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1 riplet state is again found to be completely delocalized.
2 r being highly molecular and the latter more delocalized.
3 ontrast, nucleosomes in MIC are dramatically delocalized.
4 n which the unpaired electron is extensively delocalized.
5 -GlcNAc levels are increased and OGT and OGA delocalized.
6 Au, bonding of the latter two being broadly delocalized.
7 hroism spectroscopy that Cu(A)CcP is valence delocalized.
8 O analysis shows that the aromatic system is delocalized.
9 ecretion of SlpA from the cell is relatively delocalized.
10 excited states of these nanorings are highly delocalized.
12 protonation of N-(aryloxy)imines generates a delocalized 2-azaallyl anion-type nucleophile that engag
15 s on the ability (or not) of electrons to be delocalized across heterometallic bonds, allowing for ra
16 ne axes, while their LUMOs remain relatively delocalized across the molecule, except in cruciforms su
17 or and reveal that one of the spins is fully delocalized across up to five adjacent guanines in a G-t
18 yeast lacking Nup132 (Sc/HuNUP133), Ulp1 is delocalized and can no longer antagonize sumoylation of
19 ecular packing leads to (i) the formation of delocalized and emissive excitons that enable small non-
20 electrostatic interactions with the DNA are delocalized and followed by aquation to form the monoaqu
21 ined states to band-like charge transport in delocalized and hybridized states of strongly coupled QD
22 elding pattern implies the existence of both delocalized and localized currents that have a dominant
23 he self-assembly of diamondoids, form highly delocalized and symmetric electron-deficient structures.
25 kinase previously found to be overexpressed, delocalized, and constitutively active in CLL cells.
27 gy transfer mechanism leads to excitation of delocalized, anticorrelated vibrational wavepackets on t
28 that benzocarbatriphyrins are 14pai electron delocalized aromatic systems that bypass the fused arene
30 e for collective behavior of macroscopically delocalized atomic states, a crucial element for new pro
31 ewed as a tetravalent superatom forming four delocalized Au-H-Au bonds, similar to the quadruple bond
32 s (COEs), molecules that are defined by a pi-delocalized backbone and terminal ionic pendant groups,
33 the IR photons promote bound charge pairs to delocalized band states, similar to those formed just af
37 ed as either localized on one sulfur atom or delocalized between two indistinguishable sulfur atoms.
39 parameters that describes both localized and delocalized binding to various biological systems is use
40 in an effective Hamiltonian that couples the delocalized Bogoliubov modes of the two mechanical oscil
42 chemical bond is generally given in terms of delocalized bonding orbitals, or, alternatively, in term
44 Bonding and charge density analyses indicate delocalized bonding within the gold host and the (Au,T)3
46 a polarization of the pi electrons along the delocalized C2-C1-O system in the key cyclopropyl-carben
49 te that electrons exhibit both localized and delocalized character, with a maximum Curie constant and
50 in the droplets) yielding anions with highly delocalized charge [quantified by the weighted average p
51 nd physical or chemical properties of excess delocalized charge carriers in semiconductor nanocrystal
52 Photoexcitation leads to the formation of a delocalized charge resonance state (S1) that relaxes qui
54 ominated by molecular (Frenkel) exictons and delocalized charges are promptly produced (t < 100 fs).
56 charge separation involving intermolecularly delocalized charges in nonpolar media, an integral proce
57 nction as molecular wires with transport via delocalized charges, rather than the hopping mechanism t
58 omatic and antiaromatic molecules-which have delocalized circuits of [4n + 2] or [4n] electrons, resp
59 esults in electron localized Class II-III or delocalized Class III structures that display distinct N
60 y narrow asymmetric bands, characteristic of delocalized class-III bis(diarylamino) species, to narro
61 re discussed within the framework of a fully delocalized cluster exhibiting strong double and direct
62 ong contributions to the binding energy from delocalized, collective charge fluctuations-in contrast
64 -type) colloidal ZnO nanocrystals possessing delocalized conduction-band (CB) electrons can be formed
65 nanocrystals (NCs) involves recombination of delocalized conduction-band electrons with copper-locali
67 composed of localized quantum dot states and delocalized continuum states, arising from ultra-strong
68 f the two boron pz-type orbitals, with small delocalized contributions of the 9-borafluorenyl pi syst
69 model, on the superconducting side, one has delocalized Cooper pairs but localized vortices; while o
71 und that CT at the interface first populates delocalized CT excitons with a coherent size of 4 nm.
