ライフサイエンスコーパス: diamagnetic

1 (NO)]ClO(4) confirm that the ground state is diamagnetic.

2 electronic configurations, the compounds are diamagnetic.

3 the rare earth atoms while the Ru atoms are diamagnetic.

4 Ni(II) complexes which are square planar and diamagnetic.

5 rboxylate and is six-coordinated while still diamagnetic.

6 an S = 1/2 ground state, while [2Cu2](2+) is diamagnetic.

7 easurement shows technetium dichloride to be diamagnetic.

8 erromagnetically coupled S = 1 Fe(IV) sites; diamagnetic (1)H NMR spectra are observed.

9 First, essentially complete assignments for diamagnetic 15N and 13C resonances of Pdxo have been mad

10 The diamagnetic 15N, 13C', 13C alpha, 13C beta, 1H alpha, an

11 e-4S] cluster was found to be present in the diamagnetic 2+ oxidation state and exhibited typical Mos

12 ly employed to monitor the formation of both diamagnetic (2-electron) dimers; and UV-vis spectroscopy

13 Diamagnetic 4 provides a bona fide example of a pseudote

14 The approach is based on the alkylation of diamagnetic 4-R-amino-1,2,2,5,5-pentamethyl-3-imidazolin

15 ained for the interaction of AdoMet with the diamagnetic [4Fe-4S](2+) state of PFL-AE, which is visua

16 n contains a [4Fe-4S]+ cluster paired with a diamagnetic [4Fe-4S]-like cluster.

17 , we report the synthesis and isolation of a diamagnetic, 5-coordinate Fe horizontal lineNNH2(+) spec

18 Single-electron reduction of 3 yields diamagnetic amidophenolato complex 4, capable of activat

19 ted radicals (NITIm(-)) are reduced to their diamagnetic aminoxyl form (denoted NITRed(2-)).

20 ground state of O(2) in the zinc-containing diamagnetic analogue of sperm whale deoxymyoglobin has b

21 tative analysis of these interactions, a new diamagnetic analogue of the nitroxide side chain is used

22 the ones formed by one-electron oxidation of diamagnetic analogues that are neutral or cationic.

23 ding zinc(II) salts led to the corresponding diamagnetic analogues.

24 utyl-SBP undergo a spin transition between a diamagnetic and a paramagnetic state upon heating, while

25 In addition, 3 is diamagnetic and can be characterized by NMR spectroscopy

26 The low-temperature phase (5-60 K) is diamagnetic and has a singlet ground state (2Jexp = -166

27 ic counterparts self-assemble imparts strong diamagnetic and optical anisotropies and flow/shear char

28 Cycling between diamagnetic and paramagnetic forms by heating and coolin

29 agnetostatic interaction between effectively diamagnetic and paramagnetic particles within a magnetiz

30 hly reactive main-group and transition-metal diamagnetic and paramagnetic species, and to bind strong

31 adical that can be cycled reversibly between diamagnetic and paramagnetic states via noncovalent gues

32 als, accessible only for the Mn catalyst, is diamagnetic and therefore should be EPR-silent.

33 lline 1 and 2 establish that both solids are diamagnetic, and 31P and 17O NMR spectroscopy confirm th

34 NMR spectra indicated that the complexes are diamagnetic, and a qualitative MO analysis showed that t

35 ctive reduction of the stable radical to its diamagnetic anion.

36 could be due to the influence of the strong diamagnetic anisotropy of the quadruply bonded M[quadrup

37 This is a reflection of the diamagnetic anisotropy of these trigonal oxyanions.

38 the length of the astral microtubules, their diamagnetic anisotropy, and flexural rigidity predict th

39 we have crystallographically characterized a diamagnetic arylnickel(II) complex, [(i-Pr-pybox)Ni(II)P

40 The cationic species 1(+)-3(+) are diamagnetic, as shown by the absence of a signal in the

41 cals are all readily attributed to form from diamagnetic [AsO4](3-) precursors during irradiation, pr

42 in states of the [4Fe-4S]+2 center, which is diamagnetic at 4.5 K.

