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1 te that the ion in the cluster is reduced on electron capture.
2 dissociated into monomers by reduction using electron capture.
3 ases, a nitrogen laser is used to induce the electron capture.
4 th a background gas while subjecting them to electron capture.
5 plasma conditions produce 87% efficiency for electron capture; a single spectrum yields 512 product i
6 From the number of water molecules lost upon electron capture, adiabatic recombination energies are o
7 4)(-), YH(4)(-), and LaH(4)(-) are formed by electron capture and identified by isotopic substitution
8 hod based on gas chromatography coupled with Electron capture and ion trap mass spectrometry detector
10 thod employing gas chromatography coupled to electron capture and nitrogen phosphorus detection (GC-E
11 600, and 670 electron volts, attributable to electron capture and radiative deexcitation by the solar
12 ew describes the principles and practices of electron capture and transfer dissociation (ECD/ETD or E
13 n electron transfer provides an insight into electron capture and transfer dissociations of peptide c
14 contraction reactions, processes induced by electron capture, and finally dynamic molecular motion w
16 ous mass spectrometric approaches, including electron capture atmospheric pressure chemical ionizatio
17 A similar process was found to occur under electron capture atmospheric pressure chemical ionizatio
20 ectron recombination energies resulting from electron capture by gas-phase nanodrops containing indiv
21 ted trivalent metal ion that are formed upon electron capture by hydrated trivalent lanthanide cluste
26 ere unexpected because they require that one electron capture cause more than one backbone cleavage,
27 previous LC-MS methods such as negative ion electron capture chemical ionization, no derivatization
33 observed, which indicates the similarity of electron capture cross sections for the two derivatized
34 been previously measured in nuclear beta and electron capture decay, it has never been observed in fr
36 zyl derivatives have previously been used as electron capturing derivatives because they undergo diss
39 ed out by gas chromatography (GC) coupled to electron capture detection (ECD); tandem mass spectromet
40 matography coupled with mass spectrometry or electron capture detection (GC-MS/ECD) as of yet, which
41 her with analysis by gas chromatography with electron capture detection (GC/ECD) for the determinatio
42 ination with a gas chromatography coupled to electron capture detection (HS-GC-ECD) were evaluated.
43 brane-introduction mass spectrometry, and GC-electron capture detection were used to comprehensively
44 OPs were measured by gas chromatography with electron-capture detection in 886 participants in a heal
45 using high-resolution mass spectrometry and electron-capture detection to identify the potentially f
46 (UPLC/MS/MS) and gas chromatography with an electron capture detector (GC-ECD) confirmed by gas chro
47 nalysis of Ne, Ar, Kr, Xe, N2, and O2 and an electron capture detector (GC-ECD) for SF6 analysis.
48 ed employing gas chromatography coupled with electron capture detector (GC-ECD), and validated for sc
51 linear over 2-3 orders of magnitude with an electron capture detector and detection limits were in t
52 to 0.5 ppm and from 0.01 to 0.5 ppm using GC/electron capture detector and GC/mass spectrometry, resp
56 ple amount, true coulometric operation of an electron-capture detector is difficult to establish and
57 ation detectors, flame ionization detectors, electron capture detectors, and ion mobility spectromete
58 ctrometry, in conjunction with activated ion electron capture dissociation (AI ECD) or infrared multi
59 sonance (FT-ICR) together with activated-ion electron capture dissociation (AI-ECD) or infrared multi
60 originally designed for atmospheric pressure-electron capture dissociation (AP-ECD) experiments; repu
66 We have applied two dissociation techniques, electron capture dissociation (ECD) and infrared multiph
68 using infrared multiphoton decay (IRMPD) and electron capture dissociation (ECD) as fragmentation tec
69 d several fragmentation processes, including electron capture dissociation (ECD) at low energies, hot
74 monstrated the suitability of data-dependent electron capture dissociation (ECD) for incorporation in
75 ith collision induced dissociation (CID) and electron capture dissociation (ECD) for representative p
76 osphopeptide discovery, followed by targeted electron capture dissociation (ECD) for site localizatio
81 cts (Asp and isoAsp) at the peptide level by electron capture dissociation (ECD) has been well-establ
83 f multiply charged peptide and protein ions, electron capture dissociation (ECD) has the advantages o
85 ermediate, has been shown to be analogous to electron capture dissociation (ECD) in several respects,
89 -phase hydrogen-deuterium exchange (HDX) and electron capture dissociation (ECD) mass spectrometry fo
90 s that of its gaseous ions, as determined by electron capture dissociation (ECD) mass spectrometry.
