ライフサイエンスコーパス: endothermic

1 hen conventional electron transfer is highly endothermic.

2 s general-base catalysis and the reaction is endothermic.

3 Above 30 degrees C the reactions are endothermic.

4 tions of 1-4d were found to be substantially endothermic.

5 xpansion of 1c to 3c is computed to be quite endothermic.

6 es such that the reaction is predicted to be endothermic.

7 on center, rendering attack at that position endothermic.

8 nd cationic heavy metals (Cd, Pb, and Zn) is endothermic.

9 ntities change sign with DeltaHpart becoming endothermic (+70 kJ/mol) and entropically favored (Delta

10 in the carboxyl-terminal domain so that the endothermic, allosteric activation mechanism of CRP by c

11 xidation by IV(H(2)O), is found to be highly endothermic and cannot occur; this finding is different

12 Paracoccus cytochrome c-550, the binding is endothermic and driven by a large entropy change, a patt

13 hange suggested that the binding process was endothermic and driven by entropy.

14 reviously, arguments have been made for both endothermic and ectothermic metabolisms on the basis of

15 n the thermodynamics of the reaction that is endothermic and enthalpically driven in PF6- and TF2N-ba

16 es was characterized by a relatively greater endothermic and entropic profile as compared with those

17 The interactions between FasDD and CaM are endothermic and entropically driven, suggesting that hyd

18 he interactions between CaM and myr(+)MA are endothermic and entropically driven, suggesting that hyd

19 The encapsulation of the salt is endothermic and entropically favored by the liberation o

20 hat LA adsorption on OVAn was a spontaneous, endothermic and entropically-driven process, highlightin

21 i and Moab of r-fla S. typhi as spontaneous, endothermic and entropy driven one.

22 The association of halides with [H3L](3+) is endothermic and entropy driven.

23 e organometallic complex in the cavitand was endothermic and exclusively driven by entropy (DeltaH =

24 Relative trends for a significant range of endothermic and exothermic [1,5]-shifts with different i

25 SN2 reactions in three solvents that lead to endothermic and exothermic reaction processes, and we sh

26 al noncovalent ligand makes protonation very endothermic and greatly raises the reduction potential.

27 a a stepwise pathway is 21 kcal mol(-1) less endothermic and has a 12 kcal mol(-1) lower barrier heig

28 For ground state SO2, this reaction is endothermic and has a very high activation barrier; our

29 hat the overall photoreduction of Pchlide is endothermic and that rapid dynamic searches are required

30 first tension-generating step may be weakly endothermic and that the rise of tension with temperatur

31 step(s) in the crossbridge cycle was highly endothermic and was therefore itself directly targeted b

32 The binding of LTbetaR to LIGHT was endothermic and, hence, entropy-driven.

33 tep in muscle is both temperature sensitive (endothermic) and strain sensitive.

34 : invertebrate or vertebrate, ectothermic or endothermic, and free-living or parasitic.

35 Binding is endothermic, and the binding site spans about 12 sacchar

36 eta-sheet aggregates underwent a reversible, endothermic, and very asymmetric thermal transition with

37 When food resources are scarce, endothermic animals can lower core body temperature (Tb)

38 d its corollaries state that pigmentation of endothermic animals will increase from more polar to equ

39 scent of thermoregulatory systems in larger, endothermic animals.

40 This endothermic approach eliminates runaway reaction hazards

41 s that nonavian dinosaurs were on average as endothermic as extant placental mammals.

42 s substitution of His64 with Gln leads to an endothermic association of CO with the five-coordinate h

43 calorimetry showed the binding was weak and endothermic at 15 degrees C, with a total DeltaH of > or

44 gand from the encounter complex, found to be endothermic at 6 kcal/mol.

45 Binding is endothermic at all temperatures examined, with DeltaH va

46 ilamellar EDOPC vesicles and plasmid DNA was endothermic at both physiological and low ionic strength

47 hydrophobic interactions are attractive and endothermic at moderate temperatures.

48 The association is endothermic at physiologically relevant temperatures, wh

49 atio together with the reaction heat for the endothermic bi-reforming can be conveniently obtained by

50 the case of con-T, a weak (Kd = 410 microM) endothermic binding site is observed for Zn2+.

