ライフサイエンスコーパス: demethyl

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1 nhibitor Ro-31-8220, or the calcium chelator demethyl-1,2-bis(2-aminophenoxy)ethane-N,N,N',N'-tetraac

2 anilino)-4-desoxypodophenazine (13) and 4'-O-demethyl-2'',3''-dichloro-4beta-(4-'''-nitroanilino)-4-

3 18-20, 26), 4-alpha-disubstituted-anilino-4'-demethyl-4-desoxypodophyllotoxin (27), 4-beta-trisubstit

4 otoxin (25), 4-beta-disubstituted-anilino-4'-demethyl-4-desoxypodophyllotoxins (18-20, 26), 4-alpha-d

5 studies, several new 4-beta-substituted 4'-O-demethyl-4-desoxypodophyllotoxins bearing mono-, di-, or

6 )anilino]-4-desoxypodophyllotoxin (21), 4'-O-demethyl-4beta-(-)-(4' '-camphanamido-anilino)-4-desoxyp

7 Among these, 4'-0-demethyl-4beta-(4'''- nitroanilino)-4-desoxypodophenazin

8 The target compounds include 4'-O-demethyl-4beta-[(4' '-(benzimidazol-2' '-yl)anilino]-4-d

9 hyl-desoxypodophyllotoxin (22, 23), and 4'-O-demethyl-4beta-[4' '-(benzimidazol-2' '-yl)amino]-4-deso

10 strain produced 6-deoxyerythronolide B and 2-demethyl-6-deoxyerythronolide B.

11 ocyclines, 7-fluoro-9-pyrrolidinoacetamido-6-demethyl-6-deoxytetracycline (17j, also known as TP-434,

12 tibacterial agents, 7-fluoro-9-substituted-6-demethyl-6-deoxytetracyclines ("fluorocyclines"), access

13 The analogues are iso-FAD (8-demethyl-6-methyl-FAD), 6-amino-FAD (6-NH(2)-FAD), 6-bro

14 the bicyclic isorhodopsin analogue, while 5-demethyl-8-methylisorhodopsin more closely followed nati

15 etinal (a 6-s-trans-bicyclic analogue), or 5-demethyl-8-methylretinal.

16 describes the synthesis of deamidobleomycin demethyl A(2) (3) and deamido bleomycin A(2) (4), as wel

17 pha-demethylation of obtusifoliol and its 24-demethyl analog 4alpha-,4alpha-dimethylcholesta-8,24-die

18 (11) and several 4beta-anilino-2-fluoro-4'-O-demethyl analogues were synthesized and evaluated in bot

19 thyl visual pigments and could explain why 5-demethyl artificial pigments regenerate so slowly.

20 pletely discounted, it is unlikely that this demethyl-ation reaction involves RNA cofactors or ribozy

21 The stability of 5-demethyl Batho, even though the C8-hydrogen of the polye

22 nd its application to the total synthesis of demethyl calamenene, a potent cytotoxic agent against hu

23 toxin (27), 4-beta-trisubstituted-anilino-4'-demethyl-desoxypodophyllotoxin (22, 23), and 4'-O-demeth

24 NB506), camptothecin-(para)-4beta-amino-4'-O-demethyl Epipodophyllotoxin (W1), and camptothecin-(orth

25 ), and camptothecin-(ortho)-4beta-amino-4'-O-demethyl Epipodophyllotoxin (W2)] on cleavable complex f

26 Except for the sugar, 4'-demethyl epipodophyllotoxin is identical to etoposide, e

27 eries of 4beta-[(4' '-benzamido)-amino]-4'-O-demethyl-epipodophyllotoxin derivatives (11-23) were des

28 rified form that later can be differentially demethyl esterified by pectin methyl esterase (PME) to s

29 thylation of the C-31 hydroxyl group of 31-O-demethyl-FK506 and FK520.

30 The gene encoding 31-O-demethyl-FK506 methyltransferase, fkbM, was isolated fro

31 n MA6548 yielded a mutant that produced 31-O-demethyl-FK506, confirming the involvement of the isolat

32 nd resulted in the formation of 9-deoxo-31-O-demethyl-FK506.

33 inal intermediate in the pathway, converting demethyl-Q to Q.

34 responding to the second O-methylation step, demethyl-Q(3) and Q(3), have been chemically synthesized

35 Both yeast and rat Coq3p recognize the demethyl-Q(3) precursor as a substrate.

36 urthermore, the absorption spectrum of the 9-demethyl retinal regenerated pigment exhibits a band bro

37 roteins expressed in COS cells with 11-cis 9-demethyl retinal, where the 9-methyl group on the polyen

38 stitution of the triple mutant with 11-cis-9-demethyl retinal.

39 Certain cis-isomers, 11-cis-13-demethyl-retinal and 9-cis-C17 aldehyde, were also activ

40 ) of SAM, and creatine (methyl-GAA) and SAH (demethyl-SAM) are produced.

41 d account for the unexpected blue shift of 5-demethyl visual pigments and could explain why 5-demethy

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