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1 effects on the aromatic ring and a secondary deuterium kinetic isotope effect.
2 on the basis of pH-rate profiles and solvent deuterium kinetic isotope effects.
3 own to be steady-state ordered using primary deuterium kinetic isotope effects.
4 y stopped-flow visible spectrophotometry and deuterium kinetic isotope effects.
5                                      Primary deuterium kinetic isotope effects (1 degrees DKIE) on (k
6      We recently reported abnormal secondary deuterium kinetic isotope effects (2 degrees KIEs) for h
7            Cleavage at U exhibits a large 5' deuterium kinetic isotope effect, a potential signature
8                                        alpha-Deuterium kinetic isotope effects (alpha-DKIEs) based up
9  cyclopentyl sulfonates, logarithms of alpha-deuterium kinetic isotope effects (alpha-KIE) correlate
10                                  Significant deuterium kinetic isotope effects and a positive correla
11        The experimentally observed rate law, deuterium kinetic isotope effects, and identification of
12 on, very large, weakly temperature dependent deuterium kinetic isotope effects (approximately 50) are
13           Both solvent O-H and substrate C-H deuterium kinetic isotope effects are observed for these
14                                              Deuterium kinetic isotope effects are widely used in che
15 ntribution to the mechanism by examining the deuterium kinetic isotope effect associated with the hyd
16  examining the temperature dependence of the deuterium kinetic isotope effect associated with the tra
17                                      Solvent deuterium kinetic isotope effects at pH 5.8, using APADH
18                                    A primary deuterium kinetic isotope effect [(D)(k(for) + k(rev)) a
19 x10(6) M(-1) s(-1) and (b) the small primary deuterium kinetic isotope effects, (D)V = 1.3 and (D)V/K
20                                    A solvent deuterium kinetic isotope effect (D2OVmax = 1.5) was mea
21                          Kinetic studies and deuterium kinetic isotope effects demonstrate that these
22                                              Deuterium kinetic isotope effect determinations for the
23 the solvent reorganization energies, and the deuterium kinetic isotope effects determined from the ca
24                            The corresponding deuterium kinetic isotope effects (e.g., KIE(OD)(H) = k(
25 ing that the observed value is the intrinsic deuterium kinetic isotope effect for oxidation of this s
26                                     A normal deuterium kinetic isotope effect for the overall reactio
27 o suggested by a substantial decrease in the deuterium kinetic isotope effect for the reaction of Q w
28                      The calculated hydrogen/deuterium kinetic isotope effect for the standard rate c
29                                          The deuterium kinetic isotope effects for epimerization of U
30 oduces the experimentally measured rates and deuterium kinetic isotope effects for ET and PCET.
31                  Reaction rate constants and deuterium kinetic isotope effects for the reactions of B
32                    Activation parameters and deuterium kinetic isotope effects for the substrate reac
33                                The substrate deuterium kinetic isotope effects for the wild-type and
34 owever, experimental measurements of solvent deuterium kinetic isotope effects for this enzyme do not
35                             In addition, the deuterium kinetic isotope effect from reactions of cyclo
36                   Beta-secondary and solvent deuterium kinetic isotope effects have been determined f
37                   Beta-Secondary and solvent deuterium kinetic isotope effects have been determined f
38                  Primary and alpha-secondary deuterium kinetic isotope effects have been measured for
39                                The secondary deuterium kinetic isotope effect in the reaction leading
40 ange of 5.5-9.3, and there is no significant deuterium kinetic isotope effect in the reaction of UDP-
41                                          The deuterium kinetic isotope effect increases to 3.2, consi
42 otope effect is increased, while the primary deuterium kinetic isotope effect is decreased, indicatin
43                                 The observed deuterium kinetic isotope effect is discussed briefly, a
44                         For cyclohexane, the deuterium kinetic isotope effect (k(H)/k(D)) of 1.28 (5)
45 law, rate = k1[1] + k2[1][BzOH], and a small deuterium kinetic isotope effect, k(Pd-H)/k(Pd-D) = 1.3(
46                   The observation of primary deuterium kinetic isotope effects, k(H2)/k(D2) = 3.1(3)
47                    It is shown here that the deuterium kinetic isotope effect (KIE) for the reaction
48 ion of TpTSO(2)(-) and TpT exhibits a V(max) deuterium kinetic isotope effect (KIE) of 1.7 +/- 0.2, w