43 Whereas Cs2(C14H10) is diamagnetic because of orbital polarization, Cs(C14H10)

44 La2MoO5 is diamagnetic, behavior which is not expected for a nonmet

45 coupling between Fe(II) centers through the diamagnetic bridging ligand to give an S = 4 ground stat

46 (3)] = [PhB(CH(2)PPh(2))(3)](-)), yields the diamagnetic bridging nitride species [{[PhBP(3)]Fe}(2)(m

47 ous O(2)-Fe(II) adducts, the HNO adducts are diamagnetic, but with a characteristic HNO resonance in

48 emperature superconducting phase observed in diamagnetic carbon disulfide under high pressure.

49 ner and more extended, and we observed small diamagnetic cavities and ion cyclotron waves of types th

50 paramagnetic properties as contrasted to the diamagnetic character of oxyhemoglobin.

51 carriers in vivo, we developed MRI-traceable diamagnetic Chemical Exchange Saturation Transfer (diaCE

52 )(CN)6]}.7MeOH (Mn2Co.7MeOH) analogue with a diamagnetic Co(III) central atom and the mixed Co/Os (PP

53 dry 1,2-dichloroethane affords bright green diamagnetic Co(III)(TPP)(N-py-DTDA(-)), 3b, with multipl

54 -surface approach is thus applicable to both diamagnetic (CO) and paramagnetic (NO) heme proteins wit

55 The diamagnetic cobalt(III) complex {[PhBP(3)]CoOSiPh(3)}{BA

56 The (meta)stability of this diamagnetic complex (S=0) is striking if one considers t

57 -4,4'-ditolylamine) in neat benzene produces diamagnetic complex 3 [Ni(Ph)(PN(P)N(H))], which is crys

58 MoAs(8)(2)(-) (2) is a 16 e(-) diamagnetic complex whereas MoSb(8)(3)(-) (5) and the Cr

59 Remarkably, diamagnetic complexes deriving from isoelectronic replac

60 t both Ni2+ binding sites form square-planar diamagnetic complexes.

61 10(-6) mm(3) s/kg, indicating a significant diamagnetic component relative to the suspension medium,

62 Using the diamagnetic compound [{(Me(3)SiNPPh(2))(2)CH}Yb(BH(4))(T

63 m) at the lowest field observed so far for a diamagnetic compound in agreement with quantum chemical

64 The diamagnetic compounds Cp'2Ni2E2 (1: E = S, 2: E = Se, 3:

65 Comparison of the diamagnetic contribution to the labile proton chemical s

66 ates of non-ferromagnetic materials, such as diamagnetic copper and paramagnetic manganese, to overco

67 st approximately 3-4 lower relative to their diamagnetic counterparts.

68 merization and crystallization of 3a affords diamagnetic CP 3.

69 th 3 equiv of KC(8) in THF similarly yielded diamagnetic {Cp*Mo[N(i-Pr)C(NMe(2))N(i-Pr)]}(2)(mu-eta(1

70 of octaethylporphyrin) doped into a range of diamagnetic crystals including simple four-coordinate ho

71 n the conversion of paramagnetic Cu(2+) into diamagnetic Cu(+) occurs while the reactive Cu(+) ions r

72 xygenases, presenting a mechanism in which a diamagnetic Cu(II)-superoxo complex, formed initially at

73 pushes the plasma via the Lorentz force on a diamagnetic current: j x B in a certain direction, depen

74 n by 1e(-) oxidation afforded the respective diamagnetic diferrous derivatives where the relative sta

75 ntified: a paramagnetic diferrous species, a diamagnetic diferrous species, a mixed valence Fe(2+)Fe(

76 onance (ENDOR) probe of the structure of the diamagnetic diiron(III) state.

77 cal transitions, irrespective of whether the diamagnetic dimeric species bear a double-negative charg

78 ive Fe(NO)2 unit: paramagnetic {Fe(NO)2}(9), diamagnetic dimerized forms of {Fe(NO)2}(9) and diamagne

79 rvable with clean NO is the formation of the diamagnetic dinitrosyl species Fe(TPP)(NO)2 (2), and thi

80 NaHg in THF provided excellent yields of the diamagnetic dinuclear end-on-bridged dinitrogen complexe

81 netic beads, which behave as paramagnetic or diamagnetic dipoles when immersed in a ferrofluid.

