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1 n which the unpaired electron is extensively delocalized.
2 -GlcNAc levels are increased and OGT and OGA delocalized.
3 Au, bonding of the latter two being broadly delocalized.
4 O analysis shows that the aromatic system is delocalized.
5 riplet state is again found to be completely delocalized.
6 excited states of these nanorings are highly delocalized.
7 r being highly molecular and the latter more delocalized.
8 ontrast, nucleosomes in MIC are dramatically delocalized.
10 es are MoModeltadelta* for both I and II but delocalized (3)MLCT for I(') and localized (3)MLCT for I
11 ne axes, while their LUMOs remain relatively delocalized across the molecule, except in cruciforms su
15 yeast lacking Nup132 (Sc/HuNUP133), Ulp1 is delocalized and can no longer antagonize sumoylation of
16 electrostatic interactions with the DNA are delocalized and followed by aquation to form the monoaqu
17 ined states to band-like charge transport in delocalized and hybridized states of strongly coupled QD
18 elding pattern implies the existence of both delocalized and localized currents that have a dominant
19 he self-assembly of diamondoids, form highly delocalized and symmetric electron-deficient structures.
21 kinase previously found to be overexpressed, delocalized, and constitutively active in CLL cells.
23 gy transfer mechanism leads to excitation of delocalized, anticorrelated vibrational wavepackets on t
27 e for collective behavior of macroscopically delocalized atomic states, a crucial element for new pro
28 s (COEs), molecules that are defined by a pi-delocalized backbone and terminal ionic pendant groups,
29 the IR photons promote bound charge pairs to delocalized band states, similar to those formed just af
34 ed as either localized on one sulfur atom or delocalized between two indistinguishable sulfur atoms.
35 experiments show that electronic excitation delocalizes between the two perpendicular nanorings of t
37 in an effective Hamiltonian that couples the delocalized Bogoliubov modes of the two mechanical oscil
38 chemical bond is generally given in terms of delocalized bonding orbitals, or, alternatively, in term
40 Bonding and charge density analyses indicate delocalized bonding within the gold host and the (Au,T)3
41 s observed experimentally arises mostly from delocalized bound-state excitations of the electron rath
43 lar we find that single point defects do not delocalize, but remain compact near the interfacial plan
45 a polarization of the pi electrons along the delocalized C2-C1-O system in the key cyclopropyl-carben
48 in the droplets) yielding anions with highly delocalized charge [quantified by the weighted average p
49 nd physical or chemical properties of excess delocalized charge carriers in semiconductor nanocrystal
50 Photoexcitation leads to the formation of a delocalized charge resonance state (S1) that relaxes qui
52 ominated by molecular (Frenkel) exictons and delocalized charges are promptly produced (t < 100 fs).
54 nction as molecular wires with transport via delocalized charges, rather than the hopping mechanism t
55 omatic and antiaromatic molecules-which have delocalized circuits of [4n + 2] or [4n] electrons, resp
56 esults in electron localized Class II-III or delocalized Class III structures that display distinct N
57 y narrow asymmetric bands, characteristic of delocalized class-III bis(diarylamino) species, to narro
58 re discussed within the framework of a fully delocalized cluster exhibiting strong double and direct
60 ong contributions to the binding energy from delocalized, collective charge fluctuations-in contrast
62 -type) colloidal ZnO nanocrystals possessing delocalized conduction-band (CB) electrons can be formed
63 nanocrystals (NCs) involves recombination of delocalized conduction-band electrons with copper-locali
65 f the two boron pz-type orbitals, with small delocalized contributions of the 9-borafluorenyl pi syst
66 model, on the superconducting side, one has delocalized Cooper pairs but localized vortices; while o
69 und that CT at the interface first populates delocalized CT excitons with a coherent size of 4 nm.
