ライフサイエンスコーパス: electron transfer

1 der succinate subsequently inhibited reverse electron transfer.

2 eep as -120 mV/pH-suggested a two proton-one electron transfer.

3 enase bioanodes operating utilizing a direct electron transfer.

4 Complex II subunit-subunit interactions and electron transfer.

5 NaxHyV10O28((6-x-y)-) (V10) underwent a two-electron transfer.

6 tophan, Trp-321, participates in off-pathway electron transfer.

7 a of the working electrode and favour direct electron transfer.

8 to perform directed, ultrafast and efficient electron transfer.

9 constants (DMF), most likely by photoinduced electron transfer.

10 tructs, all are within range for microsecond electron transfer.

11 throline complex that quenched QD PL through electron transfer.

12 so that it can participate in proton-coupled electron transfer.

13 in complex required for direct intercellular electron transfer.

14 providing additional degrees of freedom for electron transfer.

15 ion of the different valleys involved in hot-electron transfer.

16 harge dynamics of this peculiar mechanism of electron transfer.

17 e domain in its c-terminus to achieve direct electron transfer.

18 ons of Escherichia coli AhpF (EcAhpF) during electron transfer.

19 orm to study structurally related biological electron transfer.

20 raction of a hydrogen atom or proton-coupled electron transfer.

21 The new fusion enzyme, with its direct electron transfer abilities displays superior activity t

22 ne or its analog NL-1 appears to inhibit the electron transfer activity of mitoNEET by forming a uniq

23 metabolism in mitochondria by inhibiting the electron transfer activity of mitoNEET.

24 Capacity for electron transfer among redox cofactors versus charge re

25 multidomain protein that enables a series of electron transfers among the redox centers by accepting

26 rs are ubiquitous in biology and function in electron transfer and catalysis.

27 f the substrate's N-atom to haem-Fe(II) with electron transfer and concomitant N-O heterolysis libera

28 Beyond electron transfer and electron transfer-oxygen transfer

29 ntact time and contrasts their potential for electron transfer and in situ production of HO(*) using

30 ansfer) rather than through initial internal electron transfer and ligand-centered reduction of an ox

31 ith that of neighboring P atoms enhances the electron transfer and optimizes the charge distribution

32 This correlation between electron transfer and photocatalytic activity provides n

33 DOT:PSS has been attributed to the effective electron transfer and reactive species diffusion through

34 nism at low pH, involving protonation before electron transfer and yielding a distinct protonated mon

35 ns including dioxygen binding and transport, electron transfer, and oxidation/oxygenations.

36 Te reduction induces multiple inter-related electron transfers, and the associated cooperative effec

37 re, we explore visible-light-mediated single-electron transfer as a mechanism towards enabling site-

38 o(I), converting an initial H bond to a full electron transfer as start of the reductive dehalogenati

39 Fe protein and the MoFe protein and includes electron transfer, ATP hydrolysis, release of Pi, and di

40 The electron-transfer behavior of anilides and dianilides wa

41 Achieving fast electron transfer between a material and protein is a lo

42 al cation intermediate that is generated via electron transfer between an excited-state iridium photo

43 x I defects but also rescues the inefficient electron transfer between complex I and ubiquinone in sp

44 Na(+)-NQR uses the energy released by electron transfer between NADH and ubiquinone (UQ) to pu

45 Respiratory complex I couples electron transfer between NADH and ubiquinone to proton

46 e's strategies for achieving fast, efficient electron transfer between proteins and materials.

47 cal and chemical properties which facilitate electron transfer between the active locales of enzymes

48 terogeneous rate constant characterizing the electron transfer between the nanodots and the Fc heads

49 hanges of the aptamer probe which affect the electron transfer between the NP and the electrode surfa

50 robe spectroscopy measurements indicate that electron transfer between the TiO2 and the adsorbed mole

51 mical devices that provide information about electron transfer between two immiscible electrolyte sol

52 Flavin-based electron transfer bifurcation is emerging as a fundament

53 ding Paracoccus denitrificans) to facilitate electron transfer by providing electron shuttles (confir

54 et continuum pulses to probe the interfacial electron transfer, by detecting a specific excitonic tra

55 The electron transfer can also occur between subunits, depen

56 ng this phenomenon proved that light-induced electron transfer can be strongly modulated by vibration

57 wn through stopped-flow kinetic experiments, electron transfer capable cytb 5 - cyt c complexes were

58 nt absorption (TA) spectroscopy to reveal an electron-transfer cascade that correlates with a near-do

59 3 billion years ago, and linkage through an electron transfer chain to photosystem I, directly led t

60 c oxidase (CcO), the terminal enzyme in the electron transfer chain, translocates protons across the

61 (ROS) generation by electron slippage in the electron transfer chain.