91 llisionally activated dissociation (CAD) and electron capture dissociation (ECD) MS/MS can be used fo
94 ith the goal of elucidating the mechanism of electron capture dissociation (ECD) of larger peptide an
95 on for the peptide subunits is obtained from electron capture dissociation (ECD) of peptides and meta
96 sted electron transfer dissociation (ETD) or electron capture dissociation (ECD) provide varying degr
97 le-down mass spectrometry (MS) combined with electron capture dissociation (ECD) represents an attrac
98 f selected ions (CASI), and offline top-down electron capture dissociation (ECD) tandem mass spectrom
100 fragmented in a mass spectrometer by, e.g., electron capture dissociation (ECD) to obtain structural
101 ectrometry to obtain high mass accuracy, and electron capture dissociation (ECD) to selectively break
102 and implementing the new MS/MS technique of electron capture dissociation (ECD) yielded an increased
103 interfaced to a 12 T FTICR MS equipped with electron capture dissociation (ECD) yields very high mas
104 ge-reduced parent ion as it is formed during electron capture dissociation (ECD), called ECD+CID, is
105 e common; however, these are negligible with electron capture dissociation (ECD), consistent with its
106 greatly increased protein fragmentation from electron capture dissociation (ECD), has been applied to
107 s HD exchange, collision cross sections, and electron capture dissociation (ECD), have been used to c
114 nfrared multiphoton dissociation (IRMPD) and electron capture dissociation (ECD); however, due to the
115 , a systematic study was conducted using hot electron capture dissociation (HECD) and Fourier transfo
118 ymeric IgA1 myeloma protein were analyzed by electron capture dissociation and activated ion-electron
119 s is described that uses tandem MS data from electron capture dissociation and collisionally activate
120 ion of monophosphorylated hcTnT and mcTnT by electron capture dissociation and collisionally activate
122 , radical-driven fragmentation approaches of electron capture dissociation and the more common electr
123 high resolution mass spectrometry data using electron capture dissociation conditions that preferenti
126 down mass spectrometry (MS) methodology with electron capture dissociation for precise mapping of in
127 tion often led to facile palmitoyl loss, and electron capture dissociation frequently produced second
129 with low-energy collisions and an example of electron capture dissociation in FTICR-MS is presented.
132 ermore, mass spectrometric methods including electron capture dissociation MS(n) experiments could be
133 appearance energies of fragment ions due to electron capture dissociation of a multiply charged pept
134 nd subsequent PTM localization (using either electron capture dissociation or known PTM data stored i
137 tion (ETD) delivers the unique attributes of electron capture dissociation to mass spectrometers that
139 chniques (collision-induced dissociation and electron capture dissociation) revealed that Defr1 Y5C d
140 ctron capture dissociation, double-resonance electron capture dissociation, and collision-activated d
141 ing site identification has been achieved by electron capture dissociation, double-resonance electron
142 andem mass spectrometry experiments, such as electron capture dissociation, for which highly charged
148 istinguish between N-terminal and C-terminal electron capture dissociation/electron transfer dissocia
149 s of phosphorylation is a major advantage of electron capture dissociation; however, the low stoichio
150 ionization into gaseous ions for analysis by electron-capture dissociation (ECD) and collision-induce
152 ical-driven fragmentation techniques such as electron-capture dissociation (ECD) or electron-transfer
153 s spectrometry (MS) instrument combined with electron-capture dissociation (ECD) provided the most in
154 ollisionally activated dissociation (CAD) or electron-capture dissociation (ECD) shows loss of a smal
155 of electron-transfer dissociation (ETD) and electron-capture dissociation (ECD) spectra of peptides.