51 cannot undergo ion-induced folding exhibits endothermic binding.

52 s of environmental temperature fluctuations, endothermic birds and mammals maintain a relatively warm

53 nsfer lays the foundation for explaining how endothermic birds and mammals maintain their high, relat

54 ng (TAP) and class Ia has been documented in endothermic birds and two mammals, lineages of LMP7 are

55 structural changes (free volume collapse and endothermic bond breakage).

56 the dissociation reaction coordinate through endothermic bond breaking and concomitant gain in config

57 At lower temperatures the second phase is endothermic but gradually decreases with increasing temp

58 of 5 to form 6 was, however, computed to be endothermic by 122.0 kcal/mol whereas protonation of 6 t

59 athway for rearrangement of 6 to 8, which is endothermic by 14.5 kcal/mol, involves ring opening to Z

60 ove reactants, while the overall reaction is endothermic by 16.7 kcal/mol.

61 form UO(NO)Cl2(-) and N2 was computed to be endothermic by 169 kJ/mol, which is energetically more f

62 e to form aspirin and benzene is found to be endothermic by 2.7 kcal/mol and provides compelling evid

63 protonation of 6 to form 7 was again highly endothermic by 238.8 kcal/mol.

64 tion of 1 into 5 and N(2) was computed to be endothermic by 25.1 kcal/mol.

65 e formation of phenylaluminum dichloride, is endothermic by 33 kcal/mol.

66 he parent Bergman reaction is computed to be endothermic by 5 kcal/mol) and associated with a signifi

67 /mol, whereas the latter is calculated to be endothermic by 7.4 kcal/mol.

68 a conventional radical ion pair, A*-D*+, is endothermic by approximately 0.6 eV.

69 ecomposition reactions become - on average - endothermic by more than 0.6 eV.

70 The O-O bond homolysis is found to be endothermic by only 15 to 20 kcal/mol due to the fact th

71 attachment of other C atoms, which requires endothermic C-H activation and H* desorption steps that

72 othermic herbivore > ectothermic carnivore > endothermic carnivore.

73 ing and that this process is dependent on an endothermic change in SecA conformation.

74 However, in shortening muscle, the endothermic character of force generation becomes more p

75 essures will be substantially limited by the endothermic chemical reactions of the polyatomic species

76 Here, we report high-yielding, endothermic Cl2 photoelimination chemistry from mononucl

77 The first step in H2O oxidation involves the endothermic cleavage of a strong O-H bond (BDFE = 122.7

78 solvent, bis-guanidinium receptors form more endothermic complexes with dicarboxylates, with a favora

79 salt concentrations were dissected into its endothermic components, yielding the enthalpy change and

80 The enzyme undergoes an ATP-modulated endothermic conformational transition (ECT) believed to

81 nge is different from the well-characterized endothermic conformational transition believed to gate t

82 the lowest temperature of SWCNT growth using endothermic decomposition of CH4 gas on a specially acti

83 s suggested that ethanol conversion involves endothermic dehydration step.

84 The lanthanide triflates catalyze endothermic dehydroalkoxylation, while the palladium nan

85 py contribution (DeltaS) and the process was endothermic (DeltaH > 0).

86 t CO photodissociation is associated with an endothermic (DeltaH = 8 +/- 3 kcal mol(-1)) volume expan

87 lpic component stays small and in some cases endothermic (DeltaH degrees >/= -1 kcal/mol).

88 ebound to form a metal-bound amine is highly endothermic (DeltaH(reb)(dtbpe) = +25.1 kcal/mol).

89 drolysis reaction in beta(TP) is found to be endothermic, demonstrating that the catalytic site is ab

90 ing a model in which binding is linked to an endothermic distortion of the DNA in the complex.

91 escence anisotropy experiments to reverse an endothermic domain-dissociation reaction hypothesized to

92 iation over this temperature range showed an endothermic effect below 17 degrees C and an exothermic

93 on capture is driven by solar thermal heated endothermic electrolyses of concentrated reactants occur

94 , and V(+), intact ligand loss competes with endothermic elimination of purine and of HCN to form MNH

95 For both proteins, association involves endothermic enthalpy and positive entropy changes; thus,

96 in entropy and opposed by a relatively small endothermic enthalpy at room temperature.