82 n the redox-active NDI molecules, and 4) the diamagnetic diradical dianion using UV/Vis/NIR, EPR and

83 (4), 1, results in the formation of a novel, diamagnetic ditungsten terminal oxo compound [W(2)O(2,2'

84 ases and the bond order decreases, while the diamagnetic, doubly oxidized species becomes essentially

85 ectron oxidation of 2 by ferrocenium affords diamagnetic [(dtbpe)Ni(mu-H)SiMes(2)][BAr(F)(4)] (5), a

86 The diamagnetic effect of exciton is calculated for an arbit

87 d by the paramagnetic effect of iron and the diamagnetic effect of myelin.

88 elevant amino acid residues in the congested diamagnetic envelope have been assigned.

89 e in vivo to its hydroxylamine derivative, a diamagnetic, EPR-inactive species.

90 nally, and the contributing paramagnetic and diamagnetic factors were extracted.

91 (1)H-(15)N correlation map of substrate-free diamagnetic Fe(II) CO-bound CYP101A permits these pertur

92 almost all known iron hydrides are low-spin, diamagnetic Fe(II) compounds.

93 n that a complete electron transfer from the diamagnetic Fe(II)-Co(III) state to the paramagnetic Fe(

94 d contains the iron site as a six-coordinate diamagnetic Fe-nitrosyl complex, called NH(dark).

95 Mossbauer data show that the diamagnetic Fe-O-Fe unit contains antiferromagnetically

96 transfer attributed to the switching between diamagnetic {Fe(II)LS(mu-CN)Co(III)LS} and paramagnetic

97 magnetic dimerized forms of {Fe(NO)2}(9) and diamagnetic {Fe(NO)2}(10) DNICs (Enemark-Feltham notatio

98 nd the NHC with formation of a spin-coupled, diamagnetic {Fe(NO)}(7)-{Fe(NO)(2)}(9) complex, [(NO)Fe(

99 ial CrIII centers mediated by the equatorial diamagnetic FeII ions.

100 erogeneous solutions composed of mixtures of diamagnetic ferrocytochrome c and paramagnetic ferricyto

101 etic ferric (T(1) = 6.34 +/- 0.01 s) and the diamagnetic ferrous (T(1) = 5.04 +/- 0.06 s) enzyme, sug

102 obin chains: from paramagnetic ferrous Hb to diamagnetic ferrous oxyhemoglobin (oxyHb) with reversibl

103 e formation of the thermodynamically favored diamagnetic five-coordinate S-bound adduct, Co(TPP)(S-py

104 h 1,4-cyclohexadiene to yield the respective diamagnetic FLP-NOH product 13, which was also character

105 reaction with 1,4-cyclohexadiene to give the diamagnetic FLP-NOH product 3b.

106 Second, the solution structure of a diamagnetic form of Pdx, that of the C85S variant of gal

107 rations demonstrate that the fully oxidized, diamagnetic form of the C-center (Cox) undergoes a one-e

108 high pH where the cluster is converted to a diamagnetic form.

109 olar shifts provide improved resolution over diamagnetic forms and allow distinction between the two

110 ase transitions between the paramagnetic and diamagnetic forms.

111 t is argued that the bonding requirements of diamagnetic gallium control the electronic behavior with

112 The method starts with diamagnetic gel beads that are functionalized covalently

113 Surprisingly, complex 3 exhibits a diamagnetic ground state and a nearly square planar geom

114 a single solvent bridge, in contrast to the diamagnetic ground state found for the native cluster co

115 Conventional Mossbauer spectroscopy shows a diamagnetic ground state of the NP2-NO complex and Type

116 s formed which exhibits magnetic properties (diamagnetic ground state) and Mossbauer parameters (Delt

117 o Delta 9D and peroxo-cycled Delta 9D have a diamagnetic ground state.

118 ossbauer spectroscopic measurements indicate diamagnetic ground states at cryogenic temperatures and

119 s having the highest catalytic activity have diamagnetic ground states, consistent with the bis-mu-br

120 ly in the past to predict/refine elements of diamagnetic heme protein structures.