62 The electron-transfer chain of iron-sulfur cofactors within

63 The electron transfer characteristics of two food additives,

64 ew recent developments in these areas of the electron transfer chemistry of graphene.

65 The participation of graphene in electron transfer chemistry, where an electron is transf

66 ), electron-transfer dissociation (ETD), and electron-transfer combined with higher-energy collision

67 stantially lowers the activation barrier for electron transfer compared to the prediction of the Marc

68 concerted mechanism, in which the proton and electron transfer components of the CPET process make eq

69 ersists for 67 ns due to spin-forbidden back-electron transfer, constituting a more than thousandfold

70 oduct formation by electrode mediated direct electron transfer could be detected.

71 ntaining proteins involved in photosynthetic electron transfer, detoxification of anion radicals, cit

72 on, but targeted analysis of MS1 pairs using electron transfer dissociation (ETD) markedly reduced ad

73 Using concurrent IR photoactivation during electron transfer dissociation (ETD) reactions, i.e., ac

74 ked by more than one disulfide bond, we used electron transfer dissociation (ETD) to partially dissoc

75 energy collision induced dissociation (HCD), electron transfer dissociation (ETD), and electron captu

76 tron detachment dissociation (EDD), negative electron transfer dissociation (NETD), or extreme UV pho

77 formula (IF) using tandem mass spectrometry (electron transfer dissociation).

78 ntial ion mobility spectrometry (FAIMS) with electron transfer dissociation, we demonstrate rapid bas

79 Electron-transfer dissociation (ETD) analysis indicates

80 based on application of multi-point HR-HRPF, electron-transfer dissociation (ETD) tandem MS (MS/MS) a

81 ubly charged precursors could be achieved by electron-transfer dissociation (ETD) with increased supp

82 higher-energy collision dissociation (HCD), electron-transfer dissociation (ETD), and electron-trans

83 ced dissociation (CID), beam-type CID (HCD), electron-transfer dissociation (ETD), and the combinatio

84 In addition, electron-transfer dissociation combined with higher ener

85 Inverted-region electron transfer does not appear to be an important mec

86 However, since g-C3N4 electron-transfer dynamics are poorly understood, ration

87 taxa putatively not capable of extracellular electron transfer (e.g., Bacteroidales and Clostridiales

88 dence that AOM is coupled with extracellular electron transfer (EET) to conductive solids is relative

89 reactions mainly proceeded by intramolecular electron transfer (ET) between the triplet excited sacch

90 In both mechanisms, electron transfer (ET) from phenol occurs after the PT (

91 derivative (AQ), measured from the yield of electron transfer (eT) from the QD core to AQ, increases

92 lar H2O2 addition, supporting an alternative electron transfer (ET) pathway from the heme.

93 and energy loss may occur due to inefficient electron transfer (ET) processes.

94 The electron transfer (ET) rate constants driving the VOC ge

95 rees ' by ca. 210 mV results in increases in electron transfer (ET) rates by 30-fold, rate of O2 bind

96 MN domain is thought to be essential for the electron transfer (ET) reactions in NOSs.

97 ny of these transformations are initiated by electron transfer (ET).

98 h TAA(+) units rather than sequential single electron transfer events.

99 32 oxidation likely involves pre-equilibrium electron transfer followed by proton transfer to a water

100 g fast cation radical dimerization following electron transfer, followed by direct and crossover trap

101 nase I (CaI) enabled light-driven control of electron transfer for spectroscopic detection of redox i

102 Photodriven electron transfer from a donor excited state to an assem

103 or acetate oxidation via direct interspecies electron transfer from a heterotrophic partner bacterium

104 Electron transfer from an excited dye to TiO2 generated

105 We provide experimental evidence for electron transfer from As(III) to Fe(III) at the natural

106 rovide compelling evidence for excited-state electron transfer from chloride to the Ru metal center w

107 Electron transfer from F(-) anions to the pi-electron-de

108 due to the neutral species, consistent with electron transfer from microbe to polymer.

