ライフサイエンスコーパス: dichloromethane

1 apsules than the resorcinarenes (1.0% v/v in dichloromethane).

2 ilane 6 (treatment with hydrogen chloride in dichloromethane).

3 e then desorbed by treatment with 200 muL of dichloromethane.

4 n organic solvents like dimethylformamide or dichloromethane.

5 phoma, as well as marginal zone lymphoma for dichloromethane.

6 uantitatively removed in <5 min by 3% TFA in dichloromethane.

7 dimer shows the appearance of four waves in dichloromethane.

8 paced one-electron transfers on oxidation in dichloromethane.

9 These derivatives were then extracted with dichloromethane.

10 -0.89; tau(F) approximately 2.09-3.91 ns) in dichloromethane.

11 n situ activation method at -40 degrees C in dichloromethane.

12 promotion gives beta-selective couplings in dichloromethane.

13 (3v) symmetry is minor for bases weaker than dichloromethane.

14 and eluting target analytes and lipids with dichloromethane.

15 e cleaved from polymer beads with 50% TFA in dichloromethane.

16 tracted in aqueous 1-propanol and mixed with dichloromethane.

17 g soil), 75% of which was not extractable by dichloromethane.

18 loroethane or a cosolvent mixture of 1/9 THF/dichloromethane.

19 reactivity in dioxane but low reactivity in dichloromethane.

20 xane, tert-butyl methyl ether, n-pentane and dichloromethane.

21 mo-2-methoxypropane with diisopropylamine in dichloromethane.

22 sed disk is extracted with a small volume of dichloromethane.

23 ne (H.G1 and H.G2) in a nonpolar medium like dichloromethane.

24 cceptor using non-H-bonding solvents such as dichloromethane.

25 ient temperature, while 1 day is required in dichloromethane.

26 ], and is markedly faster in toluene than in dichloromethane.

27 etabolites and a mixture of acetonitrile and dichloromethane (1:1, v/v) for PCP.

28 From the dichloromethane/2-propanol (1:1) extract of the Indonesi

29 leaved with TFA, and following dilution with dichloromethane, "3 + 1" condensation with a pyrrole dia

30 using a mixture of n-hexane, chloroform, and dichloromethane (70 mL) for extraction.

31 near relationship at high concentrations for dichloromethane, a highly volatile compound.

32 In dichloromethane, a strong dependence on the countercatio

33 Relative energies in THF, dichloromethane, acetone, and DMSO have been estimated w

34 on (C(2) or C(6)), and solvent (1,4-dioxane, dichloromethane, acetonitrile, methanol, and in some cas

35 = 400, DeltaGalpha = -15 kJ mol(-1)) in 4:1 dichloromethane-acetonitrile.

36 ed to stabilize myoglobin against unfolding, dichloromethane actually destabilized myoglobin at all e

37 ure with a thiophene dialcohol in 2% ethanol-dichloromethane afforded a tetraphenylthiapyreniporphyri

38 Acetonitrile and dichloromethane afforded lower regioselectivity (50:50 a

39 '(4)(-) (4, Ar' = 3,5-C(6)H(3)(CF(3))(2)) in dichloromethane afforded the nonclassical polyhydride co

40 ations show the atmospheric concentration of dichloromethane-an ozone-depleting gas not controlled by

41 inimide and trifluoromethanesulfonic acid in dichloromethane and acetonitrile at -78 degrees C in the

42 of BpCCOCH3 is faster in cyclohexane than in dichloromethane and acetonitrile because of intimate sol

43 ixture design consisted of ethanol, acetone, dichloromethane and chloroform solvents and their binary

44 In dichloromethane and chloroform without an additive the 2

45 ts of a Soxhlet extraction with a mixture of dichloromethane and diethyl ether containing lipases and

46 r 17 individual PAHs through extraction with dichloromethane and gas chromatograph-mass spectrometer

47 ueezed calamansi juices were extracted using dichloromethane and headspace solid-phase microextractio

48 Philippines and Vietnam were extracted with dichloromethane and hexane, and then analysed by gas chr

49 ructed of appropriate reference compounds in dichloromethane and in acetonitrile that can be used to

50 The catalyst operates in both dichloromethane and ionic liquids and undergoes no decom

51 Screening of antioxidant potential of dichloromethane and methanolic extracts of twenty-seven

52 more, novel biological activities of hexane, dichloromethane and methanolic extracts were assessed.

