ライフサイエンスコーパス: enantiomeric

1 Enantiomeric 2,3,4-tris(hydroxyalkyl)-5-phenylpyrrolidin

2 restrictine L have been synthesized from the enantiomeric (4R)- and (4S)-4-(tert-butyldimethylsiloxy)

3 stream module by a paralog that produced the enantiomeric ACP-bound diketide caused no changes in pro

4 With our work we demonstrated specific enantiomeric activities for several amino acids on TAS1R

5 The binding of enantiomeric amines induces distinct (19)F NMR shifts of

6 We have identified enantiomeric analogues of traditional (-)-morphinans as

7 s derived from D-mannose and D-galactose are enantiomeric and are useful linkers for the synthesis of

8 groundwater systems through a combination of enantiomeric and carbon isotope fractionation to charact

9 the XB interactions in orientating the bound enantiomeric anion guests for chiral selectivity, as wel

10 This proposed electrochemical GON-based enantiomeric bio-sensor becomes a highly promising tool

11 We also apply our enantiomeric biosensors to the optimization of reaction

12 ad, they are antipodes arising from separate enantiomeric biosyntheses.

13 conversion between energetically degenerate, enantiomeric C1-symmetric conformations.

14 The diketone derived from the enantiomeric C12-fragment (R)-30 underwent reductive cyc

15 The extent and range of isomer and enantiomeric carbon isotope fractionation of HCHs with S

16 determination of the absolute configuration, enantiomeric composition and concentration of unprotecte

17 this method has the ability to evaluate the enantiomeric composition and discriminate between enanti

18 determination of the absolute configuration, enantiomeric composition and total concentration of a va

19 on the sulfenyl moiety prevented erosion of enantiomeric composition at these elevated temperatures.

20 crystal surface was studied as a function of enantiomeric composition by temperature programmed desor

21 The cyclization reaction mechanism and the enantiomeric composition of the peropyrene products are

22 rmation about the absolute configuration and enantiomeric composition of the substrate used.

23 determination of the absolute configuration, enantiomeric composition, and overall amount of cysteine

24 acids permitting the precise measurement of enantiomeric composition.

25 activity of the protein or determination of enantiomeric compositions.

26 The alkaloids are chiral, having stable enantiomeric conformations with half-lives of racemizati

27 racemic mixtures of rapidly interconverting enantiomeric conformers able to recognize a chiral analy

28 The rate of interconversion of their enantiomeric conformers depends on solvent polarity.

29 Preliminary evaluations of specific enantiomeric contributions support the use of this appro

30 Enantiomeric Cp(R)2TiCl2 complexes have been prepared; t

31 by "hand picking" of a few homochiral single enantiomeric crystals allowed for a measurement of their

32 microfluidic strategy for the separation and enantiomeric detection of D-methionine (D-Met) and D-leu

33 dic alkaloid that exists as a pair of pseudo-enantiomeric diastereomers.

34 also revealed pairs of enantiomers with high enantiomeric discrimination and different secondary stru

35 The X-ray structure shows enantiomeric discrimination where 9a optimally addresses

36 chiral micropollutants and maintaining their enantiomeric distribution during deployment.

37 ect of our approach is the implementation of enantiomeric DNA biosensors, which are synthesized from

38 of a homochiral guest liquid crystal, these enantiomeric domains become diastereomeric, exhibiting u

39 Processes not accompanied by enantiomeric enrichment (acid and base hydrolysis) and b

40 describing the isotope fractionation versus enantiomeric enrichment are demonstrated for all studied

41 Further enantiomeric enrichment of PCBs 95, 132, and 149 occurre

42 use of the Rayleigh approach to describe the enantiomeric enrichment-conversion dependencies.

43 single regioisomers with excellent levels of enantiomeric enrichment.

44 o allylic substrates or deliver little to no enantiomeric enrichment.

45 opose to draw a parallel between isotope and enantiomeric enrichments and derive a set of conditions

46 ltigram synthesis of the carbocycles in high enantiomeric excess (92% ee).

47 mplification of a spontaneously formed small enantiomeric excess (e.e.).

48 eported in excellent yields (up to >99%) and enantiomeric excess (ee 99%).

