ライフサイエンスコーパス: electrolysis

1 Koutechy-Levich plots, and constant-current electrolysis).

2 showing substantial promise for use in water electrolysis.

3 plore its use in fabrication of solar-driven electrolysis.

4 ccessfully fabricated for bifunctional water electrolysis.

5 dition of As(III) during the course of water electrolysis.

6 s sunlight to electricity and H(2) via water electrolysis.

7 offers many advantages compared to a direct electrolysis.

8 corporated them into Al(OH)3(s) flocs during electrolysis.

9 f the catalyst was demonstrated by continued electrolysis.

10 hemical double layer under the conditions of electrolysis.

11 tributed to the ions produced as a result of electrolysis.

12 ion ratio against H2O2 production during H2O electrolysis.

13 ved leading to better destabilization during electrolysis.

14 n be produced at separate times during water electrolysis.

15 or in high-surface-area electrodes for water electrolysis.

16 oxygen depolarized cathode for chlor-alkali electrolysis.

17 the content of nitrite or nitrate ions upon electrolysis.

18 ctrode, completely eradicates fouling during electrolysis.

19 site polarity, is termed herein as ambipolar electrolysis.

20 ions during H(2) electro-oxidation and H(2)O electrolysis.

21 250 microm Pt minidisc working electrode for electrolysis.

22 perchlorate at a nanomolar level without its electrolysis.

23 ggesting a reliable cathode material for CO2 electrolysis.

24 frequency (DC) without excessive problems of electrolysis.

25 etallic trapping structures because of water electrolysis.

26 that there were 4 species present during the electrolysis.

27 produced at a Pt counter electrode by water electrolysis.

28 bamazepine (>80%) was achieved within 3 h of electrolysis.

29 gnificant alteration after more than 80 h of electrolysis.

30 ity and mass activity towards alkaline water electrolysis.

31 es the most energy-inefficient step in water electrolysis.

32 talyst at the anode and cathode during water electrolysis.

33 oelectrochemistry after controlled-potential electrolysis.

34 ed with these TiO2 |MnP electrodes after 2 h electrolysis.

35 ic voltammetry (CV) and controlled potential electrolysis.

36 voltammetry and controlled-potential (bulk) electrolysis.

37 ivation of the catalyst during the course of electrolysis.

38 rt-chain carboxylates to esters via membrane electrolysis and biphasic esterification.

39 increasingly used in solid oxide fuel cells, electrolysis and catalysis, it is desirable to obtain a

40 rmance, but also offer proof of concept that electrolysis and fuel cells can be unified in a single,

41 tified for alkaline and neutral medium water electrolysis and fuel cells.

42 cted to monitor protein concentration during electrolysis and gauge changes in the electrode surface

43 licate mineral dissolution with saline water electrolysis and H2 production to effect significant air

44 evolution reaction (OER) in PEM based water electrolysis and metal air batteries remains one of the

45 s of overall water splitting by membraneless electrolysis and photocatalysis.

46 kes it possible to overcome problems such as electrolysis and the absence of steady flows.

47 ) center, as observed with preparative scale electrolysis and verified with (13)CO2.

48 is rate limiting in both the forward (water electrolysis) and reverse (H2 electro-oxidation) reactio

49 of reactions, those initiated by electrons (electrolysis) and those initiated by gaseous neutral spe

50 iently split to hydrogen by molten hydroxide electrolysis, and chlorine, sodium, and magnesium from m

51 ariety of applications, including catalysis, electrolysis, and photovoltaics.

52 electrolyte (Nafion membrane) is used in an electrolysis apparatus.

53 sities of approximately 1 mA/cm(2) over 30-h electrolysis are achieved at a 2.5-V cell voltage, split

54 radicals (e.g., HO(*)) generated from water electrolysis are responsible for defect formation on gra

55 e flow geometry design where the products of electrolysis are washed away downstream of the electrode

56 of lattice oxygen in the mechanism of water electrolysis as revealed through ab initio modelling.

