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1 -shielded) and one common unbound state (FMN-deshielded).
7 N1-methylation and then dramatically further deshielded by more than 100 ppm on formation of the 1,4-
8 The chemical shift of the amino nitrogen was deshielded by N1-methylation and then dramatically furth
9 dentical withC) orbital, explaining the more deshielded chemical shift values; it also leads to an in
10 60)H(18), previously reported) are unusually deshielded compared to "ordinary" organic compounds, pre
11 (19)F NMR spectra of 1b and 1c were strongly deshielded compared with those of the ring-opened compou
13 plex indicates covalent N-H bonding, and the deshielded delta (15N) indicates a significant contribut
14 lectron-accepting) conformation over the FMN-deshielded (electron-donating) conformation to a much gr
19 gnal at 16.1 ppm, and a 640 Hz broad, highly deshielded proton resonance with a chemical shift delta
20 short, strong hydrogen bond, i.e., a highly deshielded proton resonance, bond length of 2.64 +/- 0.0
22 complex results in the appearance of several deshielded proton resonances, including one at 14.9 ppm
23 ase induces the appearance of two additional deshielded proton resonances, one at 18.2 ppm assigned t
24 ly show a relationship between exceptionally deshielded protons beta to a benzene ring in C(60)H(18)
25 te to isomerase, proton NMR detects a highly deshielded resonance at 18.15 ppm in proximity to aromat
26 .4 ppm signal and the appearance of a broad, deshielded resonance of equal intensity with a chemical
27 of free BChE at pH 7.5 showed a broad, weak, deshielded resonance with a chemical shift, delta = 16.1
28 of the active-site serine, which showed two deshielded resonances of equal intensity at 16.5 and 15.
29 at pH 7.5, and subsequent deethylation, two deshielded resonances of unequal intensity appeared at 1
30 0 +/- 0.4) resulted in the appearance of two deshielded resonances, at 17.7 and 16.4 ppm, consistent
31 MR spectrum for Y3N@C2-C78 exhibits strongly deshielded signals for the fullerene cage (155-170 ppm)
32 the rate of conformational change to the FMN-deshielded state differed between eNOSr and nNOSr and wa
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