49   Temperature-dependent measurements of this deuterium kinetic isotope effect (KIE) show a large diff
50                                              Deuterium kinetic isotope effect (KIE) values of 5.3, 3.
51            In this time period, the apparent deuterium kinetic isotope effects (KIE(app)) were observ
52 ion kinetics, with pH, substrate and solvent deuterium kinetic isotope effects (KIE) as mechanistic p
53 -androstene-3,17-dione ( 3), alpha-secondary deuterium kinetic isotope effects (KIE) at C-6 of the st
54                                              Deuterium kinetic isotope effects (KIE) were measured, a
55                                              Deuterium kinetic isotope effects (KIEs) are reported fo
56 measurement of [Formula: see text]-secondary deuterium kinetic isotope effects (KIEs) at all sites of
57                                              Deuterium kinetic isotope effects (KIEs) of the H(*)(D(*
58                      Extraction of intrinsic deuterium kinetic isotope effects (KIEs) using single tu
59         We show, by the criterion of solvent deuterium kinetic isotope effect measurements and proton
60                            The small primary deuterium kinetic isotope effects observed using NADPH a
61                                    A solvent deuterium kinetic isotope effect of 1 is measured for ho
62         Similarly, the large alpha-secondary deuterium kinetic isotope effect of 1.15 +/- 0.02 observ
63 lyzed rate of dehydration of scytalone had a deuterium kinetic isotope effect of 1.2 at pH 7.0 and 25
64 bined with simulation reveal a large primary deuterium kinetic isotope effect of 3.3 on the covalent
65                           The unusually high deuterium kinetic isotope effect of 81 is due to the sma
66                                   A hydrogen/deuterium kinetic isotope effect of nearly 2 implicates
67                                      Primary deuterium kinetic isotope effects of 1.3 and 1.5 on V(fo
68                                      Solvent deuterium kinetic isotope effects of 1.5 and 3.2 were ob
69                                Large primary deuterium kinetic isotope effects of 13.4 +/- 1.0 and 16
70                 The pre-steady-state primary deuterium kinetic isotope effect on enzyme reduction has
71 stic studies have revealed a large substrate deuterium kinetic isotope effect on galactose oxidase tu
72 , exhibits an unusual and unexpected primary deuterium kinetic isotope effect on its Arrhenius activa
73 by S124A-GalE proceeds with a pH-independent deuterium kinetic isotope effect on k(cat) of 2.0 +/- 0.
74 ) by Y149F-GalE proceeds with a pH-dependent deuterium kinetic isotope effect on k(cat) of 2.2 +/- 0.
75 alogues with para substituents exhibit large deuterium kinetic isotope effect on k(cat), on k(cat)/K(
76 the alpha-carbon of the thiolactone caused a deuterium kinetic isotope effect on k2 of 3.2 +/- 0.2, c
77          The effect of introducing a primary deuterium kinetic isotope effect on the hydrogen transfe
78 he potential for substantial benefits of the deuterium kinetic isotope effect on the safety and dispo
79 mation and also that there is an observed C5-deuterium kinetic isotope effect on this elimination ste
80                                              Deuterium kinetic isotope effects on k(cat), k(red), k(c
81                                          The deuterium kinetic isotope effects on k(red) and k(cat) a
82                                              Deuterium kinetic isotope effects on steady state kineti
83                             We then measured deuterium kinetic isotope effects on the rate of cleavag
84                                  The solvent deuterium kinetic isotope effects on V 1 and V1/K Ser de
85                                      Primary deuterium kinetic isotope effects on V and V/K at pH 7.5
86                                  The primary deuterium kinetic isotope effects on V and V/K for the f
87                                  The solvent deuterium kinetic isotope effects on V and V/K in the di
88                 The magnitude of the primary deuterium kinetic isotope effects on V and V/K varied su
89                         Steady-state primary deuterium kinetic isotope effects on V have been determi
90                                      Solvent deuterium kinetic isotope effects on V/K were uniformly
91                                      Solvent deuterium kinetic isotope effects revealed an inverse va
92                                              Deuterium kinetic isotope effects revealed that reaction
93 ueous tetrahydrofuran have inverse secondary deuterium kinetic isotope effects, SDKIEs.
94    Initial velocity, product inhibition, and deuterium kinetic isotope effect studies were consistent
95                                  The primary deuterium kinetic isotope effect suggests that the conve
96 show apparent bimolecular rate constants and deuterium kinetic isotope effects that increase in propo
97  overall antarafacial fashion; (c) secondary deuterium kinetic isotope effects that suggest substanti
98          On the basis of the small values of deuterium kinetic isotope effects, the relatively high a
99       Key features of this route include the deuterium kinetic isotope effect to block undesired indo
100 ural products feature the strategic use of a deuterium kinetic isotope effect to improve the efficien
101 d value of 12.6 for the ratio of the primary deuterium kinetic isotope effect to the secondary isotop
102                       In this study, we used deuterium kinetic isotope effects to probe the chemical
103 hSH exhibits biphasic decay kinetics with no deuterium kinetic isotope effect upon PhSD substitution.
104                     The steady-state primary deuterium kinetic isotope effect using NADH coincide wit
105                          The alpha-secondary deuterium kinetic isotope effect using OAS-3,3-d2 is 1.1
106              Furthermore, the measurement of deuterium kinetic isotope effects using [1(S)-(2)H]DHAP
107               The magnitude of these primary deuterium kinetic isotope effects varied with metal ion
108            On the basis of data from solvent deuterium kinetic isotope effects, viscosity effects, an
109                                  A substrate deuterium kinetic isotope effect was also measured on th
110                                            A deuterium kinetic isotope effect was observed in the (3-
111 e reverse reaction direction, finite primary deuterium kinetic isotope effects were observed for all
112            Significant and identical primary deuterium kinetic isotope effects were observed for V (2
113                          Significant primary deuterium kinetic isotope effects were observed with [4S
114                                    Substrate deuterium kinetic isotope effects with 1,2-[(2)H(4)]nitr
115                                      Solvent deuterium kinetic isotope effects with 4,4-dithiopyridin

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