57 nm) and polydispersity during just 15 min of electrolysis at -0.80 V (vs RHE).

58 Controlled-potential electrolysis at 1.61 V vs NHE at pH 7.2 resulted in sust

59 a synthetic precedent for such a core, bulk electrolysis at 900 mV (versus Fc(+/0)) has been perform

60 volution takes place in controlled potential electrolysis at a relatively low overpotential of 640 mV

61 and cimetidine was achieved within 30 min of electrolysis at an applied potential of 3.5 V (0.7 A L(-

62 Hydrogen evolution can be easily achieved by electrolysis at large potentials that can be lowered wit

63 roves the reaction kinetics, and enables the electrolysis at low temperatures.

64 After checking electrolysis at the reported potential and at a more neg

65 The fabricated chip includes three electrolysis-based electrochemical pumps, one for loadin

66 This nickel was not added to the electrolysis baths deliberately, but it was found to be

67 When coupled to electrolysis, biodegradation of 1,4-dioxane was sustaine

68 the costs of hydrogen production from water electrolysis by serving as stable, low-cost supports for

69 ll the technologies for H2 production, steam electrolysis by solid oxide electrolysis cells (SOECs) h

70 This work demonstrated that bulk electrolysis can be achieved in a few seconds in these a

71 dialysis membrane interface that eliminates electrolysis-caused protein oxidation/reduction and cons

72 l reaction proceeds through constant current electrolysis (CCE) by taking advantage of the dual role

73 into ethanol was investigated in a microbial electrolysis cell (MEC) driven by the exoelectrogen Geob

74 Consequently, we developed a microbial electrolysis cell (MEC) driven by the synergistic metabo

75 When a mixed-culture microbial electrolysis cell (MEC) is fed with a fermentable substr

76 The capacity of a microbial electrolysis cell (MEC) to produce hydrogen gas (H2) usi

77 c treatment system that combined a microbial electrolysis cell (MEC) with membrane filtration using e

78 ic performance with a H2-producing microbial electrolysis cell (MEC).

79 The microbial electrolysis cell can achieve high conversion efficiency

80 odel is proposed for the optimization of the electrolysis cell characteristics.

81 e found that the durability of the AEM-based electrolysis cell could be improved by incorporating a h

82 At 50 degrees C, an AEM electrolysis cell using iridium oxide as the anode catal

83 The efficacy of our electrolysis cell was further demonstrated by a 20 L pro

84 We demonstrated an AEM-based electrolysis cell with a lifetime of >535 h.

85 forming a microbial reverse-electrodialysis electrolysis cell.

86 lectrogenesis in the bioanode of a microbial electrolysis cell.

87 ructures perform well as both fuel cells and electrolysis cells (for example, at 900 degrees C they d

88 in the rate of acetate removal in microbial electrolysis cells (MECs), but studies with fermentable

89 d at -0.06 V (vs) SHE in duplicate microbial electrolysis cells (MECs).

90 on study of ammonia recovery using microbial electrolysis cells (MECs).

91 roduced in microbial reverse-electrodialysis electrolysis cells (MRECs) using current derived from or

92 roduction, steam electrolysis by solid oxide electrolysis cells (SOECs) has attracted much attention

93 conversion systems such as solid oxide fuel/electrolysis cells and catalysts for thermochemical H2O

94 The electrolysis cells employ multilayer semiconductor anode

95 atively high redox potentials, and microbial electrolysis cells for reducing Cd(II) as this metal has

96 dizing a fuel to produce electricity, and as electrolysis cells, electrolysing water to produce hydro

97 as mixing in the headspaces of high-pressure electrolysis cells, with implications for safety and ele

98 electrode, SHE) in single-chamber microbial electrolysis cells.

99 photosynthesis, fermentation, and microbial electrolysis cells.

100 xternal power needed to drive the catalyst's electrolysis chemistry.

