by anodic oxidation at a gr

85 (M1 phase) catalyst during alkane oxidative dehydrogenation is reported.

86 nce of the high energetic demand of methanol dehydrogenation, is corroborated through a series of com

87 teps deoxygenate the alcohol components, the dehydrogenations lead to aromatization.

88 activity in olefin polymerization and alkane dehydrogenation (M = Cr) or efficient luminescence prope

89 mploy an energetically difficult, sequential dehydrogenation mechanism for acetylenic bond formation.

90 research on ammonia-borane and amine-borane dehydrogenation mediated by complex metal hydrides (CMHs

91 proceed via an unprecedented decarboxylation-dehydrogenation-monooxygenation cascade.

92 l radical has been shown to be important for dehydrogenation, much less is known regarding the course

93 Facile dehydrogenation occurred at -30 degrees C, but the resul

94 Unusually, dehydrogenation occurs by water loss.

95 ve been shown to be active for the oxidative dehydrogenation (ODH) of propane at low temperatures (<2

96 ](*+) ion; the latter brings about oxidative dehydrogenation (ODH) of saturated hydrocarbons, e.g., p

97 When the acceptorless dehydrogenation of 1-phenylethanol with precatalyst 4 wa

98 For the acceptorless dehydrogenation of 1-phenylethanol, complex 7 displayed

99 the latter formed in situ from the oxidative dehydrogenation of 1.

100 ase encoded by the igr operon, catalyzes the dehydrogenation of 2'-propanoyl-CoA ester side chains in

101 HSD10(E249Q) was unable to catalyze the dehydrogenation of 2-methyl-3-hydroxybutyryl-CoA and the

102 quantify and validate GA production through dehydrogenation of 3-dehydroshikimate (3-DHS) by purifie

103 FadE26-FadE27 catalyzes the dehydrogenation of 3beta-hydroxy-chol-5-en-24-oyl-CoA, a

104 rom the initial stage of the dehydrocoupling/dehydrogenation of 7 with [Rh(mu-Cl)(1,5-cod)](2) (2) as

105 onverts to a Ti(IV) metallacycle (4) through dehydrogenation of a pendant isopropyl group.

106 S)-epoxypropylphosphonate] in an unusual 1,3-dehydrogenation of a secondary alcohol to an epoxide.

107 The initial rate for the dehydrogenation of AB catalyzed by 3 is first order in 3

108 The dehydrogenation of acyclic alkanes to give alkylaromatic

109 Ds) are enzymes that catalyze the alpha,beta-dehydrogenation of acyl-CoA esters in fatty acid and ami

110 Four steps are involved: dehydrogenation of alcohol to aldehyde (Step 1); couplin

111 2 surface promotes the selective binding and dehydrogenation of alcohols in the presence of other oxi

112 The oxidant- and acceptor-free neat dehydrogenation of alcohols to obtain dihydrogen gas is

113 Likewise, dehydrogenation of alcohols was achieved through 1,6 met

114 The model complex mediates the dehydrogenation of alcohols, a reaction relevant to lact

115 e an effective catalyst for the acceptorless dehydrogenation of alcohols, implicating 13 as a catalys

116 of olefins and ketones and the acceptorless dehydrogenation of alcohols.

117 of olefins and ketones and the acceptorless dehydrogenation of alcohols.

118 hydrogenation of olefins or the acceptorless dehydrogenation of alcohols.

119 and oxyhalogenation of alkanes and alkenes, dehydrogenation of alkanes, conversion of alkyl halides,

120 test potential for regio- and chemoselective dehydrogenation of alkyl groups and alkanes.

121 has been made in the closely related area of dehydrogenation of alkyl groups of substrates containing

122 The development of catalysts for dehydrogenation of alkyl groups to give the correspondin

123 actical and direct method for the alpha,beta-dehydrogenation of amides is reported using allyl-pallad

124 as key intermediates in the dehydrocoupling/dehydrogenation of amine-boranes to form oligo- and poly

125 ficient precatalysts for the dehydrocoupling/dehydrogenation of amine-boranes, such as Me(2) NHBH(3).

126 and selective aerobic and/or electrochemical dehydrogenation of amines.