73 lts support a model of charge separation via delocalized CT states independent of excess heterojuncti
74 formulation of the CuA center as an electron-delocalized Cu(1.5)-Cu(1.5) system implicates both Cu(II
76 nitial bright singlet state (species I) to a delocalized dark state (species II), driven by interacti
78 I) borates, a Pu 6p orbital is observed with delocalized electron density on basal oxygen atoms contr
81 mplexes lead to highly coherent domains with delocalized electronic states displaying metallic behavi
83 s owe their optoelectronic properties to the delocalized electronic structure along their conjugated
84 ast ET and PT chemistry is attributed to the delocalized electronic structure of [Co(13)C(2)(CO)(24)]
85 (4)](2+) clusters typically exhibit pairwise delocalized electronic structures in which each Fe has a
87 p at the top of the occupied manifold of the delocalized electronic superatom spectrum of the inner c
88 pitaxial connections will lead to completely delocalized electrons and may enable the observation of
89 as YbAl3, interactions between localized and delocalized electrons can lead to fluctuations between t
90 highly stabilizing feature of molecules with delocalized electrons in closed circuits, is generally r
91 ational studies indicate that 2 features the delocalized electrons in the part of the sigma-framework
93 ysics supports this view, demonstrating that delocalized electrons make a static macroscopic polariza
94 ized status (e.g., polyaromatics), with more delocalized electrons obtained for enhanced Maxwell-Wagn
95 results demonstrate that the ability to add delocalized electrons to polyoxometalate clusters can be
99 ering alloys because it ensures that flow is delocalized, enhances tensile ductility and inhibits cat
100 ination of differently planarized and charge-delocalized enolate tautomers by anion-pi interactions.
102 find that on a 50 fs time scale an initially delocalized excess electron localizes on a single [Tf2N(
104 timize energy transport via the formation of delocalized excited states (excitons), which are critica
105 ceptor structures are observed to facilitate delocalized excited states for enhanced mixing between c
107 circular dichroism, superradiance, and fast delocalized exciton transfer, consistent with our quantu
108 l spectroscopic signatures of the multipolar delocalized exciton, including the S(2) <- S(1) electron
110 insights indicate the outstanding promise of delocalized excitonic processes available in 2D COFs, wh
112 cylinders' soft mesoscopic structure, robust delocalized excitons are retained: Internal order and st
113 r between clusters of a few pigments sharing delocalized excitons has been challenged by ultrafast op
116 , our analysis identifies a solvent exposed, delocalized Fe(2.5+) pair and a buried Fe(2+) pair.
117 he double exchange parameter, B, for valence-delocalized [Fe2S2](+) centers and demonstrate that vari
118 ) provide the only known examples of valence-delocalized [Fe2S2](+) clusters, which constitute a fund
119 rve as a sensitive probe for correlations in delocalized fermionic quantum states and for quantum met
121 cked orientation results in the emergence of delocalized Frenkel/mixed-Frenkel-CT character and the c
123 ype claudin-16, phosphomimetic claudin-16 is delocalized from the tight junction but relocated to the
124 ional results indicate a unique role for the delocalized frontier molecular orbitals of the Fe(NO)2 u
125 d to increase electron affinity and maintain delocalized frontier orbitals while significantly decrea
127 AM, but do not produce large, electronically delocalized groups or change other aspects of the tunnel
128 re carried out to determine how localized or delocalized holes on a polymer chain are and to compare
129 otogeneration occurs predominately via these delocalized hot exciton states in competition with relax
130 arge generation across large polymer phases, delocalized hot excitons may also account for the crucia
131 vent-exposed hydrophobic cluster and another delocalized hydrophobic core in the folding kinetics, ar
132 , and those whose O-H stretch vibrations are delocalized, i.e., shared between multiple O-H bonds.
135 phy suggests that the unpaired electrons are delocalized in each case across two inner 4,4'-bipyridin
136 ules showed that their pi electrons remained delocalized in individual benzenoid-type rings rather th
138 a Ni(III) complex with one unpaired electron delocalized in the ligands surrounding the metal center.