121 Cryoreduction of TDO produces a novel diamagnetic heme species, tentatively assigned as a redu

122 xol Co[(mu-OH)2 Co(NH3 )4 ]3(6+) ion to make diamagnetic heterometallic ions.

123 Measurements on a diamagnetic host jarosite doped with magnetically dilute

124 nsfer from one paramagnetic metal ion to its diamagnetic host metal ion will pave the way for future

125 crystalline dispersions in the isostructural diamagnetic host TiOPc in different stoichiometric ratio

126 ine (en) to give equilibrium mixtures of the diamagnetic HSn(9)(3-) ion along with K(x)Sn(9)((4-x)-)

127 The diamagnetic imide complex {[PhBP(3)]Fe(II)(triple bond)N

128 7O NMR spectroscopy confirm that both remain diamagnetic in solution.

129 one [4Fe-4S] (2+,1+) and one FAD, which are diamagnetic in the isolated oxidized enzyme and can be r

130 cluster and one equivalent of FAD, which are diamagnetic in the isolated oxidized enzyme and can be r

131 electron per [N(3)]Ru moiety; however, 2 is diamagnetic in the solid due to close (3.26 A) head-to-t

132 ve cage fragmentation takes place to yield a diamagnetic "inorganometallic" cobalt complex.

133 semi-metal, in the proximity with sulfur, a diamagnetic insulator.

134 y studied Pd catalysts that generally employ diamagnetic intermediates, Ni systems can more easily ac

135 Substitution of Mn(IV) magnetic centers by diamagnetic ions [e.g., Ge(IV)] allows one to "switch of

136 Other compositions besides these diamagnetic ions can undoubtedly be made using a similar

137 trochemical structuring during deposition of diamagnetic ions was demonstrated, very recently.

138 volves localized spin-orbit Mott states with diamagnetic Ir(4+)-Ir(4+) dimers.

139 The diamagnetic iron(IV) nitrides 3a and 3b exhibit unique e

140 relevant complexes also are characterized: a diamagnetic iron(IV) trihydride [PhBP(iPr)3]Fe(H)3(PMe3)

141 means of magnetic measurements that reveal a diamagnetic La(III) compound and a paramagnetic Ce(III)

142 parallel spin-labeling with paramagnetic and diamagnetic labels and show that distances in the range

143 for making wax models of these shapes using diamagnetic levitation.

144 -borane dehydrocoupling reactions, for which diamagnetic M(II) and M(IV) species have been previously

145 of the magnetic and gravitational forces on diamagnetic materials suspended in a paramagnetic medium

146 fluidic device for detecting and separating diamagnetic materials that differ in density.

147 fact, sensitive to magnetic fields, even in diamagnetic materials.

148 ted Kramers' doublet, and, when doped into a diamagnetic matrix at the single-ion level, produces a l

149 inimize it, spins are typically diluted in a diamagnetic matrix.

150 fferent mechanisms (i.e. paramagnetic versus diamagnetic mechanisms).

151 Diamagnetic metal complexes of phthalocyanines with n-bu

152 istic of the superoxide ion coordinated to a diamagnetic metal ion, and on the absence of detectable

153 observation of uncompensated spin density at diamagnetic metal ions that bridge paramagnetic metal io

154 troscopy by substituting naturally occurring diamagnetic Mg(2+) by paramagnetic oxovanadium.

155 alpha(2) and the substrate), and a distinct, diamagnetic Mn/Fe cluster, which forms approximately 900

156 This diamagnetic {Mn-NO}6 nitrosyl exhibits nuNO at 1725 cm-1

157 xes Mo(N[tBu]Ar)3 (Ar = 3,5-C6H3Me2) to form diamagnetic Mo(IV) phenyl chalcogenide complexes Mo(N[tB

158 GAF) analysis of the relaxation rates of the diamagnetic molecule, and interpreted in relation to bac

159 e used to characterize this unique series of diamagnetic molecules as a means of determining how best

160 e protons offer considerable advantages over diamagnetic molecules as chemical exchange saturation tr

161 ][8]annulene and irreversibly deactivate the diamagnetic molybdenum metallacyclobutadiene complex thr

162 to elucidate the electronic structure of the diamagnetic mononuclear side-on CuII-superoxo complex.