109 In a companion study , we show that the electron transfer from Mn(II) to the low-potential type

110 e results confirm the occurrence of a single-electron transfer from the Breslow intermediate to the m

111 hemical calculations suggest an outer sphere electron transfer from the COF to the co-catalyst which

112 al and photonic quantification of the direct electron transfer from the electrode to redox enzymes an

113 by intramolecular 2H(+)/2e(-) proton-coupled electron transfer from the saturated pincer ligand backb

114 sm that involves two asynchronous transfers: electron transfer from the substrate radical to the iron

115 An efficient photoinduced electron transfer from the tetraphenylborate anionic moi

116 rmodynamic factors that regulate the primary electron transfer function, as well as alternative funct

117 t the experimental study and modeling of the electron-transfer gated ion transport processes in carbo

118 We concluded that the plasmon-induced hot electron transfer governed the suppression of peroxide f

119 han other possible mechanisms such as single electron transfer, halogen atom transfer, and sigma-bond

120 However, inverted-region electron transfer has never been demonstrated in any nat

121 iates induced by photoredox-catalyzed single-electron transfer have been achieved, permitting the for

122 n species through singlet oxygen scavenging, electron transfer, hydrogen atom abstraction and radical

123 wer limit on the rate of this intramolecular electron transfer (IET) that is >10(4) faster than the u

124 IC), from other living cells by interspecies electron transfer (IET), or from an electrode during MES

125 rs a possible route to detecting interfacial electron transfer in a broad class of systems, including

126 ctivity of microbes capable of extracellular electron transfer in a terrestrial serpentinizing system

127 ed 36% activity by electrode mediated direct electron transfer in comparison to enzyme regeneration b

128 Ultrafast electron transfer in condensed-phase molecular systems i

129 n and has been invoked as an intermediate in electron transfer in DNA.

130 fusion and solvation dynamics on bimolecular electron transfer in ionic liquids (ILs).

131 Ultrafast interfacial electron transfer in sensitized solar cells has mostly b

132 iabatic quantum treatments of proton-coupled electron transfer in SLO and (ii) sensitivity of ENDOR p

133 effect (kH/kD = 20) suggests proton coupled electron transfer in the initial oxidation as the rate-d

134 The mechanism of this photoinduced electron transfer in the solid state and the origin of t

135 t inhabit the electrode surface and catalyze electron transfer in these systems remains largely unkno

136 ng and stability with key routes of improved electron transfer in various biosensing and bioelectroni

137 t energy transfer and ultrafast photoinduced electron transfer in well-defined multichromophoric stru

138 trode scale, indicating non-concerted proton-electron transfers in the OER mechanism.

139 w that four protons are pumped for every two electrons transferred in both cases.

140 e used as a predictor for the spin-dependent electron transfer, indicating that chiral imprinting of

141 The reaction could be viewed as an electron-transfer initiated reduction of the quinone or

142 During catalysis, NADPH-derived electrons transfer into FAD and then distribute into the

143 resolving how such weak interactions affect electron transfer is challenging.

144 is vibrationally perturbed during UV-induced electron transfer is dramatically slowed down compared t

145 505 nm populates a lower excited state where electron transfer is kinetically unfavorable.

146 Empirical evidence of plasmon-driven electron transfer is provided for the first time by dire

147 Spin-dependent intramolecular electron transfer is revealed in the Re(I)(CO)3(py)(bpy-

148 Inverted-region electron transfer is therefore demonstrated to be an imp

149 from the MoS2 nanosheets, which modifies the electron transfer kinetics and catalytic activity of the

150 hibited an increase in peak currents and the electron transfer kinetics and decrease in the overpoten

151 The rate of electron transfer kinetics at the fouled electrode surfa

152 efficiency, relatively low sensitivity, slow electron transfer kinetics, high background charging cur

153 the negative drawback of slow adsorption and electron transfer kinetics.

154 devices show excellent conductivity and fast electron transfer kinetics.