71 lts support a model of charge separation via delocalized CT states independent of excess heterojuncti
72 formulation of the CuA center as an electron-delocalized Cu(1.5)-Cu(1.5) system implicates both Cu(II
74 nitial bright singlet state (species I) to a delocalized dark state (species II), driven by interacti
75 on in zebrafish hepatocytes destabilizes and delocalizes Dnmt1 and causes DNA hypomethylation and Tp5
77 aggressive and inflammatory in nature, with delocalized E-cadherin and elevated expression of Il23a,
78 I) borates, a Pu 6p orbital is observed with delocalized electron density on basal oxygen atoms contr
82 mplexes lead to highly coherent domains with delocalized electronic states displaying metallic behavi
83 s owe their optoelectronic properties to the delocalized electronic structure along their conjugated
87 pitaxial connections will lead to completely delocalized electrons and may enable the observation of
88 understand the exchange interaction between delocalized electrons and pinned magnetic impurities in
89 as YbAl3, interactions between localized and delocalized electrons can lead to fluctuations between t
90 highly stabilizing feature of molecules with delocalized electrons in closed circuits, is generally r
91 ysics supports this view, demonstrating that delocalized electrons make a static macroscopic polariza
92 ized status (e.g., polyaromatics), with more delocalized electrons obtained for enhanced Maxwell-Wagn
94 ied a structural motif that more effectively delocalizes electrons during lithiation events in batter
96 ination of differently planarized and charge-delocalized enolate tautomers by anion-pi interactions.
98 find that on a 50 fs time scale an initially delocalized excess electron localizes on a single [Tf2N(
99 al pigments combine to form this manifold of delocalized excited states that effectively harvests lig
101 circular dichroism, superradiance, and fast delocalized exciton transfer, consistent with our quantu
103 ectly inform on the relationship between the delocalized excitons and the individual chlorophylls thr
104 cylinders' soft mesoscopic structure, robust delocalized excitons are retained: Internal order and st
105 r between clusters of a few pigments sharing delocalized excitons has been challenged by ultrafast op
107 ersion of a synthetic complex with a valence-delocalized [Fe(3.5)(micro-O)(2)Fe(3.5)](3+) diamond cor
108 he double exchange parameter, B, for valence-delocalized [Fe2S2](+) centers and demonstrate that vari
109 ) provide the only known examples of valence-delocalized [Fe2S2](+) clusters, which constitute a fund
110 rve as a sensitive probe for correlations in delocalized fermionic quantum states and for quantum met
111 hasic change in localization: they initially delocalize from the membrane within minutes and later pa
112 enocopies one another in causing Xist RNA to delocalize from the Xi and disperse into the nucleoplasm
116 ional results indicate a unique role for the delocalized frontier molecular orbitals of the Fe(NO)2 u
117 d to increase electron affinity and maintain delocalized frontier orbitals while significantly decrea
120 the Lys1901 or Arg1914 binding determinants delocalize heterodimeric envoplakin from intracellular v
121 re carried out to determine how localized or delocalized holes on a polymer chain are and to compare
122 otogeneration occurs predominately via these delocalized hot exciton states in competition with relax
123 arge generation across large polymer phases, delocalized hot excitons may also account for the crucia
124 vent-exposed hydrophobic cluster and another delocalized hydrophobic core in the folding kinetics, ar
125 , and those whose O-H stretch vibrations are delocalized, i.e., shared between multiple O-H bonds.
126 -linked peptidoglycan, because StkP and PhpP delocalize in the presence of antibiotics that target th
129 phy suggests that the unpaired electrons are delocalized in each case across two inner 4,4'-bipyridin
131 ules showed that their pi electrons remained delocalized in individual benzenoid-type rings rather th
132 localized in real space (r-space) and those delocalized in momentum-space (k-space) generates exotic
133 a Ni(III) complex with one unpaired electron delocalized in the ligands surrounding the metal center.
