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1 s quantifies both the exchange (<30 neV) and dipolar (23.5+/-1.5 neV) interaction energies responsibl
3 ead to excitation of significantly different dipolar and charge transfer plasmon (CTP) resonances, re
5 ibution clarifies the relative importance of dipolar and entropic forces in the assembly process and
6 an analytical expression accounting for both dipolar and exchange coupling to simulate the time trace
7 cial selection rule and the induced electric dipolar and magnetic quadrupolar radiation from the two
10 applications of solid-state NMR by unifying dipolar and quadrupolar interactions and highlights the
11 terparticle spin-spin interactions (magnetic-dipolar and spin-exchange) between charge-carrier spin p
13 erostructured tetrapod that is capable of 1D dipolar assembly into colloidal polymers that carry tetr
15 and V40 as well as between M35 and G37 in 2D dipolar-assisted rotational resonance spectra, and close
16 e achieved via a sequence of selective [1,3] dipolar azide-alkyne cycloadditions (AACs) or carbamate
17 olarophile intermediates that react with 1,3-dipolar azomethine imines to generate dinitrogen-fused s
22 neutron scattering measurements showing that dipolar CH3NH3(+) ions reorientate between the faces, co
24 of solution- and solid-state NMR to measure dipolar, chemical shift, and quadrupolar tensors in aque
25 an electron donor-acceptor (D-A) substituted dipolar chromophore (BTPA-TCNE) is developed to serve as
26 ained in high yields in copper-catalyzed 1,3-dipolar "click" cycloaddition using bis(TMS)butadiyne an
28 th microtubules, derived by recording direct dipolar contacts between CAP-Gly and tubulin using doubl
29 loit the presence of sizable quadrupolar and dipolar contributions in the uranium L3-edge X-ray absor
30 proximity between a spin and a certain other dipolar-coupled pair of spins in addition to regular SQ/
32 on CEACAM1-IgV dimerization and use residual dipolar coupling (RDC) measurements to characterize the
34 ow the plasticity in the model-free residual dipolar coupling (RDC) order parameters and in an ensemb
35 me P450(cam) (CYP101) obtained from residual dipolar coupling (RDC)-restrained molecular dynamics (MD
36 ngle, small-angle X-ray scattering, residual dipolar coupling and inter-domain NOE nuclear Overhauser
37 e resolved and well simulated using distinct dipolar coupling constants DCalphaH and DCalphaD for the
38 one-shot determination of accurate residual dipolar coupling constants from a single NMR spectrum.
39 mall angle X-ray scattering and NMR residual dipolar coupling data demonstrates unambiguously that th
41 al contributions; when coupled with residual dipolar coupling data, a KGSrna ensemble revealed a prev
43 present NMR resonance assignments, residual dipolar coupling data, functional analysis, and a struct
44 omain walls, but their density is limited by dipolar coupling from their fringing magnetic fields.
45 somers to deconvolve the influence of SAM-LC dipolar coupling from variations in molecular geometry,
46 infer that water exhibits distinct (1)H-(1)H dipolar coupling networks with the backbone and side-cha
47 teraction strength, we elucidate the role of dipolar coupling of molecular monolayers to their enviro
50 alone, but the addition of NMR RDC (residual dipolar coupling) restraints improves the structure mode
51 al transition moment and the axis of maximum dipolar coupling, is also confirmed by magnetophotoselec
52 his study is in good agreement with residual dipolar coupling, paramagnetic resonance enhancement, sm
56 e difference between two successive residual dipolar couplings (DeltaRDCs) involving C6/8-H6/8, C3'-H
57 spectroscopy (NOESY) spectroscopy, residual dipolar couplings (RDCs) and paramagnetic relaxation enh
64 proach based on measurement of many residual dipolar couplings (RDCs) in differentially orienting aqu
67 tes between dipolar interactions to residual dipolar couplings (RDCs) of individual consecutive H(N)-
69 EST) NMR spectroscopy for measuring residual dipolar couplings (RDCs), which provide unique long-rang
70 e experimental data afforded by NMR residual dipolar couplings (which yield both orientational and sh
72 troscopy, including measurements of residual dipolar couplings and molecular dynamics simulations, to
74 ether with spectroscopic selections based on dipolar couplings as well as two-dimensional spin-diffus
76 landscape of the complex using NMR residual dipolar couplings in replica-averaged metadynamics simul
