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1 ues that provide copper ligands is partially deuterated.
2 not be excluded; experiments with partially deuterated 1,3-butadiene indicate the formation of the t
5 dditional [1-(13)C,2-(2)H]-GA and the doubly deuterated [1-(13)C,2,2-(2)H(2)]-GA formed in the unacti
6 6.8449(2) A, and V = 894.61(3) A3 [rho(calc)(deuterated) = 1187.56(4) kg m(-3)] at 502 MPa, 180 K.
7 inverse kinetic isotope effect observed with deuterated 1S, the identification of unprecedented dihyd
10 Moreover, incubations of cell lysates with deuterated (2E)-hexadecenal revealed that no hexadecanoi
11 topologue approach using both protonated and deuterated 4,4'-bipyridine molecules demonstrates the si
16 experimentally by the observation of doubly deuterated acetic acid (CH2DCOOD), when D2O is introduce
17 and anisotropic Raman spectra of acetone and deuterated acetone isolated in an argon matrix have been
19 e analogous alkyl orthoester is treated with deuterated acid, is established utilizing the novel orth
21 dent (2)H quadrupolar splittings from methyl-deuterated alanines and one (15)N amide chemical shift a
22 ALALALWWA-ethanolamide and included pairs of deuterated alanines by using 60-100% Fmoc-l-Ala-d(4) at
24 If deuterated alcohol (EtOD or MeOD) or D2O/deuterated alcohol is used as an electrospray solvent, t
27 tron scattering length densities, the use of deuterated alpha-syn versus protiated GCase showed a lar
29 y diverse beta-chiral amines, including beta-deuterated amines, in excellent yields with high enantio
30 -gas through a container filled with aqueous deuterated ammonia reagent (ND3/D2O) and admitting the s
33 nt method based on the TAM core CT-03 or its deuterated analogue dCT-03 and trifurcated Newkome-type
34 romethazine, enalapril, and verapamil) using deuterated analogues of these drugs as internal standard
40 ase transitions of the deuterated, partially deuterated and hydrogenous organic-inorganic hybrid pero
43 ross-linking strategy, using lysine-specific deuterated and nondeuterated bis(sulfosuccinimidyl)suber
48 ior that is intermediate between that of the deuterated and undeuterated perovskite, due to extrinsic
49 samples of a wild-type GPCR (A2AR) that are deuterated apart from (1)H/(13)C NMR probes at isoleucin
51 -sn-glycero-3-phosphocholine was selectively deuterated at methylene segments C-2, C-7, and C-16 of t
52 soquinolines, and pyridines were efficiently deuterated at specific positions with high selectivity;
53 rate that replacing vitamin A with vitamin A deuterated at the carbon 20 position (C20-D3-vitamin A)
54 ion NMR experiments to study the dynamics of deuterated backbone alpha-positions, D(alpha), are devel
57 states of self-assembled, stereoselectively deuterated benzene-1,3,5-tricarboxamides ((S,S,S)-D-BTAs
58 etralutidine XB acceptor, the association in deuterated benzene/acetone/methanol 70:30:1 at 283 K rea
59 extended for the selective synthesis of C-4 deuterated benzothienopyridines 7u-v and benzofuropyridi
60 thalene is suggested by studies of partially deuterated benzylallene, which blocked naphthalene forma
61 R data acquired with samples prepared with a deuterated biphenylene rotator and a natural abundance s
62 t time we show that increasing the number of deuterated bis-allylic carbons to include both C10 and C
64 samples were first stressed in protonated or deuterated buffer (pH 8 or 9) at 40 or 50 degrees C stor
70 d OH oxidation of unsubstituted (C10H16) and deuterated (C10H13D3) alpha-pinene are investigated usin
71 In this work, the solution structure of the deuterated Ca(2+)-CIB1 protein complexed with an alphaII
73 n not only indicate metabolic activity using deuterated carbon sources but also reveal different meta
74 ate, studies examining NADPH production with deuterated carbon sources have failed to account for rou
81 ure cholesterol proximity to M2 while sterol-deuterated cholesterol was used to measure bound-cholest
82 uterated (C24:0) fatty acids and selectively deuterated cholesterol, the diffraction data obtained we
86 nducted with 1,3-butadiene and two partially deuterated counterparts (1,1,4,4-D4-1,3-butadiene and 2,
87 ation of classes of compounds in cases where deuterated counterparts are either not available or expe
88 moreover, methods for the addition of their deuterated counterparts typically require special techni
89 ossover experiments with selenide 12 and its deuterated crotyl analogue 27 indicated an intramolecula
92 Whole senescent cells were then treated with deuterated D(3)-acrylamide, and control cells were treat
93 jugated polymers made of protonated, H-, and deuterated, D-hydrogen having a weaker HFI strength.