156 uent fragmentation of the protein ions using electron-capture dissociation allowed us to allocate the
157 n (N-lobe of human serum transferrin), using electron-capture dissociation as an ion fragmentation to
160 ted using gas chromatography and detected by electron capture (ECD) or ion trap mass spectrometry (GC
161 Electron energies were chosen to match the electron capture energies of taxonomically important com
163 can be used to reduce the extent of multiple electron capture events observed when performing ECD in
164 breath samples via gas chromatography using electron capture, flame ionization, and mass selective d
165 mechanism is postulated in which nonergodic electron capture fragmentation generates an alpha-carbon
167 rbon; protonation of the latter, followed by electron capture from ferrous HRP, completes the cycle.
168 e to tag many biomolecules and drugs with an electron-capturing group such as the pentafluorobenzyl m
169 the amide superbase mechanism that involves electron capture in an amide pi* orbital, which is stabi
170 Hypervalent ammonium radicals produced by electron capture in protonated peptides undergo competit
171 Therefore, suitable analytes can undergo electron capture in the gas phase in a manner similar to
172 erivatives because they undergo dissociative electron capture in the gas phase to generate negative i
173 all three aldehydes than was possible using electron-capture ionization of O-pentafluorobenzyl oxime
175 nvestigations also suggest that dissociative electron capture is the main ionization route for format
176 This observation leads to the inference that electron capture kinetics are governed by the long-range
177 ate that when considering the means by which electron capture leads to dissociation, hydrogen deficie
179 that could be detected by gas chromatography/electron capture mass spectrometry when 1 microL of ethy
181 sma was established using gas chromatography/electron capture negative chemical ionization mass spect
182 ly by further analysis with GCxGC coupled to electron capture negative chemical ionization-time-of-fl
183 ilar to that observed for gas chromatography/electron capture negative chemical ionization/mass spect
184 bromide were optimized and detection with an electron capture negative ion chemical ionization mode w
185 S) operating in electron ionization (EI) and electron capture negative ionization (ECNI) modes using
186 pectra generated by electron impact (EI) and electron capture negative ionization (ECNI) MS, eight PH
187 ionization sources, electron impact (EI) and electron capture negative ionization (ECNI), and the eff
188 dependent method based on gas chromatography/electron capture negative ionization high-resolution mas
189 iological fluids with susequent detection by electron capture negative ionization mass spectrometry (
190 atized, and quantified by gas chromatography/electron capture negative ionization mass spectrometry.
191 erivative and analyzed by gas chromatography/electron capture negative ionization mass spectrometry.
192 ts were analyzed by using gas chromatography electron-capture negative chemical ionization mass spect
193 to their determination by gas chromatography-electron-capture negative-ion chemical-ionisation mass s
194 r anions generated from the TAA esters under electron-capture negative-ion mass spectrometric conditi
197 tion, whereas negative ions are generated by electron capture or proton transfer reactions, enabling
198 electron-based peptide dissociation methods (electron capture or transfer, ECD or ETD) have distincti
199 that the assay method exploiting the intense electron-capture properties of TAA is highly suitable fo
206 e method takes advantage of the tendency for electron capture reactions to generate charge-reduced "E
207 ultaneously record four-dimensional resonant electron capture (REC) mass spectra (m/z, ion-intensity,
208 structed and demonstrated to record resonant electron capture (REC) mass spectra of electron-capturin
209 between 12 and 25 water molecules attached, electron capture results in a narrow distribution of pro
210 tion of the charge-reduced species formed by electron capture results in extensive dissociation into
211 in this work, three-dimensional negative ion electron capture spectra are recorded in an interval on
213 ypes of neutron-star-forming supernova, with electron-capture supernovae preferentially producing sys
215 ct separation, and minimization of secondary electron capture that destroys larger product ions.
216 ply charged protein ions in the gas phase by electron capture, the main experimental challenges are j
217 ophorederivatized compounds by laser-induced electron capture time-of-flight mass spectrometry (LI-EC
218 sociation (CID) (b/y/a fragments) as well as electron capture/transfer dissociation (ECD, ETD) (c/z f
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