ライフサイエンスコーパス: electronegativity

1 into 5 subfractions (L1-L5) with increasing electronegativity.

2 OSoxy, indicating it decreased heme-thiolate electronegativity.

3 ydroxylating species by tuning heme-thiolate electronegativity.

4 reduction in T1/2 for increasing substituent electronegativity.

5 rt of the C-terminal domain, diminishing its electronegativity.

6 ing monomers times the square of the Pauling electronegativity.

7 nts yielded subfractions L1-L5 in increasing electronegativity.

8 y not be the same because of their different electronegativity.

9 lence and, less strongly, on ionic radius or electronegativity.

10 ically with leaving group hydrophobicity and electronegativity.

11 to oxygen ranking high in both abundance and electronegativity amongst the stable elements of the uni

12 n of K in PbTe as a result of the balance of electronegativity and also lowers the lattice thermal co

13 Effects resulting from the lower electronegativity and greater hydrophobicity of sulfur c

14 cture but strongly dependent on the absolute electronegativity and hardness of the interacting metal

15 he nature of pucker is dependent on both the electronegativity and stereochemistry of the substituent

16 nergy band is likely the result of a loss of electronegativity and the acceptor unit's ability to sep

17 ibutions one can judge when more traditional electronegativity arguments can be justifiably invoked i

18 vealed that those bearing groups with strong electronegativity at the R1 position (i.e., CHD-5, CHD-1

19 Concepts such as electronegativity, band width, orbital overlap, bond ene

20 Compared to the electronegativity-based charges that are widely used, th

21 mple approaches for quantitatively assessing electronegativity, chemical hardness, and ionicity, whil

22 he dominant (if not sole) contributor to the electronegativity chi, one is led to assume that P depen

23 tion initiated the idea to derive the "true" electronegativity chiSIMS from the measured ion yields P

24 Electronegativity comparisons are a useful guide in unde

25 d here is counterintuitive based upon simple electronegativity considerations, but this finding is un

26 ibutes only about one-third to the favorable electronegativity data.

27 ion formation and provide means for refining electronegativity data.

28 erage electron binding energy, a generalized electronegativity, DeltaVNN is the change in nuclear rep

29 nsfer in these oxides, suggesting that large electronegativity difference and high pressure are the k

30 er effect, rationalizes the influence of the electronegativity difference between A and Y in (AY)4 on

31 Atomic electronegativity differences between the group 13/15 an

32 in a complex metallic alloy, even though the electronegativity differences within the unit cell are l

33 ted to oxidation, such as charge-transfer or electronegativity differences.

34 In general, electronegativity dominates the ordering of spin states.

35 protein-ligand interfaces and Pauling atomic electronegativities (EN).

36 to other recent reports, Pauling's original electronegativity equation, applied as Pauling specified

37 riven by the gauche effect and the change in electronegativity from the 3'O to the 3'NH group.

38 due to its similar size but vastly different electronegativity has been substituted for hydrogen as a

39 ode in a rechargeable battery due to its low electronegativity (high cell voltage), double valence, e

40 r ability of sigma bonds being controlled by electronegativity in periods and by sigma orbital energy

41 rt the discovery of an important role of the electronegativity in the nanowire growth on arbitrary su

42 retained even with significant reduction of electronegativity in the selectivity filter, and that co

43 tor desensitization, whereas the substituent electronegativity is correlated with ligand potency.

44 Hydrogen is unique in that its electronegativity is not constant.

45 substitution, and the effect of substituent electronegativity is opposite of the effect on the therm

46 tumor effect(s) of substituents of differing electronegativities, located at the several sites compri

47 nd are analyzed in the context of an optical electronegativity model.

48 indicates that 113 variables including size, electronegativity, number of valence electrons, and posi

49 west occupied Kohn-Sham levels and elemental electronegativities of the constituent atomic species as

50 The differences in the electronegativities of the heteroatoms are largely respo

51 ectrostatic model and not with one involving electronegativities of the ligated phenoxide oxygens.

52 '-F should closely imitate the atom size and electronegativity of a 2'-OH, demonstrates low levels of

53 concentrations that increase with increasing electronegativity of A.

54 the combination of the electron affinity and electronegativity of doping elements, which serves as an

55 lic ethers might be attributed to the higher electronegativity of gallium versus aluminum.

56 on varied from 0.57 to 35 h depending on the electronegativity of the 2-substituents and the size of

57 nsic gas-phase effects involving the reduced electronegativity of the 3'-substituent.

58 that the "stickiness" of this pin (i.e., the electronegativity of the anion) contributes to the energ

59 or the zinc increased monotonically with the electronegativity of the bound substituent X, e.g., Br <

60 oupling constants ((3)JHalpha,Hbeta) and the electronegativity of the Cgamma-substituents by chemical

61 absorbates onto the surface due to the high electronegativity of the Cl ligands.

62 of the peroxo bridge is tuned by the size or electronegativity of the counterion present.

63 The size/electronegativity of the end atoms relative to the centr

64 chemists and biologists because the size and electronegativity of the fluorine atom can be used to ma

65 modeling showed a corresponding increase in electronegativity of the GSTP1 active site.

66 is may be a result of the different size and electronegativity of the halogen atoms.

67 eometric arrangement of the heteroatoms, the electronegativity of the heteroatoms, and the electronic

68 perties correlated with the ionic radius and electronegativity of the ions.

69 of the CT band follow the trend of stronger electronegativity of the ligands.

70 exploits establishing a balance between the electronegativity of the materials' constituents and the

71 dine, pyrazine, pyrimidine), indicating that electronegativity of the nitrogen can change regioselect

72 es and the reaction energies with increasing electronegativity of the substituent (F > OH > NH2, Cl >

73 in monosubstituted ethenes where the role of electronegativity of the substituent X becomes more impo

74 rge in the fluorenyl system, with increasing electronegativity of the substituent.

75 t > Pd > Cu > Co, paralleling the decreasing electronegativity of the substrate metal.

76 H, its phenoxide anion strongly reducing the electronegativity of the sulfonyl group, thereby inhibit

77 The decrease in the electronegativity of X along the series X = F, OH, Cl is

78 lity in groups is opposite to the changes in electronegativity of X and in the C-X bond polarization,

79 p(pi) orbital on boron is correlated to the electronegativity of X, and the competition between the

80 eption of C-C, the order corresponded to the electronegativity of X, suggesting that the differences

81 o right in periods parallels the increase in electronegativity of X, whereas augmentation of acceptor

82 lls' internal bioactivity, (iii) cell-wall's electronegativity or dipole moment and their relaxation

83 a given type of annelation, such as strain, electronegativity, or cyclic electron count, can be sort

84 imal widening exhibit significantly enhanced electronegativity, ranging from 0.8 to 2.5 kT/e, dependi

85 endent; the former correlated very well with electronegativity scales, whereas the latter correlated

86 ppropriate value of chi is selected from the electronegativity tables of Pauling (read in eV), Mullik

87 Oxygen has a significantly higher electronegativity than the others, and as a result, the

88 ends (i.e., atomic size, polarizability, and electronegativity) that differ from C to Si to Ge.

89 he reduction of elements with lower relative electronegativity, the highly reducing nature of the B-B

90 y that correlated strongest was the ratio of electronegativity to hardness, chi2/eta, a quantity rela

91 The electronegativity trend can be understood from an ions i

92 by relating the central chemical concept of electronegativity with the average binding energy of ele