101 Upon electrolysis, chloride is deposited at the Ag electrode

102 ntional extraction practices, direct sulfide electrolysis completely avoids generation of problematic

103 ough long-term potential cycles and extended electrolysis confirm the exceptional durability of the c

104 Br2]Br, and [Co(TimMe)(CH3CN)2](BPh4)3, bulk electrolysis confirmed the catalytic nature of the proce

105 Compared with abiotic electrochemical electrolysis control, the microbial assisted graphite ox

106 Ambipolar electrolysis could enable new approaches to recycling co

107 ablish the experimental relationship between electrolysis current and solution velocity.

108 signals were used for distance control: the electrolysis current of a mediator (constant-current mod

109 catalytic electrodes for incorporation into electrolysis devices.

110 haloacetic acids and trihalomethanes) during electrolysis dramatically exceeded recommendations for d

111 The electrolysis electrodes were formed from either platinum

112 idation" to benzoic acids; H2 is released by electrolysis, enabling additional reaction cycles.

113 cathode, respectively, achieving a very high electrolysis energy efficiency exceeding 80% at consider

114 The OER catalytic activity as well as electrolysis energy efficiency surpasses any previously

115 tside the electrolyzer that requires no post-electrolysis energy input.

116 drogen with high Faradaic efficiency in bulk electrolysis experiments over time intervals ranging fro

117 of nickel on anodes from extended-time bulk electrolysis experiments was confirmed by XPS.

118 DC-powered laboratory-scale electrolysis experiments were performed under static ano

119 e oxidation products, preparative scale bulk electrolysis experiments were undertaken.

120 Controlled potential electrolysis experiments with 1 at pH 8.0 at an applied

121 In preparative electrolysis experiments with a series of alcohol substr

122 In bulk electrolysis experiments, conducted at -1.2 V vs SCE usi

123 ucts have been characterized by voltammetry, electrolysis, fiber-optic IR spectroscopy, and ESR measu

124 ed alpha(2)-P(2)W(17)O(61)(12-) through bulk electrolysis followed by the addition of (99)TcO(4)(-).

125 This approach employs electrolysis for precise dosing of the requisite acid or

126 After electrolysis, full equilibration of the alkalized soluti

127 The preparative scale electrolysis generated epoxide-ring-opened/Friedel-Craft

128 al of eta = 360 mV, and controlled potential electrolysis generated more than 1000 turnovers at eta =

129 .3 nm increase to only 2.2 +/- 0.5 nm during electrolysis in 0.10 M NaHCO3 at -0.80 V (vs RHE).

130 They were prepared by controlled potential electrolysis in 26-80% yields.

131 The literature is largely based on electrolysis in a glass beaker or H-cells that often giv

132 with the established method of expansion by electrolysis in a Li(+) containing electrolyte, and then

133 performance, durable alkaline membrane water electrolysis in a solid-state cell.

134 These first-time results of water electrolysis in a solid-state membrane cell are promisin

135 Preparative bulk electrolysis in acetonitrile was used to obtain higher o

136 Here we demonstrate a paired electrolysis in the case of the oxidative condensation o

137 most mediated electrochemical reactions, the electrolysis in this case was not used to convert a stoi

138 Developing efficient catalysts for electrolysis, in particular for the oxygen evolution in

139 two-electron reduction products during bulk electrolysis, including formate, aqueous formaldehyde, a

140 Controlled potential bulk electrolysis indicates that 94-99% of the nominal charge

141 As water electrolysis induces no volume change and the current th

142 s underwent structural transformation during electrolysis into electrocatalytically active cube-like

143 ssolved in a 750 degrees C molten Li2CO3, by electrolysis, into O2-gas at a nickel electrode, and at

144 ne with one another to control the course of electrolysis is analyzed in detail, leading to procedure

145 Even when the electrolysis is carried out at -1.20 V, the higher-gener

146 , under which proton exchange membrane-based electrolysis is operational.

