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1 other diiron mu-carbyne complexes which are diamagnetic.
2 an S = 1/2 ground state, while [2Cu2](2+) is diamagnetic.
3 easurement shows technetium dichloride to be diamagnetic.
4 (NO)]ClO(4) confirm that the ground state is diamagnetic.
5 electronic configurations, the compounds are diamagnetic.
6 the rare earth atoms while the Ru atoms are diamagnetic.
7 Ni(II) complexes which are square planar and diamagnetic.
8 rboxylate and is six-coordinated while still diamagnetic.
10 ly employed to monitor the formation of both diamagnetic (2-electron) dimers; and UV-vis spectroscopy
13 The approach is based on the alkylation of diamagnetic 4-R-amino-1,2,2,5,5-pentamethyl-3-imidazolin
14 ained for the interaction of AdoMet with the diamagnetic [4Fe-4S](2+) state of PFL-AE, which is visua
16 , we report the synthesis and isolation of a diamagnetic, 5-coordinate Fe horizontal lineNNH2(+) spec
19 ground state of O(2) in the zinc-containing diamagnetic analogue of sperm whale deoxymyoglobin has b
22 utyl-SBP undergo a spin transition between a diamagnetic and a paramagnetic state upon heating, while
25 ic counterparts self-assemble imparts strong diamagnetic and optical anisotropies and flow/shear char
27 agnetostatic interaction between effectively diamagnetic and paramagnetic particles within a magnetiz
28 hly reactive main-group and transition-metal diamagnetic and paramagnetic species, and to bind strong
29 adical that can be cycled reversibly between diamagnetic and paramagnetic states via noncovalent gues
30 of metal-organic framework magnets based on diamagnetic and radical organic linkers, respectively.
32 lline 1 and 2 establish that both solids are diamagnetic, and 31P and 17O NMR spectroscopy confirm th
33 NMR spectra indicated that the complexes are diamagnetic, and a qualitative MO analysis showed that t
35 could be due to the influence of the strong diamagnetic anisotropy of the quadruply bonded M[quadrup
38 we have crystallographically characterized a diamagnetic arylnickel(II) complex, [(i-Pr-pybox)Ni(II)P
40 cals are all readily attributed to form from diamagnetic [AsO4](3-) precursors during irradiation, pr
45 coupling between Fe(II) centers through the diamagnetic bridging ligand to give an S = 4 ground stat
46 (3)] = [PhB(CH(2)PPh(2))(3)](-)), yields the diamagnetic bridging nitride species [{[PhBP(3)]Fe}(2)(m
47 ous O(2)-Fe(II) adducts, the HNO adducts are diamagnetic, but with a characteristic HNO resonance in
50 ner and more extended, and we observed small diamagnetic cavities and ion cyclotron waves of types th
53 carriers in vivo, we developed MRI-traceable diamagnetic Chemical Exchange Saturation Transfer (diaCE
54 opological origin associated relating to the diamagnetic circulating current around the S-vacancy.
55 )(CN)6]}.7MeOH (Mn2Co.7MeOH) analogue with a diamagnetic Co(III) central atom and the mixed Co/Os (PP
56 ntane (AdN(3)) furnished a three-coordinate, diamagnetic Co(III) imide ((Tr)L)Co(NAd) as confirmed by
57 dry 1,2-dichloroethane affords bright green diamagnetic Co(III)(TPP)(N-py-DTDA(-)), 3b, with multipl
58 -surface approach is thus applicable to both diamagnetic (CO) and paramagnetic (NO) heme proteins wit
61 -4,4'-ditolylamine) in neat benzene produces diamagnetic complex 3 [Ni(Ph)(PN(P)N(H))], which is crys
65 10(-6) mm(3) s/kg, indicating a significant diamagnetic component relative to the suspension medium,
67 m) at the lowest field observed so far for a diamagnetic compound in agreement with quantum chemical
71 racterizing the hydration state of para- and diamagnetic coordination complexes in the gas phase base
72 ates of non-ferromagnetic materials, such as diamagnetic copper and paramagnetic manganese, to overco
75 th 3 equiv of KC(8) in THF similarly yielded diamagnetic {Cp*Mo[N(i-Pr)C(NMe(2))N(i-Pr)]}(2)(mu-eta(1
76 ic plastic crystal, Me-AZADO, to the ordered diamagnetic crystalline phase, (Me-AZADO)(2), has been c
77 of octaethylporphyrin) doped into a range of diamagnetic crystals including simple four-coordinate ho
78 n the conversion of paramagnetic Cu(2+) into diamagnetic Cu(+) occurs while the reactive Cu(+) ions r
79 xygenases, presenting a mechanism in which a diamagnetic Cu(II)-superoxo complex, formed initially at
81 pushes the plasma via the Lorentz force on a diamagnetic current: j x B in a certain direction, depen
82 n by 1e(-) oxidation afforded the respective diamagnetic diferrous derivatives where the relative sta
83 ntified: a paramagnetic diferrous species, a diamagnetic diferrous species, a mixed valence Fe(2+)Fe(
85 cal transitions, irrespective of whether the diamagnetic dimeric species bear a double-negative charg
