ライフサイエンスコーパス: diffusion-limited

1 e if both the N(3)(-) and d-G reactions were diffusion limited.

2 tant, regardless of whether enzyme action is diffusion limited.

3 ried to determine if the folding reaction is diffusion limited.

4 r enzymes where reaction rates are typically diffusion limited.

5 that detection and capture is predominantly diffusion limited.

6 ier, and the rate of monomer addition is not diffusion-limited.

7 ents no energetic barrier and, therefore, is diffusion-limited.

8 second-order rate constant was approximately diffusion-limited.

9 tranded 30-mer/36-mer complex) appears to be diffusion-limited.

10 as the substrate, chemistry is thought to be diffusion-limited.

11 P2 concentration and appeared to be largely diffusion-limited.

12 strates and the overall in vitro reaction is diffusion-limited.

13 of small-molecule and protein materials are diffusion-limited.

14 anded polypyrimidine sequences appears to be diffusion-limited.

15 that the action of cytidine deaminase is not diffusion-limited.

16 e, whereas the binding rate is assumed to be diffusion-limited.

17 which the transport of passive substances is diffusion-limited.

18 wth kinetics from edge-attachment-limited to diffusion-limited.

19 Presteady state analysis demonstrates rapid diffusion-limited A3G-ssDNA binding, a slower salt-depen

20 Slow kinetics thus appear related to diffusion-limited access to electron equivalents retaine

21 ration and enzymatic activity (which remains diffusion-limited across pH5-8).

22 s, such as activation of the Ras GTPase, the diffusion-limited activation rate constant increases wit

23 -assembled irregular Au nano-mounds based on diffusion limited agglomeration at comparatively low ann

24 We introduce diffusion limited aggregation (DLA) clusters.

25 gurations that correspond to two-dimensional diffusion limited aggregation structures, suggesting tha

26 drainage networks have symmetries similar to diffusion-limited aggregation clusters.

27 seudoisocyanine dye, an equation derived for diffusion-limited aggregation of a fractal object satisf

28 ronts and the ensembled average shape of the diffusion-limited aggregation pattern, have been shown t

29 ed surfaces and exhibited both reaction- and diffusion-limited aggregation regimes with rates depende

30 ritical coagulant concentration required for diffusion-limited aggregation to occur.

31 been proposed to model landforms, including diffusion-limited aggregation, self-avoiding percolation

32 on, we show that the dynamics of fission are diffusion limited and enable the isolation of an interme

33 um corneum allows one to distinguish between diffusion-limited and dissolution rate-limited kinetics.

34 of the complex we conclude that catalysis is diffusion-limited and does not depend on protein flexibi

35 The transfer reaction is diffusion-limited and influenced by the affinities of th

36 nitial Cry1Ab adsorption rates were close to diffusion-limited and resulted in extensive adsorption,

37 Root uptake of the volatile tracers was diffusion-limited, and uptake rate constants (kv) in veg

38 In the absence of urea, rapid, near diffusion-limited ( approximately 10(9)M(-1)s(-1)) SecA

39 g, it is important to know if a reaction is 'diffusion-limited' as, if this speed limit is reached, t

40 The association process is significantly diffusion-limited, as indicated by the viscosity depende

41 devices with thin enzyme layers that are not diffusion-limited, as it is the case for the PenFETs dis

42 tured by WWCA domains grow at or below their diffusion-limited assembly rate.

43 labeled PAI-1s with trypsin suggested that a diffusion-limited association of PAI-1 and trypsin and r

44 s extremely rapid; association occurs with a diffusion-limited association rate constant.

45 hese simulations, combined with estimates of diffusion-limited association rates, suggest a short lif

46 nce information necessary to direct the near-diffusion-limited association reaction in a TR folding r

47 dimeric intermediate that forms in a nearly diffusion-limited association reaction in the stopped-fl

48 repressor, [2-66]2 TR, consists of a nearly diffusion-limited association reaction to form a dimeric

49 4.8 x 10(7) M(-1) s(-1), suggesting a nearly diffusion-limited association.

50 If k(az) for these ions is diffusion limited at ca. 5 x 10(9) M(-1) s(-1) the aqueo

51 w that while vesicle reloading at AZs is not diffusion-limited at the onset of release, diffusion lim

52 der harsher SALE conditions, deviations from diffusion-limited behavior are found due to etching and

53 The SALE process is found to follow a diffusion-limited behavior leading to core-shell morphol

54 solute ejected using high currents exhibits diffusion-limited behavior.