49 The mechanism for the high enantiomeric excess (ee) (80-90%) observed in the photoc

50 olution of homochirality requires an initial enantiomeric excess (EE) between right and left-handed b

51 Enantiomeric excess (ee) determination is crucial in man

52 We report herein an unprecedentedly high enantiomeric excess (ee) for Pd patches deposited onto C

53 diastereomeric excess (de) limits the final enantiomeric excess (ee) of any phosphorus products deri

54 sented chiral assay is able to determine the enantiomeric excess (ee) of D-cysteine in the whole rang

55 s were observed leading to variations in the enantiomeric excess (ee) of the chemisorbed layers with

56 been exploited for precise quantification of enantiomeric excess (ee) ratio (R/S) up to 99:1 in the p

57 izontal lineC bond were hydrogenated in high enantiomeric excess (up to >99% ee).

58 ould be successfully obtained with excellent enantiomeric excess (up to >99% ee).

59 ective cyclobutane products with significant enantiomeric excess (up to 95% ee).

60 drogenated in high regioselectivity and high enantiomeric excess (up to 98% ee).

61 ing scaffold with high yield (up to 99%) and enantiomeric excess (up to 99%).

62 determination of the absolute configuration, enantiomeric excess and concentration of the target comp

63 is often challenging for mixtures with high enantiomeric excess and for complex molecules with stron

64 o[3,4:1,2][60]fullerenes with high levels of enantiomeric excess and moderate to good conversions.

65 ha-disubstituted aldehyde hydrazones in high enantiomeric excess and yield.

66 ketones are prepared in good yield with high enantiomeric excess by rhodium-catalyzed allylic substit

67 molecules and quantitative determination of enantiomeric excess can be achieved in a table-top instr

68 rded a mixtures of trans-(+)-(4S,5R)-4b with enantiomeric excess ee=99% and cis-(-)-(4S,5S)-4a with e

69 t- (left-)handed twisted nanoribbons with an enantiomeric excess exceeding 30%, which is approximatel

70 methylformamide) and observed an increase in enantiomeric excess for 1-phenylethanol of 35% with the

71 eous determination of percent conversion and enantiomeric excess for each substrate.

72 c alpha-olefins into chiral products with an enantiomeric excess greater then 90 per cent.

73 sly from reaction mixtures, with an enhanced enantiomeric excess if initially enantioenriched, which

74 Enantiomeric excess is strikingly insensitive to tempera

75 e liquid chromatography purification, a high enantiomeric excess of (18)F-FDOPA ( approximately 97%)

76 overall yield of 55% (three steps) and high enantiomeric excess of 95%.

77 the enantiomer in the mixture and scale with enantiomeric excess of a component.

78 Changes in the enantiomeric excess of mixed monolayers of chiral dipept

79 ve linear model was applied to determine the enantiomeric excess of samples of two alcohols without a

80 of Leu, Pro, and Phe can be deduced from the enantiomeric excess of sublimates, the behavior of the k

81 inkers, impacts on the reaction rate and the enantiomeric excess of the aldol products.

82 The enantiomeric excess of the chiral fatty acids has been m

83 Consequently, the enantiomeric excess of the partial sublimate is dependen

84 tic amounts of host are able to increase the enantiomeric excess of the products formed.

85 vided strong evidence that the modulation of enantiomeric excess of the reaction product indeed stems

86 opure complex, alcohols are produced with an enantiomeric excess of up to 85% (S) at TOF up to 2000 h

87 lent enantioselectivity is achieved, with an enantiomeric excess of up to 99%.

88 S)-alpha-phenyltryptamine derivative with an enantiomeric excess over 99%.

89 In one case, the enantiomeric excess reaches 95:5 er, and the reactions c

90 ng asymmetric Doyle-Kirmse reactions with an enantiomeric excess up to 71 %.

91 -polyheterocycles of complex topologies with enantiomeric excess values up to 90%.

92 with up to 99% yield and in greater than 99% enantiomeric excess via dynamic kinetic resolution.

93 r the syn or anti adduct selectively in high enantiomeric excess when an appropriate chiral ligand wa

94 ssfully cross-coupled in excellent yield and enantiomeric excess with prior conversion of the pinacol

95 rmation of the 3R alcohol configuration (99% enantiomeric excess) and contrasted with racemic 1-octen

96 94%) with high enantioselectivity (up to 99% enantiomeric excess) and excellent chemoselectivity.