147 Electrolysis is participating in the trend toward contin

148 Photovoltaic-driven electrolysis is the more efficient process when measured

149 generation of dissolved hydrogen in situ via electrolysis, is described.

150 ectrochemical experiments revealed that bulk electrolysis may also be used to switch reversibly the c

151 The real cost of hydrogen from wind electrolysis may be below that of U.S. gasoline.

152 e regenerated using the controlled-potential electrolysis method.

153 hat the designed cell used in flow injection electrolysis mode reduced the NaCl concentration from 0.

154 Molten oxide electrolysis (MOE) is an electrometallurgical technique

155 We then applied FND using an electrolysis needle.

156 ative to experimental controls following the electrolysis of 0.25 M Na2SO4 solutions when the anode w

157 Reductive electrolysis of 1 and 3-5 in dichloromethane leads to th

158 Reductive electrolysis of 1, 2 and 6 in dichloromethane leads to a

159 ponding to the first voltammetric peak, bulk electrolysis of 1-5 affords the corresponding hydrodimer

160 neO](2+) takes place at 1420 mV vs NHE, bulk electrolysis of [Ru(II)-OH(2)](2+) at 1260 mV vs NHE at

161 Bulk electrolysis of a saturated CO2 solution in the presence

162 ical pathway in which ammonia is produced by electrolysis of air and steam in a molten hydroxide susp

163 ved in each i-t response due to the complete electrolysis of all of the above-mentioned redox species

164 = 0.988) and a time constant for exhaustive electrolysis of approximately 2 min.

165 Evolution of oxygen was detected during bulk electrolysis of aqueous Et-Fl(+) solutions at several po

166 Electrolysis of Co(2+) in phosphate, methylphosphonate,

167 ate could be detected upon preparative-scale electrolysis of CO2 on the same electrode in the presenc

168 Electrolysis of diatrizoate in the presence of specific

169 In our approach, electrolysis of DSP-bridged protein/peptide products, as

170 cteristics of the system are tested with the electrolysis of Li2O2.

171 Spike-like responses from electrolysis of NB or TCNQ in each experiment were obser

172 ia during the initial half-hour of reductive electrolysis of nitrite.

173 The EGB, obtained when electrolysis of p-benzoquinone, or 1,4-naphthoquinone, i

174 3(B)Fe-N2(-) couple and controlled-potential electrolysis of P3(B)Fe(+) at -45 degrees C demonstrates

175 Cyclic voltammetry and constant-potential electrolysis of potassium ferricyanide were used to char

176 ical titration methods and achieves complete electrolysis of protein samples within minutes.

177 rms the lack of methanol formation upon bulk electrolysis of PyH(+) solutions at Pt and provides a de

178 is of single emulsion droplets, or selective electrolysis of redox species in single emulsion droplet

179 ich the configuration can be altered via the electrolysis of saline solutions or deionized water.

180 f single collision signals from the complete electrolysis of single emulsion droplets, or selective e

181 ts of single-collision signals from the bulk electrolysis of single emulsion droplets.

182 rate are two base chemicals produced through electrolysis of sodium chloride brine which find uses in

183 f collision signal is observed, representing electrolysis of the droplet contents.

184 oated nanocavity allows for rapid exhaustive electrolysis of the sampled material.

185 imilarly, the small volume allows exhaustive electrolysis of the vial contents with a 3-microm radius

186 Metals cannot be extracted by electrolysis of transition-metal sulfides because as liq

187 mation and accumulation was minimized during electrolysis of wastewater containing 75 mM Cl(-).

188 by the MFC electrical performance drives the electrolysis of wastewater towards the self-generation o

189 was similar during chemical chlorination and electrolysis of wastewater, suggesting that organic bypr

190 elow 1.23 V, the thermodynamic threshold for electrolysis of water at 25 degrees C, where neither H(2

191 Typical catalysts for the electrolysis of water at low pH are based on precious me

192 e attractive candidates as catalysts for the electrolysis of water in alkaline energy storage and con

193 the capillary was created dynamically by the electrolysis of water in the running buffer.