97 acterized by a Kd value of 286 microM and an endothermic enthalpy of binding.

98 However, the endothermic enthalpy remained largely unaffected.

99 Because the binding of myosin to actin is an endothermic, entropically driven reaction, work must be

100 For example, Hf(OTf)4 mediates rapid endothermic ether right harpoon over left harpoon alcoho

101 e decomposition of nitrate, if formed, is an endothermic event.

102 omplexes was also exothermic, but additional endothermic events occurred at both lower and higher hos

103 In endothermic fish, niche expansion into cooler waters is

104 physiology, the thermal physiology of large endothermic fishes, reproductive physiology of air breat

105 the DFT calculations, this reaction is more endothermic for 1 due to the reduced stabilization of th

106 f NHC-boryl radicals to alkenes are probably endothermic for alkyl-substituted alkenes, but exothermi

107 ctron transfer was found to be significantly endothermic for all five CuRe(2) complexes: this fact, c

108 This latter reaction is even predicted to be endothermic for substituents with Hammett constant sigma

109 he fast/slow fiber difference in the rate of endothermic force generation (three- to fourfold) is con

110 Q10 approximately 2.7), similar to phase 2b (endothermic force generation) in isometric muscle.

111 In both fibers, tau(2) ("endothermic force regeneration") became faster with an i

112 cteristics of the force increase on heating (endothermic force) in muscle.

113 nd the basic effects of increased [MgADP] on endothermic force, can be qualitatively simulated using

114 e that the two irreversible high-temperature endothermic HDL transitions involve particle enlargement

115 d that binding of WT apoA-I to SEM generates endothermic heat (DeltaH approximately 30 kcal/mol) in c

116 plex is more stable and unfolds with a lower endothermic heat and lower release of counterion and wat

117 loss around 220 degrees C associated with an endothermic heat effect accompanied by amorphization; an

118 hermal titration calorimetry demonstrates an endothermic heat for the binding of heparin to CLDCs at

119 ately 18 degrees C, and unfolds with a lower endothermic heat of 8.3 kcal/mol.

120 showing that crossbridge force generation is endothermic (heat absorbed) and associated with increase

121 Ca(2+) with G-triplexes is characterized by endothermic heats.

122 t is argued that a commitment to life in the endothermic hepatic portal system favored a filiform bod

123 sed in the sequence: ectothermic herbivore > endothermic herbivore > ectothermic carnivore > endother

124 t, growth, fecundity, and development within endothermic hosts and may thus potentially influence tra

125 The DeltaH of binding comprises both an endothermic hydrophobic interaction and exothermic hydro

126 nge in the reaction energetics from strongly endothermic in betaTP to approximately equienergetic in

127 The reaction is highly endothermic in the gas phase and requires significant ex

128 Both proton-transfer events are found to be endothermic in the oxyferrous state, suggesting that the

129 Thermoregulation of the thorax allows endothermic insects to achieve power outputs during flig

130 Flying endothermic insects, including the honeybee Apis mellife

131 es, and this mechanism may occur commonly in endothermic insects.

132 t two-site binding mechanism at pH 7.0 to an endothermic interacting two-site mechanism at pH 5.2, si

133 t two-site binding mechanism at pH 7.0 to an endothermic, interacting two-site binding mechanism at p

134 In contrast, ITC measurements showed endothermic interactions of Cu, Ni, and Rh oxide/hydroxi

135 e of the meso-substituent is able to turn an endothermic interconversion process with a high energy b

136 The titration with Na(+) resulted in endothermic isotherms with (dm(5)C-dG)(4) being more end

137 gh Cu(+), the primary product corresponds to endothermic loss of the intact adenine molecule, whereas

138 In all cases, endothermic loss of the intact aromatic amino acid is th

139 ted with the oxygen demands of flying, their endothermic metabolism and unusual pulmonary architectur

140 e ability of birds to fly and to maintain an endothermic metabolism.