97 nantioenriched alpha-branched amines (>/=96% enantiomeric excess) featuring two minimally differentia

98 high enantioselectivity (typically 90 to 99% enantiomeric excess), and afford products that are key p

99 ns of carbenes into C-H bonds with up to 98% enantiomeric excess, 35,000 turnovers, and 2550 hours(-1

100 lucidate the correlation between defects and enantiomeric excess, five characterization techniques (F

101 cellent enantiomeric purities (>98% and >96% enantiomeric excess, respectively).

102 into valuable chiral benzylic amines in high enantiomeric excess, thereby producing motifs found in p

103 d reactivity and generate products with high enantiomeric excess.

104 nd provides the title compounds in excellent enantiomeric excess.

105 oth natural products were obtained in >/=99% enantiomeric excess.

106 btained in high chemical yield and with high enantiomeric excess.

107 ohols, yielding up to 96% conversion and 99% enantiomeric excess.

108 ical yield and 100% diastereoselectivity and enantiomeric excess.

109 tuted dehydropiperidinones in high yield and enantiomeric excess.

110 Yields range from 57 to 99% with 78-95% enantiomeric excess.

111 orinated compounds in good yield and in high enantiomeric excess.

112 lution process, which causes a change of the enantiomeric excess.

113 ction of alpha-arylquinolines with up to 90% enantiomeric excess.

114 th up to >98% conversion and with up to >98% enantiomeric excess.

115 ns to bicycloalkenes in high yield with high enantiomeric excess.

116 deliver target structures in high yield and enantiomeric excess.

117 ith aniline afforded the urea product in 51% enantiomeric excess.

118 hesis of tertiary phosphine oxides with high enantiomeric excess.

119 ions, nonanionic conditions, and with a high enantiomeric excess.

120 robenzofurans in consistently high yield and enantiomeric excess.

121 in up to 98 % yield and greater than 99.5 % enantiomeric excess.

122 afforded cyclization products at comparable enantiomeric excesses (ee's) and 4-7 times higher cataly

123 High yields and enantiomeric excesses are observed for various isochroma

124 ic excess ee=99% and cis-(-)-(4S,5S)-4a with enantiomeric excesses ee=77% and ee=45% respectively.

125 Primary allylic amines with enantiomeric excesses from 97 to >99% were prepared by a

126 ropyl C-H bonds in high yields and with high enantiomeric excesses in the presence of a rhodium catal

127 e presented, which consistently provide high enantiomeric excesses in the range 91-98%.

128 3-substituted morpholines in good yield and enantiomeric excesses of >95%.

129 er of substituents in the 4-position, giving enantiomeric excesses of greater than 82%.

130 entenols 3a-l in good to excellent yields in enantiomeric excesses up to 99%.

131 bound isomer, appear to be critical for high enantiomeric excesses.

132 s, high diastereomeric ratios, and excellent enantiomeric excesses.

133 -Trp which showed that the percentage of one enantiomeric form can be easily measured in the presence

134 ral symmetry break, resulting in a preferred enantiomeric form of the gyroid structure.

135 In order to find the percentage of an enantiomeric form of tryptophan in a mixture, the ITO/AP

136 rovide a set of substituted 4-HCPs in either enantiomeric form.

137 ), revealing the exclusive presence of the S-enantiomeric form.

138 l (E = 22) allowed rapid preparation of both enantiomeric forms of a C21-oxygenated precursor for syn

139 The taste of different enantiomeric forms of amino acids has been deeply invest

140 ning substrates that led selectively to both enantiomeric forms of an epoxy vinyl stannane, and a ser

141 Enantiomeric forms of BTD-2, PG-1, and PM-1 were synthes

142 mbiguously reveal the coexistence of the two enantiomeric forms of opposite handedness: the left- and

143 Chemical synthesis of the L- and D-enantiomeric forms of Rv1738 enabled facile crystallizat

144 seco-analogue of 2) of both the (-)- and (+)-enantiomeric forms of the alkaloid galanthamine [(-)-1]

145 2A and S112K Sav mutants for the SIr and RIr enantiomeric forms of the cofactor, respectively.

146 selective total syntheses of the non-natural enantiomeric forms of the recently isolated protoilludan

147 a convergent total chemical synthesis of the enantiomeric forms of the ShK toxin protein molecule.

148 Both the enantiomeric forms of the trans isomer are obtained in e

149 th natural and unnatural complements in both enantiomeric forms.

150 an interesting dimeric structure between its enantiomeric forms.