194 cal fuel in the form of molecular H2 via the electrolysis of water is regarded to be a promising appr

195 The electrolysis of water provides a link between electrical

196 The electrolysis of water to produce hydrogen and oxygen is

197 present technologies for photovoltaic-driven electrolysis of water to produce hydrogen.

198 The electrolysis of water using renewable energy inputs is b

199 es of pH gradients formed as a result of the electrolysis of water were influenced by variation of pa

200 (<1 V) that are sufficiently small to avoid electrolysis of water, can be performed in solutions hav

201 nd cathode at low applied potential to avoid electrolysis of water.

202 separated from each other in time during the electrolysis of water.

203 During water electrolysis on ceria, the increase in surface potential

204 ngly, this new setup minimized the effect of electrolysis on extraction performance while enabling hi

205 k of understanding of the mechanism of water electrolysis on perovskite surfaces.

206 titrant of acid or base is produced by water electrolysis on the rotating sample system (RSS) platfor

207 )(CH3CN)2](BPh4)3 were less stable, and bulk electrolysis only produced faradaic yields for H2 produc

208 tential, and 12 times faster than by abiotic electrolysis only.

209 er splitting for hydrogen production through electrolysis or photoelectrochemistry.

210 uced by steam reforming of natural gas, wind electrolysis, or coal gasification.

211 Coulombic efficiency over 50 cycles by bulk electrolysis owing to efficient, long-distance intrapart

212 orted piperidine (SiO(2)-Pip)], and the main electrolysis parameters (current density, charge consump

213 cm(2) with 29,000 turnovers per site over an electrolysis period of 2 h.

214 2 through at least 29 turnovers over an 15 h electrolysis period with a 45% Faradaic yield and no obs

215 low-cost, earth-abundant materials for water electrolysis/photolysis.

216 atives are designed to take advantage of the electrolysis process inherent to operation of the ES ion

217 ich is about 50-55 % of state-of-the-art HCl electrolysis processes.

218 Conventional water electrolysis produces H(2) and O(2) simultaneously, such

219 Previous mu-FFE devices have been limited by electrolysis product formation at the electrodes.

220 In all cases except 2b, the bulk electrolysis product is [R3S3](+), consistent with earli

221 The electrolysis product is stabilized in the water core of

222 d as an intermediate in the formation of the electrolysis product, the trisulfide [Ar3S3](+).

223 on different RAPs is accessible and that the electrolysis products are stable upon cycling.

224 Instead, the generation of electrolysis products at higher currents proved to be th

225 -5 V), which reduces the quantity of gaseous electrolysis products below a threshold that interferes

226 ane for the transport and removal of gaseous electrolysis products generated at the electrodes.

227 itions, suggesting that effective removal of electrolysis products is more important than originally

228 Identified halogenated and oxygenated electrolysis products typically underwent further transf

229 n the separation channel effectively removes electrolysis products, allowing continuous operation.

230 These electrolysis products, manifested as bubbles, decreased

231 TO by nanoITO-Ru(V)(O)(3+) leads to multiple electrolysis products.

232 organic contaminant treatment, test compound electrolysis rate constants were measured in authentic l

233 This design minimizes contamination from the electrolysis reactions by keeping the particles distant

234 Together these results indicate that electrolysis reactions generating hypochlorous acid from

235 tensity as a function of the transport rate, electrolysis reactions, and the modulation frequency of

236 A specialized vacuum electrolysis reactor was designed, constructed, and util

237 ions, where oxygen (O2) gas formed via water electrolysis reacts in the bulk of the plasma to form NO

238 self-powered reactor for in situ wastewater electrolysis, recovering nitrogen from wastewater.