135 that a significant fraction of the charge is delocalized in the tert-butyl group of the radical catio
136 oring HRAS, NRAS or KRAS mutations, SCH66336 delocalized, inhibited signaling and preferentially inhi
137 r interaction with Ag (or Cu) as involving a delocalized interaction with contributions from the carb
138 synergy between the bond-forming and charge-delocalizing interactions lead to a dramatic (>hundred-b
139 molecular nature of the exciton and the more delocalized intermolecular nature of electrons and holes
143 , in particular, dipolar ligands and exciton-delocalizing ligands, on their electronic energies; (ii)
144 tment process is often required to remove or delocalize lignin, which may also generate inhibitors th
148 the ground state of the drug shows a highly delocalized lone pair on the amine nitrogen of the melph
149 oxygen-induced trap level, 0.34 eV below the delocalized lowest unoccupied molecular orbital of P(NDI
155 ipolar and quadrupolar electric and magnetic delocalized modes, only dipolar electric and quadrupolar
156 e rationalized by considering a qualitative, delocalized molecular orbital description, which provide
157 mpounds correlated well with the energy of a delocalized molecular orbital first appearing on an arom
160 functional theory calculations highlight the delocalized nature of the low energy singlet excited sta
161 studies have been complicated by the highly delocalized nature of the porphyrin, and calculations re
162 nyl group especially effective at helping to delocalize negative charge due to some cyclopentadienide
163 Loss of the dystrophin-sarcoglycan complex delocalizes nitric oxide synthase (NOS) to alter its sig
166 xygen lone pair on flat sites, whereas it is delocalized on both C and O atoms on concave sites, incr
167 e cyclohexene-bridged Z-derivatives are spin-delocalized on the EPR time scale but charge-localized o
168 he magnetic interaction between the electron delocalized on the fullerene cage and the guest H2 has b
170 r C-S bond cleavage, and the charge and spin delocalized on their structures, were also useful to end
171 uggest unpaired electron density is strongly delocalized onto the non-innocent [N(3)] ligand, with a
173 ulations demonstrate that the electron spins delocalized onto the thiophene unit lead to the accelera
175 ws that the photogenerated plasmon is highly delocalized onto TiO2, and thus, it is shared by the ele
176 on the possible role of charge transfer and delocalized or excitonic states in the photophysics of t
177 The singly reduced anions do not appear to delocalize over the entire length of the longer conjugat
179 and IR spectra indicates that the polaron is delocalized over 2-3 porphyrin units in the linear oligo
181 sfer includes the fact that the excitons are delocalized over a few neighboring sites, but the role o
182 ons, it is proposed that the MLCT states are delocalized over both benzoate Cr(CO)(3) groups, as supp
186 ls with lowest unoccupied molecular orbitals delocalized over the 1,4-di(pyridin-4-yl)buta-1,3-diyne
187 concentric pi-systems, with two pi-electrons delocalized over the central pentagonal B unit and anoth
188 The unpaired electron in this molecule is delocalized over the entire helical core composed of six
190 ex suggests the formation of a radical anion delocalized over the neighboring PDI units, and this res
191 produced by charge separation are frequently delocalized over the pi systems of the final oxidized do
192 a localized HOMO topology while the LUMO is delocalized over the polymer backbone, so that the lowes
193 One of these VTs has the charge and spin delocalized over the porphyrin and the styrylruthenium m
195 but for P-TMI the NTOs have electron density delocalized over the two units as a result of extensive
196 LUMO level of Mo(tfd)(3) is calculated to be delocalized over the whole molecule, which is expected t
197 iron in the case of the S = 1/2 compound, or delocalized over the {Fe(NO)} unit in the S = 0 complex.