55 nce and labeling studies are consistent with diffusion-limited bimetallic self-quenching by electron

56 The deviation from diffusion-limited binding indicates that a ligand-specif

57 d immunoassay has been developed to overcome diffusion-limited binding kinetics that often impedes ra

58 This is consistent with the diffusion-limited binding of MBP, in contrast to the rap

59 rotein CD63 were analyzed by measuring their diffusion-limited binding rate to an SPR sensor surface

60 ion in solution using a formalism describing diffusion-limited binding under controlled flow conditio

61 ding rates could not account for affinity if diffusion-limited binding was assumed.

62 , at least 10 times slower than expected for diffusion-limited binding.

63 mately 10(7) M(-1) s(-1) are compatible with diffusion-limited binding.

64 dynamics-is developed for the calculation of diffusion-limited biomolecular association reaction rate

65 ts indicates that the release of Zn2+ is not diffusion limited but is instead kinetically controlled

66 es at or within the surface of the MCLW, the diffusion-limited capture rate has been replaced by fast

67 stable beta-barrel fold and dimer assembly, diffusion-limited catalysis, and electrostatic guidance

68 s to such a degree that activation rates are diffusion limited, causing the two time scales to merge.

69 otocol combining plasmonic nanoantennae with diffusion-limited chemotherapies.

70 enerate virtual aggregates formed via either diffusion limited cluster aggregation or reaction limite

71 Here, we extend the principle of rapid diffusion-limited cluster aggregation (DLCA) to a multic

72 nfinitely strong interparticle bonds lead to diffusion-limited cluster aggregation (DLCA).

73 Monte Carlo simulations, based on a modified diffusion-limited cluster aggregation model, strongly su

74 accord with expectation, varied from 1.7 for diffusion-limited cluster aggregation to 2.3 for reactio

75 dynamics simulations using the framework of diffusion-limited cluster aggregation.

76 ransfer is often slow because it is gated by diffusion-limited collisions between sensitizer and cata

77 This was consistent with diffusion-limited complex formation at basic pH but rapi

78 nd compared CRM, resolving power (R(m)), and diffusion-limited conditional theoretical reduced mobili

79 tion reaction (ORR) was studied under proton diffusion-limited conditions in slightly acidic electrol

80 rt was orders-of-magnitude higher than under diffusion-limited conditions.

81 umns was examined under both adsorption- and diffusion-limited conditions.

82 al groundwater containing O2 or NO3(-) under diffusion-limited conditions.

83 ive enough for the reaction to proceed under diffusion-limited control.

84 s the melting point, thus promoting the film diffusion-limited crystallization.

85 s constant value is the same as that for the diffusion limited current in a semi-infinite medium.

86 acoustic levitation causes an enhancement of diffusion-limited current on the order of 16%.

87 harged porous media at high rates, above the diffusion-limited current.

88 l dependencies in the simulated steady-state diffusion-limited currents are also reported.

89 Comparison of diffusion-limited currents in pendant and levitated drop

90 Fitting diffusion-limited data with regular compartmental models

91 loped to accurately estimate parameters from diffusion-limited data.

92 The diffusion-limited delivery of chemoattractant from a mic

93 We show that our system is not 'diffusion-limited', despite having a k(+) in the often-q

94 (<100 fs) in blends prepared without ODT or diffusion-limited dissociation in samples prepared with

95 ior with defined reaction limited (RLCA) and diffusion limited (DLCA) aggregation regimes.

96 rization of tumor hypoxia as being primarily diffusion-limited does not accurately portray the tumor

97 GSI in vivo resulted in inhibitory but diffusion-limited effects on Notch 3 signaling, resultin

98 ificantly improved mutants, some approaching diffusion-limited efficiency.

99 10(10) M(-1) s(-1), a value consistent with diffusion-limited electron transfer.

100 Ultrafast diffusion-limited electrostatically driven Get3.Get4/5 a

101 -consistently explained by load-insensitive, diffusion-limited elongation of (+)-end-tethered actin f

102 14) binding to a Pm kringle accompanies near-diffusion-limited encounter complex formation followed b

103 o-state model for helix formation yields the diffusion-limited end-to-end contact rate of the coil st

104 ical, whereas the chlorine exchange presents diffusion-limited exchanges proceeding through a more co

105 In a subset of diffusion-limited experiments, we show that kinetic isot

106 is close to that of the source; in contrast, diffusion-limited export leads to small phloem concentra

107 ve between membrane compartments in part via diffusion-limited, fluid phase transfer through the cyto

108 s assembly proceeds through the formation of diffusion-limited, fractally patterned aggregates on the

109 :SERCA regulatory complex was rapid, showing diffusion-limited FTR (tau=1.4 second).