155 ty of the acceptor QDs affect the dot-to-dot electron-transfer kinetics.

156 eduction relying both on direct and mediated electron transfer mechanism are then discussed.

157 e in such a regime, that the inverted-region electron transfer mechanism becomes important.

158 ochemically active, there exists an internal electron transfer mechanism that interferes with stabili

159 have been directed towards understanding the electron transfer mechanism, and a useful tool called th

160 and transient absorption studies support the electron transfer mechanism.

161 Extracellular electron-transfer mechanisms involved in the acquisition

162 mplex I-dependent O2 consumption and reverse electron transfer-mediated reactive oxygen species (ROS)

163 transformations ranging from proton-coupled electron-transfer-mediated cyclizations to C-C bond cons

164 horseradish peroxidase) with ferrocyanide as electron-transfer mediator, achieving a linear range fro

165 or not properly accounted for in bimolecular electron transfer models based on a spherical diffusion-

166 old, enabling stringent tests of bimolecular electron transfer models.

167 Multiple-site concerted proton-electron transfer (MS-CPET) reactions were studied in a

168 e single molecule response of plasmon-driven electron transfer occurring in single nanosphere oligome

169 ncrease of peroxide yield), in which the hot electron transfer of Ag nanostructure offered a sufficie

170 ions in their cages and a consequence of the electron transfer of metal ions in their cage by reducti

171 nsor surface that efficiently restricted the electron transfer of redox probe Fe(CN)6(4-/3-) were uti

172 y in CpI and a low reorganization energy for electron transfer on/off the H cluster.

173 Outer-sphere reductive single electron transfer (OS-SET) has been proposed for such di

174 Furthermore, electron transfer oxidation of other substrates such as

175 Often, they are active for electron transfer oxidations of a myriad of substrates a

176 Beyond electron transfer and electron transfer-oxygen transfer aerobic transformation

177 bind the enzyme to the electrode and enhance electron transfer parameters the gold surface was modifi

178 dynamic analyses evidence a concerted proton-electron transfer pathway for these processes.

179 proficiencies of the catalytic site and the electron transfer pathway in each enzyme.

180 plex structure was generated and a potential electron transfer pathway was identified.

181 e results are essential to understanding the electron transfer pathways and mechanism of Na(+)-NQR ca

182 RC employs coherence (i) to sample competing electron transfer pathways, and ii) to perform directed,

183 lel and otherwise identical donor-->acceptor electron-transfer pathways structurally distinct, enabli

184 e complex is shown to mediate proton coupled electron transfer (PCET) at the {SN} ligated site, point

185 A cobalt-catalyzed proton-coupled electron transfer (PCET) mediated regioselective ortho-s

186 riments implicate a concerted proton-coupled electron transfer (PCET) pathway, based on various piece

187 Proton-coupled electron transfer (PCET) reactions at a phenol donor and

188 for important electrochemical proton-coupled electron transfer (PCET) reactions, such as the intercon

189 is facilitated by sequential proton-coupled electron transfer (PCET) steps along a pathway of redox

190 ectron and proton donors by a proton-coupled electron-transfer (PCET) mechanism to complete the O2-to

191 thylammonium iodide (Fc(+)), a photo-induced electron transfer (PET) fluorescent probe system was dev

192 he internal charge transfer and photoinduced electron transfer (PET) modulators on the same molecule.

193 been attributed to some form of photoinduced electron transfer (PET) quenching, which is diminished i

194 tion dynamics of the chain, and photoinduced electron transfer (PET), a contact-based method, to quan

195 xcited triplet states by way of photoinduced electron transfer (PeT), followed by recombination of th

196 od sensing mechanisms, such as photo-induced electron transfer (PET), intramolecular charge transfer

197 nzyme hybrids are composed of a photoinduced electron transfer (PeT)-based fluorescent voltage indica

198 tate quenchers that operate via photoinduced electron transfer (PeT).

199 etion of NdbC increases the amount of cyclic electron transfer, possibly via the NDH-12 complex, and

200 at alkaline pH, suggesting a proton-coupled electron transfer precedes formation of the fully oxidiz

201 em is achieved by a consecutive photoinduced electron transfer process (conPET) and allows the room t

202 is and NMR spectroscopies to investigate the electron transfer process between mitoNEET and the cytos

203 d molecular mechanism for the proton-coupled electron transfer process linked to the Q reduction, we

204 et state is deactivated further via a second electron transfer process, generating viologen cation ra

205 lts are explained in terms of a pH-dependent electron transfer process, in which the oxidized dopamin

206 not significantly inhibit the proton-coupled electron transfer process.