127 Though numerous catalysts for the dehydrogenation of ammonia borane (AB) are known, those

128 PMe2Ph)2H (3) have been tested for catalytic dehydrogenation of ammonia borane (AB).

129 cient homogeneous ruthenium catalyst for the dehydrogenation of ammonia borane (AB).

130 -stable and promote the catalytic hydrolytic dehydrogenation of ammonia borane.

131 The catalytic dehydrogenation of ammonia- and amine-boranes by a dimet

132 of betulin, a highly selective PIFA mediated dehydrogenation of an oxime, and a subsequent Lossen rea

133 Light-driven dehydrogenation of benzyl alcohol (BnOH) to benzaldehyde

134 AP) was also synthesized and detected in the dehydrogenation of benzyl alcohol.

135 The oxidative-dehydrogenation of carboxylic acids to selectively produ

136 ighly practical and step-economic alpha,beta-dehydrogenation of carboxylic acids via enediolates is r

137 Furthermore, the photodriven dehydrogenation of cyclic alkanes gave an excellent appa

138 (CHMe2)2-4-methylphenyl]2(-)), catalyses the dehydrogenation of cycloalkanes to cyclic alkenes, and l

139 e initial Pd(II) catalyst mediates the first dehydrogenation of cyclohexanone to cyclohexenone, after

140 influence on the rate of Pd(TFA)2-catalyzed dehydrogenation of cyclohexanone to cyclohexenone, while

141 The dehydrogenation of cyclohexanones affords cyclohexenones

142 d out a mechanistic investigation of aerobic dehydrogenation of cyclohexanones and cyclohexenones to

143 Pd(DMSO)(2)(TFA)(2) as a catalyst for direct dehydrogenation of cyclohexanones and other cyclic keton

144 Pd(II) catalyst systems that effect aerobic dehydrogenation of cyclohexanones with different product

145 A palladium(II)-catalyzed oxidative dehydrogenation of cyclohexene-1-carbonyl indole amides

146 The catalytic dehydrogenation of cyclohexenes is showcased in an effic

147 through the development of a method for the dehydrogenation of cyclohexenones that allows for point-

148 cyclohexenones, without promoting subsequent dehydrogenation of cyclohexenones to phenols.

149 investigation of a proposed mechanism of the dehydrogenation of dimethylaminoborane (DMAB) by a homog

150 ium-catalyzed methodology for the alpha,beta-dehydrogenation of esters and nitriles is reported.

151 catalysts were used for 1 hour in oxidative dehydrogenation of ethane to ethylene at 650 degrees C,

152 Iridium-mediated dehydrogenation of ethanol to acetaldehyde has led to th

153 this respect, hydrogenation of CO2 to FA and dehydrogenation of FA are crucial reaction steps.

154 he Ag48Pd52/WO2.72, catalytically active for dehydrogenation of formic acid (TOF = 1718 h(-1) and Ea

155 iciently promotes a tandem process involving dehydrogenation of formic acid and hydrogenation of C-C

156 We report the transfer-dehydrogenation of gas-phase alkanes catalyzed by solid-

157 yde and water to form the gem-diol (Step 2); dehydrogenation of gem-diol to carboxylic acid (Step 3);

158 ter, a deactivation product in the catalytic dehydrogenation of glycerol, was characterized by XRD, D

159 complex mechanistic landscape that involves dehydrogenation of H(3)B.NMe(2)H to give the amino-boran

160 ed Si-B separation in 1 enables a metal-free dehydrogenation of H2 O to give the silanone-borane 3 as

161 eside at Pd-Au interface sites tend to favor dehydrogenation of HCOOH, whereas Pd atoms in Pd(111)-li

162 The dehydrogenation of higher alcohols available from renewa

163 bon atoms through the Cu bulk after complete dehydrogenation of hydrocarbon molecules on the Cu surfa

164 propose a unique mechanism for the transfer dehydrogenation of hydrocarbons to olefins and discuss a

165 strikingly higher activity for the oxidative dehydrogenation of isobutane in comparison to the closed

166 nicotinamide adenine dinucleotide-dependent dehydrogenation of l-alpha-aminoadipic semialdehyde/L-De

167 demethylation, oxidation, or dehydroxylation/dehydrogenation of lignocellulose fragments as the prima

168 catalytic action of the coatings facilitates dehydrogenation of linear olefins in the lubricating oil

169 ity hydrogen by microwave-promoted catalytic dehydrogenation of liquid alkanes using Fe and Ni partic

170 The predicted mechanism begins with the dehydrogenation of methanol to formaldehyde through a ne

171 ed surface charge on the biochars; while the dehydrogenation of methylene groups, which yielded incre

172 Furthermore, the kinetic rates of dehydrogenation of Mg-0.1In alloy hydride doped with a t

173 e, with (Phebox)Ir(OAc)(H), the acceptorless dehydrogenation of n-dodecane.