53 The procedure involves three parts: dichloromethane and PEG are first dried; the reaction st

54 with a dilute solution in 1:1 n-pentane and dichloromethane and pumping away the solvent.

55 xtraction solvent ratios, varying amounts of dichloromethane and salts were performed with fifty repr

56 s were 1840muL of acetonitrile and 160muL of dichloromethane and the re-suspended mixture consisting

57 solvent basicity bounded at the lower end by dichloromethane and the upper end by tributyl phosphate,

58 eaction in Scholl precursors in a mixture of dichloromethane and various acids (10% v/v).

59 ed by the reaction of sodium salt and CsF in dichloromethane and water.

60 Thus, dichloromethane and xenon have opposite effects on myogl

61 MCRred1 reacts with chloroform and dichloromethane and, like F(430), can catalyze dehalogen

62 ction by diethyl ether instead of more toxic dichloromethane, and (3) concentration by vacuum automat

63 tained in the weakly basic solvents benzene, dichloromethane, and 1,2-dichloroethane.

64 d in acetonitrile, benzene, tetrahydrofuran, dichloromethane, and halobenzene solvents relative to cy

65 as a singlet ground state in cyclohexane, in dichloromethane, and in acetonitrile and decays by WR to

66 ns (i.e., methanol combined with chloroform, dichloromethane, and methyl-tert butyl ether and isoprop

67 g from polar to nonpolar (methanol, acetone, dichloromethane, and n-hexane) were selected to maximize

68 ck of a quinone oxidant, avoidance of use of dichloromethane, and the increased yield of macrocycle f

69 e are added dropwise to a solution of PEG in dichloromethane; and finally, the product solution is fi

70 Xenon and dichloromethane are inhalational anesthetic agents whose

71 d encapsulation efficiency compared to using dichloromethane as core and shell solvents.

72 LLE using dichloromethane as organic phase was combined with the d

73 Using ethyl acetate and dichloromethane as shell- and core-phase solvents, respe

74 ryldiazoacetates, and its compatibility with dichloromethane as solvent.

75 ne transfer and allows the strain to grow on dichloromethane as the sole carbon and energy source.

76 dered using a Polarized Continuum Model with dichloromethane as the solvent.

77 e, and trifluoromethanesulfonic anhydride in dichloromethane at -55 degrees C, reaction with glycosyl

78 nce of a stochiometric amount of BF3.OEt2 in dichloromethane at -78 degrees C.

79 ne and boron trifluoride diethyl etherate in dichloromethane at 0 degrees C rapidly affords a cyclic

80 uring the bromination of benzodiazocine 8 in dichloromethane at 0 degrees C, and the second during th

81 At 0.33 mM in dichloromethane at 25 degrees C the cyclic metalloporphy

82 While EPR spectra of monoradicals in dichloromethane at 295 K reveal the expected three-line

83 with 0.5 equiv of 1,3,5-trimethoxybenzene in dichloromethane at 40 degrees C.

84 ith a mixture of triphosgene and pyridine in dichloromethane at reflux.

85 tones via triphosgene-pyridine activation in dichloromethane at reflux.

86 ount of zinc chloride etherate (10 mol %) in dichloromethane at room temperature gave 2,5-di- and 2,3

87 late (8), and i-Pr2NEt and their coupling in dichloromethane at room temperature with alkene acceptor

88 On exposure to dichlorodicyanoquinone in wet dichloromethane at room temperature, equatorial 4-O-benz

89 initial pH 6.0 aqueous phase, an intervening dichloromethane barrier containing the calix[4]pyrrole c

90 as been studied in gas phase and in aqueous, dichloromethane, benzene, and cyclohexane solutions usin

91 , (8.4), (8.4), and (8.2) kcal/mol in water, dichloromethane, benzene, and cyclohexane, respectively,

92 Ethanol, dichloromethane, benzene, and heptane were selected as r

93 rtho substituent were treated with 1% TFA in dichloromethane, benzofurans were released from resin in

94 [NBu(4)][B(C(6)F(5))(4)] in tetrahydrofuran, dichloromethane, benzotrifluoride, and acetonitrile and

95 In acetonitrile and in dichloromethane BpCCO2CH3 has a singlet ground state.

96 ttern was seen for SQ stored in the light in dichloromethane but with a slower formation of SQ-[OOH]

97 nteraction by solvent is large (about 70% in dichloromethane), but not complete, and that current sta

98 onjugants varied in their ability to grow on dichloromethane, but their fitness on dichloromethane di

99 be reduced considerably, especially for the dichloromethane (by a factor of 3).