110 eukaryotic pathogens may also be related to diffusion-limited functions.

111 transition from secretion limited growth to diffusion limited growth.

112 clusters and suggest that kinetically (i.e., diffusion) limited growth should not be assumed.

113 that lead to divergent predictions: either a diffusion-limited growth model in which plaques grow by

114 y, it roughens more rapidly, consistent with diffusion-limited growth physics.

115 tion process of oxidized species following a diffusion-limited growth regime for DOPC and in the case

116 ally observed presence of a sub-exponential, diffusion-limited growth regime in colonies, which is ab

117 characterized by a rate that is greater than diffusion limited (>10(10) s(-1) M(-1)) and the second p

118 croarray gap height would delay the onset of diffusion-limited hybridization by increasing the amount

119 Chronic or diffusion-limited hypoxia is relatively well characteriz

120 ular factor will find its mass transfer rate diffusion-limited if it is stationary with respect to it

121 Although oxygen is abundant in vivo, it is diffusion-limited in vitro.

122 The diffusion-limited ion-transfer current increased with th

123 n the length scale at which oxygen supply is diffusion-limited, its occurrence requires very high cel

124 ylammonium as the redox mediator exhibited a diffusion-limited k degrees for the previously KCl-prote

125 )) can be decomposed into contributions from diffusion-limited (k(D)) and reaction-limited (k(R)) rat

126 exchange, consistent with mixed surface- and diffusion-limited kinetics arising from prominent partic

127 n to metallic nanoparticles with essentially diffusion-limited kinetics in a laboratory microwave rea

128 For critical tests of whether diffusion-limited kinetics is an option for the solution

129 l (accuracy <or=7%) for the pair, indicating diffusion-limited kinetics of crystallization.

130 FEN1 sculpts DNA with diffusion-limited kinetics to test DNA substrate.

131 and C2B copenetrate into these bilayers with diffusion-limited kinetics.

132 of protein microarrays can be compromised by diffusion-limited kinetics.

133 ilibrium and the kinetic competition between diffusion-limited lateral lattice growth versus fluctuat

134 While single cell suspensions can improve diffusion-limited mass transfer, direct cell-cell intera

135 his can be achieved by measuring the rate of diffusion-limited mass uptake to a sensor surface modifi

136 sing these array electrodes for steady-state diffusion-limited measurements in electroanalytical appl

137 independent of the tip diameter, indicating diffusion-limited membrane transport of the redox molecu

138 crystal structures employing controlled and diffusion-limited microfluidic environments is demonstra

139 Through the use of a diffusion-limited model for the intimin-tir binding inte

140 ncluding quaternary organization of P450 and diffusion-limited models.

141 ith transport, whilst the former may include diffusion-limited movement of lactate into the bulk cyto

142 in helical domains that move collectively at diffusion-limited nanosecond time scales.

143 leads to an approximately 10,000-fold longer diffusion-limited observation time per molecule than is

144 e stalk as a morphological adaptation to the diffusion-limited, oligotrophic environments where C. cr

145 ations that are prone to bind NTRs with near diffusion-limited on rates, as shown by stopped-flow kin

146 ion of the copper phyllosilicate followed by diffusion-limited or reaction-limited growth of the copp

147 ed with the highest OV exhibited the highest diffusion-limited ORR current (5.5 mA cm(-2) ) among a s

148 of the corresponding current images for the diffusion-limited oxidation of the redox mediator indica

149 ability that is lower than the corresponding diffusion-limited permeability.

150 ition new Glu's for catalysis is as rapid as diffusion-limited positioning of a small substrate, and

151 ing that the movement is directional but not diffusion limited process.

152 y experiments gave results consistent with a diffusion-limited process and revealed a working electro

153 h explosive materials that precedes the slow diffusion-limited process of forming the bulk solid from

154 he volume phase transition of hydrogels is a diffusion-limited process the size of the synthesized hy

155 PRM displays the features consistent with a diffusion-limited process within our experimental condit

156 sed) complex is close to that expected for a diffusion-limited process, (2) the extent of activation

157 eceptors that are slower than expected for a diffusion-limited process, suggesting that agonist bindi

158 ults, the rate constant is undervalued for a diffusion-limited process, suggesting that functional ad

159 s formed that binds GroES weakly in a rapid, diffusion-limited process.

160 essary to determine if the binding is a true diffusion-limited process.

161 Besides the fast complexation reactions, diffusion-limited processes, especially lateral diffusio

162 It has been thought that diffusion-limited protein association is dominated by lo

163 physical time scales of protein folding and diffusion-limited protein-protein encounter has suggeste

164 (i.e. Microtox((R))) or low sensitivity and diffusion limited protocols (i.e. amperometric microbial

165 osphorescence lifetimes and with the help of diffusion-limited quenching with iodide ions.