207 ion, thereby allowing more rapid interfacial electron transfer process.

208 lasting a few trillionths of a second of the electron-transfer process in the photoexcited type-II he

209 Quantitative studies of electron transfer processes at electrode/electrolyte int

210 Moreover, these compounds display reversible electron transfer processes in both the cathodic and ano

211 two different optical signals related to the electron transfer processes occurring at two compartment

212 le for studying mediator-dependent microbial electron transfer processes or simulating redox gradient

213 Current understanding of the photophysical electron transfer processes present in CD photocatalytic

214 ns in practical devices rests on a series of electron transfer processes whose dynamics and efficienc

215 because it is an important tool for studying electron transfer processes, but also because it is real

216 ble time-resolved information related to the electron transfer processes.

217 nge for biogeochemical reactions that invoke electron transfer processes.

218 ene and AuNPs, which facilitated exceptional electron-transfer processes between the electrolyte and

219 These light-induced electron-transfer processes display a remarkably high qu

220 atomic level, transient species involved in electron-transfer processes.

221 Electron-transfer products were identified as the reduce

222 resulting modified electrodes show enhanced electron transfer properties and better mass transfer pe

223 This shift in absorption and the effect on electron transfer properties is investigated via computa

224 ning ligand, affecting the excited state and electron transfer properties of these molecules.

225 Br(-)], each with distinct photophysical and electron-transfer properties.

226 Vacancy-rich layered materials with good electron-transfer property are of great interest.

227 While structures of several extracellular electron transfer proteins are known, an understanding o

228 resembles the binding between donor-acceptor electron transfer proteins.

229 rs such as H2; (ii) physical contact through electron-transfer proteins; or (iii) mediator-generating

230 ces of evidence against initial outer-sphere electron transfer, proton transfer, or substrate coordin

231 coupled (PCET) and decoupled proton transfer-electron transfer (PT/ET) schemes involving negatively c

232 )MLCT excited and cannot be formed by static electron transfer quenching of the (3)MLCT state.

233 BOD surface coverage (Gamma), heterogeneous electron transfer rate (kS) and a maximum biocatalytic c

234 The apparent heterogeneous electron transfer rate constants (kS) of CtCDH were calc

235 The electron transfer rate from the ZnTPP lowest excited sin

236 zymes, the EAPC anode showed 1.7-fold higher electron transfer rate than the CA anode.

237 We define a polarization for the electron-transfer rate constant and show that it correla

238 the data needed to estimate the (very fast) electron transfer rates (both rate constants >/= 4000 s(

239 ity to minimize fluorescence while enhancing electron transfer rates between the photoexcited photore

240 ymes provides a possible mechanism to adjust electron transfer rates for efficient catalysis under di

241 bservations were confirmed by measurement of electron transfer rates in cells grown under the two con

242 s of the composites, including heterogeneous electron transfer rates, were probed using cyclic voltam

243 ine the mechanism of a single proton-coupled electron transfer reaction at one of eight iron-sulfur c

244 Our results indicate that the electron transfer reaction coordinates between a triplet

245 Visible-light-prompted electron-transfer reaction initiates the oxidation.

246 Hydroquinones are important mediators of electron transfer reactions in soils with a capability t

247 These proton-coupled electron transfer reactions occur without substrate bind

248 p-chlorobenzoic acid are oxidized via direct electron transfer reactions, while p-benzoquinone and te

249 ectronic energy levels and predictably guide electron-transfer reactions, leading to the changes in r

250 s indicate that the key step involves single-electron-transfer reduction of aldehydes or imines follo

251 of functional groups or carbon matrices for electron transfer remain unknown.