163 been more elusive for PI largely due to the diamagnetic nature of its ground state.

164 enter) and reduced (NiSOD(red), containing a diamagnetic Ni(2+) center) states.

165 to a low-spin form of the cluster containing diamagnetic Ni(II) centers.

166 persistent radicals and leads initially to a diamagnetic nitroso compound, which is transformed into

167 O instead oxidized them to the corresponding diamagnetic nitrosonium perchlorate salts.

168 The density of the diamagnetic object can be determined by measuring its po

169 In a typical measurement, a diamagnetic object of unknown density is placed in a con

170 MagLev-the levitation of diamagnetic objects in a paramagnetic fluid within a mag

171 e very small differences in density of solid diamagnetic objects suspended in a paramagnetic medium.

172 etic suspension for the separation of purely diamagnetic objects, such as bio-macromolecules or heavy

173 ch reacts with additional NO to generate the diamagnetic (ON=NO)(2-) product, {[(Me(3)Si)(2)N](2)Y}(4

174 onverts paramagnetic red crystals into green diamagnetic ones.

175 gnetic methods, which are blind to important diamagnetic or antiferromagnetically coupled states.

176 ge values of the permittivity lead to strong diamagnetic or paramagnetic behavior characterized by su

177 Magnetic levitation (MagLev) of diamagnetic or weakly paramagnetic materials suspended i

178 rdinates a Cu ion available either in Cu(+) (diamagnetic) or Cu(2+) (paramagnetic) form.

179 ts showed a single-crystal sample of 1 to be diamagnetic over the entire temperature range of 10-300

180 sually small transport gap relative to other diamagnetic oxides.

181 fies its spontaneous self-association to the diamagnetic P2, previously characterized as the stacked

182 nversion of the paramagnetic ortho-H2 to the diamagnetic para-H2 causes the ENDOR signal to decrease

183 ndex) is actually higher than that of their (diamagnetic) parent-contrary to conventional expectation

184 We show that diamagnetic particles can be remotely manipulated by a m

185 icient to magnetically guide and deliver the diamagnetic particles to desired locations, where they c

186 n alternative magneto-gravitational trap for diamagnetic particles, such as diamond nanocrystals, wit

187 cles induces attractive interactions between diamagnetic particles.

188 A repeatable bidirectional paramagnetic <--> diamagnetic photomagnetic effect has been observed in th

189 At room temperature, 4 exists as a diamagnetic pi-dimer (interplanar separation of approxim

190 agnetic pi-dimer form to the low-temperature diamagnetic pi-dimer structure is accompanied by an incr

191 usceptibility measurements show that 10 is a diamagnetic pi-dimer, whereas 10d is a diamagnetic sigma

192 onic structure and not to the formation of a diamagnetic pi-dimer.

193 centers which retain the conformation of the diamagnetic precursor.

194 Here we use Ni2+ as a diamagnetic probe to further understand Cu2+ binding to

195 idants to generate a more highly fluorescent diamagnetic product (II) and thus can be used as a highl

196 t radical] and the step [product radical --> diamagnetic product] that involves hydrogen atom transfe

197 Images are reconstructed from the weak diamagnetic properties of the sample and require an abun

198 the knowledge of specific assignments in the diamagnetic protein and relied on magnetization transfer

199 d NMR restraints from H98S ARD, a metal-free diamagnetic protein that is isostructural with ARD'.

200 te-of-the-art liquid-state determinations of diamagnetic proteins, including a well-defined active si

201 Exposure of a red pyridine (py) solution of diamagnetic (py)(2)Fe(II)(H(2)N-OEP) (1) (H(2)N-OEP is t

202 R band from NO appears at 1920 cm(-1), and a diamagnetic quadrupole iron doublet appears in Mossbauer

203 t-shift increments produced by oxidizing the diamagnetic R state HbCO to the paramagnetic R state flu

204 paramagnetic mixed-valence dimers, and then diamagnetic radical-cation dimers following subsequent o

205 vely concentrated solutions (e.g., 80 mM) of diamagnetic redox-active species (e.g., TMPD) is control

206 Finally, convective behavior with diamagnetic redox-active species and magnet millielectro

207 ain-chain and most-side chain protons in the diamagnetic, reduced form at pH 9.2 and 333 K by two-dim

208 ain-chain and most side-chain protons in the diamagnetic, reduced form by two-dimensional NMR techniq

209 resonance assignments have been made for the diamagnetic region of Tdxo (ca. 80% of the protein).