166 in the absence of nucleotides binds DNA at a diffusion limited rate but cannot efficiently cleave DNA

167 ich is approximately 50-fold slower than the diffusion limited rate of association.

168 and hydrogen peroxide, occurs at nearly the diffusion limited rate.

169 1) s(-1), approximately 40% of the estimated diffusion limited rate.

170 sicles, and calcium ions approached the same diffusion-limited rate (>10(7) m(-1) s(-1)) that has bee

171 at the scissile phosphate, reacts at a fully diffusion-limited rate (k2/K1/2 = 1.1 x 10(9) M-1 s-1).

172 r, with a slope of -1, and extrapolated to a diffusion-limited rate at pK(a)(app) approximately 1.

173 f Rho hexamer interact with poly(C) RNA at a diffusion-limited rate constant close to 8 x 10(8) m(-1)

174 t reacts rapidly with N3- with an apparently diffusion-limited rate constant of (6.6 +/- 0.2) x 10(9)

175 ith [NO] = 200 muM) forming a 6c heme with a diffusion-limited rate constant of 2 x 10(8) M(-1)s(-1).

176 quantity k(lim) represents approximately the diffusion-limited rate constant, and s the free energy d

177 energy but also substantially increases the diffusion-limited rate for complexes in which long-range

178 posed of earth-abundant materials and with a diffusion-limited rate in acidified water, is efficient

179 in the inner vestibule, occurred at the same diffusion-limited rate in both open and closed states.

180 peptides containing the myo1c IQ motifs at a diffusion-limited rate in the presence and absence of ca

181 We show that this rate is also close to the diffusion-limited rate of contact formation.

182 The diffusion-limited rate of intramolecular contact is abou

183 grew approximately 3.4-fold faster than the diffusion-limited rate of unattached barbed ends.

184 ccus furiosus rubredoxin range from near the diffusion-limited rate to a billion-fold slower for the

185 NO then reacts at a nearly diffusion-limited rate with deoxyhemoglobin to form iron

186 This reacted at a diffusion-limited rate with fXa, even without PZ, and pr

187 he wild-type substrate reacts at a partially diffusion-limited rate, and a faster-reacting SRL, conta

188 Cu(2+) binds to Abeta at a near diffusion-limited rate, initially forming component I.

189 Since *NO reacts with LOO* at an almost diffusion-limited rate, steady state concentrations of 3

190 detect dissolved electroactive species at a diffusion-limited rate.

191 sociation rate constants were at or near the diffusion-limited rate.

192 tion of profilin-actin above the theoretical diffusion-limited rate.

193 rstitial space, where it neutralizes NO at a diffusion-limited rate.

194 Here we show how nearly diffusion-limited rates are achieved, by analysing ion c

195 For long chains, both reaction-limited and diffusion-limited rates are significantly smaller in den

196 end diffusion coefficients obtained from the diffusion-limited rates are smaller than the sum of the

197 s to actively elongating complexes at nearly diffusion-limited rates but remains bound for only 0.3-0

198 Both sensitizers were quenched at nearly diffusion-limited rates by 1 and 2.

199 Thus, VIIa.TF is inhibited at near diffusion-limited rates by Xa.TFPI formed during catalys

200 een used to measure the reaction-limited and diffusion-limited rates of loop formation in disordered

201 A Stern-Volmer analysis yielded much larger diffusion-limited rates than simple kinetic theory predi

202 These radicals react at diffusion-limited rates to form the powerful oxidant per

203 pport transmembrane ion conduction at nearly diffusion-limited rates while discriminating for K+ over

204 , a product of NO and O2- that forms at near diffusion-limited rates, and rapidly decomposes upon pro

205 tic efficiency of 2.6 x 10(8) M(-1) s(-1), a diffusion limited reaction indicating catalytic perfecti

206 A and H2B polypeptides associate in a nearly diffusion limited reaction to form a dimeric ensemble, d

207 Since peroxynitrite is formed by the diffusion-limited reaction between the two radical speci

208 oxidizing species as a result of the nearly diffusion-limited reaction between tyrosyl radical and s

209 a transition state model by a switch from a diffusion-limited reaction in native RCs, where electron

210 loading while eliminating the constraints of diffusion-limited reaction kinetics.