174 The dehydrogenation of n-hexane and cycloalkanes giving n-he

175 The catalytic dehydrocoupling/dehydrogenation of N-methylamine-borane, MeNH(2).BH(3) (

176 ts also showed that the DeltaH value for the dehydrogenation of nanostructured MgH(2)-0.1TiH(2) is si

177 The magnesium was derived by dehydrogenation of nanostructured MgH(2)-0.1TiH(2) prepa

178 Efficient aerobic dehydrogenation of non-native secondary amine substrates

179 through two different sub-pathways including dehydrogenation of OCHO and CO oxidation.

180 The conceptual dehydrogenation of pericyclic reactions yields dehydrope

181 on pincer complexes and reversible oxidative dehydrogenation of primary alcohols/reduction of aldehyd

182 zable functionality and is selective for the dehydrogenation of primary amines (-CH2NH2) in the prese

183 idant-free, acceptorless, and chemoselective dehydrogenation of primary and secondary amines to the c

184 urnover rates for monomolecular cracking and dehydrogenation of propane and n-butane differed among z

185 Possible reaction pathways for the oxidative dehydrogenation of propane by vanadium oxide catalysts s

186 The exothermic oxidative dehydrogenation of propane reaction to generate propene

187 e 40-100 times more active for the oxidative dehydrogenation of propane than previously studied plati

188 ydrocarbon conversion reactions, such as the dehydrogenation of propane, the hydrogenation of propene

189 vidence for the mechanism of CYP3A4-mediated dehydrogenation of raloxifene to a reactive diquinone me

190 se findings not only confirm CYP3A4-mediated dehydrogenation of raloxifene to a reactive diquinone me

191 Dehydrogenation of raloxifene to an electrophilic diquin

192 rate interactions that control the selective dehydrogenation of raloxifene to its protein-binding int

193 elucidate CYP3A4-mediated oxygenation versus dehydrogenation of raloxifene.

194 in lysine biosynthesis, the NAD(+)-dependent dehydrogenation of saccharopine to lysine, is another NA

195 In this report, reversible acceptorless dehydrogenation of secondary alcohols and diols on iron

196 Polymerizations occur via initial formal dehydrogenation of self-assembled diacids with subsequen

197 rhaps most attractive goal in this area, the dehydrogenation of simple alkanes to yield alkenes (spec

198 ral motif has evolved to enable catalysis of dehydrogenation of steroid- or polycyclic-CoA substrates

199 alyst system has been identified for aerobic dehydrogenation of substituted cyclohexenes to the corre

200 unctionalized MOF (bpy-UiO-Pd) catalyzes the dehydrogenation of substituted cyclohexenones to afford

201 DesII can also catalyze the dehydrogenation of TDP-D-quinovose to the corresponding

202 , no Bronsted acids) tandem Wacker oxidation-dehydrogenation of terminal olefins was accomplished usi

203 iently used as catalysts in the acceptorless dehydrogenation of tetrahydroquinoline/indoline derivati

204 o-quinone-based catalysts for the oxidative dehydrogenation of tetrahydroquinolines to afford quinol

205 lysis through two catalytic cycles involving dehydrogenation of the alcohol and decarbonylation of th

206 Dehydrogenation of the alkane is not rate-determining si

207 ficient precatalysts for the dehydrocoupling/dehydrogenation of the amine-borane Me2NH.BH3 (3) to aff

208 The products imply varying degrees of dehydrogenation of the boron centers with concomitant fo

209 Thermally induced dehydrogenation of the H-bridged cation L2B2H5(+) (L=Lew

210 monooxygenations, E. lathyris ADH1 catalyzes dehydrogenation of the hydroxyl groups, leading to the s