100 trile, nitromethane, 1,2-dichloroethane, and dichloromethane, carried out using various chloride salt

101 elds were measured for all compounds in both dichloromethane (CH(2)Cl(2)) and dimethylacetamide (DMAc

102 However, the solvent dichloromethane (CH2Cl2) can be employed to form stable

103 ed-bed plasma reactor for the remediation of dichloromethane (CH2Cl2, DCM).

104 d toluene but not with chlorinated solvents (dichloromethane, chloroform).

105 facile in such solvents as benzene, toluene, dichloromethane, chloroform, and pyridine; was unaffecte

106 complished by washing the aqueous phase with dichloromethane, chloroform, or hexane.

107 e study indicate that the choice of solvent, dichloromethane compared to toluene and toluene/methanol

108 extraction time and a 100-fold reduction in dichloromethane consumed per sample while maintaining th

109 We have explored this issue using dichloromethane consumption in Methylobacterium strains.

110 fluoroisopropanol hydrogen bonded complex in dichloromethane-d2 were determined to be k1 > 10(5) M(-1

111 ethanol (E3), ethanol:HCl (100:1, v/v) (E4), dichloromethane (D5) and hexane (H6) were prepared.

112 arate, complementary extraction chemistries, dichloromethane (DCM) and a methyl tert-butyl ether/hexa

113 (EF) of chemicals extracted from the soil by dichloromethane (DCM) and air were found.

114 inct Dehalobacter strains that respire CF to dichloromethane (DCM) and ferment DCM to nonchlorinated

115 Pyridine derivatives and dichloromethane (DCM) are commonly used together in a va

116 The microbial mixed culture RM grows with dichloromethane (DCM) as the sole energy source generati

117 m (quaternary and primary) chloride salts in dichloromethane (DCM) solution and in the solid-state.

118 e permethylated and partitioned into a water-dichloromethane (DCM) solvent mixture.

119 dy, biotic degradation of chloroform (CF) to dichloromethane (DCM) was carried out by the Dehalobacte

120 ~17 nm) compared with that of 1a solution in dichloromethane (DCM).

121 e (DMF) compared with those in chloroform or dichloromethane (DCM).

122 ptive process and directly enabled effective dichloromethane degradation across diverse Methylobacter

123 a significant impact on trichloromethane and dichloromethane degradation and that compound-specific i

124 strating that effective use of an introduced dichloromethane degradation pathway required one of seve

125 to compare abiotic and biotic chloroform and dichloromethane degradation.

126 ing multiple mechanisms were contributing to dichloromethane degradation.

127 ns that independently evolved in two natural dichloromethane-degrading strains.

128 Methylobacterium extorquens DM4 expresses a dichloromethane dehalogenase (DcmA) that has been acquir

129 The glutathione (GSH)-dependent dichloromethane dehalogenase from Methylophilus sp. stra

130 In concentrated solutions of dichloromethane, Deoxofluor (1) efficiently fluorinates

131 In dichloromethane, DIBA(i)OPr behaves as a bulky reducing

132 row on dichloromethane, but their fitness on dichloromethane did not correlate with the phylogeny of

133 the same reactions in the molecular solvents dichloromethane, dimethylsulfoxide, and methanol.

134 en organic molecules (acetone, acetonitrile, dichloromethane, ethanol, ethyl acetate, hexane, and tol

135 A solvent ratio of 50:50 dichloromethane/ethanol was found to be optimum for sele

136 nia, chlorine, tetrahydrothiophene, benzene, dichloromethane, ethylene oxide, and carbon monoxide.