210 s and 1H-15N NOEs have been measured for the diamagnetic region of the protein.

211 ave been used for structure determination in diamagnetic regions of the protein.

212 ometry experiments show a strong, adjustable diamagnetic response when a field is applied perpendicul

213 arge class of materials with paramagnetic or diamagnetic response, simple functional forms of the tem

214 ir heteroanalogues showed no indication of a diamagnetic ring current by proton NMR spectroscopy, but

215 on NMR spectrum showed that it has a reduced diamagnetic ring current in comparison to other carbapor

216 s and found to intrude into the pi-cloud and diamagnetic ring current of the neighboring acridine.

217 R spectrum confirms the presence of a strong diamagnetic ring current, and the meso-protons show up a

218 liporphyrins affords dications with enhanced diamagnetic ring currents where the internal CH shifts t

219 he dications showed the presence of enhanced diamagnetic ring currents.

220 followed by aerobic oxidation generates two diamagnetic Ru(III) species [1 a (cis) and 1 b (trans)]

221 l is due to the conversion of heme P460 to a diamagnetic S = 0 state and concomitant loss of magnetic

222 and antiferromagnetically coupled to form a diamagnetic S = 0 state.

223 e splitting of Delta E(Q) = 1.14 mm/s, and a diamagnetic (S = 0) ground state.

224 deoxy-Hb, combines with triplet O2, forming diamagnetic (S = 0) oxy-Hb.

225 In addition, seven diamagnetic (S = 0, d(6) and d(8)) systems studied previ

226 The results indicate that NifB-co is a diamagnetic (S=0) 8-Fe cluster, containing two spectrosc

227 al time at high-magnetic field in a range of diamagnetic sample fluids.

228 ce from transport, the unprecedentedly large diamagnetic screening, and the presence of approximately

229 ng experimentally that acoustic phonons in a diamagnetic semiconductor (InSb) scatter more strongly f

230 del of non-local dielectric screening, these diamagnetic shifts also constrain estimates of the A and

231 lso allow observation of the small quadratic diamagnetic shifts of both A and B excitons in monolayer

232 estimation as the difference of observed and diamagnetic shifts.

233 = -14.9 K), while the dimer phase beta-1b is diamagnetic, showing no indication of thermal dissociati

234 is a diamagnetic pi-dimer, whereas 10d is a diamagnetic sigma-dimer.

235 O favors Co-S bond heterolysis, yielding the diamagnetic six-coordinate purple N-bound Co(III)(TPP)(N

236 charged nitroxide probes (EPR) and of simple diamagnetic small molecules (NMR) were selected to discl

237 [CpCo(azpy)] 2 is isolated as an air-stable, diamagnetic solid via chemical reduction with cobaltocen

238 s tightly linked to C-H activation or that a diamagnetic species Cu(II)-O2* has been formed.

239 tion of paramagnetic nitroxide moieties to a diamagnetic species resulted in the appearance of CEST.

240 2] suggest that addition of H2 should form a diamagnetic species, and this is the case.

241 aramagnetic ion, it can also be observed for diamagnetic species, since the magnetoelectrolysis pheno

242 des compelling evidence that the latter is a diamagnetic species.

243 the hydride transfer reaction that yields a diamagnetic species: O3 + HO2- HO3- + O2.

244 e to structural perturbations by the bulkier diamagnetic spin label analog.

245 o(CNAr(Mes2))(4)]BAr(F)(4), which contains a diamagnetic, square planar monovalent cobalt center.