86 ive Fe(NO)2 unit: paramagnetic {Fe(NO)2}(9), diamagnetic dimerized forms of {Fe(NO)2}(9) and diamagne
87 rvable with clean NO is the formation of the diamagnetic dinitrosyl species Fe(TPP)(NO)2 (2), and thi
88 NaHg in THF provided excellent yields of the diamagnetic dinuclear end-on-bridged dinitrogen complexe
90 n the redox-active NDI molecules, and 4) the diamagnetic diradical dianion using UV/Vis/NIR, EPR and
91 (4), 1, results in the formation of a novel, diamagnetic ditungsten terminal oxo compound [W(2)O(2,2'
92 ases and the bond order decreases, while the diamagnetic, doubly oxidized species becomes essentially
93 ectron oxidation of 2 by ferrocenium affords diamagnetic [(dtbpe)Ni(mu-H)SiMes(2)][BAr(F)(4)] (5), a
97 (1)H-(15)N correlation map of substrate-free diamagnetic Fe(II) CO-bound CYP101A permits these pertur
99 n that a complete electron transfer from the diamagnetic Fe(II)-Co(III) state to the paramagnetic Fe(
102 transfer attributed to the switching between diamagnetic {Fe(II)LS(mu-CN)Co(III)LS} and paramagnetic
103 magnetic dimerized forms of {Fe(NO)2}(9) and diamagnetic {Fe(NO)2}(10) DNICs (Enemark-Feltham notatio
104 nd the NHC with formation of a spin-coupled, diamagnetic {Fe(NO)}(7)-{Fe(NO)(2)}(9) complex, [(NO)Fe(
106 etic ferric (T(1) = 6.34 +/- 0.01 s) and the diamagnetic ferrous (T(1) = 5.04 +/- 0.06 s) enzyme, sug
107 obin chains: from paramagnetic ferrous Hb to diamagnetic ferrous oxyhemoglobin (oxyHb) with reversibl
108 e formation of the thermodynamically favored diamagnetic five-coordinate S-bound adduct, Co(TPP)(S-py
109 h 1,4-cyclohexadiene to yield the respective diamagnetic FLP-NOH product 13, which was also character
114 t is argued that the bonding requirements of diamagnetic gallium control the electronic behavior with
117 promotes suppression of the transition to a diamagnetic ground state characteristic of U(IV), and in
118 a single solvent bridge, in contrast to the diamagnetic ground state found for the native cluster co
119 Conventional Mossbauer spectroscopy shows a diamagnetic ground state of the NP2-NO complex and Type
120 ossbauer spectroscopic measurements indicate diamagnetic ground states at cryogenic temperatures and
127 nsfer from one paramagnetic metal ion to its diamagnetic host metal ion will pave the way for future
128 crystalline dispersions in the isostructural diamagnetic host TiOPc in different stoichiometric ratio
129 ine (en) to give equilibrium mixtures of the diamagnetic HSn(9)(3-) ion along with K(x)Sn(9)((4-x)-)
132 one [4Fe-4S] (2+,1+) and one FAD, which are diamagnetic in the isolated oxidized enzyme and can be r
133 cluster and one equivalent of FAD, which are diamagnetic in the isolated oxidized enzyme and can be r
134 electron per [N(3)]Ru moiety; however, 2 is diamagnetic in the solid due to close (3.26 A) head-to-t
137 y studied Pd catalysts that generally employ diamagnetic intermediates, Ni systems can more easily ac
138 Substitution of Mn(IV) magnetic centers by diamagnetic ions [e.g., Ge(IV)] allows one to "switch of
144 relevant complexes also are characterized: a diamagnetic iron(IV) trihydride [PhBP(iPr)3]Fe(H)3(PMe3)
145 means of magnetic measurements that reveal a diamagnetic La(III) compound and a paramagnetic Ce(III)
146 parallel spin-labeling with paramagnetic and diamagnetic labels and show that distances in the range
148 -borane dehydrocoupling reactions, for which diamagnetic M(II) and M(IV) species have been previously
149 that interrogate the FC state of rigorously diamagnetic [M(bpy)(3)](2+) complexes, where bpy is 2,2'
151 of the magnetic and gravitational forces on diamagnetic materials suspended in a paramagnetic medium
154 ted Kramers' doublet, and, when doped into a diamagnetic matrix at the single-ion level, produces a l
158 istic of the superoxide ion coordinated to a diamagnetic metal ion, and on the absence of detectable
159 observation of uncompensated spin density at diamagnetic metal ions that bridge paramagnetic metal io
161 alpha(2) and the substrate), and a distinct, diamagnetic Mn/Fe cluster, which forms approximately 900
163 xes Mo(N[tBu]Ar)3 (Ar = 3,5-C6H3Me2) to form diamagnetic Mo(IV) phenyl chalcogenide complexes Mo(N[tB
164 GAF) analysis of the relaxation rates of the diamagnetic molecule, and interpreted in relation to bac
165 e used to characterize this unique series of diamagnetic molecules as a means of determining how best
166 e protons offer considerable advantages over diamagnetic molecules as chemical exchange saturation tr
167 ][8]annulene and irreversibly deactivate the diamagnetic molybdenum metallacyclobutadiene complex thr
168 to elucidate the electronic structure of the diamagnetic mononuclear side-on CuII-superoxo complex.