77 ), the close to zero values for the residual dipolar couplings of the backbone amides, and minimal de
78 veal enantiotopic recognition using residual dipolar couplings or to determine the absolute configura
79 iment DROSS, we resolved (13)C-(1)H residual dipolar couplings that were interpreted with a statistic
80 ng chemical shift perturbations and residual dipolar couplings was employed to obtain a structural mo
81 d peptide would be evident in local residual dipolar couplings, and possibly differences in homonucle
82 ttering, nuclear magnetic resonance residual dipolar couplings, dipolar electron-electron resonance s
83 ased on NOE distance restraints and residual dipolar couplings, shows that the NHR and CHR helices re
88 OESY cross-peaks that cannot be explained by dipolar cross-relaxation or chemical exchange are descri
89 ive pentacyclic intermediate formed by a 1,3 dipolar cyclo-addition of prFMN with the alpha-beta doub
90 that prFMN can function as a dipole in a 1,3 dipolar cyclo-addition reaction as the initial step in a
93 prolinates, obtained by enantiocatalyzed 1,3-dipolar cycloaddition (1,3-DC) of imino esters and nitro
97 heterocyclic scaffolds involves a formal 1,3-dipolar cycloaddition between nitrile ylides or nitriliu
98 n/hydroxylamine oxidation/intramolecular 1,3-dipolar cycloaddition cascade efficiently converted an o
99 hereby combining the key features of the 1,3-dipolar cycloaddition chemistry of azides and cyclopropa
100 inhibitor-cofactor adduct suggests that 1,3-dipolar cycloaddition chemistry supports reversible deca
101 a catalytic asymmetric azomethine ylide 1,3-dipolar cycloaddition followed by an intramolecular Au(I
102 for a highly regio- and stereoselective 1,3-dipolar cycloaddition in the presence of an aminocatalys
103 the reaction can be considered a normal 1,3-dipolar cycloaddition involving M horizontal lineC bonds
104 Finally, we showed that Cu-catalyzed 1,3-dipolar cycloaddition is also chemically compatible with
107 in the Machetti-De Sarlo base-catalyzed 1,3-dipolar cycloaddition of acrylamide to N-methylnitroacet
108 o rationalize stereoselectivities of the 1,3-dipolar cycloaddition of chiral allyl ethers and emphasi
109 -u have been achieved in high yields via 1,3-dipolar cycloaddition of compound 3 with various alkynes
110 ormation of pyrazolines by means of a formal dipolar cycloaddition of cyclic alpha,beta-unsaturated k
111 oits a known bioorthogonal reaction, the 1,3-dipolar cycloaddition of nitrileimines and electron-poor
114 pure pyrrolidines have been obtained by 1,3-dipolar cycloaddition of stabilized azomethine ylides an
115 m the major cycloadducts obtained by the 1,3-dipolar cycloaddition of sugar enones with azomethine yl
116 onate 1,5-shift precursor, a copper-mediated dipolar cycloaddition reaction ("click") with azide part
117 or templates its own synthesis through a 1,3-dipolar cycloaddition reaction between a nitrone compone
118 gment, using the Cu(I)-catalyzed Huisgen 1,3-dipolar cycloaddition reaction of azides and alkynes.
120 omologation, transphosphorylation, and a 1,3-dipolar cycloaddition reaction of diazoalkylphosphonates
122 tors of DM2 RNA dysfunction by a Huisgen 1,3-dipolar cycloaddition reaction, a variant of click chemi
127 the use of independent (nontethered) bis-1,3-dipolar cycloaddition reactions and the characterization
128 arylacridines has been developed via the 1,3-dipolar cycloaddition reactions of arynes with N-oxides.
129 nition sites-that react pairwise through 1,3-dipolar cycloaddition reactions to create a network of f
130 dergo irreversible, recognition-mediated 1,3-dipolar cycloaddition reactions with a stoppering maleim
132 hich are prepared in situ, is exemplified by dipolar cycloaddition reactions with nitrones to give hi
133 dine recognition site can participate in 1,3-dipolar cycloaddition reactions with two maleimides that
136 thine ylides via the domino Mannich reaction-dipolar cycloaddition to form 3,3-disubstituted pyrrolid
138 to oximes, cyclization to nitrones, and 1,3-dipolar cycloaddition to tricyclic isoxazolidines as sin
139 tion and intramolecular azomethine ylide 1,3-dipolar cycloaddition toward the total synthesis of (+/-
140 s and 3,3-difluoropyrrolidines through a 1,3-dipolar cycloaddition with a simple azomethine ylide and
144 ivation of nitro-olefins facilitated the 1,3-dipolar cycloaddition with hydrazones, affording optical
147 tuted BODIPY via the copper(I)-catalyzed 1,3-dipolar cycloaddition yielding the first corrole-BODIPY
148 more, these cycloadducts underwent retro-1,3-dipolar cycloaddition yielding unexpected regioisomers.