239 voids the high energy costs and emissions of electrolysis, requires signification "dilution" (~ 8 Mt)

240 molar CdCl(2)-KCl was processed by ambipolar electrolysis, resulting in the production of liquid Cd a

241 of the complex before and after 18+ hours of electrolysis reveals negligible decomposition under cata

242 Controlled potential electrolysis shows sustained water oxidation over multip

243 trong quantifiable convective effects during electrolysis, similar to those obtained with rotating el

244 rable ionization mode of DESI or traditional electrolysis solvent systems, and the absence of backgro

245 tion did not appreciably deplete, the second electrolysis step may be used to partially compensate fo

246 emanding reduction-first pathway, while bulk electrolysis studies confirm a high product selectivity

247 Controlled potential electrolysis studies confirm that the product of isoprop

248 Cyclic voltammetry and controlled potential electrolysis studies demonstrate that the immobilized ca

249 , infrared spectroelectrochemistry, and bulk electrolysis studies.

250 , we used the presence of a thioacetal in an electrolysis substrate to selectively oxidize a proximal

251 H bands were detected in floated flocs after electrolysis, suggesting the sorption and subsequent rem

252 Also, mass shift before and after electrolysis suggests the linkage pattern of cross-links

253 Here we report a photovoltaic-electrolysis system with the highest STH efficiency for

254 ts demonstrate the potential of photovoltaic-electrolysis systems for cost-effective solar energy sto

255 Extended time-scale controlled potential electrolysis (t > hours) and spectroscopic (EPR and in s

256 D efforts towards efficient and stable water electrolysis technologies.

257 chip electrochemical pumping system based on electrolysis that offers certain advantages over designs

258 upport fast (reversible) HET for Fe(CN)6(4-) electrolysis, the first time this has been reported at a

259 iency for methanation of 80% during extended electrolysis, the highest Faradaic efficiency for room-t

260 lectrode potentials below the onset of water electrolysis, thereby eliminating gas bubble formation a

261 gh a combination of voltammetry, preparative electrolysis, thiol-electrode modifications, and kinetic

262 ectly proportional to the square root of the electrolysis time.

263 lly 99 at. % (13)C1 was determined by vacuum electrolysis to be 98.9 at. % (13)C1.

264 e study on a new technology for chlor-alkali electrolysis to be introduced in Germany.

265 des that had been subjected to different pre-electrolysis treatments.

266 7BL/6 mice underwent trigeminal stereotactic electrolysis (TSE) to destroy the ophthalmic branch of t

267 ice underwent either trigeminal stereotactic electrolysis (TSE), or sham operation, to ablate the oph

268 4S] clusters in the 2+ and 3+ states by bulk electrolysis under an O2-free atmosphere.

269 ater and use of the GAC as the cathode of an electrolysis unit also debrominated sorbed CH3Br.

270 degrees C and 25 bar of steam pressure, the electrolysis voltage necessary for 2 mA cm(-2) current d

271 Direct water electrolysis was achieved with a novel, integrated, mono

272 Although the principle of indirect electrolysis was established many years ago, new, exciti

273 Oxygen production through water electrolysis was not detected on the anode due to the pr

274 On the basis of these results, electrolysis was performed, resulting in the simultaneou

275 Bulk electrolysis was used to generate HA in a defined reduct

276 The volume of the gas generated due to water electrolysis was used to quantitate water oxidation or r

277 n an elevated residual current reading after electrolysis were eliminated.

278 Cyclic voltammetry and bulk electrolysis were employed to define the thermodynamics

279 ubstantial residual currents observed during electrolysis were found to be a result of NaCl back diff

280 A gaseous HCl electrolysis with Fe(3+) /Fe(2+) redox-mediated cathode

281 t COD and NH4(+) can be removed after 2 h of electrolysis with minimal energy consumption (370 kWh/kg

282 ntaining nanoclusters in water via precision electrolysis with strict pH control and (ii) an improved

283 ailable fluid that can be pumped in a single electrolysis without gas evolution is determined solely