198 e of a carbon nanotube because electrons are delocalized over thousands of atomic sites, and rapidly
200 les of sigma-bonds made of a single electron delocalized over two neighboring atoms were until recent
201 referential formation of interchain excitons delocalizing over more than one polymer backbone in the
203 at the edge of transformed patches including delocalized p120-catenin and E-cadherin as well as invas
204 s is especially so in systems of interacting delocalized particles, for which a direct experimental m
208 theoretical model that explores how coherent delocalized phonon-like modes in DNA provide single-stra
209 results support the conclusion that coherent delocalized phonon-like modes play an important role in
210 by invoking exciton self-trapping, in which delocalized photogenerated holes contract in response to
211 re doubly aromatic, each with six completely delocalized pi and sigma electrons, which describe the b
212 e highly stable and doubly aromatic with six delocalized pi and six delocalized sigma electrons and s
213 und to exhibit triple pi aromaticity with 11 delocalized pi bonds, analogous to benzo(g,h,i)perylene
214 ation indicated the feasibility of combining delocalized pi electrons and spin-polarized d electrons
216 arge-transfer (CT) excited state between the delocalized pi electrons of the carbon linker and the Si
218 icenter ptC strip stems from both the highly delocalized pi orbital of ZGNRs and nearly perfect match
219 closed-shell B(22)(2-) species reveal seven delocalized pi orbitals, which are similar to those in a
222 ent with charge separation through access to delocalized pi-electron states in ordered regions of the
223 posite design by the incorporation of both a delocalized pi-electrons system in a closely bound accep
224 carbon basal plane, conferred upon it by the delocalized pi-electrons, (i) causes a downshift of e(g)
225 BODIPY core is feasible, a hemicyanine-like delocalized pi-system gives rise to novel blue and effic
230 ton-localization microscopy reveals that the delocalized plasmons are capable of focusing multiple na
236 nodal excitations from gapped (localized) to delocalized quasiparticles characterized by a longer lif
237 lic hydroxyl to give a quinone methide and a delocalized radical in the heptadienone chain that under
238 upon deprotonation is largest when a highly delocalized radical is combined with an initially less s
240 ed, such that the hydrophobic electronically delocalized region positions within the inner membrane w
244 CD saturation magnetization data for valence-delocalized S = 9/2 [Fe2S2](+) centers facilitated deter
245 and investigating the properties of valence-delocalized S = 9/2 [Fe2S2](+) fragments in higher nucle
246 imilar valence-localized S = 1/2 and valence-delocalized S = 9/2 forms as a function of pH, with pKa
247 s in partial or full conversion from valence-delocalized S = 9/2 to valence-localized S = 1/2 [Fe2S2]
248 e observation that mixed-valence para-Fe2 is delocalized shows that electron localization in meta-Fe2
249 he all-boron fullerene, bonded uniformly via delocalized sigma and pi bonds, is not perfectly smooth
250 hey satisfy the 4n+2 rule of aromaticity for delocalized sigma electrons and fulfill other requiremen
251 bly aromatic with six delocalized pi and six delocalized sigma electrons and should exist for a serie
254 ddition reaction of a thermally generated pi-delocalized singlet vinylcarbene, the intramolecular var
255 ry photoexcitations in conjugated dimers are delocalized singlets that enable fast and efficient iSF.
256 pairing result from in-phase overlap of the delocalized SOMOs on neighboring molecules-that is the i
257 re therefore converted into relatively inert delocalized species A(*) and/or B(*) that inhibit the ch
258 te complex 1 generates a 37-electron valence-delocalized species with no gross structural reorganizat
261 ronic structure with an unexpected partially delocalized spin, as evidenced by electron paramagnetic
267 onally to localized surface states or to the delocalized states of the QD core, (ii) energy or electr
268 fur ions on the surfaces of the QDs (and not delocalized states within the QDs) are the electron dono
272 lecular systems containing an electronically delocalized structure are the basis of emerging optoelec
273 rporation of targeting moieties into the non-delocalized structure of pentamethine and heptamethine i
274 ity of electronic structure in this strongly delocalized superchromophore and reflect the complicatio
275 esonances transitions to that from spatially delocalized surface plasmon excitations, exhibiting mult
276 the addition and removal of electrons from a delocalized system should lead to considerable increases
280 degree of conjugation and the capability to delocalize the pi-electrons which contribute to the stab
282 s attributed to the inability to efficiently delocalize the spin on a phenyl unit, starkly contrary t
283 l symmetry of the electronic ground state by delocalizing the ligand hole in the LMCT excited state o
284 boron atoms in the dihydrides are bonded by delocalized three-, four-, or five-center sigma and pi b
285 en-shell molecules, in which spin density is delocalized through a helical conjugated backbone, hold
286 ybrid theory, the parent radicals of AOs are delocalized through allylic rearrangement, and as a cons
287 isotopic labeling shows that the radical is delocalized throughout the adenine ring of A2503, althou
290 ocenyl cations, the transition from a charge delocalized to a localized state is addressed by resonan
291 h transiently expressed SEC6A1A variants are delocalized to the Golgi, a finding confirmed in a renal
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