ライフサイエンスコーパス: diatomic

1 emely rapid electronic dynamics in atoms and diatomics.

2 s close to that predicted (740 cm(-1)) for a diatomic (18)O-(18)O stretch.

3 tions defined by the contact between oxygen (diatomic) and the picket-fence porphyrin (macromolecule)

4 port a short H/H distance in the coordinated diatomic, and DFT calculations show that the transition

5 mal side of the heme rather than the typical diatomic binding pocket on the distal side when the 5-co

6 mal side of the heme rather than the typical diatomic binding pocket on the distal side.

7 ed on simple theoretical considerations of a diatomic cleavage of a stable covalent bond, for example

8 rd-like coordination of the active site with diatomic CO and cyanide ligands.

9 the resonance Raman spectrum of 2 reveals a diatomic Co-O vibration band at 770 cm(-1), which provid

10 The (2FeH) subsite features a diatomic coordination sphere composed of three CO and tw

11 In this work, we design and propose a linear diatomic elastic metamaterial using dual-resonator conce

12 ctron spin density localized on the internal diatomic gadolinium cluster and not on the heterofullere

13 In mammals, the diatomic gas is critical to the cyclic guanosine monopho

14 t study on the slow phase of the dynamics of diatomic gas molecule interaction with NPs comprises an

15 ternative to heme or flavin for redox and/or diatomic gas sensing and regulation of DGC activity.

16 Developing a means of delivering a diatomic, gaseous free radical has been a technical chal

17 vity to a heme-binding domain for sensing of diatomic gases such as oxygen, carbon monoxide, and nitr

18 to the control of gene networks by steroids, diatomic gases, and other small molecules.

19 lso show that E75-heme responds to the small diatomic gases, nitric oxide and carbon monoxide.

20 The diatomic [Ge2](4-) unit is characterized by the shortest

21 nse to ligating the substrate complex with a diatomic, H-bond acceptor ligand.

22 the electronic and rotational shifts of the diatomic halides of Pb and Tl have been made by Tiemann

23 Nitric oxide, NO, the diatomic hybrid of dinitrogen and dioxygen, has extensiv

24 The influence of these diatomics identifies EG as the key catalytic intermediat

25 e interaction, and reactivity with exogenous diatomics) illustrating the utility of these non-native

26 of bimolecular reactions of silicon nitride diatomics in chemical vapor deposition techniques and in

27 nt analysis of bonding in a great variety of diatomics, including more or less polar ones.

28 eported that aimed at lowering the access of diatomic inhibitors to the active site pocket, but the m

29 atoms on different molecules combine to form diatomic ions that are detected with a NanoSIMS instrume

30 ved, wherein the electronic structure of the diatomic is observed to mimic that present in the isoele

31 he E7 channel that can accommodate an apolar diatomic ligand and enhances ligand uptake particularly

32 netics measurements, optical absorbance, and diatomic ligand binding studies.

33 -dependent kinetic measurements of ultrafast diatomic ligand binding to the "bare" protoheme (L(1)-Fe

34 ed by significant reductions in the rates of diatomic ligand binding to the heme iron.

35 s a significant influence on the kinetics of diatomic ligand binding to the heme.

36 firmed reduced redox state and the status of diatomic ligand complexes during X-ray diffraction data

37 Diatomic ligand discrimination by soluble guanylyl cycla

38 s also highlight the importance of the trans diatomic ligand in altering the binding and sensitivity

39 kyl isocyanides (CNRs) identify pathways for diatomic ligand movement into and out of Mb, with their

40 The nature of diatomic ligand recombination in heme proteins is elucid

41 otential interactions between the heme-bound diatomic ligand, substrate l-NHA, and the surrounding pr

42 .5 A to accommodate the presence of a mobile diatomic ligand, suggesting a mechanism for communicatio

43 KatG (compound III) also contains a low-spin diatomic ligand-heme adduct (heme-O2), it is reasonable

44 r the sGC heme pocket conformation to retain diatomic ligands and thus activate the enzyme alone or i

45 The diatomic ligands are sensitive reporter groups for struc

46 The structures of various diatomic ligands bound to the heme iron can mimic the di

47 Leu residue inhibits distal coordination of diatomic ligands by decreasing k(on) as well as increasi

48 provide unambiguous experimental proof that diatomic ligands can enter and exit a globin through an

49 key event in the mechanism of photolysis of diatomic ligands following a porphyrin ring pi-pi* trans

50 alculations yielded vibrational modes of the diatomic ligands for conceivable H-cluster structures.

51 bstrate binding event prevents the escape of diatomic ligands from the distal heme binding pocket, st

52 Diatomic ligands in hemoproteins and the way they bind t

53 Three unusual diatomic ligands in the form of two cyanides (CN(-)) and

54 We have probed the dynamics of the diatomic ligands NO and CO within the isolated heme doma

55 Therefore, the formation of the diatomic ligands relies on dedicated biosynthesis pathwa

56 The reduced heme iron binds diatomic ligands such as CO only under destabilizing con

57 vity, interactions between Tyr171 and distal diatomic ligands turn the kinase activity on and off.