94 ation of intact Chlamydomonas cells with per-deuterated D31-16:0 (palmitic) acid yielded D31-18:0 (st
95 ere repeated where the DPPC acyl chains were deuterated (D62-DPPC), allowing spectral resolution of t
96 driving force in the oxidation of partially deuterated DEK, the 1,2-acyl group migration is observed
98 In this paper we report the synthesis of a deuterated derivative of phosphonated trityl radical, pT
99 bipolar organic spin valve (OSV), based on a deuterated derivative of poly(phenylene-vinylene) with s
100 raordinary low line width of the synthesized deuterated derivative, p1TAM-D (DeltaHpp </= 50 mG, Lore
102 ved mass spectra as well as experiments with deuterated dibutylamine helped to unravel the mechanism
104 yl ketone (DTbuK), and a series of partially deuterated diethyl ketones (DEK) is studied in the gas p
105 thylamino)styryl-4H-pyran (DCM) laser dye in deuterated dimethyl sulfoxide and its excited state rela
110 antiomer is antitumorigenic, whereas the (+)-deuterated enantiomer has little to no effect on tumor g
114 quent stable isotope labeling analysis using deuterated ethanol determined that NAT is a novel metabo
116 went facile, reversible ligand exchange with deuterated ethylene at 298 K, and ethylene ligands were
117 rption (TPD) experiments were conducted with deuterated ethylene glycols for comparison with DFT resu
119 solely responsible for the FLIT signal, and deuterated FLIT peptide provided an internal standard th
120 s resulting from exposure of filter-adsorbed deuterated fluoranthene to N2O5/NO3/NO2 and that collect
121 n C(6)F(5)H and C(5)F(5)N, (ii) formation of deuterated fluoroarene products when reactions are perfo
122 ured maps of atmospheric water (H2O) and its deuterated form (HDO) across the martian globe, showing
123 tituting the salts used for LC-MS with their deuterated form shifts the mass of PCs by the number of
124 expensive isotopic reagents ((18)O water and deuterated formaldehyde) and requires no postlabeling cl
126 ituting protiated LC-MS additives with their deuterated forms provides a way to distinguish PCs and P
128 dial-soup Miller-Urey style experiments with deuterated gases and reagents to compare the spark-disch
129 deuterium-labeled internal standards (triply deuterated GHRP-4 and GHRP-2 metabolite) were used to op
130 c clamp, with a primed, constant infusion of deuterated glucose and infusion of 20% dextrose as requi
131 an spectra (SCRS) when Escherichia coli used deuterated glucose and Pseudomonas sp. used deuterated n
132 f deuterated naphthalene compared to that of deuterated glucose was observed, presumably owing to dif
133 gion, generating electrons that reacted with deuterated glycerol, C(3)D(5)(OD)(3), to produce D atoms
134 peak shifts observed in the THz spectrum of deuterated glycine in heavy water, which allow us to sep
136 mixtures of racemic mono- and prochiral bis-deuterated glycine-2-(13)C were resolved and well simula
138 d compared isotope effects using natural and deuterated glycolate in either natural or deuterated sol
140 n of the reaction products (hydrogenated and deuterated graphene) was carried out by thermogravimetri
141 nsfer pathways of PS I in whole cells of the deuterated green alga Chlamydomonas reinhardtii using hi
144 stinct F sites in a 50% fluorine-substituted deuterated hydrous magnesium silicate (clinohumite, 4Mg(
145 synthesis of substituted indenes selectively deuterated in position 3, which are rare in literature.
147 s of cocaine (COC) from brain tissue using a deuterated internal standard (COC-d(3)) combined with wi
148 ent parameters, including comigration with a deuterated internal standard or in silico prediction of
151 xycodone, clozapine, and buspirone and their deuterated internal standards using the matrix 3-nitrobe
156 amide (DAM-57), an ergot derivative, and its deuterated isotopologues; we also provide theoretical pr
161 oaches to simultaneously quantify native and deuterated lipid products, we were able to demonstrate t
163 tion, were identified by specific binding of deuterated liposomes to antibodies directed against amyl
164 sly prepared isotopically labeled protein to deuterated lysates, rendering the biological environment
165 h an approach that combines the synthesis of deuterated materials, optoelectronic properties measurem
167 tions with dimethylallyl derivatives bearing deuterated methyl groups at the distal (C3) carbon atom
168 e shape experiments performed on selectively deuterated methyl groups, we probed the 3-fold symmetric
169 (2)H NMR relaxation performed on selectively deuterated methyl groups, we probed the dynamics in the
170 on-Optimized Spectroscopy (TROSY) and highly deuterated, methyl-protonated samples to study the 230 k
172 eference points from linear regressions of a deuterated n-alkanes reference system was introduced, pr
173 rational C-D frequency shifts of solubilized deuterated n-hexane confirm that it resides in a dry, oi
177 nd, the primary kinetic isotope effects from deuterated nicotinamide nucleotides confirm that hydride
180 ibrational frequencies of deuterated and non-deuterated PA in the gas phase and in various solvents (
183 ures and structural phase transitions of the deuterated, partially deuterated and hydrogenous organic
185 ted ion drift time distributions (XIDTDs) of deuterated peptic peptides are mobility-matched to corre
188 ther investigated PFD and long-acting form, "deuterated PFD," immune-modulating properties by evaluat
189 s reaction offers a catalytic route to ortho-deuterated phenylacetic acids and benzoic acids and demo
190 ra and T1 relaxation times obtained from the deuterated phenylalanine side chains in free and HAP-ads
192 st cells adherent on a quartz substrate in a deuterated phosphate-buffered saline environment at room
193 anthracene-functionalized tri-BCP containing deuterated polystyrene (d(8)-PS) and poly(methyl methacr
194 ring and neutron scattering experiments with deuterated polystyrene (dPS) grafted silica and poly(vin
199 poration using stable isotope labelling with deuterated precursors followed by high resolution NanoSI
202 unlabeled product precedes production of the deuterated product, showing that the methylated species
203 n (pH 2.5) and cooling (0 degrees C) and the deuterated protein (or a digest thereof) is analyzed by
204 ed using mixed (15)N/(13)C labeling and with deuterated protein, MAS at omegar/2pi = 60 kHz, omega0H/
206 n to compensate for isotope shift effects in deuterated proteins, COMPASS is far more accurate for la
207 methods for preparation of site-selectively deuterated PUFAs require rather long, laborious, and exp
208 pparent PE-water distributions of pyrene and deuterated pyrene (performance reference compound) were
209 MR detection was applied to regioselectively deuterated pyridine complexes to investigate the symmetr
210 otope effects (IEs) on basicities of various deuterated pyridine isotopologues and of 2,6-lutidine-2,
211 ying a combination of [4-(13)C]erythrose and deuterated pyruvate during growth on deuterium oxide.