139 that a significant fraction of the charge is delocalized in the tert-butyl group of the radical catio
140 ed molecular orbital (LUMO) band is strongly delocalized in two-dimensions, which is unprecedented fo
141 duced structural changes result in local and delocalized increases in Tpm flexibility and prominent c
142 oring HRAS, NRAS or KRAS mutations, SCH66336 delocalized, inhibited signaling and preferentially inhi
143 r interaction with Ag (or Cu) as involving a delocalized interaction with contributions from the carb
144 molecular nature of the exciton and the more delocalized intermolecular nature of electrons and holes
145 he radical cation in the ring-closed form is delocalized into the phenyl ring, and/or (ii) the lowest
150 the ground state of the drug shows a highly delocalized lone pair on the amine nitrogen of the melph
151 ork, previously shown to give rise to highly delocalized low-lying (3)MLCT states for other Group VII
152 oxygen-induced trap level, 0.34 eV below the delocalized lowest unoccupied molecular orbital of P(NDI
153 ) Mes, including a low-lying and extensively delocalized LUMO and a wide HOMO-LUMO gap, which arise f
156 ximal tryptophan (0.4 ps) and is followed by delocalized migration of the produced WH(*+) radical alo
159 ipolar and quadrupolar electric and magnetic delocalized modes, only dipolar electric and quadrupolar
160 mpounds correlated well with the energy of a delocalized molecular orbital first appearing on an arom
161 overturn the well-known conclusion that both delocalized molecular orbitals and localized molecular o
163 into the origin of the far-IR localized and delocalized motions present in peptides and where they c
164 ranched donor-acceptor molecules varies from delocalized/multipolar to localized/dipolar depending on
166 functional theory calculations highlight the delocalized nature of the low energy singlet excited sta
167 studies have been complicated by the highly delocalized nature of the porphyrin, and calculations re
170 xygen lone pair on flat sites, whereas it is delocalized on both C and O atoms on concave sites, incr
171 e cyclohexene-bridged Z-derivatives are spin-delocalized on the EPR time scale but charge-localized o
172 he magnetic interaction between the electron delocalized on the fullerene cage and the guest H2 has b
173 r C-S bond cleavage, and the charge and spin delocalized on their structures, were also useful to end
175 ulations demonstrate that the electron spins delocalized onto the thiophene unit lead to the accelera
177 ws that the photogenerated plasmon is highly delocalized onto TiO2, and thus, it is shared by the ele
178 on the possible role of charge transfer and delocalized or excitonic states in the photophysics of t
182 and IR spectra indicates that the polaron is delocalized over 2-3 porphyrin units in the linear oligo
183 sfer includes the fact that the excitons are delocalized over a few neighboring sites, but the role o
184 ons, it is proposed that the MLCT states are delocalized over both benzoate Cr(CO)(3) groups, as supp
186 ying states, in which molecular orbitals are delocalized over Chl(D1) and Phe(D1) as well as one weak
191 ound 2, the unpaired electron is also partly delocalized over the CAAC ligand (carbene) C and N atoms
192 The unpaired electron in this molecule is delocalized over the entire helical core composed of six
195 ex suggests the formation of a radical anion delocalized over the neighboring PDI units, and this res
197 One of these VTs has the charge and spin delocalized over the porphyrin and the styrylruthenium m
199 but for P-TMI the NTOs have electron density delocalized over the two units as a result of extensive
202 les of sigma-bonds made of a single electron delocalized over two neighboring atoms were until recent
203 s, the excess charge carrier forms a polaron delocalized over up to 10-20 molecules in the most condu
206 smaller electronic couplings for the highly delocalized P3DT anions as enabling the inverted behavio
208 as from single-molecule spectroscopy, single delocalized pai-electron dye systems are isolated in rel
209 that both ReB(4)(-) and ReB(4) possess four delocalized pai-electrons, including two pai-electrons i
210 oelectronic properties owing to their highly delocalized pai-systems, low-lying frontier orbitals tha
211 s is especially so in systems of interacting delocalized particles, for which a direct experimental m
215 theoretical model that explores how coherent delocalized phonon-like modes in DNA provide single-stra
216 results support the conclusion that coherent delocalized phonon-like modes play an important role in
217 by invoking exciton self-trapping, in which delocalized photogenerated holes contract in response to
218 re doubly aromatic, each with six completely delocalized pi and sigma electrons, which describe the b
219 e highly stable and doubly aromatic with six delocalized pi and six delocalized sigma electrons and s
220 und to exhibit triple pi aromaticity with 11 delocalized pi bonds, analogous to benzo(g,h,i)perylene
221 ation indicated the feasibility of combining delocalized pi electrons and spin-polarized d electrons
223 closed-shell B(22)(2-) species reveal seven delocalized pi orbitals, which are similar to those in a
226 ent with charge separation through access to delocalized pi-electron states in ordered regions of the
227 posite design by the incorporation of both a delocalized pi-electrons system in a closely bound accep
228 carbon basal plane, conferred upon it by the delocalized pi-electrons, (i) causes a downshift of e(g)
229 BODIPY core is feasible, a hemicyanine-like delocalized pi-system gives rise to novel blue and effic
235 ton-localization microscopy reveals that the delocalized plasmons are capable of focusing multiple na
236 ormation of e(-) and h(+) pairs that lead to delocalized polaronic V(3+) and V(5+) cation states.