58 all possible spin states of the three common diatomic ligands, CO, NO, and O2, and high-spin heme iro

59 ilities of the de novo heme proteins to bind diatomic ligands, we measured the affinity for CO, the k

60 or the increase in electron density on bound diatomic ligands, which is required for peroxidase funct

61 dG lyses the substrate tyrosine to yield the diatomic ligands.

62 forms of EPO, LPO, and MPO toward binding of diatomic ligands.

63 stimate the numbers of unpaired electrons in diatomic LnB clusters.

64 ate atoms using a two-photon transition to a diatomic molecular state.

65 mechanistic details for the activation of a diatomic molecule by a prototypical FLP.

66 example, the dissociative adsorption of the diatomic molecule H2--a central step in many industriall

67 orbit coupling show that the U[triple bond]C diatomic molecule has a quintet (Lambda = 5, Omega = 3)

68 h the ground-state reactant atom and product diatomic molecule have open-shell character, which intro

69 rong density, the right size and shape for a diatomic molecule is found between the other side of the

70 ms in two steps: first, the two atoms of the diatomic molecule undergo consecutive collisions with a

71 uency ratio, which is appropriate for the UC diatomic molecule, and another new band at 891 cm(-1) gi

72 rom crystals soaked in H2O2 revealed a bound diatomic molecule, assigned to a cis-mu-1,2-peroxo bridg

73 As a homonuclear diatomic molecule, N(2) is difficult to detect spectrosc

74 As a small diatomic molecule, NO has been assumed to freely diffuse

75 ee-dimensional magneto-optical trapping of a diatomic molecule, strontium monofluoride (SrF), at a te

76 p orbitals of hydrogen and alkali atoms into diatomic molecule-like dimers and free-electron bands of

77 function as gates for escape of the product diatomic molecule.

78 yond the hitherto achieved imaging of simple diatomic molecules and is based on the combination of a

79 low 1 microkelvin have been demonstrated for diatomic molecules assembled from pre-cooled alkali atom

80 dely investigated, the valence isoelectronic diatomic molecules EX (E = group 13 element, X = group 1

81 eration and various quantum trajectories for diatomic molecules for the first time.

82 is used to eject highly rotationally excited diatomic molecules into alcohols and water, rotational c

83 t highly mobile loops can limit diffusion of diatomic molecules into and out of a protein cavity, a r

84 The first row diatomic molecules N2 and CO have played central roles i

85 Isolated diatomic molecules of iodine monochloride (ICl) were pho

86 ulations suggest that rotational dynamics of diatomic molecules play an essential role in filamentati

87 bjFixLH, contains a heme cofactor that binds diatomic molecules such as carbon monoxide and oxygen an

88 hemical reactor, concentrating and orienting diatomic molecules such as NO, CO, O(2), and H(2)O(2) in

89 idence is particularly clear from studies of diatomic molecules that molecular vibration can be stron

90 is conserved over the entire range from its diatomic molecules to clusters and further to crystals.

91 created a quantum superposition of atoms and diatomic molecules two chemically different species.

92 ctronic early transition metal heterogeneous diatomic molecules, M-X- (M = Ti,Zr,W; X = O or C).

93 Of the simple diatomic molecules, oxygen is the only one to carry a ma

94 For diatomic molecules, these lines originate from points wh

95 ong-field processes is built upon studies of diatomic molecules, which typically have electronic stat

96 , in a pressure range between 50 and 94 GPa, diatomic nitrogen can be transformed into a non-molecula

97 The triple bond of diatomic nitrogen has among the greatest binding energie

98 sotropic (1)H/(2)H hyperfine coupling to the diatomic of Co-H2 is nearly 4-fold smaller than for Fe-H

99 function of GCS-type transducers is to bind diatomic oxygen and perhaps other gaseous ligands, and t

100 exception being the formation of ozone from diatomic oxygen in the presence of UV radiation or elect

101 Uint is photogenerated from incorporation of diatomic oxygen to IPU and is subjected to thermolysis w

102 oral pathogen Streptococcus mutans to reduce diatomic oxygen to water while oxidizing NADH to NAD(+).

103 A versatile diatomic physiological messenger, nitric oxide (NO), is

104 These diatomic products form an enzyme-bound Fe(CO)x(CN)y synt

105 ilylene, and L:Si=Si:L, a carbene-stabilized diatomic silicon molecule with the Si atoms in the forma

106 physically meaningful only for monatomic or diatomic solids.

107 s three-electron reduction gives an antimony diatomic species capped by two carbenes.

108 ted to be viable for a significant number of diatomic species.

109 Expulsion of diatomic sulfur, S(2), is unlikely from the unimolecular

110 We propose a simple diatomic system trapped inside an optical cavity to cont

111 resulting from cleavage of N(2) and CO, the diatomics with the two strongest bonds in chemistry.