211 and nitrating species, is formed by the near diffusion-limited reaction of .NO and O2.- during activa

212 of peroxynitrite (ONOO(-)) arising from the diffusion-limited reaction of exogenous NO and endogenou

213 ynitrite (ONOO(-)/ONOOH), the product of the diffusion-limited reaction of nitric oxide (*NO) with su

214 eroxynitrite is formed in macrophages by the diffusion-limited reaction of superoxide and nitric oxid

215 eady-state kinetic parameters that suggest a diffusion-limited reaction of UCH-L3 with Ub-AMC.

216 The diffusion-limited reaction rate constant is shown to sca

217 ensions serves as a model for predicting the diffusion-limited reaction rate, as first discussed by v

218 The glycerol effect suggests a diffusion-limited reaction, and the small salt effect in

219 1)) that are much lower than predicted for a diffusion-limited reaction.

220 s deduce that RecQ binds to ssDNA via a near diffusion-limited reaction.

221 y intermediates that may otherwise form in a diffusion-limited reaction.

222 Northrup and Erickson model of docking-type diffusion-limited reactions and yields reaction rate con

223 mes of the HemNP homoaggregation rate in the diffusion-limited regime.

224 , despite having a k(+) in the often-quoted 'diffusion-limited' regime (10(5)-10(6) M(-1) s(-1) at hi

225 n order of magnitude lower than the expected diffusion limited resolution (Rmax).

226 ide linear range of 0.8-200mM chloride and a diffusion-limited response time; sweat chloride levels c

227 lso showed the reduced iR drop, steady-state diffusion-limited response, and reduced sensitivity to c

228 erent redox systems; well-defined and stable diffusion-limited responses were obtained in all but two

229 RPLC adsorption of hemoglobin (a system with diffusion-limited retention) was found to give 95% bindi

230 ant folate in plasma) is also a potent, near diffusion limited, scavenger of singlet oxygen and quenc

231 rofile and the simulated results for a fast, diffusion-limited second-order annihilation process (k(a

232 west central Colorado contains fine-grained, diffusion-limited sediment lenses that are substantially

233 nomer folding reaction is followed by a near diffusion-limited self-association reaction to form the

234 isopropylethoxysilane (APDIPES) yielded near diffusion-limited separations and exhibited little chang

235 eory to biological problems in 2D shows that diffusion-limited signalling is an efficient mechanism o

236 are needed for optimal tumor growth beyond a diffusion-limited size.

237 3.25 x 0.9 mm(2) area can be captured with a diffusion-limited spatial resolution of 750 mum.

238 tent species can bind ligand at or very near diffusion-limited speeds, suggesting that the binding po

239 lection mode revealed that, under apparently diffusion-limited steady-state conditions, there was a s

240 cal equations were developed to describe the diffusion-limited steady-state current and steady-state

241 the transferred charges per species from the diffusion-limited steady-state current.

242 In addition, simulations of the diffusion-limited steady-state currents at the integrate

243 chemical events in catalysis rather than by diffusion-limited substrate binding or product release.

244 pact CSR-FGF-2-HSPG triad formation assuming diffusion-limited surface reactions.

245 l tert-butyl ether, methyl isobutyl ketone), diffusion-limited (theoretical), R d, conditional, R c,

246 consistent with enhanced oxygen flux within diffusion-limited tracheal systems.

247 or pyrene accumulation were much slower than diffusion-limited transport of solute in solution to the

248 ceptors into the clusters is consistent with diffusion-limited trapping with D approximately 10(-1) m

249 different condition such as hypoxia within a diffusion-limited tumor region.

250 aw suggests that catalysis will be about 50% diffusion limited under conditions where [substrate] <<

251 the enzyme-catalyzed steps are significantly diffusion limited under physiological conditions.

252 The folding rate approaches the diffusion-limited value and is much faster than possible

253 The kf was slower than a diffusion-limited value, suggesting that conformational

254 are apparent when the potential is below the diffusion-limited value.

255 r occurred with a rate constant close to the diffusion-limited value.

256 This increase in Koff was not diffusion limited, was independent of AMPAR endocytosis,

257 g in a relatively inert pathway conducive to diffusion-limited water flow.

258 ,4'-trihydroxychalcone are approximately 50% diffusion-limited, whereas the reactions of both dihydro

259 of cGMP hydrolysis by light-activated PDE is diffusion limited, which is not the case for spontaneous

260 actions, the product formation appears to be diffusion limited, with a number of intermediate phases

261 The transducer's response time is diffusion-limited, with a typical measurement requiring

262 The electrophoretic separation is diffusion-limited, without significant adsorption of the

263 Geochemical gradients that developed in the diffusion-limited zones led to locally supersaturated co

264 nerals that form in dead-end one-dimensional diffusion-limited zones that are connected to a larger r