252 s some quantifiable variability but that the electron transfer remains in any case in the quasi-rever

253 detection was based on that the variation of electron transfer resistance (Rct) and differential puls

254 us measured by following the increase in the electron transfer resistance of the redox couple using F

255 f the thiolated aptamer with CT26 cells, the electron-transfer resistance of Fe (CN)6(3-/4-) redox co

256 loping cytocompatible PET-RAFT (photoinduced electron transfer-reversible addition-fragmentation chai

257 tractive for multifunctional optoelectronic, electron transfer sensing, and other photochemical appli

258 s reactive radicals through discrete, single-electron transfer (SET) events.

259 activation likely proceeds through a single electron transfer (SET) mechanism.

260 Single electron transfer (SET) reactions are effected by the co

261 y facets of its chemistry based on a) single-electron transfer (SET), and b) hydride delivery reactio

262 sfer (HAT) and second sequential proton loss electron transfer (SPLET) mechanisms are less energy dem

263 ion of AQH2 seems to take place via a double electron transfer step involving both TAA(+) units rathe

264 ifferent mechanistic routes of the essential electron-transfer step (ET) of this reaction in order to

265 metal oxides involves four concerted proton-electron transfer steps on metal-ion centres at their su

266 proceed via either a sequence of proton and electron transfer steps, concerted H atom transfer steps

267 , thermodynamic analyses, and calculation of electron transfer) suggested hematite reduction as a pro

268 icals derived from amide carbonyls by single electron transfer take place under mild conditions and e

269 mplex I, and can be rescued by inhibition of electron transfer through complex I or pharmacologic dep

270 Subsequent electron transfer through the additional accessory [FeS]

271 radient for charge separation and subsequent electron transfer to a solution-based hydrogen-evolving

272 nd cyclization cascades, triggered by single electron transfer to amide-type carbonyls by SmI2-H2O-Li

273 Radical heterocyclizations triggered by electron transfer to amide-type carbonyls, using SmI2 -H

274 For both mechanisms, one- and two-electron transfer to Cl (strain CBDB1) or H (strain 14DC

275 by the Co(II) species and (2) excited-state electron transfer to Co(III) species.

276 monomer reference systems designed to probe electron transfer to each of the individual PDI molecule

277 mediate activates the alkyl iodide by single electron transfer to enable a radical carbonylation path

278 TyrOH(*+) is formed in approximately 1 ps by electron transfer to excited flavin and decays in approx

279 h charge is generated on g-C3N4, followed by electron transfer to exfoliated carbon nitride containin

280 was oxidized to the stable radical TEMPO by electron transfer to ferrocenium oxidants coupled to pro

281 ycle, allowing intramolecular proton-coupled electron transfer to lower the potentials for oxidation

282 P450 (cytP450) metabolism and is capable of electron transfer to many redox partners.

283 dissociation events are involved in coupling electron transfer to proton translocation, are unknown.

284 (III) oxidation step does not involve direct electron transfer to the enzyme from Mn(III), which is s

285 , Trp104 can directly compete with Tyr21 for electron transfer to the flavin through a nonproductive

286 al intra-domain cross-talk and for efficient electron transfer to the redox partner AhpC required for

287 h neighbouring Ru(II) dyes via self-exchange electron transfer to ultimately oxidize a distant co-anc

288 ding aminoketyl radicals generated by single-electron transfer to unactivated aliphatic amides; howev

289 A direct electron transfer type glucose dehydrogenase was immobil

290 igate the effects of anion delocalization on electron transfer using zinc meso-tetraphenylporphyrin (

291 new type of surface assembly, intra-assembly electron transfer was investigated by transient absorpti

292 0 or C70 fullerenes, ultrafast host-to-guest electron transfer was observed to compete with the excit

293 nd potassium ferrocyanide as mediator of the electron transfer) was adsorbed on the surface.

294 ial participation, likely being mediators in electron transfer, was indicated by specific inhibition

295 +x)-) (V4), and HVO4(2-) proceeded via a one-electron transfer, while that of NaxHyV10O28((6-x-y)-) (

296 and the remaining HOBr reacted with DOM via electron transfer with a reduction of HOBr to bromide (>

297 yl radical to the vinyl boronate followed by electron transfer with another molecule of alkyl iodide,

298 FeS cluster chain (F-clusters) functions in electron transfer with CdSe.

299 osine residue that reacts via proton-coupled electron transfer with the iron(III)-superoxo species an

300 Subsequent ultrafast electron transfer within the triradical forms D(+*)-A-R(