172 th appropriate design of supporting ligands, diamagnetic Ni(IV) sigma-aryl fluoride intermediates can
175 persistent radicals and leads initially to a diamagnetic nitroso compound, which is transformed into
182 e very small differences in density of solid diamagnetic objects suspended in a paramagnetic medium.
183 etic suspension for the separation of purely diamagnetic objects, such as bio-macromolecules or heavy
184 ch reacts with additional NO to generate the diamagnetic (ON=NO)(2-) product, {[(Me(3)Si)(2)N](2)Y}(4
186 gnetic methods, which are blind to important diamagnetic or antiferromagnetically coupled states.
187 ge values of the permittivity lead to strong diamagnetic or paramagnetic behavior characterized by su
190 The SOPs carry a magnetic moment and a large diamagnetic orbital magnetization of a possible topologi
191 ts showed a single-crystal sample of 1 to be diamagnetic over the entire temperature range of 10-300
194 fies its spontaneous self-association to the diamagnetic P2, previously characterized as the stacked
195 nversion of the paramagnetic ortho-H2 to the diamagnetic para-H2 causes the ENDOR signal to decrease
196 ndex) is actually higher than that of their (diamagnetic) parent-contrary to conventional expectation
198 icient to magnetically guide and deliver the diamagnetic particles to desired locations, where they c
199 n alternative magneto-gravitational trap for diamagnetic particles, such as diamond nanocrystals, wit
201 A repeatable bidirectional paramagnetic <--> diamagnetic photomagnetic effect has been observed in th
203 agnetic pi-dimer form to the low-temperature diamagnetic pi-dimer structure is accompanied by an incr
204 usceptibility measurements show that 10 is a diamagnetic pi-dimer, whereas 10d is a diamagnetic sigma
208 idants to generate a more highly fluorescent diamagnetic product (II) and thus can be used as a highl
209 t radical] and the step [product radical --> diamagnetic product] that involves hydrogen atom transfe
211 d NMR restraints from H98S ARD, a metal-free diamagnetic protein that is isostructural with ARD'.
212 te-of-the-art liquid-state determinations of diamagnetic proteins, including a well-defined active si
213 Exposure of a red pyridine (py) solution of diamagnetic (py)(2)Fe(II)(H(2)N-OEP) (1) (H(2)N-OEP is t
214 R band from NO appears at 1920 cm(-1), and a diamagnetic quadrupole iron doublet appears in Mossbauer
215 paramagnetic mixed-valence dimers, and then diamagnetic radical-cation dimers following subsequent o
216 vely concentrated solutions (e.g., 80 mM) of diamagnetic redox-active species (e.g., TMPD) is control
218 ain-chain and most-side chain protons in the diamagnetic, reduced form at pH 9.2 and 333 K by two-dim
219 al exponential temperature dependence of the diamagnetic response above the transition temperature T(
220 ometry experiments show a strong, adjustable diamagnetic response when a field is applied perpendicul
221 arge class of materials with paramagnetic or diamagnetic response, simple functional forms of the tem
222 ir heteroanalogues showed no indication of a diamagnetic ring current by proton NMR spectroscopy, but
223 on NMR spectrum showed that it has a reduced diamagnetic ring current in comparison to other carbapor
224 s and found to intrude into the pi-cloud and diamagnetic ring current of the neighboring acridine.