212 lation of free amino groups in paCOS using a deuterated reagent; (ii) labeling the reducing end with
217 experiments of (13)C-labeled M2TM and methyl-deuterated rimantadine in lipid bilayers showed that the
219 of multiply deuterated 5'-deoxyadenosine and deuterated S-adenosylmethionine when the reaction is car
222 gle spinning (MAS) NMR has focused on highly deuterated samples, in which only a small number of prot
224 ng a series of peptide substrates with alpha-deuterated Ser, for the determination of the dehydration
228 easurements of the primary product formed in deuterated solvent show that the heme Fe(III) is coordin
229 wever, a slower subunit exchange is noted in deuterated solvent, reflecting the poorer solubility of
230 pable of exchanging up to 90% of solvent for deuterated solvent, with a good recovery and repeatabili
236 Nd3+ and Er3+ MCs in the solid state and in deuterated solvents, upon excitation at low energy, are
239 decay rate of syn-CH3CHOO compared with the deuterated species, giving rise to a significant kinetic
240 ce and wastewater samples; thus the use of a deuterated standard (sucralose-d6) was crucial for preci
241 barbituric acid and mass spectrometry with a deuterated standard to characterize MDA pools in the veg
243 ization of MS conditions and the addition of deuterated standards, resulted in assay linearity to the
244 interference or overlap of signals from the deuterated stator, which is insensitive to the {(1)H}-(1
248 he solvent (pentane or diethyl ether); the 3-deuterated substrate, 3-Ddman, was also investigated as
251 heavy-enzyme KIEs of ~3 on k(cat)/K(M) with deuterated substrates are greater than the product of th
255 By harnessing such low-cost and versatile deuterated substrates, Raman-DIP has the potential to pr
258 e effects of 1.0185 with either protiated or deuterated sugar, together with the absence of any solve
259 ecular decay rates for selectively and fully deuterated syn methyl-substituted Criegee intermediates
261 tematic shift in the mass of monomers in the deuterated system is consistent with the decomposition o
263 ental investigation of DNA containing methyl-deuterated thymine reveals a large isotope effect establ
264 ly deuterated precursors, partially to fully deuterated triazoles were assembled where the final deut
265 bservable molecules, the spin isomers of the deuterated trihydrogen cation, ortho-H2D(+) and para-H2D
266 ine (22% as choline-d9, with d9 indicating a deuterated trimethyl amine group) and meeting folate-int
267 in situ by the photochemistry of protium and deuterated triplet 2-formylphenylnitrene isolated in an
269 the doublet to a singlet, while for 3,5-ring-deuterated tyrosine-labeled enzyme, no changes occur in
270 ple, only 4% and 6% deuterium loss for fully deuterated ubiquitin and beta(2)-microglobulin were obse
273 aracterized the IR stretching frequencies of deuterated variants of proline and the corresponding car
284 matopoietic transplantation (AHSCT) received deuterated water at biologically relevant time intervals
286 gluconeogenesis to EGP was quantitated using deuterated water corrected for transaldolase exchange.
288 s are inefficient, which curtails the disk's deuterated water formation and its viability as the sole
289 Complementary sedimentation velocity with deuterated water gives a picture of an alpha,beta-protom
290 pplicable for studying gluconeogenesis using deuterated water in cell culture and animal experiments.
292 (13)C-labeled dissolved inorganic carbon and deuterated water provided further insights into producti
293 these E. coli cells in LB broth prepared in deuterated water showed no incorporation of deuterium in
298 a crude bacterial cell lysate could also be deuterated without the need for separate purification st
299 imensional IMS-MS datasets (undeuterated and deuterated) without the need for dataset alignment.
300 o compare the spark-discharge products of a "deuterated world" with the standard reaction in the "hyd
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