151 was quantified by the Rayleigh equation and enantiomeric fractionation factors (epsilon(e)) for S. i

152 In addition, enantiomeric fractionation has the potential as a comple

153 cross China, we measured the concentrations, enantiomeric fractions (EFs), compound-specific carbon i

154 Enantiomeric fractions in the middle xylem, top bark, to

155 d between KO and WT mice, with larger HO-PCB enantiomeric fractions in WT compared to KO mice.

156 within these patterns form a pair of chiral enantiomeric gyroid labyrinths (srs nets) over a broad r

157 The enantiomeric homogeneity of light-driven molecular motor

158 rther optimization, the discovery of a minor enantiomeric impurity with agonist activity led to the f

159 oth MOFs allow for only direct gauche-gauche enantiomeric interconversion of the glutarate moieties.

160 Using enantiomeric iridium catalysts, vinyl aziridine 3a react

161 f a 14-hydroxy (the 4a-hydroxy) group in the enantiomeric isoquinolinones, (+)- and (-)-2), gave (+)-

162 d Sci USA 107(26):11676-11681, where the two enantiomeric labyrinthine domains of the gyroid are conn

163 lly adopt 310 helical conformations in which enantiomeric left- and right-handed conformers are, nece

164 curate environmental risk assessments at the enantiomeric level.

165 ly suppress the self-assembly process of the enantiomeric macroanions, which is further used to separ

166 oisomers derived from each configurationally enantiomeric macrocycle was investigated in CD3SOCD3 sol

167 handedness is dictated by the choice of the enantiomeric macrocyclic dimer.

168 The conversion of the enantiomeric mixture into diastereomers yielded well-res

169 pure ligands are compared with samples using enantiomeric mixtures of ligands.

170 ed on the adsorption of pure enantiomers, of enantiomeric mixtures, and of prochiral molecules on chi

171 ved that the error in the measurement of the enantiomeric molar ratio can be related to the E value.

172 ctions are enabled by two complementary, non-enantiomeric multifunctional catalysts, which mutually a

173 When equimolar solutions of the enantiomeric naphthalenediimide-based highly rigid trian

174 The enantiomeric Nazarov transition structures, which are co

175 CN5 bromodomain, together with GSK4028 as an enantiomeric negative control.

176 mage form of KRas bound to its corresponding enantiomeric nucleotide triphosphate, this study sets th

177 trated, including natural variants and novel enantiomeric or diastereomeric counterparts.

178 Petromyroxol is a nonracemic mixture of enantiomeric oxylipids isolated from water conditioned w

179 ated ones, the absolute configuration of the enantiomeric pair (6R, 12aR)/(6S, 12aS) can be confident

180 An enantiomeric pair of chiral metal-organic materials (CMO

181 Reported herein is an enantiomeric pair of doubly-bridged naphthalene-1,8:4,5-

182 ve reaction produces four stereoisomers (two enantiomeric pairs): following a catalytic asymmetric tr

183 l-mannose are delineated, and for all eight enantiomeric pairs, d and l entities display different c

184 tion along the antisymmetric pathways led to enantiomeric pairs.

185 zofuran derivative KMS88009, ZAbeta3W, the D-enantiomeric peptide D3 and its tandem version D3D3 on A

186 e the in vitro and in vivo efficacy of the D-enantiomeric peptide RD2, a rationally designed derivati

187 The enantiomeric phosphonic acid analogs of Leu and hPhe, wh

188 Finally, we also discovered that enantiomeric PORCN inhibitors show very different activi

189 HOS ligand is favored, which affords the (S)-enantiomeric product.

190 ely directing the formation of either of two enantiomeric products by a reaction involving 1,22-remot

191 les obtained for the pathways leading to the enantiomeric products suggest that the rate- and stereod

192 and assign the absolute configuration of the enantiomeric products.

193 Its enantiomeric profiling was studied for the first time in

194 and (R)-tosylates were obtained in excellent enantiomeric purities (>98% and >96% enantiomeric excess

195 e stereoinvertivebly cross-coupled with high enantiomeric purities (77-97% ee).

196 has been applied to the determination of the enantiomeric purities of delta- and epsilon-chiral prima

197 in good yield ( approximately 40%) and high enantiomeric purity (ee >93%).