149 rough a tandem Knoevenagel condensation, 1,3-dipolar cycloaddition, and transition metal-free oxidati
150 trapping it with appropriate alkenes via 1,3-dipolar cycloaddition, the details of the overall mechan
151 mplex as a catalyst following a two-step 1,3-dipolar cycloaddition/intramolecular alkylation sequence
154 lidene carbene mediated Li-N insertions, and dipolar cycloadditions by controlling the reaction param
158 dipoles and catalysts have been used in 1,3-dipolar cycloadditions of N-metalated azomethine ylides
160 razolo[1,5-a]pyridin-2(1H)-ones, whereas 1,3-dipolar cycloadditions of these dipoles to typical acety
161 ences for the preferred reaction path of 1,3-dipolar cycloadditions to acetylenes should be of consid
162 to give tetrahydroindolizines (stepwise 1,3-dipolar cycloadditions with 3) and cyclopropanes (with 4
163 Az10) that undergoes copper(I)-catalyzed 1,3-dipolar cycloadditions with alkynes to yield strongly fl
165 ) cycloadditions, including diazomethane 1,3-dipolar cycloadditions, a thermally promoted methylenecy
166 hydroboration and diboration of alkenes, 1,3-dipolar cycloadditions, alkynylation of iminium salts in
171 nza A full length M2 protein, the buildup of dipolar-dephased (15)N signals from the tetrad of His37
172 hange process can be monitored indirectly by dipolar-dephased (15)N signals through polarization tran
178 gly electron donating carbene groups and (2) dipolar effects arising from the syn relationship betwee
179 n addition to the expected electrostatic and dipolar effects caused by the charged residues (Glu113,
180 lectric and magnetic delocalized modes, only dipolar electric and quadrupolar magnetic modes remain a
185 gnetic resonance residual dipolar couplings, dipolar electron-electron resonance spectra), the range
188 aberrations in the point spread function of dipolar emitters, which can adversely affect the quality
192 metal ion binding stoichiometry, and pulsed dipolar ESR spectroscopy evaluated the Cu(2+) binding si
193 show how DEER experiments can be extended to dipolar evolution times of ca. 80 mus, permitting distan
194 We have investigated numerically toroidal dipolar excitation at optical frequency in metamaterials
195 tic dipolar resonances leads to the toroidal dipolar excitation, when space-inversion symmetry is bro
197 s propagate binary information by relying on dipolar field coupling to reorient closely spaced nanosc
199 er moments turn in-plane and act to yoke the dipolar fields from the adjacent hard layer perpendicula
200 involves preliminary generation of a key 1,2-dipolar gallium complex and its subsequent participation
203 few million years has indeed been dominantly dipolar in intensity yet only approximately 60% of the p
204 spin ice that is made up of a large array of dipolar interacting nanomagnets and undergoes phase tran
205 report a quantitative study on the magnetic dipolar interaction between singlet-fission-induced corr
206 as Smax V cr(-0.37), which tallies with a dipolar interaction exponent of 2/3 in EC materials and
209 een the considered confined geometry and the dipolar interaction underlying the ferroelectric phase i
214 ..pi) interactions and long-range attractive dipolar interactions (C-Cl and NO2) could lie at the ori
219 mental effects of inter-radical exchange and dipolar interactions can be minimised by placing the rad
220 tial TiO2 coating, during which the magnetic dipolar interactions induced the anisotropic self-assemb
222 ractions and minimization of Mn-nuclear spin dipolar interactions result in unprecedentedly long phas
223 ss-correlated relaxation (CCR) rates between dipolar interactions to residual dipolar couplings (RDCs
224 the molecule unit and strong intra-molecular dipolar interactions using strong anisotropy metal ions
225 ar molecules, with their long-range electric dipolar interactions, offer a unique platform for studyi
226 ficient identification of numerous (1)H-(1)H dipolar interactions, which provide distance constraints
233 motion is generated through a combination of dipolar interparticle gradient forces, time-dependent to
234 or the first time as dipolarophiles in a 1,3-dipolar intramolecular cycloaddition reaction, leading t
236 e of their surface chemistry, in particular, dipolar ligands and exciton-delocalizing ligands, on the
241 ction we adjusted the extinction peak of the dipolar mode at the telecommunication band (lambda 1.55
242 mperature dependence of reorientation of the dipolar molecular cations systematically described here
243 ere, we show that a two-dimensional array of dipolar molecular rotors can undergo simultaneous rotati
245 d to behave as an acceptor and thus generate dipolar molecule with mu above 5 D, whereas in 2b and 2d
247 designed for two-photon absorption behave as dipolar molecules in the S1 electronic excited state.