211 Dehydrogenation of the indoline aminals with potassium p

212 DesII also catalyzes the dehydrogenation of the nonphysiological substrate TDP-D-

213 drogenase (CBFD), continues with the further dehydrogenation of this carbon to yield a carbonyl in a

214 The reaction proceeds via successive dehydrogenation of two saturated carbon-carbon bonds of

215 The dehydrogenation of unactivated alkanes is an important t

216 The dehydrogenations of alcohol (Step 1) and gem-diol (Step

217 C catalyst showed high activity in oxidative dehydrogenations of several N-heterocycles.

218 cell electrocatalysts for partial oxidation (dehydrogenation) of hydroxyl-containing fuels.

219 kyl arenes were prepared in a one-pot tandem dehydrogenation/olefin metathesis/hydrogenation sequence

220 ng this method, we discovered an accelerated dehydrogenation pathway for the conversion of tetrahydro

221 the catalyst in oxygenating a substrate via dehydrogenation points to a new direction for understand

222 nal C-C strain is initially relieved; as the dehydrogenation proceeds, the molecules experience a pro

223 alpha-olefin from pincer-Ir catalyzed alkane dehydrogenation, proceeds via two mechanistically distin

224 lude an intramolecular coupled hydrogenation-dehydrogenation process, the functionalization of a C-H

225 etal-based systems in catalyzing the alcohol dehydrogenation process.

226 lowers the activation barrier for the alpha-dehydrogenation process.

227 chain of highly selective C-H activation and dehydrogenation processes, followed by specific intermol

228 kane dehydrogenation, and yields of terminal dehydrogenation product (alpha-olefin) that are much hig

229 n the absence of impurities to achieve clean dehydrogenation products, which is particularly challeng

230 st, yields the major hydroxylation and minor dehydrogenation products.

231 oxyl of a specific monolignol to deprive its dehydrogenation propensity would disturb the formation o

232 A rhodium-catalyzed dehydrogenation protocol for the conversion of 3,5-diary

233 glycine or glutamine significantly decreased dehydrogenation rates without concurrent changes in the

234 Specifically, cracking-to-dehydrogenation ratios for propane and n-butane were muc

235 tized in a final step through a DDQ-mediated dehydrogenation reaction (DDQ=2,3-dichloro-5,6-dicyano-1

236 (DFT) study of the mechanism of the methanol dehydrogenation reaction catalyzed by [RuH(2)(H(2))(PPh(

237 ion of TiH(2) on the equilibrium pressure of dehydrogenation reaction of MgH(2).

238 nter and an unprecedented vinylogous Saegusa dehydrogenation reaction to address C-ring functionality

239 xample of a homogeneous and selective alkane dehydrogenation reaction using a base-metal titanium cat

240 By contrast, HppE catalyses an unusual dehydrogenation reaction while converting the secondary

241 mplex 3, the active catalytic species in the dehydrogenation reaction, is independently synthesized a

242 rate of H2 release at the late stage of the dehydrogenation reaction.

243 a catalyst resting state during the alcohol dehydrogenation reaction.

244 et radical chemistry is coopted to perform a dehydrogenation reaction.

245 al data indicate ligand participation in the dehydrogenation reaction.

246 for the industrially important light alkane dehydrogenation reaction.

247 H-MFI and on the monomolecular cracking and dehydrogenation reactions of n-butane.

248 tionally flexible polymer chains followed by dehydrogenation reactions using thermal annealing.

249 .05 and 1.01 +/- 0.05 in the deamination and dehydrogenation reactions, respectively, using Na(2)S(2)

250 t via in situ one-pot metal/ligand oxidative-dehydrogenation reactions.

251 dox neutral deamination versus the oxidative dehydrogenation reactions.

252 to formic acid and methanol and the reverse dehydrogenation reactions.

253 d as a carrier of intermediates that undergo dehydrogenation, reductive cleavage, and carboxylation t

254 pathways of stereoisomerization, oxidation, dehydrogenation, reductive debromination, and ring openi

255 The bond transformation proceeds by a tandem dehydrogenation/reductive ether cleavage.

256 nd thermodynamic properties of MgH(2) during dehydrogenation-rehydrogenation cycles, a nanostructured

257 trile) complex, 4, exhibit high levels of AB dehydrogenation, releasing over 2.0 equiv of H2.