198 hod is illustrated by the synthesis, in high enantiomeric purity (generally 95-99% ee), of a variety

199 atively undeveloped area of determination of enantiomeric purity and/or absolute configuration of rem

200 s confirm, that the observed small losses of enantiomeric purity are traced to a triflate-mediated do

201 A simple NMR-based determination of enantiomeric purity is also described.

202 The retention of enantiomeric purity is attributed to a high binding affi

203 The high enantiomeric purity of a chiral N-(diphenylphosphinoyl)p

204 ue could be useful for the assessment of the enantiomeric purity of a microcrystalline powder.

205 In contrast, the enantiomeric purity of gamma-C6 significantly decreased

206 agonal crystalline domains regardless of the enantiomeric purity of the perylene bisimide.

207 n conditions on the substrate conversion and enantiomeric purity of the products were investigated.

208 urity were characterised by gamma-C6 of high enantiomeric purity remaining stable during the whole po

209 ddition with almost complete conservation of enantiomeric purity, a finding that argues against the i

210 e a class of tetracyclic compounds with high enantiomeric purity.

211 livers alpha-aminocarbonyl compounds in high enantiomeric purity.

212 stereocontrol and with very small erosion of enantiomeric purity.

213 s phosphines and their derivatives with high enantiomeric purity.

214 iomers or are inadequately characterized for enantiomeric purity.

215 products are readily recrystallized to high enantiomeric purity.

216 family of bicyclic beta-amino acids of high enantiomeric purity.

217 utyrolactone derivatives, without erosion of enantiomeric purity.

218 ivers beta-aminocarbonyl compounds with high enantiomeric purity.

219 o-arylated benzylamines are obtained in high enantiomeric purity.

220 both epoxide and thiirane in high yields and enantiomeric purity.

221 trahydrofuran derivatives without erosion of enantiomeric purity.

222 ealed by mass spectrometry analysis on quasi-enantiomeric pyrrolidino[60]fullerenes.

223 By using flow-injection MS/MS, enantiomeric quantitation of GSK2251052A by the kinetic

224 of components of a diastereomeric (E,Z) and enantiomeric (R,S) oxime into a third reactor column whe

225 e obtained in 63-95% yield and 91:9 to >99:1 enantiomeric ratio (e.r.).

226 n up to >98% yield, >98:2 SN2':SN2, and 99:1 enantiomeric ratio (er).

227 ves in good yield (up to 86 %) and excellent enantiomeric ratio (up to 99.5:0.5 e.r.).

228 ith up to 42:1 diastereomeric ratio and 94:6 enantiomeric ratio (up to 99:1 er after recrystallizatio

229 rystallization of the synthetic products and enantiomeric ratio analysis were subsequently performed.

230 a turnover frequency of 6,100 h(-1), a 99:1 enantiomeric ratio and 100% chemoselectivity.

231 cost-effective, and fast assessment of their enantiomeric ratio and total concentration.

232 nalysis of the temperature dependence of the enantiomeric ratio established a linear relationship of

233 nch-selectivity and stereoselectivity and an enantiomeric ratio greater than 99:1.

234 gives the corresponding cyclopropane with an enantiomeric ratio of 70/30 and, thus, provides proof of

235 In a compensatory manner, the enantiomeric ratio of the other diastereomeric pair decr

236 obtained in 66-91% yield and 84:16 to >99:1 enantiomeric ratio through reactions performed at ambien

237 re obtained in 69-99% yield and up to a 98:2 enantiomeric ratio using the same reaction conditions.

238 were easily synthesized in good to excellent enantiomeric ratio with good yields.

239 carbon center with up to 90% yield and 97:3 enantiomeric ratio, with only water as the byproduct.

240 eomeric ratio (for allyl additions) and 99:1 enantiomeric ratio.

241 obtained in 60 to >98 % yield and up to 99:1 enantiomeric ratio.

242 ition of NBu4BAr(F)4 leading to a diminished enantiomeric ratio.

243 enantiomeric reductions and the experimental enantiomeric ratio.

244 (branched/linear) selectivity and 83:17-99:1 enantiomeric ratio.

245 allene (vs propargyl) selectivity, and 98:2 enantiomeric ratio.

246 meric pairs drifts spontaneously to a higher enantiomeric ratio.

247 roducts in up to 77 % overall yield and 99:1 enantiomeric ratio.

248 o >98:2 diastereomeric ratio, and 85:15-99:1 enantiomeric ratio.

249 s in more than 85 per cent yield and >/=97:3 enantiomeric ratio.

250 re isolated in up to 97 % yield and 98.5:1.5 enantiomeric ratio.

