ライフサイエンスコーパス: desired product

1 s (but unexpected) atropisomerization to the desired product.

2 thylmorpholine, the same reaction affords no desired product.

3 by electrophilic cyclization to deliver the desired product.

4 ffer pH 10, room temperature) to release the desired product.

5 ithin the specific biosynthetic pathway of a desired product.

6 ate triester, followed by elimination of the desired product.

7 llowed by elimination of water generates the desired product.

8 seen to have the highest selectivity for the desired product.

9 rmediate with an ArX led to formation of the desired product.

10 s, and oxidization of cysteines to yield the desired product.

11 termediate and improve the final titers of a desired product.

12 roups contained in both the reactant and the desired product.

13 corresponding 2-aminopyranose results in the desired product.

14 generated in situ, cyclization afforded the desired product.

15 n products that includes, at low levels, the desired product.

16 eld and only small amounts (< or =2%) of the desired product.

17 rification process can be used to obtain the desired product.

18 egulated to produce a significant yield of a desired product.

19 g employed and progress achieved towards the desired product.

20 olefins (10 and 11) gave poor yields of the desired products.

21 and convert multiple target molecules to the desired products.

22 r selection of iodide substrates to generate desired products.

23 ega-chloro or omega-bromo derivatives to the desired products.

24 e NEt(3)H(+) and NMe(4)(+) yield none of the desired products.

25 the reactions to completion and isolate the desired products.

26 heir concentrations can impact the yields of desired products.

27 ysis and deprotection procedures to give the desired products.

28 d to be ineffective for the synthesis of the desired products.

29 , which metabolizes soluble saccharides into desired products.

30 e more reactive, giving higher yields of the desired products.

31 C18 columns separated excess reactants from desired products.

32 s for the reduction of carbon dioxide to the desired products.

33 e and suitable for scale-up synthesis of the desired products.

34 the cycloaddition reaction and provided the desired product 26a in 78% yield.

35 using a Lewis acid and Et(3)SiH to give the desired product 3 in good overall yield of ( approximate

36 The desired product, 3-ethynyl-L-tyrosine, was released from

37 ith both a solubility similar to that of the desired products and a tendency not to crystallize.

38 ntensity ratios of ions corresponding to the desired products and the primer-template complexes.

39 Under the reaction conditions, the desired products are delivered in high yields with ee va

40 Therefore, the desired products are easily recovered with consistently

41 The desired products are formed in up to 90% yield and >99:1

42 Desired products are isolated in 63-97% yield and 73.5:2

43 The desired products are obtained in 44 to 92% yield, and in

44 The desired products are obtained in 63-95% yield and 91:9 t

45 ines are difficult coupling partners and the desired products are often produced in low yields.

46 ch essential enzymes divert flux away from a desired product, as well as in the production of polyket

47 protonated with a suitable base to yield the desired product, [B20H17SH]4-.

48 s predicted by FBA to increase production of desired products, but GDBB has only been available on a

49 gime, which is aimed at linear growth of the desired products, can also produce artifacts by exponent

50 ion of biologics are essential to ensure the desired product characteristics.

51 uration associated with hydrogenation to the desired product cinnamyl alcohol.

52 olysis of unsubstituted benzamidine, and the desired product could not be isolated, apparently becaus

53 From the monomers, the desired product dendrimer--the last uncommitted intermed

54 idene-containing deactivation product or the desired product depending on the reaction conditions.

55 th substrate enantiomers react to afford the desired product diastereomers in high stereoselectivity.

56 clic carbene (NHC) complexes, furnishing the desired products efficiently (66-97% yield of isolated p

57 of controlling Mo speciation to achieve the desired product formation, which has important implicati

58 he examined production host for enabling the desired product formation.

59 ese two opposing forces is mandatory for the desired product formation.

60 selectivity without compromising the rate of desired product formation.

61 it only specific types of sites required for desired product formation.

62 result, further purification to separate the desired product from uncomplexed (68)Ga is not necessary

63 es and dramatically increases selectivity to desired products furfuryl alcohol and methylfuran.

64 derwent reductive cyclization to provide the desired product in 60% yield.

65 ehydes were examined and found to afford the desired product in good overall yield with high enantio-

66 /decarboxylation sequence that furnished the desired product in good yield.

67 by 16G3 (22-fold) was sufficient to form the desired product in greater than 90% yield.

68 The reaction produced the desired product in high isolated yields using a wide ran

69 anthracene-tagged boronic acid to yield the desired product in high purity and yield without the use

70 t loadings as low as 2.5 mol % Ni afford the desired product in high yield in both gram-scale and sma

71 xoaldehyde and thiols through iminium to the desired product in moderate to good yields.