258 4 and C2H2 formation occur via C2H6 and C2H4 dehydrogenation, respectively.

259 oses at the surface of unbiased Pt through a dehydrogenation route to yield H(ads) at the Pt surface.

260 ransposition reaction, and (4) the final RCM/dehydrogenation sequence for the formation of (-)-acylfu

261 enone, while it strongly inhibits the second dehydrogenation step, conversion of cyclohexenone to phe

262 FT calculations show that the first proposed dehydrogenation step, to give H(2)B horizontal lineNMe(2

263 d identify the turnover-limiting step of the dehydrogenation step, which involves a change in the coo

264 reaction, the catalyst mainly influences the dehydrogenation step, which is essential to avoid the fo

265 For the second dehydrogenation step, which ultimately affords [H(2)BNMe

266 vage transition states form via equilibrated dehydrogenation steps that replace several C-H bonds wit

267 proceeds via a sequence of condensation and dehydrogenation steps which give rise to selective C-C a

268 cies formed in sequential quasi-equilibrated dehydrogenation steps, which replace C-H with C-metal bo

269 tem, electron transport chain, and substrate dehydrogenation subsystems listed in increasing order of

270 t, we propose a mechanism for catalytic DMAB dehydrogenation that exhibits an energy barrier of appro

271 to a kinetic preference for primary alcohol dehydrogenation, the site-selective modification of glyc

272 n important role in orienting raloxifene for dehydrogenation through a combination of electrostatic a

273 oxygen atoms to form -CH3O with a following dehydrogenation to -CH2O; a following oxidative dehydrog

274 ious studies could not differentiate between dehydrogenation to a diquinone methide and the more comm

275 tead, a surface basic site-catalyzed ethanol dehydrogenation to acetaldehyde, acetaldehyde to acetone

276 y X-ray crystallography and shown to undergo dehydrogenation to afford the aniline product.

277 at account for both metal-mediated substrate dehydrogenation to aminoborane and catalyzed polymer enc

278 ugh two C-N bond formations and an oxidative dehydrogenation to form highly substituted products in g

279 ve adsorption of methanol and its subsequent dehydrogenation to formaldehyde.

280 The photocatalysts are also active for amine dehydrogenation to give N-alkyl aldimines and H(2).

281 emperature (<100 degrees C) aqueous methanol dehydrogenation to H2 and CO2.

282 this result suggests that the preference of dehydrogenation to occur at channel intersections is muc

283 The reaction proceeds by dehydrogenation to the ketone, followed by an aldol reac

284 olefin hydrogenation as well as amine-borane dehydrogenation/transfer hydrogenation.

285 a Curtin-Hammett scenario in which methanol dehydrogenation triggers rapid, reversible diene hydrome

286 Monomolecular alkane cracking and dehydrogenation turnovers occurred with strong preferenc

287 s undergo rapid and reversible hydrogenation/dehydrogenation under the reaction conditions and also t

288 Currently, the most active catalysts for FA dehydrogenation use precious metals.

289 l phenols with concurrent N-hydroxycarbamate dehydrogenation using a common oxidant.

290 and KH2PO4 in acetone and water, followed by dehydrogenation using palladium on charcoal in diphenyle

291 olecular reactions, and the selectivities to dehydrogenation versus cracking and to terminal cracking

292 ide intermediate, which then undergoes alpha-dehydrogenation via interaction with an oxygen adatom or

293 thioether formation through the light chain dehydrogenation was more preferred on antibodies with la

294 n-Suzuki coupling reaction followed by a DDQ dehydrogenation, we have been able to synthesize derivat

295 ng and/or catalysis of raloxifene supporting dehydrogenation were identified with the two models, and

296 Dianions underwent smooth dehydrogenation when generated using Zn(TMP)2 2 LiCl as

297 The second route is oxidative dehydrogenation which produces ethylene using CO2 as a s

298 escoping of allyl-palladium catalyzed ketone dehydrogenation with organocuprate conjugate addition ch

299 These effects of entropy are stronger for dehydrogenation, with a later and looser transition stat

300 etal-catalyzed redox design, on the basis of dehydrogenation/Wolff-Kishner (WK) reduction, to simulta