137 -[di(4-methoxyphenyl)amino]styryl}benzene in dichloromethane exhibit five lines over a wide temperatu

138 The electrochemistry of these compounds in dichloromethane exhibits, besides several reversible red

139 nd evaluate the bioactive compounds from the dichloromethane extract of the fruits of Heracleum mante

140 of a semi-purified fraction, DW-F5, from the dichloromethane extract of W. tinctoria leaves against m

141 However, dichloromethane extract proved the utmost antioxidant ac

142 carbon constituted approximately 40% of the dichloromethane-extractable carbon (DeOC) in the soil.

143 LC/MS analysis of dichloromethane extracts of (ADSR-1), (ADSR-2) and (ADSR

144 nti-diabetic effects of methanol, hexane and dichloromethane extracts of the aerial parts of Ocimum b

145 The enrichment factor for dichloromethane fermentation was -15.5 +/- 1.5 per thous

146 The dichloromethane-fermenting culture transformed dichlorom

147 cai samples were extracted sequentially with dichloromethane followed by methanol.

148 (TIPS) propynal 1 with 3,4-diethylpyrrole in dichloromethane, followed by oxidation with 2,3-dichloro

149 the dialdehydes with the tetrapyrrole in TFA-dichloromethane, followed by oxidation with dilute aqueo

150 olates were quantitatively eluted in 3 ml of dichloromethane for analysis by HPLC.

151 olvent to milk for protein precipitation and dichloromethane for lipid removal, was developed to dete

152 When stored as a solution in dichloromethane for one month, the PCO-isomer rearranges

153 Chloroform transformation and dichloromethane formation was up to 8-fold faster and 14

154 benzyltriethylammonium nitrite (BTEA-NO2) in dichloromethane gave the crystalline 2,6-dichloropurine

155 Although there are gaps in the database for dichloromethane genotoxicity (i.e., DNA adduct formation

156 old acetonitrile and the chlorosugar in cold dichloromethane gives essentially quantitative yields of

157 Dichloromethane, however, gives only C-Cl cleavage produ

158 Fifteen milliliters of 20% (vol/vol) dichloromethane in methanol was passed through the colum

159 completed an updated toxicological review of dichloromethane in November 2011.

160 nnosyl donor is achieved at -60 degrees C in dichloromethane in the presence of 2,4,6-tri-tert-butylp

161 hlorotrityl chloride resin (Barlos resin) in dichloromethane in the presence of diisopropylethylamine

162 , in a matter of minutes at -60 degrees C in dichloromethane, in the presence of 2,4,6-tri-tert-butyl

163 The (1)H NMR spectra recorded in deuterated dichloromethane indicated the presence of contact ion pa

164 lic activity, the key activation pathway for dichloromethane-induced cancer.

165 fluorine (F) atoms in d3-acetonitrile and d2-dichloromethane involve efficient energy flow to vibrati

166 the nitration of toluene by NO2(+)BF4(-) in dichloromethane is accurately predicted from trajectorie

167 Dichloromethane is better suited for generating the more

168 traction of caffeine with a minute amount of dichloromethane, isolating caffeine from the sample matr

169 The dichloromethane/isopropanol solvent has been identified

170 Reductive electrolysis of 1, 2 and 6 in dichloromethane leads to a different reaction, which we

171 Reductive electrolysis of 1 and 3-5 in dichloromethane leads to the removal of the addend and t

172 able pre-equilibrium for dissociation of the dichloromethane ligand in the trimethyl phosphite comple

173 s (SQUID) indicate that the diradical in the dichloromethane matrix predominantly adopts anticonforma

174 nate) and other small molecules (chloroform, dichloromethane, mercaptoethanol, and nitric oxide), we

175 The samples were dissolved in acetone-dichloromethane-methanol (3:2:1, v/v/v) and diluted with

176 -lock micro test tube, homogenized in 1.5 mL dichloromethane-methanol (8:2) and mixed in a mixer mill

177 water followed by an organic extraction with dichloromethane/methanol, with resuspension of the dried

178 sting of LiChrolut EN resins and eluted with dichloromethane/methanol.

179 flates but was successful when four solvent (dichloromethane) molecules were taken into account.