237 the core-localized electron density, highly delocalized polarons with mobilities equivalent to films
239 nodal excitations from gapped (localized) to delocalized quasiparticles characterized by a longer lif
240 upon deprotonation is largest when a highly delocalized radical is combined with an initially less s
244 CD saturation magnetization data for valence-delocalized S = 9/2 [Fe2S2](+) centers facilitated deter
245 and investigating the properties of valence-delocalized S = 9/2 [Fe2S2](+) fragments in higher nucle
246 imilar valence-localized S = 1/2 and valence-delocalized S = 9/2 forms as a function of pH, with pKa
247 s in partial or full conversion from valence-delocalized S = 9/2 to valence-localized S = 1/2 [Fe2S2]
248 rates that are characteristic of a circular delocalized S(1) excited state are preserved in the low-
250 e observation that mixed-valence para-Fe2 is delocalized shows that electron localization in meta-Fe2
251 he all-boron fullerene, bonded uniformly via delocalized sigma and pi bonds, is not perfectly smooth
252 hey satisfy the 4n+2 rule of aromaticity for delocalized sigma electrons and fulfill other requiremen
253 bly aromatic with six delocalized pi and six delocalized sigma electrons and should exist for a serie
255 es at the Au-thiol interface, and not by the delocalized sigma states in the C-C backbones, clarifyin
256 perature, long-range incoherent transport of delocalized singlet excitons on pico- to nanosecond time
257 ry photoexcitations in conjugated dimers are delocalized singlets that enable fast and efficient iSF.
258 re therefore converted into relatively inert delocalized species A(*) and/or B(*) that inhibit the ch
259 ronic structure with an unexpected partially delocalized spin, as evidenced by electron paramagnetic
261 Cu-Cu spectroscopic features, and a valence delocalized state of Cu(A) are difficult to reproduce in
263 nfined state and a nearby Fermi reservoir of delocalized states has underpinned many advances in spin
264 onally to localized surface states or to the delocalized states of the QD core, (ii) energy or electr
265 fur ions on the surfaces of the QDs (and not delocalized states within the QDs) are the electron dono
269 lecular systems containing an electronically delocalized structure are the basis of emerging optoelec
270 rporation of targeting moieties into the non-delocalized structure of pentamethine and heptamethine i
271 high-quality DFT calculations, a symmetric, delocalized structure with no difference in bond length
273 th possess a 13-atom icosahedral core with 8 delocalized superatomic electrons (8e), but their emissi
274 ity of electronic structure in this strongly delocalized superchromophore and reflect the complicatio
275 esonances transitions to that from spatially delocalized surface plasmon excitations, exhibiting mult
276 the addition and removal of electrons from a delocalized system should lead to considerable increases
278 r complex (1(2-)) featuring an extended, pai-delocalized, tetra-amidate macrocyclic ligand (TAML) as
279 eutral triplet exciton is substantially more delocalized than the positive polaron, exceeding 10 mono
281 boron atoms in the dihydrides are bonded by delocalized three-, four-, or five-center sigma and pi b
282 en-shell molecules, in which spin density is delocalized through a helical conjugated backbone, hold
283 ybrid theory, the parent radicals of AOs are delocalized through allylic rearrangement, and as a cons
284 isotopic labeling shows that the radical is delocalized throughout the adenine ring of A2503, althou
288 ocenyl cations, the transition from a charge delocalized to a localized state is addressed by resonan
290 h transiently expressed SEC6A1A variants are delocalized to the Golgi, a finding confirmed in a renal
297 monoradicals, based on either a localized or delocalized view, whichever is suitable, are then discus
299 converge toward a picture of electrons being delocalized within crystalline domains of increased size