72 been used to determine that a portion of the desired product in the Pd-catalyzed fluorination of elec

73 s were easy to perform affording most of the desired products in 33-93% yields.

74 cid residues was carried out to generate the desired products in 47-88% yield and 90:10 to >98:2 Z:E

75 reated with trimethylaluminum, affording the desired products in 68-97% yields (22 examples).

76 ketone precursors could directly lead to the desired products in a single operation while the reactio

77 etric hydrogenation conditions affording the desired products in excellent enantio- and diastereosele

78 lable amino acid-based ligand and afford the desired products in excellent yields and in up to 95% ee

79 lic enamines efficiently, thus affording the desired products in excellent yields with excellent ster

80 examined for this transformation, providing desired products in good to excellent yield.

81 This eco-friendly approach afforded the desired products in good to excellent yields in only 10

82 ld conditions and facile purification of the desired products in good to excellent yields.

83 i products at room temperature to afford the desired products in good to excellent yields.

84 ole (95/5) for 1.5 h at 0 degrees C gave the desired products in good yield and purity.

85 lfenyl and (R)-toluenesulfinyl providing the desired products in good yields as crystalline intermedi

86 newly designed quinidine dimer to afford the desired products in good yields with enantioselectivitie

87 e and nitroolefin substrates and provide the desired products in good yields with enantioselectivitie

88 mployed in this transformation providing the desired products in good yields.

89 tide with FeSO(4).7H(2)O in DMF afforded the desired products in high purities (73-94%).

90 is step is followed by oxidation to give the desired products in high yield on scales of up to 25 g.

91 lly proceed within one hour, and deliver the desired products in high yields and enantiomeric ratios.

92 es in the presence of Yb(OTf)3 to afford the desired products in high yields.

93 ng indole, indoline, and indazole afford the desired products in moderate to high yields.

94 under relatively mild conditions, afford the desired products in moderate yields.

95 This two-step procedure afforded the desired products in overall yields of 5-36%, and it tole

96 The one-pot sequence affords the desired products in significantly higher yields than our

97 give rise to efficient ARCM and deliver the desired products in the optically enriched form.

98 mol % of the alkylating agent to afford the desired products in up to >98 % yield with >98 % anti-Ma

99 s complete within four hours, furnishing the desired products in up to 77 % overall yield and 99:1 en

100 e addition of an allyl moiety and afford the desired products in up to 83 % yield and 98:2 enantiomer

101 in situ-generated iminium ions provides the desired products in up to 96% yield.

102 tified along the pathway to formation of the desired product, including isomeric di-, tri-, and tetra

103 Thus, achieving selective release of the desired product is crucial for improving the process eco

104 t is strongly hindered, whereas that for the desired product is lowered in energy.

105 and entirely nonselective in cases where the desired product is observed.

106 zation to provide a much higher yield of the desired product, lactonized phosphotriester 5.

107 entury is to achieve 100% selectivity of the desired product molecule in multipath reactions ("green

108 ion reaction, with measurable amounts of the desired product observed only when THF was utilized.

109 challenges originate from the fact that the desired product of the combined process is formed by a b

110 , and secondary sulfonamide also provide the desired products of esters, ethers, thioether, and terti

111 isomers, including 2- or 3-methylpentane, as desired products of n-hexane isomerization (140 Torr n-h

112 e catalyst poisons, the reaction rate to the desired product on a catalyst coated with a thiol was 40

113 The formation of the desired products relies on C-H bond cleavage from this a

114 ' (usually a functional) group to obtain the desired product selectively.

115 alyst surface is essential for achieving the desired product selectivity.

116 that purification must be used to obtain the desired products, titers of which are typically low and

117 ethod prevents spontaneous conversion of the desired products to the thermodynamically favored bisind

118 ted and exchanged for benzene to produce the desired product TpW(NO)(PMe3)(eta(2)-benzene) in either

119 ial role in achieving quantitative yields of desired products under metal-free conditions.

120 n palladium has been found that leads to the desired products under mild conditions and in high yield

121 yst design and achieve high selectivities to desired products.Understanding the mechanism of CO2 redu

122 ly designing a precursor that would form the desired product upon low-temperature annealing, which al

123 Isolated yields of desired products using Bi(OTf)(3) were compared with yie

124 veral cases, the p-bromobenzoate salt of the desired product was directly isolated from the reaction

125 In contrast, an enhanced rate toward the desired product was found for PRO-Pt in comparison to th

126 with DPPA as no or only trace amounts of the desired products were observed with other metal complexe

127 withdrawing groups at the substrates and the desired products were obtained in good to excellent yiel

128 anisole (95/5) for 1.5 h at 0 degrees C, the desired products were obtained in good yield and purity.

129 terminal oxidant provides good yields of the desired products with reaction times significantly reduc