180 ed to a solution of cis-cyclooctene (COE) in dichloromethane/[NBu(4)][B(C(6)F(5))(4)] containing a ca

181 five diaryldisulfides have been studied in a dichloromethane/[NBu4][B(C6F5)4] electrolyte.

182 tandard Scholl reaction conditions (FeCl(3), dichloromethane) occurs for perylene-substituted porphyr

183 ssociations between the chlorinated solvents dichloromethane (odds ratio (OR) = 1.69, 95% confidence

184 s requiring a higher percentage (1.6% v/v in dichloromethane) of methanol to disassemble the capsules

185 tracted with NaOH/methanol, partitioned into dichloromethane on a ChemElut column and cleaned-up by s

186 hat although currently modest, the impact of dichloromethane on ozone has increased markedly in recen

187 inetic photoacidity when operating either in dichloromethane or acetonitrile solutions.

188 trifluoroacetic acid followed by addition of dichloromethane or dibromomethane to remove the lipids.

189 In dichloromethane or trifluoroacetic acid (TFA), the react

190 0673 in the cytochrome P4502E1 gene, CYP2E1 (dichloromethane: OR = 4.42, 95% CI: 2.03, 9.62; P(intera

191 by moderately polar (methanol) and nonpolar (dichloromethane) organic solvents, and is hypothesized t

192 of these intermediates with a Lewis acid in dichloromethane permits the regeneration of a reactive a

193 The 2011 IRIS assessment of dichloromethane provides insights into the toxicity of a

194 Dichloromethane reacts to give the corresponding 4-chlor

195 OSPW extracted using dichloromethane removed the potential for sample matrix

196 Cl) to the solutions of o-chloranil, oCA, in dichloromethane resulted in the transient formation of t

197 Cyclic voltammetry measurements of 1(Bz) in dichloromethane reveal separation of the first and secon

198 In dichloromethane, reversible chelation and partial displa

199 Recent epidemiologic studies of dichloromethane (seven studies of hematopoietic cancers

200 utations, using a continuum solvation model (dichloromethane), show that allostery contributes approx

201 We identified a dichloromethane-soluble fraction (Qu Mai fraction AD [QM

202 oranes) have been studied photometrically in dichloromethane solution at 20 degrees C.

203 gle crystal X-ray diffraction methods and in dichloromethane solution by means of continuous variatio

204 rearrangement reactions of five epoxides in dichloromethane solution have been studied at the M062X/

205 ndicate that the molecular capsules exist in dichloromethane solution in the absence of any cations.

206 ster-2,2'-bipyridine; bpz = 2,2'-bipyrazine) dichloromethane solution led to the formation of two con

207 d dextran particles were then suspended in a dichloromethane solution of polylatic-co-glyclic acids (

208 ninic acid and p-thiocresol react rapidly in dichloromethane solution to give the selenosulfide along

209 Evidence for anion binding in dichloromethane solution was obtained from static fluore

210 The procedure uses Bodipy FL in basic dichloromethane solution with Mukaiyama's reagent (2-chl

211 n-bound dimers, both in the gas phase and in dichloromethane solution, showing that attenuation of in

212 minescence upon addition of BQ to PbS QDs in dichloromethane solution.

213 different resorcinarenes was investigated in dichloromethane solution.

214 lpy change of DeltaHD = -9.5 kcal mol(-1) in dichloromethane solution.

215 s 2 and 3 by NMR line-broadening analysis in dichloromethane solution.

216 vior of pillar[5]quinone was investigated in dichloromethane solution.

217 Dichloromethane solutions of the cationic receptor compl

218 and 0.032 in 4.0 x 10(-5) and 4.0 x 10(-3) M dichloromethane solutions, respectively.

219 nd 0.013 for 5.0 x 10(-5) and 5.0 x 10(-3) M dichloromethane solutions, respectively.

220 radiation of 8.0 x 10(-5) and 8.0 x 10(-3) M dichloromethane solutions, respectively.

221 2*) affords only the long-bonded pi-dimer in dichloromethane solutions, under conditions in which the

222 e units was investigated in acetonitrile and dichloromethane solutions.

223 ction analysis of a photochemically inactive dichloromethane solvate was used to confirm the molecula

224 The O-O bond in 4 undergoes heterolysis in dichloromethane solvent and is postulated to produce nit

225 esence of a palladium Lewis acid catalyst in dichloromethane solvent at room temperature.