249 tetrapod from CdSe@CdS that carries a single dipolar nanoparticle tip from a core-shell colloid of Au
250 halide perovskites can be attributed to the dipolar nature and the dynamic behavior of these cations
252 dines that cannot be attributed to classical dipolar NOE or chemical exchange peaks have been investi
253 ic interaction, changing it to predominantly dipolar or even to exponential one at lateral distances
254 of particle-particle spacing enabled either dipolar or quadrupolar lattice modes to be selectively a
256 -state NMR site-specific measurements of the dipolar order parameters and (15)N rotating frame spin-l
257 osecond timescales, and the experimental NMR dipolar order parameters are in quantitative agreement w
259 No quantitative correlation between the dipolar orientation of the water-wires and their effects
263 ically exist in three-dimensional systems of dipolar particles with weakly broken time-reversal symme
264 lasmon peak of Au nanoparticles and in-plane dipolar peak of Ag@Au NPLs relies on the intensity and d
266 Couplings between protons, whether scalar or dipolar, provide a wealth of structural information.
267 r response of a meta-atom, resulting in e.g. dipolar, quadrupolar, or multipolar emission on demand.
271 molecular and intramolecular distances using dipolar recoupling techniques, solid state NMR chemical
272 fp-RFDR (finite-pulse radio-frequency-driven dipolar recoupling) pulse sequence under ultrafast MAS.
274 um is sensitive to the lipid composition and dipolar relaxation arising from water penetration, but d
275 s shift) for exposed Trp directly reports on dipolar relaxation near the interface (both water and po
276 ve-absorbing mechanism reveal a unique Debye dipolar relaxation with an Eddy current effect in the ab
277 o determine the contribution of polarity and dipolar relaxations of LAURDAN in each pixel of an image
278 Our theoretical model reveals that in-plane dipolar repulsion between petals in the cluster favors t
279 in is a foldamer for strand mimicry in which dipolar repulsion is a central determinant of conformati
280 The strong coupling among three magnetic dipolar resonances leads to the toroidal dipolar excitat
281 nanodisks and substrate forms three magnetic dipolar resonances, at normal incidence of plane electro
283 he excited state evolves further to a purely dipolar S1 state with the excitation localized entirely
284 O/SAM/SHSAM surface potential imposed by the dipolar SAMs causes band bending and favorably alters th
287 he creation of new states of matter (such as dipolar skyrmions, hedgehog states) and associated pheno
288 approach for determining the strength of the dipolar solute-induced reaction field, along with the gr
289 pping separation using mixed aqueous-aprotic dipolar solvent (N,N-dimethylacetamide (DMA) and N,N-dim
290 in-crystal ground state of artificial kagome dipolar spin ices and high-energy, low-entropy 'monopole
291 en, disordered ensemble of about one million dipolar spin impurities in diamond at room temperature.
292 high precision the (1)H(alpha)-(13)C(alpha) dipolar tensor and carboxylate chemical shift anisotropy
293 alysis of backbone (1)H-(15)N and (1)H-(13)C dipolar tensors and peak intensities from 3D MAS NMR spe
294 tural degrees of freedom beyond the familiar dipolar terms responsible for (anti)ferroelectric order.
297 tudies on the low-temperature physics of the dipolar trident lattice, but also demonstrate how this f
298 ok into an artificial frustrated system, the dipolar trident lattice, where the balance of competing
300 n powder samples by mixing with the strongly dipolar zwitterionic p-benzoquinonemonoimine C6 H2 (-cdo
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