251 % yield, >98% diastereoselectivity and >99:1 enantiomeric ratio.

252 2 ratio, 96:4 diastereomeric ratio and 98:2 enantiomeric ratio.

253 y, >95:5 Z:E selectivity, and 81:19 to >99:1 enantiomeric ratio.

254 yield, 88:12 diastereomeric ratio, and 94:6 enantiomeric ratio.

255 8:2 S(N)2'/S(N)2 selectivity, and 85:15-99:1 enantiomeric ratio.

256 llylic alcohols in up to 98% yield and >99:1 enantiomeric ratio.

257 esired products in up to 83 % yield and 98:2 enantiomeric ratio.

258 s obtained in high yields, but with moderate enantiomeric ratios (up to 78:22).

259 ch to 1-alkyl-3-methyleneindan-1-ols in high enantiomeric ratios (up to 96:4 er).

260 High enantiomeric ratios (up to 98.5:1.5) and excellent diast

261 charge experiment and the occurrence of high enantiomeric ratios of amino acids in re-crystallization

262 Enantiomeric ratios of the resolved TB derivatives range

263 centers are afforded in excellent yields and enantiomeric ratios of up to 99:1.

264 ary boronic esters with yields up to 87% and enantiomeric ratios up to 96:4 e.r.

265 3 and 16, 17, and 21 in yields up to 96% and enantiomeric ratios up to 99:1.

266 idines, and azepanes in high yields and high enantiomeric ratios via enantioselective formation and s

267 of the propargyl alcohol led to high product enantiomeric ratios when the reaction was conducted in a

268 iral Cu-alkyl species, resulting in improved enantiomeric ratios.

269 to synthetically valuable aziridines in high enantiomeric ratios.

270 on state complexes and rationalize different enantiomeric ratios.

271 le-pot operation in excellent diastereo- and enantiomeric ratios.

272 n high yields and good diastereoisomeric and enantiomeric ratios.

273 ete diastereospecificity, and generally high enantiomeric ratios.

274 ons of catalytically competent poses for the enantiomeric reductions and the experimental enantiomeri

275 stable than the RR dimer as a result of the enantiomeric relationship between R-Delta and S-Delta, a

276 Enantiomeric resolution, at the same time with stronger

277 thetic kinetic resolution process to produce enantiomeric rocaglamides and aglains.

278 rescence response that is independent of the enantiomeric sample composition and readily correlated t

279 helical conformations, the equally populated enantiomeric screw-sense conformers of which are in slow

280 transmitted through a chiral overlayer cause enantiomeric selective chemistry in an adsorbed adlayer.

281 ly, for the entropically driven separations, enantiomeric selectivity can increase at higher temperat

282 e use of additives (i.e., cyclodextrins) for enantiomeric separation as well as any covalent immobili

283 Proton nuclear magnetic resonance and enantiomeric separation identified D-tryptophan.

284 The synthesis, the enantiomeric separation, and the characterization of new

285 microwave-assisted synthesis of 4BP-TQS, its enantiomeric separation, and their functional evaluation

286 enges to overcome in this field such as high enantiomeric separation.

287 can produce interesting secondary effects in enantiomeric separations.

288 Therefore, both enantiomeric series of spiro compounds can be obtained b

289 on to accessing synthetic steroids of either enantiomeric series, these steroidal products have been

290 hesis of hydromorphone was completed in both enantiomeric series.

291 2CH2I, and (iii) a pair of rigid tetrameric, enantiomeric single-handed (P)- and (M)-helical nanotube

292 use fatty acids attached via ester bonds to enantiomeric sn-glycerol 3-phosphate.

293 lies on the fact that carbohydrates exist in enantiomeric states, several conformations, anomeric con

294 The discovery of clusters with enantiomeric structures is essential to design new chira

295 olute configuration (3R,5S,6S,7R,11S,14R) is enantiomeric to that originally proposed by the isolatin

296 teric crowding in the catalyst pocket of one enantiomeric transition state, is the main cause for ste

297 s found to be the key interaction in the two enantiomeric transition states.

298 a range of supramolecular nanotubes from the enantiomeric triangular naphthalenediimide-based macrocy

299 particular emphasis on the first syntheses, enantiomeric versions, and syntheses that led to the rev

300 tion during the self-assembly process of two enantiomeric wheel-shaped macroanions, [Fe28(mu3-O)8(Tar