226 diethyl ether 1:2v/v (solvent A) as well as dichloromethane (solvent B).

227 growth in the three surveyed solvent media (dichloromethane, tetrahydrofuran, and acetonitrile).

228 However, in dichloromethane the Ni(II) reaction product is interpret

229 In dichloromethane, the macrocycles prevail in wide-stretch

230 In dichloromethane, the reaction between radicals 1 and 2 i

231 matography and ranged from -5.9 kcal/mol for dichloromethane to -13.5 kcal/mol for toluene.

232 were condensed with dipyrrylmethanes in TFA/dichloromethane to afford good to excellent yields of di

233 in solvents of widely different polarities (dichloromethane to dimethyl sulfoxide).

234 ly reactive complexes abstract chloride from dichloromethane to generate U(NDipp)(2)Cl(R(2)bpy)(2) or

235 cal 1+ slowly abstracts a chlorine atom from dichloromethane to give the 18-electron complex [ReCp(CO

236 It reacts with dichloromethane to give the [Zr]Cl[OCH2CH2N(CH2Cl)(i)Pr2

237 te and trifluoromethanesulfonic anhydride in dichloromethane to provide a ready source of the nitroni

238 ing: On BDD, this pathway accounted for 40% (dichloromethane) to 100% (tetrachloromethane) and on TDI

239 butylhydrogen peroxide, trifluoroacetic acid-dichloromethane) to form mixtures of the chain isomer of

240 Recrystallization of O-PtC(2) from dichloromethane/toluene gave single crystals of PtC(2) x

241 rt-butyl-4-methylpyridine as the base, and a dichloromethane/toluene solvent mixture, ethyl 1-thio-be

242 BDD produced mainly short chained OCBPs (dichloromethane, trichloromethane, and tetrachloromethan

243 ate monoester anhydrides form efficiently in dichloromethane/triethylamine from 1 equiv of the alcoho

244 Thus, heating an aminobenzanilide in dichloromethane under reflux in the presence of 1 equiv

245 Solutions of (p-tosyl)CH(2)NCAuCl in dichloromethane undergo significant oligomerization lead

246 chloromethane-fermenting culture transformed dichloromethane up to three times faster with Fe(0) comp

247 performed in toluene over those obtained in dichloromethane using the diastereomeric chiral cationic

248 rylene dyad (PDIPe) has been investigated in dichloromethane using ultrafast transient electronic abs

249 ent exposure of these crystals to acetone or dichloromethane vapor results in the reformation of crys

250 Dichloromethane was classified as likely to be carcinoge

251 ntional continuous overnight extraction with dichloromethane was used to remove NDMA from the aqueous

252 les and placed in a two-phase liquid such as dichloromethane/water, these materials will accumulate a

253 Crystals grown from benzene and dichloromethane were characterized by X-ray diffraction,

254 iquid, and compared to a similar reaction in dichloromethane, where these parameters were found for r

255 relatively stable mixed-valence state in the dichloromethane, whereas in the acetonitrile both the fi

256 are safer solvents than the previously used dichloromethane, which can form an explosive byproduct w

257 ained by fast precipitation from hexanes and dichloromethane, which displayed slower dynamics within

258 mol concentrations at 25 degrees C for 4h in dichloromethane with 200- to 5000-fold excess of BODIPY

259 ReL3 reduces acids to H2 in dichloromethane with an overpotential of 380 mV and a tu

260 th various aldehydes using 10 mol % InBr3 in dichloromethane with high selectivity.

261 udied as glucosyl donors at -60 degrees C in dichloromethane with preactivation by 1-benzenesulfinyl

262 ] capable of delivering dichloromethide from dichloromethane with subsequent transfer to nitrones und

263 sing a one-phase extraction method (methanol-dichloromethane) with appropriate internal standards.

264 n near lambda(max)700 nm (epsilon: 45 000 in dichloromethane) with singlet oxygen ((1)O2) production

265 the regioselectivity of this reaction, as in dichloromethane without TBAF the 2,7-diamino isomer was

266 Sustained growth in dichloromethane would therefore offset some of the gains