246 The decay to a diamagnetic state is complete and no paramagnetic interm

247 808 nm laser light irradiation, whereas the diamagnetic state is recovered in an almost quantitative

248 henalenyl units of the dimer, whereas in the diamagnetic state the electrons migrate to the interior

249 increases by two orders of magnitude in the diamagnetic state, and the band gap decreases.

250 -210 mV for the one-electron reduction to a diamagnetic state.

251 ds the known (77)Se chemical shift range for diamagnetic substances from approximately 3300 ppm to al

252 eltachi(p) compares to the anisotropy of the diamagnetic susceptibilities of the components in the ce

253 f experimental and computational tools: NMR, diamagnetic susceptibility exaltation, current density a

254 -independent chemical shifts (NICS) and high diamagnetic susceptibility exaltations indicate that the

255 Stabilization energies are compared with diamagnetic susceptibility exaltations, Lambda, CSGT-B3L

256 The diamagnetic susceptibility exhaltations (Deltachi) of 3,

257 Constant diamagnetic susceptibility gives rise to a temperature i

258 determined the average net anisotropy of the diamagnetic susceptibility, Deltachi(p), of a whole Para

259 ed in strong magnetic fields were typical of diamagnetic systems, indicating an exchange-coupled S =

260 he characterization of molecular orbitals in diamagnetic systems.

261 rove that an increase in the strength of the diamagnetic term leads to an effective decoupling of the

262 o the case of the atomic case, can contain a diamagnetic term proportional to the square vector poten

263 he metal ion is changed from paramagnetic to diamagnetic the VCD amplification vanishes completely.

264 In the case of the diamagnetic thorium corrole, variable-temperature, DOSY

265 3 at room temperature, giving no discernible diamagnetic titanium complexes, but at -30 degrees C the

266 Another diamagnetic transition at about 3 K suggests that there

267 of the acid dissociation constant Ka(LAC) of diamagnetic transition metal hydride and dihydrogen comp

268 be used to obtain an estimate of the pKa of diamagnetic transition metal hydride and dihydrogen comp

269 gnetic compound was obtained by reduction of diamagnetic, triply bonded V(2)(DPhF)(4) with KC(8).

270 sed reduction chemistry can be effected in a diamagnetic trivalent system using the dinitrogen reduct

271 aneous self-association of TTF+* to form the diamagnetic [TTF+,TTF+] dication and to also undergo the

272 e characteristic optical transitions in such diamagnetic two-electron dimers are shown to be related

273 gnetic resonance (SSNMR) studies of natively diamagnetic uniformly (13)C,(15)N-enriched proteins, int

274 f [N(n-Bu)(4)][3] is facile and provides the diamagnetic uranium(VI) nitridoborate complex (C(6)F(5))

275 2 to dry O2 resulted in the formation of the diamagnetic V(V) oxocluster [V{N(H)Ar(Me6)}2]2(mu-O-Li-O

276 ; the isotropic shift was displaced from the diamagnetic value and varied with temperature consistent

277 ed to be generally applicable for studies of diamagnetic vanadium sites in metalloproteins.

278 e IV, the Ru center is seven-coordinated and diamagnetic, whereas in oxidation state II, the complex

279 Most organisms are simply diamagnetic, while magnetotactic bacteria and migratory

280 tween redox centers: the shortest species is diamagnetic, while the dication with the longest bridge

281 electron DFT analysis shows the 3- ion to be diamagnetic with Ih symmetry and a 1.33 eV HOMO-LUMO gap

282 by attraction towards a magnet when normally diamagnetic yeast Saccharomyces cerevisiae were grown wi

283 ide alkoxide cage complexes, and their doped diamagnetic yttrium analogues, in which competing relaxa

284 The binding of nitric oxide to YZ* to form a diamagnetic YZ-NO species uncouples the S2 state from YZ

285 Replacement of bound cobalt with diamagnetic zinc removes the paramagnetic-induced orient

286 he native Fe(2+) (high spin) was replaced by diamagnetic Zn(2+) to prevent spectral line broadening o

287 th the native high spin Fe(2+) exchanged for diamagnetic Zn(2+), prepared in (1)H(2)O and (2)H(2)O so

288 ndividually observed and characterized using diamagnetic Zn2+ as a substitute for Mg2+.