141 d temperature; the findings indicate that an endothermic molecular step underlies muscle force genera

142 forms ranging from single atom (N) to highly endothermic molecules (N2, N3, N4, N5, N6) and chains (N

143 units, with the ultimate goal of performing endothermic, multielectron transformations that are coup

144 hat nonavian dinosaur metabolism was neither endothermic nor ectothermic but an intermediate physiolo

145 at of reaction of the hydrogenation with the endothermic one of the CO2 release from the capturing re

146 By this means, the endothermic oxidation-reduction reaction is pulled such

147 Cd(II) exhibited a characteristic exothermic-endothermic pattern that was used to infer the metal bin

148 The endothermic peak at 46.7 degrees C is attributed to a la

149 ons in the differential scanning calorimetry endothermic peak enthalpies and loss of birefringence in

150 The absence of an endothermic peak for both MPs confirmed all extract solu

151 ted starch was broadened with a shift of the endothermic peak to higher temperature.

152 tion was observed in the region of the first endothermic peak where the two thermolabile domains melt

153 e inclusion complexes showed the presence of endothermic peaks between 80 degrees C and 150 degrees C

154 New endothermic peaks in the calorimetric thermograms of tre

155 d the exothermic phase without affecting the endothermic phase, but it was regained upon addition of

156 ut 6.7 kcal/mol enthalpic advantage over the endothermic phase.

157 Both exothermic and endothermic phases produce highly negative DeltaC(p) deg

158 inding data conformed to both exothermic and endothermic phases with magnitudes of DeltaG degrees , D

159 rd characteristics such as feathers, flight, endothermic physiology, unique strategies for reproducti

160 shown to be the driving interaction for the endothermic physisorption process of organic vapor parti

161 s were generally higher for ectothermic than endothermic predators, although dietary patterns were si

162 The bent DNA 34-bp mode is most endothermic, presumably because of the cost of HU-induce

163 from state A to state B) was found to be an endothermic process (positive DeltaHswitching) for both

164 e dry reforming of methane (DRM) is a highly endothermic process conducted under harsh conditions; he

165 ors is a sequential two-step, entropy-driven endothermic process.

166 Adsorption reactions are favorable endothermic processes as evidenced by increased adsorpti

167 ct kinetic and thermodynamic (exothermic and endothermic) properties.

168 action, F(-) with dimethyl sulfoxide, and an endothermic proton-transfer reaction with a competing ex

169 Dynamics of an endothermic proton-transfer reaction, F(-) with dimethyl

170 DRM is also a highly endothermic reaction and requires operating temperatures

171 The competitive endothermic reaction Cl(-) + CH(3)Br --> CH(3) + ClBr(-)

172 Modeling of the endothermic reaction cross sections yields the 0 K bond

173 force generation step is an entropy driven, endothermic reaction that accompanies a burial of large

174 f 16.4 microM at 25 degrees C, pH 6.0, in an endothermic reaction that is driven by a large entropy c

175 Similarly, Pi binding is also an endothermic reaction with Kb = 167 +/- 17 M(-1), deltaHb

176 he energy barrier as much as possible for an endothermic reaction without yielding a significant conc

177 and free energy of inactivation indicated an endothermic reaction, not spontaneous degradation, where

178 mally hidden in DSC analysis by simultaneous endothermic reactions of soil minerals.

179 No endothermic reactions were observed.

180 he air-exposed reaction proceeds via slight, endothermic rearrangements of crystalline intermediates

181 iency by using excess fuel-cell heat for the endothermic reforming reaction.

182 of electron transfer is displaced toward the endothermic region by 0.5-0.8 eV.

183 The endothermic reverse reaction required as little as 18 mi

184 s the photoluminescent state of CdSe through endothermic reverse triplet-triplet energy transfer.

185 The endothermic S(N)2 reaction Cl(-) + CH(3)F --> CH(3)Cl +

186 at it plays a critical role in the efficient endothermic singlet fission process.

187 sion, whereas crystalline tetracene displays endothermic singlet fission with near-unity quantum yiel

188 The results showed an endothermic, spontaneous and an entropy-driven dissoluti

189 Gibbs energy and dissolution entropy showed endothermic, spontaneous and entropy-driven dissolution

190 olutionary transitions leading to the modern endothermic state of birds and mammals is incomplete, pa

191 SecA-membrane interaction is regulated by an endothermic step that is azide inhibitable.

192 largely driven by the preceding two strongly endothermic steps of ATP hydrolysis and attachment of M.

