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1 ract a hydrogen atom from the C9 position of dethiobiotin.
2 e to produce carbon radicals at C9 and C6 of dethiobiotin.
3 yme that catalyzes the addition of sulfur to dethiobiotin.
4 hydrogen atoms at the C9 and C6 positions of dethiobiotin.
5 drogen atoms from the C6 and C9 positions of dethiobiotin.
6 o saturated C6 and C9 atoms in the substrate dethiobiotin.
7 m between the saturated C6 and C9 carbons of dethiobiotin.
8 m between the saturated C6 and C9 carbons of dethiobiotin.
9 atom into the saturated C6 and C9 carbons of dethiobiotin.
10 n synthesis requires incubation of BioB with dethiobiotin, AdoMet, reductants, exogenous iron, and cr
11 ]2+ cluster located approximately 4-5 A from dethiobiotin, and we have proposed that a bridging sulfi
12 rgonic acid (DAPA) or to ADP and the product dethiobiotin (DTB) permitted derivation of an enzyme mec
13 Biotin synthase catalyzes the conversion of dethiobiotin (DTB) to biotin through the oxidative addit
14 s the oxidative addition of a sulfur atom to dethiobiotin (DTB) to generate the biotin thiophane ring
15 s the oxidative addition of a sulfur atom to dethiobiotin (DTB) to generate the biotin thiophane ring
16 catalyzes the formation of the cyclic urea, dethiobiotin (DTB), from (7R,8S)-diaminononanoic acid (D
17 in complex with S-adenosyl-L-methionine and dethiobiotin has been determined to 3.4 angstrom resolut
18 inserting a sulfur atom between C6 and C9 of dethiobiotin in an S-adenosylmethionine (SAM)-dependent
19 a mechanism for incorporation of sulfur into dethiobiotin in which a sulfur atom is oxidatively extra
22 o sustain growth of a bioB- mutant strain on dethiobiotin-supplemented medium, suggesting the enzymes
24 largonic acid aminotransferase (DAPA-AT) and dethiobiotin synthetase (DTBS) catalyze the antepenultim
26 -diaminopelargonic acid synthase (DAPAS) and dethiobiotin synthetase (DTBS), at respective resolution
27 n which each bifunctional monomer contains a dethiobiotin synthetase-like amidoligase N-terminal doma
29 ion of sulfur between the C6 and C9 atoms of dethiobiotin to complete the thiophane ring of biotin.
31 product of the BioA-catalyzed reaction into dethiobiotin, which is subsequently detected by displace
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