225 R spectrum confirms the presence of a strong diamagnetic ring current, and the meso-protons show up a
226 rated that these derivatives retained strong diamagnetic ring currents and the presence of the intern
227 liporphyrins affords dications with enhanced diamagnetic ring currents where the internal CH shifts t
230 followed by aerobic oxidation generates two diamagnetic Ru(III) species [1 a (cis) and 1 b (trans)]
231 l is due to the conversion of heme P460 to a diamagnetic S = 0 state and concomitant loss of magnetic
232 S = 1/2) d(3) Fe(V) configuration in 2 and a diamagnetic (S = 0) d(2) Fe(VI) configuration in 3 Their
237 imide, with alkyl groups leading to low-spin diamagnetic (S=0) complexes and an aryl group leading to
239 ce from transport, the unprecedentedly large diamagnetic screening, and the presence of approximately
240 ng experimentally that acoustic phonons in a diamagnetic semiconductor (InSb) scatter more strongly f
241 del of non-local dielectric screening, these diamagnetic shifts also constrain estimates of the A and
243 lso allow observation of the small quadratic diamagnetic shifts of both A and B excitons in monolayer
245 = -14.9 K), while the dimer phase beta-1b is diamagnetic, showing no indication of thermal dissociati
247 ron(IV) and iron(V) carbyne complexes, as in diamagnetic (SiP(3))Fe=CCH(3) and the paramagnetic catio
248 O favors Co-S bond heterolysis, yielding the diamagnetic six-coordinate purple N-bound Co(III)(TPP)(N
249 charged nitroxide probes (EPR) and of simple diamagnetic small molecules (NMR) were selected to discl
250 [CpCo(azpy)] 2 is isolated as an air-stable, diamagnetic solid via chemical reduction with cobaltocen
252 tion of paramagnetic nitroxide moieties to a diamagnetic species resulted in the appearance of CEST.
254 aramagnetic ion, it can also be observed for diamagnetic species, since the magnetoelectrolysis pheno
258 o(CNAr(Mes2))(4)]BAr(F)(4), which contains a diamagnetic, square planar monovalent cobalt center.
260 808 nm laser light irradiation, whereas the diamagnetic state is recovered in an almost quantitative
261 henalenyl units of the dimer, whereas in the diamagnetic state the electrons migrate to the interior
263 ds the known (77)Se chemical shift range for diamagnetic substances from approximately 3300 ppm to al
265 eltachi(p) compares to the anisotropy of the diamagnetic susceptibilities of the components in the ce
266 f experimental and computational tools: NMR, diamagnetic susceptibility exaltation, current density a
267 Stabilization energies are compared with diamagnetic susceptibility exaltations, Lambda, CSGT-B3L
269 determined the average net anisotropy of the diamagnetic susceptibility, Deltachi(p), of a whole Para
270 ed in strong magnetic fields were typical of diamagnetic systems, indicating an exchange-coupled S =
271 lding effects by a neighboring heavy atom in diamagnetic systems, with particular emphasis on the "sp
273 rove that an increase in the strength of the diamagnetic term leads to an effective decoupling of the
274 o the case of the atomic case, can contain a diamagnetic term proportional to the square vector poten
275 he metal ion is changed from paramagnetic to diamagnetic the VCD amplification vanishes completely.
277 The neutral even alternate arenes are always diamagnetic; thus, the isolation of Cn(*) and (Py)Cn(*)
278 3 at room temperature, giving no discernible diamagnetic titanium complexes, but at -30 degrees C the
281 be used to obtain an estimate of the pKa of diamagnetic transition metal hydride and dihydrogen comp
282 of the acid dissociation constant Ka(LAC) of diamagnetic transition metal hydride and dihydrogen comp
283 gnetic compound was obtained by reduction of diamagnetic, triply bonded V(2)(DPhF)(4) with KC(8).
284 sed reduction chemistry can be effected in a diamagnetic trivalent system using the dinitrogen reduct
285 aneous self-association of TTF+* to form the diamagnetic [TTF+,TTF+] dication and to also undergo the
286 e characteristic optical transitions in such diamagnetic two-electron dimers are shown to be related
287 gnetic resonance (SSNMR) studies of natively diamagnetic uniformly (13)C,(15)N-enriched proteins, int
288 f [N(n-Bu)(4)][3] is facile and provides the diamagnetic uranium(VI) nitridoborate complex (C(6)F(5))
289 2 to dry O2 resulted in the formation of the diamagnetic V(V) oxocluster [V{N(H)Ar(Me6)}2]2(mu-O-Li-O
292 e IV, the Ru center is seven-coordinated and diamagnetic, whereas in oxidation state II, the complex
294 tween redox centers: the shortest species is diamagnetic, while the dication with the longest bridge
295 electron DFT analysis shows the 3- ion to be diamagnetic with Ih symmetry and a 1.33 eV HOMO-LUMO gap
296 by attraction towards a magnet when normally diamagnetic yeast Saccharomyces cerevisiae were grown wi
297 ide alkoxide cage complexes, and their doped diamagnetic yttrium analogues, in which competing relaxa
298 he native Fe(2+) (high spin) was replaced by diamagnetic Zn(2+) to prevent spectral line broadening o
299 th the native high spin Fe(2+) exchanged for diamagnetic Zn(2+), prepared in (1)H(2)O and (2)H(2)O so