193 substrate reveal a binding reaction that is endothermic, suggesting that cobB recognition of substra

194 ergy of electron transfer (DeltaGET) becomes endothermic, syn-anti isomerization is the dominant path

195 eral phenomenon in non-avian ectothermic and endothermic tetrapods.

196 mic isotherms with (dm(5)C-dG)(4) being more endothermic than (dC-dG)(4) by 700 cal/mol basepair.

197 action, is computed to be only slightly more endothermic than the comparable cyclization reaction of

198 0.3 kcal.mol(-1), a value significantly less endothermic than those values suggested from gas-phase m

199 es C, the first DSC heating scan exhibits an endothermic transition at 46.7 degrees C, a small hump n

200 On heating, anhydrous C16:0-SM exhibits an endothermic transition at 75 degrees C (delta H = 4.0 kc

201 71.5 degrees C, followed by a chain-melting endothermic transition at 78 degrees C.

202 exhibited a scan-rate-dependent irreversible endothermic transition at all stages of solubilization.

203 ding site by scanning calorimetry showing an endothermic transition beginning around 725 degrees C ac

204 t 1 deg.C/minute it exhibits an irreversible endothermic transition between 35 and 42 degrees C depen

205 s melt and dissociate reversibly in a second endothermic transition between 60 and 90 degrees C also

206 the low-affinity site strongly inhibits the endothermic transition but does not reduce the rate of A

207 ic binding site on SecA does not perturb the endothermic transition but produces a 10-fold accelerati

208 Data are discussed which indicate that the endothermic transition in the complex is consistent with

209 nd bithiazole-thiophene oligomers display an endothermic transition in their DSC trace below their re

210 The endothermic transition of alkali-treated starch was broa

211 By DSC hydrated GM1 undergoes a broad endothermic transition TM = 26 degrees C (delta H = 1.7

212 that polymorph alpha irreversibly undergoes endothermic transition to polymorph beta much before its

213 ed C16:0-LacCer undergoes a complex two-peak endothermic transition with maxima at 69 degrees C and 7

214 y (DSC), anhydrous C16:0-GalSulf exhibits an endothermic transition, T(M) = 93 degrees C (DeltaH = 5.

215 m their consistent effects in inhibiting the endothermic transition.

216 gelation (dynamic rheology); and (3) protein endothermic transitions (differential scanning calorimet

217 Protein endothermic transitions (thermal denaturation), rheologi

218 slower heating rate (1.5 degrees C/min), two endothermic transitions are observed at 66 degrees C and

219 y heating curve of the emulsion showed three endothermic transitions at 24.3 degrees C, 33.0 degrees

220 bsequent heating run shows three overlapping endothermic transitions at 66 degrees C, 69 degrees C, a

221 C investigations reveal the presence of four endothermic transitions between 50 and 300 degrees C.

222 reversible melting processes and undergo two endothermic transitions each, at 189/237 and 59/80 degre

223 Endothermic transitions showed similar trends to rheolog

224 Multiple endothermic unfolding transitions were observed by diffe

225 stinct ITC profiles (i.e., exothermic versus endothermic) upon interaction with actinonin.

226 results suggest that the modern dichotomy of endothermic versus ectothermic is overly simplistic.

227 d plants) is separated from the highest (for endothermic vertebrates) by a factor of about 20.

228 habitats impose severe metabolic demands on endothermic vertebrates, and understanding how high-alti

229 ence thermal stress at each feeding event on endothermic vertebrates.

230 calculations show C-CN bond activation to be endothermic, which contradicts the observation of therma

231 he attachment process was nonspontaneous and endothermic, which may be associated with structural cha

232 We found that the Mg2+ binding reaction is endothermic with a binding constant (Kb) = 142 +/- 4 M(-

233 fully cNMP-ligated CRP-mutant complexes were endothermic with binding constants as high as 6.6 +/- 1.

234 .0 pM, the reaction releases 3.8 protons, is endothermic with DeltaHrxn of +6.4 kcal mol-1, and entro

235 Complex formation was endothermic with less than 1 kcal absorbed per mole of l

236 nthalpy of the binding reaction changes from endothermic with the wild-type hSBDb to exothermic with

237 eleased upon Zn(II) binding, the reaction is endothermic, with DeltaHrxn of +7.7 kcal mol-1, and entr